Boiling Water Reactor Basics Larry Nelson November 2008 GE Global Research Overview z z z z z z Big Picture - BWR Plants Major Components BWR Evolution BWR Features vs. PWR Features Electrochemical Potential (ECP) Concept ECP Monitoring & NobleChemTM GE Global Research 2 The Big Picture GE Global Research 3 Primary Containment GE Global Research 4 BWR Power Cycle NUCLEAR STEAM SUPPLY SYSTEM (NSSS) BALANCE OF PLANT (BOP) Moisture Separator and Reheater Steam Reactor Vessel Turbine Generator HP LP LP Separators and Dryers Condenser Feedwater Extraction Steam Core Demineralizers Recirc Pump Recirc Pump Extraction Steam Feed Pumps Heaters Condensate Pumps Drain Pumps GE Global Research Heaters 5 ABWR Power Cycle NUCLEAR STEAM SUPPLY SYSTEM (NSSS) BALANCE OF PLANT (BOP) Reactor Vessel Moisture Separator Reheater Main Steam Low Pressure Turbine Generator Feedwater Suppression Pool High Pressure Turbine Condenser Feedwater Pump Offgas System CP High Pressure Feedwater Heater Stack Low Pressure Feedwater Heaters Steam Jet Air Ejector Gland Steam Condenser CBP Condenser GE Global Research Condensate Purification System 6 BWR Major Components BWR Jet Pump z z GE Global Research Provide core flow to control reactor power which yields higher power level without increasing the Rx size Provide part of the boundary required to maintain 2/3 core height following a recirculation line break event 8 Lower Plenum z z z z z z z GE Global Research CRD Guide Tubes CRBs CRD housings Stub Tubes In-core Housings Guide Tubes Flux monitor dry tubes 9 BWR Core Shroud Shroud and Sep Core Spray Spargers hroud abilizer yp of 4) Ecentric Aligner Top Guide Core Plate Stud (Typical) Ecentric Aligner Cor Shro Core Shroud Stainless Steel Cylinder z Surrounds the Core z – Separates upward flow through the core from downward flow in the downcomer annulus – Provides a 2/3 core height floodable volume GE Global Research 10 Fuel Assembly & Control Blade GE Global Research 11 Steam Separator Wet Steam Ret W ing r S Turning vanes impart rotation to the steam/water mixture causing the liquid to be thrown to the outside z 163 standpipes z T ( To ecirc GE Global Research Stan 12 Steam Dryer Provides Qsteam dryer = 99.9% to the Main Turbine z Wet steam is forced horizontally through dryer panels – Forced to make a series of rapid changes in direction – Moisture is thrown to the outside z z GE Global Research Initial power uprate plants experiences FIV – minimized by design improvements 13 BWR Evolution BWR Reactor Evolution Dresden 1 KRB Oyster Creek Dresden 2 ABWR GE Global Research ESBWR 15 BWR Development VBWR (Vallecitos Boiling Water Reactor) – 1st General Electric BWR power plant – Built in 1957 (near San Jose, California) – 1st commercial BWR; 5 MWe supplied to Pacific Gas & Electric grid (through 1963) – 1000 psig (66.7 atm) operating pressure GE Global Research 16 BWR Development BWR1 z Introduced in 1955 BWR2 z Introduced in 1963 1st commercial plant in 1960 z 3 plants (Dresden 1) z Characteristics: z 8 plants – Internal steam separation – Low power density core z Characteristics: – 5 Recirculation loops – External or Internal steam – Flow control load following separation – Low