2nd Generation Biofuels – State of the art: an overview on demonstration plants around the world Dina Bacovsky, BIOENERGY 2020+ Alternative Propulsion Systems and Energy Carriers Austrian, European and global R&D- and demonstration projects, research institutions and funding programs Vienna, 16.10.2009 in cooperation with Background Bioenergy 2020+ Competence centre: research, consulting & engineering in bioenergy merged from Austrian Bioenergy Centre and reNet www.bioenergy2020.eu IEA Bioenergy Task 39 'Commercializing 1st- and 2ndGeneration Liquid Biofuels from Biomass' international network: development and deployment of biofuels for transportation part of IEA's Implementing Agreement on Bioenergy www.task39.org 2nd gen biofuels demoplants map and report • commissioned by IEA Bioenergy Task 39 • data collection on pilot and demonstration facilities for the production of biofuels from lignocellulosic raw materials Rethinking Propulsion. 2 Interactive map of 2nd gen biofuels demoplants http://biofuels.abc-energy.at/demoplants/ Rethinking Propulsion. 3 2nd Generation Biofuels Feedstock: lignocellulosic raw materials 2 main pathways: biochemical conversion: fermentation thermochemical conversion: gasification + combined pathways Product: Biofuels for transportation Rethinking Propulsion. 4 Thermochemical Biofuel Facilities Chemrec CHOREN Coskata Conzepte Technik Umwelt AG Cutec ECN Enerkem Flambeau River Biofuels LLC Forschungszentrum Karlsruhe GTI Gas Technology Institute NSE Biofuels Oy Range Fuels Research Triangle Institute Southern Research Institute Tembec Chemical Group Vienna Univ. of Technology Rethinking Propulsion. 5 Thermochemical Biofuel Facilities Chemrec 25 projects 8 currently operational CHOREN Coskata Conzepte Technik Umwelt AG Cutec ECN Enerkem Flambeau River Biofuels LLC Forschungszentrum Karlsruhe GTI Gas Technology Institute NSE Biofuels Oy Range Fuels Research Triangle Institute Southern Research Institute Tembec Chemical Group Vienna Univ. of Technology Rethinking Propulsion. 6 Thermochemical Biofuel Facilities Chemrec Various technologies 7 highlighted CHOREN Coskata Conzepte Technik Umwelt AG Cutec ECN Enerkem Flambeau River Biofuels LLC Forschungszentrum Karlsruhe GTI Gas Technology Institute NSE Biofuels Oy Range Fuels Research Triangle Institute Southern Research Institute Tembec Chemical Group Vienna Univ. of Technology Rethinking Propulsion. 7 Biochemical Biofuel Facilities AE Biofuels Abengoa BBI BioVentures BioGasol Borregaard Industries DDCE Inbicon Iogen KL Energy Lignol Energy M-real Hallein Mossi & Ghisolfi Procethol 2G Pacific Ethanol Queensland University of Techn. SEKAB Technical University of Denmark Terrabon Verenium Weyland AS Rethinking Propulsion. 8 Biochemical Biofuel Facilities AE Biofuels Abengoa 33 projects 13 currently operational BBI BioVentures BioGasol Borregaard Industries DDCE Inbicon Iogen KL Energy Lignol Energy M-real Hallein Mossi & Ghisolfi Procethol 2G Pacific Ethanol Queensland University of Techn. SEKAB Technical University of Denmark Terrabon Verenium Weyland AS Rethinking Propulsion. 9 Biochemical Biofuel Facilities AE Biofuels Abengoa Various technologies 6 highlighted + POET BBI BioVentures BioGasol Borregaard Industries DDCE Inbicon Iogen KL Energy Lignol Energy M-real Hallein Mossi & Ghisolfi Procethol 2G Pacific Ethanol Queensland University of Techn. SEKAB Technical University of Denmark Terrabon Verenium Weyland AS Rethinking Propulsion. 10 Important Thermochemical Technology Options Biomass VUT CTU Enerkem Fluidised Bed Gasifier Entrained Flow Gasifier Chemrec CHOREN FZK Gas Upgrading Biological Conversion Biofuel Synthesis Coskata Biofuel: Ethanol, FT-liquids, DME, Methanol, Bio-SNG Rethinking Propulsion. 