H A&S 220c Energy and Environment: Life Under the Pale Sun More review problems on the science core. (Refer to your class notes or the lectures posted on the web.) (Next Tuesday’s quiz will have an essay question relating to the Arctic, like the examples on the earlier review problem handout, and some short questions from the science core and the Greenland/Arctic readings, such as those below). You will be given some choice of problems to solve, from a larger number. The problems marked with an asterisk (*) are not ‘short’, and not quiz problems. But they may help if you work on them. The rest are potential quiz problems. • Mechanical energy. If a ball is dropped from a height of 100m, what will its velocity of fall be at the ground, assuming its total mechanical energy is conserved? After bouncing it will not go as high as 100m; what happens to the mechanical energy that seems to be lost? • Describe why the thermal energy of air is much greater than its mechanical energy in a wind-storm, with winds of 10 meter/sec. • We pay for electricity by the kilowatt-hour (kwh). How many Joules are equivalent to 1 kwh? (It is helpful to write the units and cancel them to get the answer…for example if we are given a speed of 10 miles per second and want miles per hour, XX mile/hour = 10 mile/sec x 60 seconds/minute x 60 minutes/hour = 36000 mile/hour.) • One practical result of the discussion of chemical bonding is the ‘richness’ or ‘intensity’ of chemical energy. Many fuels and foods have energy content in the range 10 to 50 million Joules per kg. (MJ/kg). This energy content is determined usually by burning the fuel and measuring the heat produced. How does the kinetic energy of a metric ton of water (1000 kg) moving at 1 meter per second (m sec-1) compare with the chemical or ‘food’ energy in a candy bar ( say 0.1 kg)? • *Suppose someone suggests heating your home by storing the summer’s heat in swimming pool full of water, and then circulating the warm water through radiators in winter. How big a swimming pool would you need? • CO2 pollution of the atmosphere comes from burning of fossil fuels. Describe the differing amounts of CO2 that result from gasoline (octane) and methane (natural gas), by comparing the ratio of carbon to hydrogen atoms in each substance. Generally, what is the approximate ratio of C to H atoms in long hydrocarbon molecules? (Further work: compare also with coal and wood combustion.) • Why does ice float, in terms of its molecular structure, whereas most substances are more dense in the solid phase than the liquid phase? • What force is the origin of chemical bonds, which hold atoms together to form molecules? What are the main factors that decide whether a bond is strong or weak? • If you pass an electric current through a beaker of water, bubbles of gas appear. What chemical bonds are being broken to make this happen, and how what is the makeup of that gas? • Jupiter is 484 million miles..779 million km.. from the sun or 5.2 times the Earth’s distance from the sun. What is the ratio of the energy flow (power) of solar radiation arriving at Jupiter, compared with the Earth? • What is the Arctic Circle? • Solar energy reaching the Earth varies in intensity (power) due to several astronomical effects (the simplest being the rotation of the Earth). Describe some other of these effects. • *[Done in class] We would like to find a quick way to estimate the efficiency of an automobile engine. [The efficiency of a heat engine like the Stirling engine is defined as the ratio of useful work it does to the rate of heat flow that drives it. Since total energy is conserved, the incoming heat is divided into work plus outgoing (‘exhaust’) heat flow. We are told that automobiles are something like 20% efficient in converting the heat of burning gasoline into kinetic energy of the car] You could measure this by the following simple test: drive on a level road at 50 mph (22 meters/sec); take your foot off the throttle and coast to a stop. The ratio of the kinetic energy of the car at speed, to the time it takes to slow to a stop, is a power, that is energy divided by time. When the car is moving steadily, the engine power goes into fighting the air drag and the friction forces within the car’s drive train. When you take your foot off, those forces are unopposed and bring the car to a stop. So, measuring the time it takes to stop gives us an estimate of those forces. Suppose you do this. The car weighs 2000 kg, and it takes 30 sec to slow to 25 mph, ½ its initial speed. What is the force implied by this deceleration? What is the change in energy divided by the change in time? If this force is close to the force required to keep the car going at 50 mph, this gives an estimate of the power in watts (and hence estimate as the power required to drive steadily at 50 mph. What would this be in horsepower (1 h.p. = 747 watts)? If we get 20 miles per gallon, what is the efficiency of the car? •* Steady-state box models. Tetrachloroethylene is an organic solvent used in dry cleaning. It gets into ground water which people drink. Government standards suggest that anything greater than about 1 part per million is dangerous. Suppose a dry cleaning company dumps 100 kg per year into the ground. A ground water stream is flowing by at a speed V of 10 meters per day, and it has a cross-sectional area A of 100 square meters. What will the concentration of the pollutant be on average? [assume the solvent is uniformly mixed across the underground stream and flows with it…is this likely a good assumption?] . Note that the rate of flow of water is ρVA kg/sec where ρ = 103 kg m-3 is the density of water. [A useful number here is the number of seconds in a year which is π x 107, to within one percent]. • *If the Greenland ice cap melted, how much would sea level rise around the world, on average (Greenland is about 2000 km x 500 km in area and the ice cap is 3 km high at its peak) How much heat would it take to melt this much ice (in Joules)? If the melting occurred over 1000 years, how much heat flow would this represent (in Watts)? Compare this number with the average heat flow in the ocean-atmosphere system which is 5 x 1015 watts … 5 petawatts. • Why does a mist of very fine droplets (at room temperature) feel cool when it lands on your forehead? • Describe the shape of the water molecule, and some the effects of that shape on the properties of water. • * From the website: The point here is to begin to work with the large numbers of energy consumption round the world. Election day: what does it mean to energy and environment? There are strong opinions from all sides. And abrupt change is everywhere ($50-55 per barrel of oil today, as little as $12 per barrel in 1998, $28 per barrel one year ago) Energy independence? The USA uses about 1/4 of the world's energy resources. Oil is the largest part of our energy profile, currently 20 million barrels per day, half of that imported. In studying the Arctic environment this pall of global fuel consumption hangs over us: we will see how ocean and atmosphere react to human energetics during the remainder of the term. The Arctic is melting, ecosystems shifting, but its behavior is not simple. With US oil production declining, how do we manage the near future? In the end we will see that climate change and the dynamics of human activity are tightly linked. Our response to the problem will have implications to every aspect of life, and especially to our relations with the rest of the world. [let's do the numbers: one barrel of oil is 42 gallons, that is 159 liters. It has 6 x 10^9 Joules (6 billion J) of chemical energy. Dividing by 42, one gallon of oil has 1.4 x 10^8 Joules...like 140 candy bars. The more common unit is Joules per kg.of fuel, which for crude oil is about 4.5 x 10^7 Joules/kg; quite similar to many other fuels, except hydrogen which is the clear winner (see figure below). Gauge this against your daily activity: 20 million barrels per day divided by 295M US citizens is .067 barrels per person each day, or 2.8 gallons of oil per person per day. And..only 19.5 gallons of gasoline can be refined from the 42 gallons of oil in a barrel. How do you imagine the energy use per person compares with other countries, and with Greenland? ]