CHEMISTRY FINAL REVIEW CHAPTER 2 chemical change physical change phase change CHAPTER 3 sig figs metric conversion scientific notation density CHAPTER 4 protons neutrons electrons nucleus atomic number mass number how to determine the number of protons how to determine the number of neutrons how to determine the number of electrons CHAPTER 5 valence electrons principle quantum numbers number of electrons in each orbital how to determine the number of valence electrons writing electron configurations CHAPTER 6 periodic table periodic law metals nonmetals metalloids group names transition elements trends : electronegativity atomic radius ionization energy CHAPTER 7 oxidation numbers cation anions octet rule properties of ionic bonds properties of covalent bonds CHAPTER 8 atoms ions molecules diatomic molecules molecules molecular compounds single bonds double bonds triple bonds shape of s orbital shape of p orbital shape of d orbital Polarity Van der waals forces dipoles dispersion forces hydrogen bonds CHAPTER 9 polyatomic ions naming and writing formulas acids and bases CHAPTER 10 moles mole roadmap conversions % composition CHAPTER 11 balancing equations writing equations types of reactions: combustion decomposition single replacement double replacement synthesis net ionic equations CHAPTER 12 stoichiometry mass-mass problems Unit Conversions Worksheet 1) How many inches are there in 45.6 cm? (There are 2.54 cm in 1 inch) 2) How many centimeters are there in 1.23 x 10-6 kilometers? 3) How many hours are there in 34.5 years? 4) How many inches are there in 355 millimeters? 5) How many milliliters are in a cubic meter? (There are 1,000 L in 1 m3) 6) How many miles are there in 3.44 x 108 inches? There are 0.61 miles in 1 km). Need help with chemistry? Visit www.chemfiesta.com! Unit Conversions Worksheet - Solutions 1) How many inches are there in 45.6 cm? (There are 2.54 cm in 1 inch) 18.0 inches 2) How many centimeters are there in 1.23 x 10-6 kilometers? 0.123 cm 3) How many hours are there in 34.5 years? 3.02 x 105 hours 4) How many inches are there in 355 millimeters? 14.0 inches 5) How many milliliters are in a cubic meter? (There are 1,000 L in 1 m3) 1.00 x 106 mL 6) How many miles are there in 3.44 x 108 inches? There are 0.61 miles in 1 km). 5.33 x 103 miles Need help with chemistry? Visit www.chemfiesta.com! Significant Figures Practice Worksheet How many significant figures do the following numbers have? 1) 1234 _____ 2) 0.023 _____ 3) 890 _____ 4) 91010 _____ 5) 9010.0 _____ 6) 1090.0010 _____ 7) 0.00120 _____ 8) 3.4 x 104 _____ 9) 9.0 x 10-3 _____ 10) 9.010 x 10-2 _____ 11) 0.00030 _____ 12) 1020010 _____ 13) 780. _____ 14) 1000 _____ 15) 918.010 _____ 16) 0.0001 _____ 17) 0.00390 _____ 18) 8120 _____ 19) 7.991 x 10-10_____ 20) 72 _____ http://www.chemfiesta.com Solutions to the Significant Figures Practice Worksheet 1) 2) 3) 4) 5) 6) 7) 8) 9) 10) 11) 12) 13) 14) 15) 16) 17) 18) 19) 20) 4 2 2 4 5 8 3 2 2 4 2 6 3 1 6 1 3 3 4 2 http://www.chemfiesta.com Significant Figure Calculations Solve the following mathematical problems such that the answers have the correct number of significant figures: 1) 334.54 grams + 198 grams = ___________________ 2) 34.1 grams / 1.1 mL = ___________________ 3) 2.11 x 103 joules / 34 seconds = ___________________ 4) 0.0010 meters – 0.11 m = ___________________ 5) 349 cm + 1.10 cm + 100 cm = ___________________ 6) 450 meters / 114 seconds = ___________________ 7) 298.01 kilograms + 34.112 kilograms = ___________________ 8) 84 m/s x 31.221 s = ___________________ www.chemfiesta.com © 2008 Cavalcade Publishing; All Rights reserved Significant Figure Calculations – Answers Solve the