11 VUT FT-Process Rethinking Propulsion. 12 SNG Process (VUT, CTU) Rethinking Propulsion. 13 Enerkem Process Rethinking Propulsion. 14 Chemrec Process Rethinking Propulsion. 15 CHOREN Process Carbo-V Process: 1. Low-temperature gasification 2. High-temperature gasification 3. In-blow of ground char 4. Syngas conditioning 5. Catalytic conversion to FT-liquids 6. Upgrade of raw FT-liquids Rethinking Propulsion. 16 FZK Process Stroh, u.a. Straw,Heu wood, .... Häcksler Chopper kaltes Strohhäcksel Hot sand 550°C Cold chopped straw heisser Sand ca. 500 °C M Heater, Heizer Heat carrier loop Sandkreislauf Pyrolysis gas Pyroly segas Pyrolyseöl Kühler Cooler Slurry Slurry Pyrolysekoks M Doppelschnecken-Reaktor Twin screw mixer reactor Rethinking Propulsion. 17 Coskata Process (Hybrid Technology) Gasification 2. Gas clean-up 3. Fermentation 4. Separation 1. Rethinking Propulsion. 18 Important Biochemical Technology Options Corn cobs, corn stover, wheat straw, wood waste,… Biomass Pretreatment Fractionation Steam explosion, acid, ionic liquids,… Enzymes Hydrolysis Lignin Sequential or separate C6 and C5 fermentation Fermentation CHP Distillation Ethanol Process Integration Distillation Ethanol Rethinking Propulsion. 19 Abengoa Process steam explosion, biomass fractionation, separate C5/C6 fermentation, biomass gasification CHP Rethinking Propulsion. 20 Inbicon Process coupled to multifuel biomass power plant, lignin is separated for fuelling power plant, hydrothermal pre-treatment, high gravity hydrolysis, yeast fermentation Rethinking Propulsion. 21 Iogen Process lignin separation for steam and electricity generation, modified steam explosion, own enzyme production, separate hydrolysis and fermentation, process integration: heat integration, water recycling, co-product production Rethinking Propulsion. 22 KL Energy Process enzymatic fermentation, lignin separation after ethanol distillation, lignin pellets as co-product Rethinking Propulsion. 23 SEKAB Process enzymes with pretreatment of diluted acid in one step Rethinking Propulsion. 24 Verenium Process separate C5 and C6 fermentation, distillation residues sent to boiler for steam generation Rethinking Propulsion. 25 POET Process integrated into conventional ethanol facility, utilizes corn cobs for production of cellulosic ethanol and own power requirements Rethinking Propulsion. 26 Number of Projects number of projects sorted by capacity and status 14 number of projects 12 10 planned 8 under construction 6 operational 4 2 0 < 50 < 500 < 5.000 < 50.000 < 500.000 planned 2 0 2 8 6 under construction 1 5 7 1 1 operational 4 6 4 2 0 capacity [t/a] Rethinking Propulsion. 27 Announced Capacities possible development of 2nd generation biofuels capacities 1.800.000 1.600.000 1.200.000 hybrid 1.000.000 thermochemical 800.000 biochemical 600.000 400.000 200.000 0 20 04 20 05 20 06 20 07 20 08 20 09 20 10 20 11 20 12 20 13 20 14 20 15 20 16 capacity [t/a] 1.400.000 year Rethinking Propulsion. 28 Global Biofuels Production in 2008 Rethinking Propulsion. 29 Conclusions ~ 40 companies operate or currently build facilities for biofuel production from lignocellulosics Various technologies applied Various biofuels produced Currently, no technology winner to be seen Once proven, the development could be rapid Significant production not before 2020 Rethinking Propulsion. 30 Contact Dina Bacovsky BIOENERGY 2020+ Address: Tel: Fax: web: Email: Gewerbepark Haag 3 3250 Wieselburg - Land Austria +43-7416-52238-35 +43-7416-52238-99 www.bioenergy2020.eu dina.bacovsky@bioenergy2020.eu Rethinking Propulsion. 31 Thank you for your attention !!!!! Rethinking Propulsion. 