Results of Advanced Cryo-Tanks Research Project CHATT CHATT (Cryogenic Hypersonic Advanced Tank Technologies) Martin Sippel, Alexander Kopp Space Launcher Systems Analysis (SART), DLR, 28359 Bremen, Germany David Mattsson Swerea SICOMP, Piteå, Sweden Aron Lentsch Orbspace, Austria Craig Walton Gas Dynamics Ltd (UK) Presenter: Martin Sippel (project coordinator) Overview of Presentation Objectives of CHATT Organization of CHATT Research activities in CHATT Example of major CHATT results Conclusion Objectives of CHATT In future aviation and particularly in hypersonic systems, new propellants will be used, such as liquid hydrogen, liquid methane and possibly liquid oxygen. In Europe (FRP7) LAPCAT, ATLLAS, and FAST20XX investigate advanced vehicles with these fuels for passenger transport. The question of cryogenic propellant storage inside an airliner – although of critical importance but by far not yet mastered – has not been addressed up to now in sufficient detail. The need for more detailed investigations on liquid hydrogen tanks in future airliners is not only urgent in hypersonic aviation, but is also essential for environmental reasons in subsonic aviation. Thus, a project like CHATT (Cryogenic Hypersonic Advanced Tank Technologies) was strongly needed. System driven approach Cryogenic fuel propulsion is already operational in advanced launcher systems (e.g. in Europe’s Ariane rocket). However, the airliner systems will require more complex technology than rockets: ultra light-weight and reusable propellant tank systems. All advanced cryogenic tank technologies to be investigated within CHATT are driven by system demands of future hypersonic passenger configurations. All cryo-tank technologies should be assessed by the system requirements. Two vehicles already under study in the EU-funded cooperative projects LAPCAT and FAST20XX are investigated. System driven approach The A2 Mach 5 Civil Transport of Reaction Engines Limited This horizontal take-off aircraft design should be capable of flying from Brussels (Belgium) to Sydney (Australia) in 5 hours. Pre-cooled Scimitar engine exploits the thermodynamic properties of liquid hydrogen. The airframe configuration is an efficient structural shape with circular cross section hydrogen tankage and uninterrupted carrythrough wing spars. System driven approach Rocket-propelled SpaceLiner based on two stage RLV has been proposed by DLR and is an interesting alternative to air-breathing hypersonic passenger airliners. Rocket powered RLV-concept is highly attractive because flight durations are two to three times lower than those of even the most advanced airbreathing systems. (Australia – Europe in 90 minutes) orbiter stage passenger rescue capsule LOX-tank orbiter booster stage LOX-tank booster LH2-tank booster LH2-tank orbiter Organization of CHATT CHATT is part of the European Commission’s Seventh Framework Programme (FP7) and run on behalf of the Commission by DLR-SART. Eleven different partners from seven European countries have been participating in CHATT: Short Name Country Participant organization name DLR Germany Deutsches Zentrum für Luft- und Raumfahrt FOI Sweden Totalförsvarets Forskningsinstitut SICOMP Sweden Swerea Sicomp ULB Belgium Université Libre de Bruxelles ORB Austria Orbspace ELTE Hungary Loránd Eötvös University (ELTE) Budapest TUD Netherlands Technical University Delft ECM Germany Engineered Ceramic Materials GmbH CENAERO Belgium Centre de Recherche en Aéronautique ASBL GDL UK Gas-Dynamics Limited ALE Netherlands Advanced Lightweight Engineering Organization of CHATT / 2 Total budget is exceeding 4.2 M€ with an EU contribution of almost 3.3 M€. The project started in January 2012, has been running for 42 months and ended on June 30th 2015. Balanced funding distribution in Europe: Financial Distribution Breakdown 9% Germany 8% 2% 30% 12% 18% 21% Sweden Belgium Netherlands UK Austria Hungary Research activities in CHATT Challenges of CFRP tanks for cryogenics Extremely light-weight structural design of propellant tanks is absolutely essential for any successful hypersonic passenger transport. NASA TM-2006-214346 Challenges of CFRP tanks for cryogenics CFRP composites seem to be the most attractive material. However, one of the challenges in developing cryogenic CFRP tanks is finding solutions for problems caused by differences in thermal expansion coefficients (CTE). Permeation of hydrogen molecules into non-metallic materials is a critical issue and should be avoided. (Infiltration of GH2 into X-33 tank structure was contributor to the test failure.) Metallic liners could help but are creating new challenges: overcome differences in CTE of