following mathematical problems such that the answers have the correct number of significant figures: 1) 334.54 grams + 198 grams = 533 grams (rounded from 532.42 grams) 2) 34.1 grams / 1.1 mL = 31 g/mL (not rounded) 3) 2.11 x 103 joules / 34 seconds = 62 J/s (rounded from 62.0588 J/s) 4) 0.0010 meters – 0.11 m = -0.11 m (rounded from -0.109 m) 5) 349 cm + 1.10 cm + 100 cm = 500 cm (rounded from 450.1 cm) 6) 450 meters / 114 seconds = 3.9 m/s (rounded from 3.9474 m/s) 7) 298.01 kilograms + 34.112 kilograms = 332.12 kg (rounded from 332.122 kg) 8) 84 m/s x 31.221 s = 2600 m (rounded from 2622.564 m) www.chemfiesta.com © 2008 Cavalcade Publishing; All Rights reserved Scientific Notation Worksheet Convert the following numbers into scientific notation: 1) 3,400 _______________________________ 2) 0.000023 _______________________________ 3) 101,000 _______________________________ 4) 0.010 _______________________________ 5) 45.01 _______________________________ 6) 1,000,000 _______________________________ 7) 0.00671 _______________________________ 8) 4.50 _______________________________ Convert the following numbers into standard notation: 9) 2.30 x 104 _______________________________ 10) 1.76 x 10-3 _______________________________ 11) 1.901 x 10-7 _______________________________ 12) 8.65 x 10-1 _______________________________ 13) 9.11 x 103 _______________________________ 14) 5.40 x 101 _______________________________ 15) 1.76 x 100 _______________________________ 16) 7.4 x 10-5 _______________________________ For chemistry help, visit www.chemfiesta.com © 2003 Cavalcade Publishing – All Rights Reserved Scientific Notation Worksheet - Solutions Convert the following numbers into scientific notation: 1) 3,400 3.4 x 103 2) 0.000023 2.3 x 10-5 3) 101,000 1.01 x 105 4) 0.010 1.0 x 10-2 5) 45.01 4.501 x 101 6) 1,000,000 1 x 106 7) 0.00671 6.71 x 10-3 8) 4.50 4.50 x 100 Convert the following numbers into standard notation: 9) 2.30 x 104 23,000 10) 1.76 x 10-3 0.00176 11) 1.901 x 10-7 0.0000001901 12) 8.65 x 10-1 0.865 13) 9.11 x 103 9,110 14) 5.40 x 101 54.0 15) 1.76 x 100 1.76 16) 7.4 x 10-5 0.000074 For chemistry help, visit www.chemfiesta.com © 2003 Cavalcade Publishing – All Rights Reserved Electron Configuration Practice Worksheet In the space below, write the unabbreviated electron configurations of the following elements: 1) sodium ________________________________________________ 2) iron ________________________________________________ 3) bromine ________________________________________________ 4) barium ________________________________________________ 5) neptunium ________________________________________________ In the space below, write the abbreviated electron configurations of the following elements: 6) cobalt ________________________________________________ 7) silver ________________________________________________ 8) tellurium ________________________________________________ 9) radium ________________________________________________ 10) lawrencium ________________________________________________ Determine what elements are denoted by the following electron configurations: 11) 1s22s22p63s23p4 ____________________ 12) 1s22s22p63s23p64s23d104p65s1 ____________________ 13) [Kr] 5s24d105p3 ____________________ 14) [Xe] 6s24f145d6 ____________________ 15) [Rn] 7s25f11 ____________________ Determine which of the following electron configurations are not valid: 16) 1s22s22p63s23p64s24d104p5 ____________________ 17) 1s22s22p63s33d5 ____________________ 18) [Ra] 7s25f8 ____________________ 19) [Kr] 5s24d105p5 ____________________ 20) [Xe] ____________________ Need homework help? Visit www.chemfiesta.com ! Need homework help? Visit www.chemfiesta.com ! Electron Configurations - Solutions Note: The electron configurations in this worksheet assume that lanthanum (La) is the first element in the 4f block and that actinium (Ac) is the first element in the 5f block. If your periodic table doesn’t agree with this, your answers for elements near the f-orbitals may be slightly different. 