32 Vienna University of Technology Location: Güssing, Austria Raw Material: syngas from gasifier Product: 0.2 t/a FT-liquids; Pilot facility, operational, start-up 2005 Partners: Repotec, Biomassekraftwerk Güssing Rethinking Propulsion. 33 Conzepte Technik Umwelt Location: Güssing, Austria Raw Material: syngas from gasifier Product: 100 Nm3/h SNG; Demo facility, operational, start-up 2008 Partners: Vienna University of Technology, Austria; Paul Scherrer Institute, Switzerland; Repotec, Austria Rethinking Propulsion. 34 Enerkem I Location: Sherbrooke, Canada Raw Material: 20 types of feedstock tested Product: 375 t/a ethanol; Pilot facility, operational, start-up 2003 Rethinking Propulsion. 35 Enerkem II Location: Westbury, Canada Raw Material: Creosoted electricity poles Product: 4 000 t/a ethanol; Demo facility, under commissioning, start-up 2009 Rethinking Propulsion. 36 Enerkem III Location: Edmonton, Canada Raw Material: MSW Product: 30 000 t/a ethanol; Commercial facility, announced Partners: Greenfield Ethanol Investment: 70 million CAD Funding: 20 million CAD Rethinking Propulsion. 37 Chemrec I Location: Pitea, Sweden Black liquor gasification Product: 1 800 t/a DME Pilot facility, under construction, start-up 2010 Partners: AB Volvo, Haldor-Topsoe, Preem, Total, Delphi, ETC Investment: 28 million EUR Rethinking Propulsion. 38 Chemrec II Location: Örnsköldsvik, Sweden Black liquor gasification Product: 132 000 t/a (Methanol) or 95 000 (DME) t/a; Demo facility, planned, start-up 2013 Partners: Domsjoe Fabriker AB Investment: 250 million EUR The recovery boiler in the paper mill will be replaced or supplemented by a gasification based fuel generating and pulp mill cooking chemicals recovery system. Rethinking Propulsion. 39 CHOREN I Location: Freiberg, Germany Raw Material: dry wood chips from recycled wood and residual forestry wood; in the future add.: SRF Product: 14 000 t/a FT-liquids Commercial facility, under construction, start-up 2009 Investment: 100 million EUR Rethinking Propulsion. 40 CHOREN II Location: probably Schwedt, Germany Raw Material: dry wood chips from recycled wood; SRF Product: 200 000 t/a FT-liquids; commercial facility, planned Rethinking Propulsion. 41 Forschungszentrum Karlsruhe Location: Karlsruhe, Germany Raw Material: lignocellulosics Product: 100 l/h diesel; gasoline type fuel; Partners: LURGI GmbH Pilot facility, under construction Rethinking Propulsion. 42 Forschungszentrum Karlsruhe Projects Fast pyrolysis Stroh BioSyncrude preparation 1. De-central Biomass 2. High pressure entrained flow gasification central 3. Gas conditioning 4. Fuel synthesis 2 MW fast pyrolysis completed, 5 MW high pressure entrained flow gasification under construction, gas cleaning and methanol synthesis and Methanol to Fuel in design Synthetic fuel Rethinking Propulsion. 43 Coskata I (Hybrid Technology) Location: Madison, United States Raw Material: wood chips, natural gas Product: 120 t/a ethanol; Demo facility, under construction, start-up 2009 (operational pilot facility installed in Warrenville, United States) Rethinking Propulsion. 44 Coskata II (Hybrid Technology) Location: Clewiston, United States Raw Material: sugarcane waste, others Product: 300 000 t/a ethanol; Commercial facility, planned Investment: 400 million USD Rethinking Propulsion. 45 Abengoa I Location: York, United States Raw Material: corn stover Product: 75 t/a ethanol; Pilot facility, operational, start-up 2007 Partners: NREL, Auburn University Funding: 35 million USD Rethinking Propulsion. 46 Abengoa II Location: Hugoton, United States Raw Material: corn stover Product: 34 000 t/a ethanol; Commercial facility, under construction, start-up 2011 Funding: 76 million USD Rethinking Propulsion. 