AP Chemistry Syllabus Nathan Peck Room 207 Homework: 10% of quarter grades. All homework that is graded will be turned in on time, no late work accepted. Problem sets for some of our units will be due the date of the unit tests. Laboratory: 35% of quarter grades. Lab work is done weekly with a partner. All reports are to be completed individually and turned in the following week. No late lab reports are accepted. All lab reports are to be maintained in a laboratory portfolio that will be checked and graded periodically throughout the year. Complete list follows the schedule at the end of this document. Tests: 55% of quarter grades. Unit tests occur about 6 times per semester. Final Exam: 20% of semester grade. Comprehensive test made to simulate an AP Chemistry exam experience. Textbook: General Chemistry by Petrucci and Harwood, 7th ed., Prentice Hall, 1997. ISBN: 0-13-533498-5 Schedule Monday, August 21 A Tuesday, August 22 B Wednesday, August 23 A Thursday, August 24 B Friday, August 25 In Class Prefixes Unit Conversion SigFigs Clerical Work Isotopes and Masses Homework - Review Chapter 1 - Probs 68 and 70 (p. 29) - Read Article - Read 2-3 to 2-5 - Problems 16, 26 (p.60) Article Discussion Q-Day Lab Set-Up Moles Hmwk Review - Read Occurrence of Elements (pp. 58-9) - Read 3-1 to 3-4 Preparation of zinc iodide THP - Lab A In Class Homework Monday, August 28 B Tuesday, August 29 Element Occurrences Combustion Analysis - Read 3-5 and skim the rest of Chapter 3 - Probs 50, 61, and 62 - Probs 54 & 55 on p. 93 A Wednesday, August 30 Two Component Mixtures Quiz Chemical Reactions B Thursday, August 31 Limiting Reactant Lab - Read 4-4 and 4-5, and skim the rest of chapter 4 -Finish Lab Report - Probs 74 & 79 on p. 94 Redox reactions Ion Quiz - Probs 13, 21, and 71 on pages 122-125 A Friday, September 1 B Monday, September 4 Tuesday, September 5 A Wednesday, September 6 B Thursday, September 7 A Friday, September 8 In Class Zero Homework Go Cards! Basic Solutions Redox Rxns Redox Stoich. - Read 5.1 to 5.4 -Probs 14 &35 p. 157 -Probs 53 and 65 on pp. 158-9 Read 5.5, skim 5.6 Prob 51a,b on p. 158 Questions/Review - Stoichiometry Summarized - Intro Reaction Rates - Measuring rates - Rate Laws -Finish lab report on Limiting Reactant Lab Monday, September 11 - Zero Order Rates - First Order Rates - Second Order Rates In Class Stoich Test A Tuesday, September 12 Go over test Intro Rates Prob 5 & 26 p.535 and 537 Rate Laws Rate Equations Half-life Read 15-8 Probs 33 and 34 on p. 538 B B Wednesday, September 13 A Read 15.1 thru 15.7 -Study for Test Monday Homework Read 15.1 thru 15.7 Thursday, September 14 B Friday, September 15 Kinetic Theory Ea Catalysis THP Separation of Mixtures – Prob 41 on p. 539 Carbonate Lab A Monday, September 18 B Tuesday, September 19 A Wednesday, September 20 B Thursday, September 21 A Friday, September 22 B Monday, September 25 A Tuesday, September 26 B Wednesday, September 27 A Thursday, September 28 B Friday, September 29 In Class Half-Life Homework Read 15-9 to 15-11 Crystal Violet Lab Prob 69 on page 541 Probs 18 - 24 pp. 536 and 537 Ea Catalysis Reaction Mechanisms Junior Chnallenge THP Start Carbonate report Finish Carbonate Report Intro Equilibrium K & ICE K manipulations In Class Bromate Rate Lab -Finish lab report on Crystal Violet – Due Monday Homework Probs 34, 69, 77 & 82 on pp. 538 - 542 Rate review-O3 Lab Data Intro Equilibrium Read 16-1 and 16-2 Prob 25 on p.574 THP K ICE K manipulations Work in Excel K vs T Read 16.3 thru 16-5 Prob 31 on p. 575 Equilibrium Spec Lab FeSCN+2 Finish report on Bromate Rate Lab In Class Homework Read 17-1 and 17-2 A Monday, October 2 Review of rates Q and K Finish Bromate Rate Lab Report Read 17-1 to 17-5 A Wednesday, October 4 ICE K manipulations LeChatelier