1) sodium 1s22s22p63s1 2) iron 1s22s22p63s23p64s23d6 3) bromine 1s22s22p63s23p64s23d104p5 4) barium 1s22s22p63s23p64s23d104p65s24d105p66s2 5) neptunium 1s22s22p63s23p64s23d104p65s24d105p66s24f145d106p67s25f5 6) cobalt [Ar] 4s23d7 7) silver [Kr] 5s24d9 8) tellurium [Kr] 5s24d105p4 9) radium [Rn] 7s2 10) lawrencium [Rn] 7s25f146d1 11) 1s22s22p63s23p4 sulfur 12) 1s22s22p63s23p64s23d104p65s1 rubidium 13) [Kr] 5s24d105p3 antimony 14) [Xe] 6s24f145d6 osmium 15) [Rn] 7s25f11 einsteinium 16) 1s22s22p63s23p64s24d104p5 not valid (take a look at “4d”) 17) 1s22s22p63s33d5 not valid (3p comes after 3s) 18) [Ra] 7s25f8 not valid (radium isn’t a noble gas) 19) [Kr] 5s24d105p5 valid 20) [Xe] not valid (an element can’t be its own electron configuration) Need homework help? Visit www.chemfiesta.com ! Protons, Neutrons, and Electrons Practice Worksheet Fill in the blanks in the following worksheet. Please keep in mind that the isotope represented by each space may NOT be the most common isotope or the one closest in atomic mass to the value on the periodic table. Atomic symbol Atomic number Protons Neutrons Electrons B Atomic mass 6 11 24 31 37 39 29 89 35 43 100 207 Pb 102 89 Mo 70 225 53 81 100 206 159 No Yb 261 172 106 http://www.chemfiesta.com 159 Solutions for the Protons, Neutrons, and Electrons Practice Worksheet: Atomic symbol Atomic number B Na Ga Y Cu Tc Pb Yb Ac Mo Tl Fm No Yb Sg 5 11 31 39 29 43 82 70 89 42 81 100 102 70 106 http://www.chemfiesta.com Protons Neutrons Electrons 5 11 31 39 29 43 82 70 89 42 81 100 102 70 106 6 13 37 50 35 57 125 102 136 53 125 159 159 101 159 5 11 31 39 29 43 82 70 89 42 81 100 102 70 106 Atomic mass 11 24 68 89 64 100 207 172 225 95 206 259 261 172 265 CHEMISTRY REVIEW WORKSHEET 1. The atomic number of an element is __________________________? Does this number ever change for atoms of the same element? 2. The atomic mass number of an element is ___________________________? If this number changes for an atom of a specific element you have an (ion, isotope) ___________________? Has the number of protons or neutrons changed? 3. When an element exists in nature by itself, it must have a charge of ________? When that charge changes to become either plus or minus, you have changed the number of ___________________? If the charge becomes minus, you have (more or less) ____________ electrons than protons? 4. An atom has 7 protons, 7 electrons, and 8 neutrons. Fill in the blanks below for this atom: Atomic Number _______ Atomic mass: _______ Charge: ________ This atom belongs to which element? 5. An ion of oxygen has a charge of –2. How many protons and electrons does the ion have? Protons ______________ Electrons ______________ 6. An ion of potassium has a charge of +1. How many protons and electrons does this ion have? Protons ______________ Electrons ______________ 7. The mineral fluorite is made of fluorine and calcium. Use the periodic table of the elements to determine what charge each of these elements will take in order to form a compound. Charge on fluorine _________ Charge on calcium __________ Using this information, write a chemical formula for the compound, which makes up fluorite: 8. The element oxygen will always take a charge of –2 in naturally occurring rocks and minerals. The chemical formula for the compound, which makes up the mineral quartz, is SiO2. What is the charge of silicon in this compound? 