Material Safety Data Sheet
N,N-Diethylethylenediamine, 98+%
MSDS# 37248
Section 1 - Chemical Product and Company Identification
MSDS Name:
Catalog Numbers:
Synonyms:
N,N-Diethylethylenediamine, 98+%
AC150700000, AC150700050, AC150701000, AC150705000
2-Diethylaminoethylamine
Acros Organics BVBA
Janssen Pharmaceuticalaan 3a
2440 Geel, Belgium
Acros Organics
One Reagent Lane
Fair Lawn, NJ 07410
800-ACROS-01
+32 14 57 52 11
+32 14 57 52 99
201-796-7100
800-424-9300
703-527-3887
Company Identification:
Company Identification: (USA)
For information in the US, call:
For information in Europe, call:
Emergency Number, Europe:
Emergency Number US:
CHEMTREC Phone Number, US:
CHEMTREC Phone Number, Europe:
Section 2 - Composition, Information on Ingredients
---------------------------------------CAS#:
Chemical Name:
%:
EINECS#:
---------------------------------------Hazard Symbols:
100-36-7
N,N-Diethylethylenediamine
>98
202-844-7
C
Risk Phrases:
10 21 35
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Danger! Flammable liquid and vapor. Harmful if absorbed through the skin. Causes digestive and respiratory tract irritation
with possible burns. Causes severe eye and skin irritation with possible burns. Target Organs: Eyes, skin, mucous
membranes.
Potential Health Effects
Eye:
Causes severe eye irritation and possible burns.
Skin:
Causes severe skin irritation. Harmful if absorbed through the skin.
Ingestion: May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns.
May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing,
Inhalation: shortness of breath and pulmonary edema. Causes chemical burns to the respiratory tract. Inhalation may be fatal
as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Chronic: No information found.
Section 4 - First Aid Measures
Eyes:
Skin:
Ingestion:
Inhalation:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation
with water is required (at least 30 minutes).
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Do NOT induce vomiting and seek IMMEDIATE MEDICAL ADVICE.
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is
difficult, give oxygen.
Notes to
Physician:
Section 5 - Fire Fighting Measures
General
Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved
or equivalent), and full protective gear. Vapors may form an explosive mixture with air. Vapors can travel
to a source of ignition and flash back. Will burn if involved in a fire. Containers may explode in the heat of a
fire. Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas.
Do NOT use water directly on fire. Use water spray to cool fire-exposed containers. Use dry chemical,
carbon dioxide, or alcohol-resistant foam.
Extinguishing
Media:
Autoignition
Not available
Temperature:
Flash Point: 30 deg C ( 86.00 deg F)
Explosion
Not available
Limits: Lower:
Explosion
Not available
Limits: Upper:
NFPA Rating: health: 3; flammability: 3; instability: ;
Section 6 - Accidental Release Measures
General
Information:
Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove
all sources of ignition. Use a spark-proof tool. Provide ventilation.
Section 7 - Handling and Storage
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Ground and bond
containers when transferring material. Do not get in eyes, on skin, or on clothing. Empty containers retain product
Handling: residue, (liquid and/or vapor), and can be dangerous. Do not ingest or inhale. Discard contaminated shoes. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Use only with adequate ventilation. Keep away from heat, sparks and flame.
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.
Section 8 - Exposure Controls, Personal Protection
+-------------------- +------------------- +------------------- +----------------- +
|
Chemical Name
|
ACGIH
|
NIOSH
|OSHA - Final PELs|
|-------------------- |------------------- |------------------- |----------------- |
| N,N-Diethylethylene|none listed
|none listed
|none listed
|
| diamine
|
|
|
|
+-------------------- +------------------- +------------------- +----------------- +
OSHA Vacated PELs: N,N-Diethylethylenediamine: None listed
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use
adequate ventilation to keep airborne concentrations low.
Exposure Limits
Personal Protective Equipment
Eyes:
Wear chemical splash goggles and face shield.
Skin:
Clothing:
Wear appropriate protective gloves to prevent skin exposure.
Wear appropriate protective clothing to prevent skin exposure.
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a
Respirators: NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
Physical State: Liquid
Color: Not available
Odor: ammonia-like
pH: Not available
Vapor Pressure: 0.4 mbar @ 20 deg C
Vapor Density: 4.0
Evaporation Rate: Not available
Viscosity: Not available
Boiling Point: 145 - 147 deg C @ 760 mm Hg
Freezing/Melting Point: Not available
Decomposition Temperature: Not available
Solubility in water: Soluble
Specific Gravity/Density: .8270g/cm3
Molecular Formula: C6H16N2
Molecular Weight: 116.21
Section 10 - Stability and Reactivity
Chemical Stability:
Conditions to Avoid:
Incompatibilities with Other Materials
Hazardous Decomposition Products
Hazardous Polymerization
Stable under normal temperatures and pressures.
Ignition sources, excess heat, electrical sparks, exposure to flame.
Strong oxidizing agents, acids, acid chlorides, carbon dioxide, acid anhydrides.
Nitrogen oxides, carbon monoxide, carbon dioxide.
Has not been reported.
Section 11 - Toxicological Information
RTECS#:
CAS# 100-36-7: KV3500000
RTECS:
CAS# 100-36-7: Oral, rat: LD50 = 2830 mg/kg;
LD50/LC50:
Skin, rabbit: LD50 = 820 uL/kg;
.
Other:
Carcinogenicity: N,N-Diethylethylenediamine - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
Other:
See actual entry in RTECS for complete information.
Section 12 - Ecological Information
Not available
Section 13 - Disposal Considerations
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - Transport Information
US DOT
Shipping Name: N,N-DIETHYLETHYLENEDIAMINE
Hazard Class: 8
UN Number: UN2685
Packing Group:
Canada TDG
Shipping Name: Not available
Hazard Class:
UN Number:
Packing Group:
Section 15 - Regulatory Information
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 10 Flammable.
R 21 Harmful in contact with skin.
R 35 Causes severe burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 100-36-7: 1
Canada
CAS# 100-36-7 is listed on Canada's DSL List
Canadian WHMIS Classifications: E, B2
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
and the MSDS contains all of the information required by those regulations.
CAS# 100-36-7 is not listed on Canada's Ingredient Disclosure List.
US Federal
TSCA
CAS# 100-36-7 is listed on the TSCA
Inventory.
Section 16 - Other Information
MSDS Creation Date: 3/04/1998
Revision #6 Date 7/20/2009
The information above is believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantibility or any other warranty, express or implied,
with respect to such information, and we assume no liability resulting from its use. Users should make
their own investigations to determine the suitability of the information for their particular purposes. In no
event shall the company be liable for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential, or exemplary damages howsoever arising, even if the
company has been advised of the possibility of such damages.
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