47 Abengoa III Location: Babilafuente, Salamanca, Spain Raw Material: steam explosion, wheat/wheat straw, corn stover Product: 4 000 t/a ethanol; Demo facility, under construction, start-up 2009 Partners: CIEMAT, University of Lund Funding: 4 million EUR Rethinking Propulsion. 48 Inbicon I Location: Fredericia, Denmark Raw Material: straw Product: ethanol; c5 molasses; solid biofuel; Pilot facility, operational, start-up 2003 Investment: 5 million EUR Funding: 2 million EUR Rethinking Propulsion. 49 Inbicon II Location: Fredericia, Denmark Raw Material: straw Product: ethanol; c5 molasses; solid biofuel; Pilot facility, operational, start-up 2004 Investment: 15 million EUR Funding: 5 million EUR Rethinking Propulsion. 50 Inbicon III Location: Kalundborg, Denmark Raw Material: wheat straw Product: 4 000 t/a ethanol; c5 molasses; solid biofuel; Demo facility, under construction, start-up 2009 Investment: 50 million EUR Funding: 10 million EUR Rethinking Propulsion. 51 Iogen I Location: Ottawa, Canada Raw Material: wheat, barley and oat straw Product: 1 600 t/a ethanol; demo facility, operational, start-up 2004 Rethinking Propulsion. 52 Iogen II Location: Birch Hills, Canada Raw Material: wheat straw, etc. Product: 70 000 t/a ethanol; Commercial facility, planned, start-up 2011 Partners: Royal Dutch Shell Oil Company; investor: Goldmann Sachs Rethinking Propulsion. 53 KL Energy Corporation Location: Upton, United States Raw Material: wood waste, including cardboard and paper Product: 4 500 t/a ethanol; Demo facility, operational, start-up 2007 Partners: South Dakota School of Mines and Technology Investment: 7 million USD Rethinking Propulsion. 54 SEKAB I Location: Örnsköldsvik, Sweden Raw Material: primary wood chips and sugarcane bagasse, but other raw materials will be studied such as wheat, corn stover, energy grass, recycled waste etc Product: 80 t/a ethanol; pilot facility, operational, startup 2004 Partners: University of Umea, Technical University of Lulea, SEKAB E-technology AB Investment: 2 million SEK Rethinking Propulsion. 55 SEKAB II Location: Örnsköldsvik, Sweden Raw Material: flexible for wood chips and sugarcane bagasse Product: 4 500 t/a ethanol; Demo facility, planned, start-up 2011 Rethinking Propulsion. 56 SEKAB III Location: Örnsköldsvik, Sweden Raw Material: wood chips or sugarcane bagasse, depending on location Product: 50 000 t/a ethanol; Demo facility, planned, start-up 2014 Partners: SEKAB will be a technology provider and the plant would probably be owned by some other partner, maybe with minority ownership of SEKAB. Investment: 1 500 million SEK Rethinking Propulsion. 57 SEKAB IV Location: Örnsköldsvik, Sweden Raw Material: Product: 120 000 t/a ethanol; Commercial facility, planned, start-up 2016 Partners: SEKAB will be a technology provider and the plant would probably be owned by some other partner, maybe with minority ownership of SEKAB. Rethinking Propulsion. 58 Verenium I Location: Jennings, United States Raw Material: Sugar cane bagasse, energy cane Product: 150 t/a cellulosic ethanol; Pilot facility, operational, start-up 2007 Rethinking Propulsion. 59 Verenium II Location: Jennings, United States Raw Material: Sugarcane bagasse, dedicated energy crops, wood products and switchgrass Product: 4 200 t/a cellulosic ethanol; Demo facility, operational, start-up 2009 Investment: 79 million USD Rethinking Propulsion. 60 POET Project Liberty Location: Emmetsburg, United States Raw Material: corn cobs, agricultural residues Product: 500 000 t/a ethanol, of which 100 000 t/a cellulosic ethanol; Commercial facility, planned, start-up 2011 Rethinking Propulsion. 61