9. An atom has 6 protons, 7 neutrons, and 6 electrons. Fill in the blanks below for this atom: Atomic number _____ Atomic mass number _____ Charge ______ This atom belongs to which element? 10. A calcium ion has a charge of +2. How many protons and electrons does it have? Protons ______________ Electrons ______________ Molar Mass Practice Worksheet Find the molar masses of the following compounds: 1) NaBr 2) PbSO4 3) Ca(OH)2 4) Na3PO4 5) (NH4)2CO3 6) C6H12O6 7) Fe3(PO4)2 8) (NH4)2S 9) Zn(C2H3O2)2 10) AgF http://www.chemfiesta.com Solutions to the Molar Mass Practice Worksheet: Important note to students: All of the units given here are “grams per mole”, which may be abbreviated as “g/mol”, “grams/mol”, or “g . mol-1”, depending on how your teacher likes to see it written. They all mean the same thing, but it’s probably a good idea to use whatever your teacher showed you in class. Also, remember that if you don’t use units in your answer, the answer is wrong! All answers are rounded to the nearest 0.1 grams. 1) 2) 3) 4) 5) 6) 7) 8) 9) 10) 102.9 g/mol 303.3 g/mol 74.1 g/mol 164.0 g/mol 96.0 g/mol 180.0 g/mol 357.4 g/mol 68.1 g/mol 183.4 g/mol 126.9 g/mol http://www.chemfiesta.com Balancing Equations Practice Worksheet Balance the following equations: 1) ___ NaNO3 + ___ PbO ! ___ Pb(NO3)2 + ___ Na2O 2) ___ AgI + ___ Fe2(CO3)3 ! ___ FeI3 + ___ Ag2CO3 3) ___ C2H4O2 + ___ O2 ! ___ CO2 + ___ H2O 4) ___ ZnSO4 + ___ Li2CO3 ! ___ ZnCO3 + ___ Li2SO4 5) ___ V2O5 + ___ CaS ! ___ CaO + ___ V2S5 6) ___ Mn(NO2)2 + ___ BeCl2 ! ___ Be(NO2)2 + ___ MnCl2 7) ___ AgBr + ___ GaPO4 ! ___ Ag3PO4 + ___ GaBr3 8) ___ H2SO4 + ___ B(OH)3 ! __ B2(SO4)3 + ___ H2O 9) ___ S8 + ___ O2 ! ___ SO2 10) ___ Fe + ___ AgNO3 ! ___ Fe(NO3)2 + ___ Ag http://www.chemfiesta.com Solutions for the Balancing Equations Practice Worksheet 1) 2 NaNO3 + PbO ! Pb(NO3)2 + Na2O 2) 6 AgI + Fe2(CO3)3 ! 2 FeI3 + 3 Ag2CO3 3) C2H4O2 + 2 O2 ! 2 CO2 + 2 H2O 4) ZnSO4 + Li2CO3 ! ZnCO3 + Li2SO4 5) V2O5 + 5 CaS ! 5 CaO + V2S5 6) Mn(NO2)2 + BeCl2 ! Be(NO2)2 + MnCl2 7) 3 AgBr + GaPO4 ! Ag3PO4 + GaBr3 8) 3 H2SO4 + 2 B(OH)3 ! B2(SO4)3 + 6 H2O 9) S8 + 8 O2 ! 8 SO2 10) Fe + 2 AgNO3 ! Fe(NO3)2 + 2 Ag http://www.chemfiesta.com Fun With Predicting Reaction Products Predict the products of each of the following chemical reactions. If a reaction will not occur, explain why not: 1) ____ Ag2SO4 + ____ NaNO3 ! 2) ____ NaI + ____ CaSO4 ! 3) ____ HNO3 + ____ Ca(OH)2 ! 4) ____ CaCO3 ! 5) ____ AlCl3 + ____ (NH4)PO4 ! 6) ____ Pb + ____ Fe(NO3)3 ! 7) ____ C3H6 + ____ O2 ! 8) ____ Na + ____ CaSO4 ! Fun With Predicting Reaction Products – Answers Predict the products of each of the following chemical reactions. If a reaction will not occur, explain why not: Before moving on, here are some general rules of thumb for how to figure out what will be made (and if the reaction will occur at all): 1) If something that has carbon and hydrogen reacts with oxygen, it’s probably a combustion reaction. The products will be CO2 and H2O. 2) If two elements or very simple molecules combine with each other, it’s probably a synthesis reaction. The products will probably be predictable using the octet rule to find charges. 