K vs T B Thursday, October 5 Test on Rates and K Read 17-7 Probs 25, 32, 37, and 39 on pp. 615-616 - Finish FeSCN lab - Probs 41 and 44 on p. 616 Homework Probs 41 and 44 on p. 616 B Tuesday, October 3 A Friday, October 6 - strong vs weak acids – p(stuff) B Monday, October 9 In Class Acid Base Equilibrium Hydrolysis Study for Test A Tuesday, October 10 Buffers Prob 55 and 65 on p. 617 B Wednesday, October 11 A/B Lab - Titration Read 18-1 Prob 23 on p. 648 Acid and Base Problem Set Review Chapter 17 Read 18-2 Prob 24 on p. 648 Finish Titration Lab & Questions - Prob 35 on p. 649 Homework Finish the A/B Prob Set – Discussed Tuesday in class and due Thursday Finish Titration Lab Questions – due Thursday A Thursday, October 12 B Friday, October 13 Titration Curve A Monday, October 16 In Class Acid Base Problems Review B Tuesday, October 17 Prob Sets and Lab A Wednesday, October 18 Buffer Lab Study like you have a big test tomorrow B Thursday, October 19 A/B Test Read 19-1 and 19-2 Write up Buffer Lab A Friday, October 20 No School B Tuesday, October 24 In Class - Go Over A/B tests - Intro to solution K’s - Calculating Solubility - Buffer Lab A Wednesday, October 25 - B Thursday, October 26 - Monday, October 23 A Friday, October 27 Weekend Separations based on solubility Common Ion Effects Calculating Ksp Lab Complex Ions Sulfide separations Homework Read 19-1 – 19-6 Prob 18, 35, 41 on pp. 6823 Read 19-7 to 19-9 Read 19-10 THP Finish Buffer Lab Report Probs 40, 43, 50, 59 on pp. 683-4 B In Class Complex Ions Sulfide separations Homework Prob 30, 55 and 63 on pp. 683-5 Work on Prob Set B Wednesday, November 1 Work Homework ProbsProb Set Intro QA Qual Analysis #1 Lab A Thursday, November 2 Review and Quiz? B Friday, November 3 Ksp/A/B Test Study Everything Finish Prob Set Ksp Lab due Friday Read 7.1 and 7.2 Monday, October 30 A Tuesday, October 31 Finish Ksp Report A Monday, November 6 B Tuesday, November 7 A In Class Intro thermo Endo/Exo How to measure energy? Q=mc(dT) Hess’ Law Heats of formation Homework Read 7.3 – 7.4 Probs 6 – 8 on p. 233 Wednesday, November 8 Thermite Read 7.5 –7.7 Prob 14 on p. 233 B Thursday, November 9 Qual. Lab #2 THP Fuels Entropy Read 7.7 and 7.8 Probs 22 - 24 on p. 234 In Class Entropy Gibbs Homework Read 20-1 to 20-3 G and K What about T Read 20-4 THP B Wednesday, November 15 Thermo Lab Read 20-5 & 20-6 Prob 34 on p. 718 A Thursday, November 16 Prob Set Read 20-7 & 20-8 B Friday, November 17 Qual Lab #3 THP Monday, November 20 In Class Review Prob Set Homework Study Hard B Tuesday, November 21 Thermo Test Start Flow Chart for QA and finish the Thermo Lab Report Eat a lot!! Complete Flow Chart for QA A Friday, November 10 B Monday, November 13 A Tuesday, November 14 A A Wednesday, November 22 Go over test QA Prep time B Monday, November 27 to Friday, December 1 In Class Qualitative Analysis AAAAA In Class Homework Work on the report that is due before class on Monday, December 4th. Read 21-1 thru 21-4 during the week Homework Monday, December 4 B Tuesday, December 5 A Wednesday, December 6 B Thursday, December 7 A Friday, December 8 B Monday, December 11 A Tuesday, December 12 B Wednesday, December 13 A Thursday, December 14 B Friday, December 15 A Thursday, January 4 A Friday, January 5 Review the QA Thermo Review Redox Review Intro Electrochem -Cells -SEP Reduction Potentials Spontaneity, G and E E vs E-zero E vs K E vs [x] Corrosion Read Santa Review Read 21-1 to 21-4 Electro Lab THP Faraday’s Laws Electrolysis Electro Test Study and Sleep Lots Exam Review Sleep Lots and Study Some Study for Hours Probs 6 & 7 on p. 757 Prob 11 & 13 on p. 757 Read 21-6 Prob 30, 35 on p.758/9 Read 21-7 Prob 41a & 42a I'd study real hard. Free Response Exam Quantitative and Equations Exam In Class Homework Exam