power density core z GE Global Research 17 BWR Development BWR3 BWR4 z Introduced in 1965 z Introduced in 1966 z First Jet Pump application z Increased power density z 9 plants Characteristics: – Low power density core – Internal Jet Pumps – 2 Recirculation loops z 25 Plants Characteristics: – High power density core – Mark I or II containment z GE Global Research z 18 BWR Development BWR5 BWR6 Introduced in 1969 z Improved safeguards (ECCS) z Recirculation flow control valves z 8 plants z z z Characteristics: – Valve flow control load Introduced in 1972 z Added fuel bundles; increased output; Improved fuel safety margins z Improved Recirc system performance z 8 plants z Characteristics: following – Valve flow control – ECCS injects into core shroud – 8 x 8 fuel bundle GE Global Research 19 BWR Development ABWR ESBWR Introduced in 1991 z Currently in licensing and design z Blend of best features: z Characteristics: operating BWRs, available new – Passive Safety technologies, & modular – Natural Circulation; No Recirc construction techniques Loops or Pumps z 4 plants – Safety improvements (reduced z Characteristics: core damage frequency) – Safety improvements – Design life 60 years (reduced core damage – Larger Main Generator (~1600 frequency) MWe) – Design life 60 years – No external Recirc Loops; Reactor Internal Pumps z GE Global Research 20 Operating Parameters for Selected BWRs Parameter BWR/4 (Browns Ferry 3) BWR/6 (Grand Gulf 1) ABWR ESBWR 3293/1098 3900/1360 3926/1350 4500/1590 21.9/6.4 21.8/6.4 21.1/7.1 27.6/7.1 Fuel Bundles (number) 764 800 872 1132 Active Fuel height (m) 3.7 3.7 3.7 3.0 Power density (kW/l) 50 54.2 51 54 Recirculation pumps 2 (large) 2 (large) 10 zero Number of CRDs / type 185/LP 193/LP 205/FM 269/FM Safety system pumps 9 9 18 zero Safety Diesel Generator 2 3 3 zero Core damage freq./yr 1E-5 1E-6 1E-7 1E-8 Safety Bldg Vol (m3/MWe) 120 170 180 135 Power (MWt / MWe) Vessel height / diameter (m) GE Global Research 21 ESBWR Reactor Pressure Vessel GE Global Research 22 ESBWR Passive Safety GE Global Research 23 ESBWR Gravity Driven Cooling System • Simple design • Simple analyses • Extensive testing • Large safety margins Before After GE Global Research Gravity driven flow keeps core covered 24 BWR vs. PWR BWR and PWR… the main differences Pressurized Water Reactor Boiling Water Reactor Pressurizer Pressure/Temperature Chemical & Volume Control Reactor Pressure Vessel T/G T/G Turbine Generator Turbine Generator Steam Generator Reactor Pressure Vessel Condenser Condenser 2 loops heat balance/ heat transfer GE Global Research 1 loop heat balance/ heat transfer 26 Principle of Steam Generation BWR PWR z RPV Pressure ~7 MPa (1020 z RPV Pressure ~15 MPa (~2240 psig) z RPV Temperature 288 oC (550 ºF) z Steam Generated in RPV (with Separator & Dryer) z Bulk Boiling Allowed in RPV psig) z RPV Temperature 326 oC (~618 ºF) z Steam Generated in Steam Generator (via Second Loop) z No Bulk Boiling in RPV BWR BWRhas hasLower LowerRPV RPVPressure Pressureand andSimplified SimplifiedSteam SteamCycle Cycle GE Global Research 27 Major NSSS Components BWR z RPV (with Dryer & Separator) z No Steam Generator z No Pressurizer z Natural