Equilibrium Thermodynamics ChE 3063 Instructor: Office: Text: Fall 2014 G. L. Price U301 Keplinger Hall Smith, Van Ness, and Abbott, Introduction to Chemical Engineering Thermodynamics, 7th Ed., McGraw-Hill The course website is: http://www.personal.utulsa.edu/~geoffrey-price/Courses/ChE3063/Fall2014/ChE3063F14.html You can find ALL homework, projects, resources, and a calendar at that site. Chemical Engineering Department Educational Objectives: Our educational objectives are to prepare graduates such that, within a few years of graduation, they have established chemical engineering careers in the petroleum, natural gas, chemicals, alternative energy, environmental, materials, or biotechnology industries, and/or have begun graduate studies in chemical engineering or related fields such as medicine, law, and business administration. Course Objectives: By the end of this course the student will be able to: 1. 2. 3. 4. 5. Determine the properties of pure substances using charts and equations, including departures from ideal gas. Determine the properties of ideal and non-ideal mixtures using both charts and equations. Test experimental data for thermodynamic consistency. Determine phase equilibrium and phase changes of mixtures, include bubble points, dew points, flashes, and liquid-vapor phase diagrams using modern computing tools where appropriate. Determine equilibrium concentrations for single and multiphase reactive systems. Course Schedule: A tentative course schedule is attached. Some changes may be made as the class proceeds. Grading Policy: 50 minute exams, average of 3 Final Project(s) Homework (average of all) A B C D F - 55% 30% 7.5% 7.5% 90 - 100 80 - 89 70 - 79 60 - 69 below 60 All exams including the final will be open book unless otherwise specified. The instructor designs exams and gives partial credit in grading exams based upon the scale given above, so no curves are applied beyond partial credit. No exam grades will be dropped. In deciding the final grades for the class, the instructor occasionally gives slightly better grades than indicated above when there is good reason. Homework is designed to represent the minimum concepts required to pass the class. Students are encouraged to work more problems. Other Policies: 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. Attendance: Class attendance is required. The experience of the instructor has been that students that don't attend class do poorly, so it is to your benefit to be here. No late homework is accepted. Please do everything possible to notify the instructor prior to the exam if you must miss an exam. General instructor contact hours are 8:00 - 11:30 a.m. every weekday unless otherwise announced. Please be aware that chairman’s duties may take me away from the office, but I will do my best to be available during those times. Other times are available by appointment. Though students are encouraged to work together on homework, copying of homework is strictly prohibited. There is a difference between similar solutions that might be expected after students study together and copied solutions. You may bring any type of calculator to an exam, but laptops and electronic notebooks (iPad, Kindle, etc.) are prohibited from exams. Also prohibited are any WIFI or cellular capable devices. Please leave cell phones at home the day of an exam, but if you bring one, it must be completely off for the entire exam. If any phone rings, buzzes, tweets or make any noise at all during an exam, the phone will be confiscated by Dr. Price or the exam proctor and is subject to search to see if any information pertinent to the exam has been exchanged or attempted to be exchanged with another person. Any phone which is on during an exam is considered an act of academic dishonesty. Academic Dishonesty cases will be handled according to the College of Engineering and Natural Sciences (ENS) Academic Misconduct Policy for undergraduates. The first instance of academic misconduct will result in a zero on the assignment, and a second infraction will result in an F in the course. All infractions will be reported Dean Reeder’s office in ENS where further sanctions may be applied by Dr. Reeder. Grade appeals for the final grade in the course (not individual assignments) must be submitted in writing to the instructor. Students with disabilities should contact the Center for Student Academic Support to self-identify their needs in order to facilitate their rights under the Americans with Disabilities Act. Class Content: We will basically follow this order. Chapter Numbers and titles from Smith, Van Ness and Abbott: 3 4 6 10 11 12 13 14 Volumetric Properties of Pure Fluids Heat Effects Thermodynamic Properties of Fluids Vapor/Liquid Equilibrium: Introduction Solution Thermodynamics: Theory Solution Thermodynamics: Applications Chemical Reaction Equilibria Topics in Phase Equilibrium Design Projects: Design projects constitute more work than homework sets and are later in the semester. See the website for the actual projects. ChE 3063 Equilibrium Thermodynamics Fall 2014 Calendar Chapters referred to below are from the textbook by Smith, Van Ness, and Abbott. Reading assignments should be done by date shown. All homework assignments are due in class the day they show on the calendar unless otherwise specified in class. Monday Wednesday Friday August 25 Lecture: Review material Read Chapter 3 27 Lecture: Chapter 3 Read Chapter 4 29 Lecture: Chapter 4 Read Chapter 6 5 Lecture: Chapter 6 12 Homework 2 due Lecture: Chapter 10 19 Lecture: Chapter 10 Read Chapter 11 26 Homework 3 due Lecture: Chapter 11 September 1 Holiday 3 8 Lecture: Chapter 6 Read Chapter 10 10 15 Lecture: Chapter 10 22 Exam I 29 Lecture: Chapter 11 17 24 Lecture: Chapter 4 Homework 1 due Lecture: Chapter 10 Lecture: Chapter 10 Lecture: Chapter 11 October 1 Homework 3 due Lecture: Chapter 11 3 Lecture: Chapter 11 Read Chapter 12 6 Lecture: Chapter 12 8 Lecture: Chapter 12 10 Homework 4 due Lecture: Chapter 12 13 Lecture: Chapter 12 Read: Chapter 13 15 Homework 4 due Lecture: Chapter 13 17 Lecture: Chapter 13 Project 1 Due 20 Exam II 22 Project 1 Due Lecture: Chapter 13 24 Exam II Homework 5 due Lecture: Chapter 13 29 Homework 5 due Lecture: Chapter 13 31 27 Lecture: Chapter 13 Lecture: Chapter 13 November 3 Lecture: Chapter 13 5 Lecture: Chapter 13 7 Lecture: Chapter 13 Project 2 Due 10 Exam III 12 Lecture: Chapter 13 14 Lecture: Chapter 13 Homework 6 due 17 Lecture: Chapter 13 Read Chapter 14 19 Lecture: Chapter 14 21 Lecture: Chapter 14 24 Thanksgiving Break 26 Thanksgiving Break 28 Thanksgiving Break 5 Lecture: Chapter 14 Project 3 Due December 1 Lecture: Chapter 14 8 last class day 3 Lecture: Chapter 14 Final Exam is Wednesday, December 17th from 9:00 am to 11:25 am in KEP U3 ChE 3063 Homework Set #1 Due: September 3, 2014 Do the following problems in Smith, VanNess and Abbott: 3.30 3.35 3.38 - part a) only