Results Read Packet EMR PhotoElectric Effect Quantum Mechanics Read 9.1 – 9.3 and 9.5 – 9.8 Prob 42 on p. 309 In Class Redox Titration Lab Homework Read 9.10 – 9.11 Prob 21 on p. 307 - Quantum Numbers - Electron configurations Skim 10-1 to 10-5 Read 10-6 and 10-7 Prob 23 on p. 307 Prob 54 p. 309 Probs 64 & 68 on p. 310 B Monday, January 8 A Tuesday, January 9 B Wednesday, January 10 A Electron Configs Anomalies Thursday, January 11 B Friday, January 12 Periodic Table Periodic Properties Probs 26 and 27 on p. 342 Magnetism In Class MLK Day Read 10.8 Probs 51 & 52 on p. 343 (Test on Tues. 1/17) Homework None Go over tests Intro Bonding Read 11-4 thru 11-6 Prob 36 on p. 382 Intro bonding Lewis Structures Formal Charges Resonance Read 11-7 Prob 50, p. 383 Finish Lab Report Geometry and Polarity and bond Length Read 11-7 Prob 50, p. 383 Finish Lab Report Review 11-8 Read 12-1 to 12-3 Prob 82 on p. 384 Homework Read 11.1 to 11.3 A Monday, January 15 B Tuesday, January 16 A Wednesday, January 17 B Thursday, January 18 A Friday, January 19 B Monday, January 22 B Tuesday, January 23 A Wednesday, January 24 B Thursday, January 25 A Friday, January 26 B Monday, January 29 A Hybridization Sigma and Pi Review Bond Energies In Class Ionic Bonding Coulomb’s Law Intro bonding Lewis Structures Formal Charges Resonance Geometry and Polarity and bond Length Read 11-4 thru 11-7 Prob 36 on p. 382 Hybridization Sigma and Pi Review Bond Energies Pi bonds and resonance Laserdisco Bonding in Metals In Class Pi bonds and resonance Bonding in Metals Read 11-7 Prob 50, p. 383 Turn in Lab Report Review 11-8 Read 12-1 to 12-3 Prob 82 on p. 384 Homework Read 12-4 Work on the packet Prob 50, p. 383 Finish Lab Report Tuesday, January 30 B Wednesday, January 31 Intro Organic chem. OC Projects/Presents Read 27-1 through 27-4 VDW Forces Solids Read 27-5 though 27-9 Finish Orgo Presentation (on ppt) Review other orgo ppts or finish yours A Thursday, February 1 Organic Presentations B Friday, February 2 Finish Orgo presents A Monday, February 5 B Tuesday, February 6 A Wednesday, February 7 B/A Thursday, February 8 A Friday, February 9 B Monday, February 12 A Tuesday, February 13 B Wednesday, February 14 A Thursday, February 15 B In Class Finish Orgo Presents VDW Forces Review for test Liquids and evp Bonding and Orgo Test Go over tests EVP Water Lab - Study for Bonding/Orgo Test (Tues) - Finish Bonding Packet (due Tues) - Review other orgo ppts handouts Homework Read 13-1 and 13-2 Prob 4, 55, & 56 on page 458 and 462 Study for Test Read 13-7 and skim 13-8 and 13-9 THP Prob 81 on page 464 Probs 7-10 on p. 458 Relative Humidity Properties of Solids Phase diagrams In Class EVP RH Read 13-4 Prob C on page 465 Phase Diagrams Read 13-5 and 13-6 Probs 2 & 4 pp. 457-8 IHP Properties of Solids Read 13-4 Prob C on page 465 Properties of Solids Sulfur Chem Prob 81 on page 464 Homework THP Friday, February 16 Condensed Lab Prob E on page 465 In Class Prez Day Homework Read a newspaper, at least one story per section Compare Solids Intro Solutions M, m, X, % Henry’s Law Evp of solutions Raoult’s Law Read 14-1 to 14-5 Probs 25 and 26 on page 497 Heats of Solution Lab Read 14-6, skim 14-7 RQ 14 and 17, p. 497 Colligative Properties Osmotic Pressure Read 14-8 and 14-9 THP Monday, February 26 In Class Solution Problem Set Homework Work on finishing the Problem Set A Tuesday, February 27 Practice ACS Test Work on finishing the Problem Set Due tomorrow Review ACS Packets A Monday, February 19 Tuesday, February 20 A Wednesday, February 21 B Thursday, February 22 A Friday, February 23 Finish Lab Report on evp of water B B Wednesday, February 28 Ideal Solutions Non Ideal Solutions A Thursday, March 1 Go over Prob Sets Finish Lab Report on MW of Sulfur B Friday, March 2 ACS Review