Circulation (ESBWR) z RPV mounted pumps (ABWR) z Bottom Entry Control Rod Drives GE Global Research PWR z RPV z 2 - 4 Steam Generators z 1 Pressurizer z Reactor Coolant Pumps outside of RPV z Top Entry Control Rod Clusters 28 Electrochemical Potential (ECP) Concept Stress Corrosion Cracking History in BWRs # of BWRs Operating BWRs N. America Europe Asia GE 34 4 11 Non-GE 0 16 21 80,000 MWe installed GE Global Research Total 49 38 Repair costs >$1B / BWR Stress Corrosion Cracking History • 1969 1st detected in sensitized SS • 1970s Stainless steel welded piping • 1980s BWR internals • 1990s Low stress BWR internals 30 “Nuclear Chain Reactions on One Slide” HEAT X E=mc2 n 235 U Etc. 235 U HEAT n n “Moderator” Y Water or Graphite n 238 U high energy neutron GE Global Research n 239 Pu low energy neutron H20 X,Y H+ + OH- Radioactive by-products e.g. Kr, Cs, I, Ba, Th, Np 31 Water Radiolysis Generates Species Harmful to Materials H2 H* n e γ OH* H2 O H2 O + O2 H2O2 OHHO2 HO2 Commonly Observed species (n,p) - * N2 NO2NO3- Oxidant (H2O2 and O2) Generation By Water Radiolysis GE Global Research 32 Stress Corrosion Cracking Environment Cr depletion occurs during welding of stainless steels with high carbon levels Stress Microstructure Plastic Strain (%) 20 15 1.E-05 Sensitized 304 Stainless Steel 30 MPa√m, 288C Water 0.06-0.4 μS/cm, 0-25 ppb SO4 SKI Round Robin Data filled triangle = constant load open squares = "gentle" cyclic 1.E-06 5 0 -25 -20 -15 -10 -5 0 5 10 15 20 25 Relative Distance From Weld Fusion Line (mm) Crack Growth Rate, mm/s 10 316L (A14128, square ) 304L (Grand Gulf, circle ) non-sensitized SS 50%RA 140 C (black ) 10%RA 140C (grey ) 1.E-07 CW A600 42.5 28.3 14.2 μin/h CW A600 GE PLEDGE Predictions 30 MPa√m Sens SS 0.5 2000 ppb O2 Ann. 304SS 200 ppb O2 0.25 Weld GE Global Research ←2000 ppb O2 25 ← 200 ppb O2 GE1 Scan B 600A GE1 Scan D 600A GE2 Scan C 600A GE2 Scan D 600A GE3 Scan D 600A GE3 Scan C 600A GE8 Scan C 400A GE8 Scan D 400A GE9 Scan D 300A GE9 Scan C 300A GE4 Scan C 600A GE4 Scan D 600A ← 500 ppb O2 30 Outside Plastic strain occurs during welding and leads to cracking in stainless steels with low carbon (L-grade SS) 1.E-08 0.1 0.06 μS/cm GE PLEDGE Predictions for Unsensitized Stainless Steel (upper curve for 20% CW) 1.E-09 -0.6 -0.5 -0.4 -0.3 -0.2 -0.1 0.0 0.1 0.2 0.3 0.4 Corrosion Potential, Vshe 33 Stress Corrosion Cracking Prediction & Application Complex phenomenon must be understood mechanistically as “crack tip system” processes LAB Lab understanding & data must be verified by plant data before use in BWR prediction PLANT PREDICTION Insights yield novel technology like NobleChem GE Global Research 34 Stress Corrosion Cracking Mitigation Radiation Field Response Crack Growth Response Main Steam Radiation Field Normalized Main Steam Line Activity Low Hydrogen Moderate Hydrogen High Hydrogen Feedwater Hydrogen Concentration (PPM) • • High crack growth rates at high corrosion potential (ECP) • ECP is a dominant variable effecting SCC response Hydrogen injection results in an increase in main steam line radiation fields NobleChem™ Basics Electro Chemical Potential (ECP) Response ECP, mV (SHE) 200 NWC – In-core NWC - Piping 0 - 200 - 400 HWC NobleChem - 600 0.5 1.0 1.5 // 2.0 • With excess H2, O2 is consumed & its level at the surface is zero • H2 + O2 reaction is catalyzed with NobleChem particles • Hydrogen added is more effective – lower radiation fields Hydrogen Injection Rate (ppm) GE Global Research 35 ECP Monitoring & NobleChem TM BWR ECP Monitoring Locations Modified LPRM Assembly for Bottom-of-Core ECP Monitoring (3 ECP Sensors) Full Function Data Acquisition System Air Conditioner Recirculation\Decon Flange Assembly (4 ECP Sensors) Multiplexer Personal Computer Digital Multimeter Deskjet Printer AC Line Conditioner Modified LPRM Assembly for Lower Plenum ECP Monitoring (2 or 3 ECP Sensors) Drywell Multimeter/ Multiplexer Core Plate EDM one new hole in Guide Tube Simplified Data Acquisition System Personal Computer Drain Line Flange Assembly (4 ECP Sensors) Inlet to LPRM (ECP sensors inside and above) GE Global Research 37 Lower Plenum ECP Monitoring High Temperature Prefilm (in laboratory) Fe/Fe3O4 Platinum Noble Metal Treated SS Electrode Core Plate 2.75 in. (70 mm) Inlet Cooling Holes in LPRM Cover Tube Lower Cooling Holes in LPRM Cover Tube, ECP Sensors Inside and Above Holes GE Global Research 1/2” diameter Inlet Cooling Hole in In Core Monitor Housing Local Power Range Monitor Assembly 38 Bottom Plenum ECP Response Lower Plenum ECP 200 100 HWC is Effective In Mitigating IGSCC But…Lower Plenum Requires More H2 Middle ECP (mV SHE) 0 Bottom -100 -200 IGSCC Mitigation Potential -230 mV(SHE) -300 Core Plate ECP -400 -500 0 0.5 1 1.5 2 2.5 FEEDWATER HYDROGEN (ppm) GE Global Research 39 Basis for NobleChem Technology TM 1.0 GE Global Research 2.0 (ppm) 40 HWC vs. NobleChem Technology TM 200 TM Before NobleChem - 1994 ECP mV(SHE) 0 TM After NobleChem - 1999 -230 mV(SHE) -200 IGSCC Mitigation -400 -600 0 0.4 0.8 1.2 1.6 2 Feedwater H2 (ppm) BWR/4 Low ECP After NobleChemTM and Low Hydrogen GE Global Research 41 ECP Reduction With NobleChem TM 300 200 100 Non-NobleChem Plant Data ECP mV(SHE) 0 -100 Upper Core - UC -200 -230 mV(SHE) -300 Lower Core - LC -400 Lower Plenum - LP -500 NobleChem Plant Data for UC, LC, LP, RRS RRS -600 0 0.5 1 1.5 2 2.5 Feedwater Hydrogen, ppm Provides Low ECPs At All Internal Locations GE Global Research 42 Noble Metal Distribution After On-Line Application Pt PARTICLE SIZE DISTRIBUTION (based on number) 100% S TATI STICS M ean : 6.1 Std . De v. : 2.3 Minim um : 2.1 Ma xim um : 2 1.8 O bject Co unt : 17 331 (b ased on num b er) 25% 20% 90% nm nm nm nm 80% 70% 60% 50% 15% 40% 10% 30% Cumulative Number Relative Number Frequency 30% 20% 5% 10% 0% 100 nm 0% 0.5 1.5 2.5 3.5 4.5 5.5 6.5 7.5 8.5 9.5 10.5 11.5 12.5 13.5 14.5 15.5 16.5 17.5 18.5 19.5 Particle Diameter (nm) Nano-particle Pt Generation By On-Line NobleChemTM GE Global Research 43 Summary Reactor operation at low ECP is essential for minimizing component degradation in all BWR designs including the ESBWR z ESBWR is GEH’s latest evolution in BWR design – 4500 MWt/~1575MWe – Natural circulation – Passive safety features – Significant simplification z ESBWR is under licensing review by USNRC z ESBWR chosen by NuStart, Dominion and Exelon as reference design z GE Global Research 44