the liner with respect to the structural shell strong impact on overall weight Innovative solutions are required and their feasibility is to be proven in relevant tests. Challenges of CFRP tanks for cryogenics Research in CHATT will increase the knowledge within Europe, with advancement from a pure material science level to a practical cryogenic CFRP tank demonstrator level. The project should take the first steps towards a common European development of future aerospace reusable lightweight composite cryogenic CFRP tanks. Four different subscale CFRP-tanks are planned to be designed, manufactured (ALE, TU-Delft, Sicomp, DLR-FA), and tested under mechanical and thermal loads. Not only will the advantages and disadvantages of using liner/linerless tank designs be investigated, but also issues related to the realization of more complex geometrical tank shapes. Related technologies for cryogenic tanks Thermal insulation of cryogenic tanks is more demanding than in launcher applications because typical operation times are hours instead of minutes Aerogels are promising, innovative materials NASA TM-2006-214346 Aerogel / Cryogels The aerogel is an open-celled, nanoporous, solid foam that is composed of a continuous 3-D network and the pores of the network are filled up by air. The aerogel exhibits a high porosity of more than 50%. Advantages of aerogels exist for aerospace applications: excellent thermal and acoustic insulation thermal conductivity (in air) is 0.03 – 0.004 W/mK. It almost blocks all the three types of heat transfer (convection, conduction, and radiation). Light solid material with density of 10 – 600 kg/m3 Good resistance to damage from space radiation and outgassing. Related technologies for cryogenic tanks Sloshing behavior and control: sloshing of fluids within tanks can have significant impact on flight control because the vehicle may experience a noticeable shift in its center of gravity anti-sloshing devices and tank design are susceptible to reduce these effects but will come at the cost of increased mass and production effort system aspects will be investigated with reference configurations Propellant feed system: lower densities of fluids require tanks of large sizes and hence long feed lines and cavitation is to be avoided innovative propellant cross-feed between the two SpaceLiner stages will be simulated in steady and transient behavior Related technologies for cryogenic tanks Pressurization using advanced ceramic heat exchangers: C/SiC ceramic matrix composites (CMC) with high silicon content allow achieving air-tight materials with negligible porosity, high heat conductivity and low CTE 2 basic heat exchanger concepts with such thin-walled materials will be designed, manufactured and tested Cabin pressurization and oxygen supply: air-conditioning system based on similar system used in ATLLAS I: bleed air from intake exhaust to be cooled using cryogenic fuel, and then compressed to achieve conditions required for the cabin air supply. power for compressor and other cabin sources to be provided by Rankine cycle, 15 kW prototype turbine to be manufactured and tested Final research results of CHATT Aerogel / Cryogels Two types of porous alumina system were prepared by sol-gel technique; cryogel and aerogel at ELTE Budapest. Nanoporous Aerogel Pore size 10-20 nm, porosity 40-50 %; specific surface area 300-500 m2 g-1 Hierarchical (macro- and meso-)porous Cryogel The preparation technique of aluminum oxide cryogels is a newly developed method. Using this method, the expensive supercritical drying process can be avoided. The cryogels possess higher porosity and total pore volume, while the aerogels have larger specific surface area due to their nanoporous system. Cryogel 250 000x Aerogel 250 000x TEM images Aerogel 100 000x SEM images Cryogel 1000x Aerogel / Cryogels / 2 ELTE developed a new technology to produce an insulating blanket for high temperature application ( 1500 C). The insulating material is a fiber-reinforced composite. The fiber-reinforced composite consists of aluminum oxide cryogel pellets connected by aluminum oxide fibers. The SEM images represent the new composite material and for comparison a Spaceloft insulating blanket (applicable up to 600 C) made by NASA, ASPEN. A: SEM image of 3D composite layer of Al2O3 produced at ELTE. B: Spaceloft insulating blanket produced by ASPEN (NASA). CFRP tanks Four different subscale tank concepts have been designed and manufactured within CHATT: Cylindrical tank with liner by DLR Dry wound cylindrical tank with liner by ALE Cylindrical tank without liner by FOI/SICOMP Complex shape tank by TUD Subsequent tests of tanks have included: leak-check, pressurization, multiple cryogenic fluids tanking and draining (LN2), investigation of fluids sloshing on DLR hexapod system with cylindrical DLR-tank using water. CFRP tanks - Cylindrical tank with liner Cylindrical tank with liner by DLR-Braunschweig: length 3 m (Cylindrical length: 2.4 m) diameter 1 m total volume: 1.9 m³ Different design and manufacturing concepts have been analyzed. PE-liner produced in rotation molding process. Afterwards wet winding on the liner with low viscosity epoxy resin. First layer is helix glass layer with angle of 6.8° CFRP tanks - Cylindrical tank with liner Winding of the helix CFRP layer (left) and final CFRP hoop layer (right): Finished tank is finally wrapped with peel ply for removal of excess resin and cured in autoclave: Delivered for testing in 2014. CFRP tanks - Dry wound tank with liner Dry wound cylindrical tank with liner by ALE: Technical tank design data: Length 0.57 m Diameter 0.29 m Volume 33 l Liner PE, blow molded Reinforcement T700 carbon fiber, dry wound Calculated strain at 12 bar and at LH2 temperature in half of the fiber network: CFRP tanks - Dry wound tank with liner Winding of helix layer (left) and winding of hoop layer (right) at ALE: Demonstrator tank after winding with protection foil: CFRP tanks - Cylindrical “tank” without liner Linerless tank demonstrators built in Sweden are not closed volume tanks but rather tubes with a cylindrical section and open ends. The linerless demonstrator tank concept is based on the utilization of thin-ply laminates. Manufacturing of tube demonstrator tank is performed at Swerea SICOMP while testing is executed at FOI. Novel spread-tow material from Swedish Oxeon company used named TeXtreme®. TeXtreme® used first time for wet filament winding in CHATT 2 mm thick TeXtreme® carbon/epoxy laminate with 0 % void content: CFRP tanks - Cylindrical “tank” without liner Several tubes with different fibre architecture, different laminate thickness and orientation were manufactured. Final optimized hybrid demonstrator casing consists of 4 layers of T700 wound at ±45°and 20 layers of TeXtreme® at ±25° Tube manufacturing with ±45°layer of T700 (left), ±25° layer of TeXtreme ® (right): Test set-up at FOI: CFRP tanks - Complex shape tank with liner Complex shape tank with liner investigated and built by TU Delft because of potentially improved volumetric efficiency. Simplest possible structure of a multibubble tank selected: Planar arrangement of identical spheres with double symmetry and bubbles radii all at the same 150 mm. Composite overwrapped subscale tank with a hoop fiber reinforcing the intersections and thus providing structural support. External UD carbon tow (roving) is applied over the tank wall from the outside to the inside: CFRP tanks - Complex shape tank with liner Manufacturing challenge: fibers must be very carefully wrapped over intersections and tube for effective load transfer between laminate membrane and tows. Multibubble tank integrating a hoop fiber has been manufactured in July and later pressure tested: POM (polyoxymethylene) liner is made in closed mold by rotation molding and selected tank wall material is 913C carbon/epoxy. Sloshing Simulation and Tests Objective: To investigate the effects of sloshing in cryogenic fuel tanks, including the risk of failure of the CFRP structure. Work is split into 3 sub-workpackages: experimental test campaign; numerical simulations; sloshing model for flight dynamics. Heat Exchanger Design & Testing HX-Design (ORBSpace, ECM) Two parallel activities helped to develop the design: Small-scale manufacturing trials; FE thermo-mechanical stress analysis Small scale trials with CeSIC material prepared by ECM. Two step manufacturing process; porous 'green-body' first machined to form narrow channels; green-body then infiltrated with liquid silicon under vacuum with up to 1600°C. Conclusion The key objectives of CHATT with a total budget exceeding 4.2 M€ are to investigate different CFRP cryogenic pressure tanks, propellant crossfeed systems, advanced thermal insulation materials, and ceramic heat-exchangers. Four different subscale CFRP-tanks have been designed, manufactured and tested. CHATT contributed to significant progress in the design of composite tanks for cryogenic propellant applications. Polymer liners are sensitive to cracking. Linerless tank technology is promising and should be further refined and introduced into complete tanks. In future projects lessons learned of CHATT will be useful to bring European composite tank technologies forward. Next step in development of European composite cryotank should focus on fully integrated tank demonstrator.