Take ACS Test tonight or tomorrow Monday, March 5 In Class Laserdisco Homework Review Solids and Liquids B Tuesday, March 6 Go over Problem Sets Study for Test on Condensed States A A Wednesday, March 7 Condensed Test Read 6-1 to 6-3 Go over tests Intro Gas Chem MM & D Gas Lab Probs 41, 42, and 48 on p. 197 In Class MM & D KMT Homework Read 6-6 and 6-7 Avogadro’s Law Dalton Prob 65 on page 198 Molecular Speed Effusion Real Gases Colligative Property Review Exercise Read 6-8 and 6-9 Prob 77 on p. 199 Grading Day End of Qtr In Class MM & D KMT Homework Read 6-6 and 6-7 Finish MW of sulfur lab Prob 65 on page 198 Wednesday, March 28 Avogadro’s Law Dalton Molecular Speed Effusion Gases and Equilibrium A Thursday, March 29 Real Gases Finish Butane Lab Report B Friday, March 30 Seawater Lab Part #1 Read 26-1 to 26-4 In Class Homework B Thursday, March 8 A Friday, March 9 Read 6-4 and 6-5 Prob 45 and 46 on p. 197 B Monday, March 12 A Tuesday, March 13 B Wednesday, March 14 A Thursday, March 15 B Friday, March 16 Monday, March 26 A Tuesday, March 27 B Read Chapters 30 and 31 over break Read 6-8 and 6-9 Prob 77 on p. 199 A Monday, April 2 B Tuesday, April 3 Complex Ions A EDTA Lab: Complexometric Titrations Part 1 Wednesday, April 4 Intro Nuclear Chemistry B Thursday, April 5 Finish EDTA Lab A Friday, April 6 Ionizing Radiation Read over Lab Procedures and backgrounds Finish Lab report for seawater B In Class Induced Radioactivity Rates of Decay Binding Energy Fission/Fusion Nuclear Power Homework ACS Awards Night Nuke Applications Review Study for test B Thursday, April 12 Nuclear Shielding Lab Start Nuke Lab Reports A Friday, April 13 Transition Metals Read 24-1 through 24-4 In Class Rare Earth Elements and Inner transitions Homework Read 24-5 through 24-7 THP Nuclear half-life lab – Ba137 Read 25-1 to 25-5 Isomerism Read 25-6 to 25-8 THP Monday, April 9 B Tuesday, April 10 A Wednesday, April 11 THP B Monday, April 16 B Tuesday, April 17 A Wednesday, April 18 B Thursday, April 19 A Friday, April 20 Seawater Lab Part 2 Finish Nuke Lab reports Complex Ions and Coordination Chemistry THP In Class Chemistry of the Living State Homework Read 28-1 to 28-2 B Monday, April 23 B Tuesday, April 24 Chemistry of Vitamin C Lab Read 28-4 A Wednesday, April 25 Lipids Read 28-5 B Thursday, April 26 Proteins Read 28-6 A Friday, April 27 Nucleic Acids THP Monday, April 30 to May 4th In Class Review Old AP Test Problems Homework Review Packets Due Friday Monday, May 7 to May 11 In Class Review Old AP Test Problems Homework Review Packets Due Friday B Summary of Laboratory exercises: AP Chemistry Labs: 2006-2007 1. The Reaction of Iodine with Zinc 2. Limiting Reactant 3. Beer’s Law 4. Separation of Carbonates 5. Rate Law Determination of Crystal Violet 6. Study of the Kinetics of a Reaction 7. Determination of the Equilibrium Constant for the Formation of FeSCN+2 8. Acid/Base Titration 9. Standardization of a Base; Equivalent Weight of an Acid 10. Concentration and pH of the Phosphate Buffer System 11. Determination of the Solubility Product of an Ionic Compound 12. Thermochemistry and Enthalpy of Reaction 13. Qualitative Analysis a. Identification of Silver, Lead, and Mercurous Ions b. Identification of Ferric, Aluminum, and Zinc Ions c. Identification of Alkaline Earth and Alkali Metal Ions 14. Analysis of Commercial Bleach 15. Organic Presentations 16. Vapor Pressure and Enthalpy of Vaporization of Water 17. Heats of Solution, KOH and KNO3 18. Using Freezing Point Depression to Find Molecular Weight of Sulfur 19. Determining a Value for R 20. Molecular Weight of Butane 21. Pacific Ocean Water Analysis 22. Radioactivity and Effects of Shielding 23. Half-Life of Barium – 137 24. The Chemistry of Vitamin C 25. Complexometric Titrations - EDTA