3) If one compound has an arrow coming off of it, it’s probably a decomposition reaction. The products will either be a couple of very simple molecules, or some elements, or both. 4) If a pure element reacts with another compound (usually, but not always, ionic), it’s probably a single displacement reaction. The products will be the compounds formed when the pure element switches places with another element in the other compound. Important note: these reactions will only occur if the pure element on the reactant side of the equation is higher on the activity series than the element it replaces. • 5) • 6) If two ionic compounds combine, it’s probably a double displacement reaction. Switch the cations and balance out the charges to figure out what will be made. Important note: These reactions will only occur if both reactants are soluble in water and only one product is soluble in water. If an acid and a base combine, it’s an acid-base reaction. The products will be an ionic compound and water. On the next page are explanations of how this works in sample problems: 1) ____ Ag2SO4 + ____ NaNO3 ! no reaction! Examining this reaction, it appears that a double displacement reaction will occur. This would lead to the conclusion that the products would be AgNO3 and Na2SO4. However, for this reaction to occur, both reactants and only one of the products must be soluble in water. If you look up the solubilities on a chart, you’ll find that Ag2SO3 is partly soluble in water, and all of the other compounds are totally soluble in water. This tells us that this reaction will not occur. 2) ____ NaI + ____ CaSO4 ! no reaction! Another double displacement reaction, this time with Na2SO4 and CaI2 as products. Because both products are soluble in water and CaSO4 is only partially soluble in water, the conditions for a successful double displacement reaction are not met. 3) 2 HNO3 + 1 Ca(OH)2 ! 1 Ca(NO3)2 + 2 H2O It’s an acid-base reaction, and acid-base reactions occur readily whether or not the reactants are both soluble in water. 4) 1 CaCO3 ! 1 CaO + 1 CO2 It’s a decomposition reaction. If you didn’t guess that these were the products, you should have at least known that it was a decomposition reaction and predicted that this would have broken into its constituent elements, Ca, C, and O2. 5) 1 AlCl3(aq) + 1 (NH4)3PO4(aq) ! AlPO4(s) + 3 NH4Cl(aq) This is a double displacement reaction, except in this case both of the reactants and only one product are soluble in water. Because the conditions for a successful reaction are met, the reaction does occur! 6) ____ Pb + ____ Fe(NO3)3 ! no reaction! Though this is a single displacement reaction, lead is lower on the activity series than the iron it would replace. As a result, this reaction does not occur. 7) 2 C3H6 + 9 O2 ! 6 CO2 + 6 H2O The reactants suggest that this is a combustion reaction, meaning that the products must be carbon dioxide and water. Once you figure this out, the only thing left to do is balance it, as shown. 8) 2 Na + 1 CaSO4 ! 1 Na2SO4 + 1 Ca This should clearly be a single displacement reaction. Because sodium is higher on the activity series than calcium, this reaction does occur. Mole Calculation Practice Worksheet Answer the following questions: 1) How many moles are in 25 grams of water? 2) How many grams are in 4.5 moles of Li2O? 3) How many molecules are in 23 moles of oxygen? 4) How many moles are in 3.4 x 1023 molecules of H2SO4? 5) How many molecules are in 25 grams of NH3? 6) How many grams are in 8.2 x 1022 molecules of N2I6? http://www.chemfiesta.com http://www.chemfiesta.com Solutions for the mole calculation practice worksheet: 1) 2) 3) 4) 5) 6) 1.39 moles 134.1 grams 1.38 x 1025 molecules 0.56 moles 8.85 x 1023 molecules 106.7 grams http://www.chemfiesta.com Percent Composition Worksheet Find the percent compositions of all of the elements in the following compounds: 1) CuBr2 Cu: ___________ Br: ___________ 2) NaOH Na: ___________ O: ___________ H: ___________ 3) (NH4)2S N: ___________ H: ___________ S: ___________ 4) N2S2 N: ___________ S: ___________ For chemistry help, visit www.chemfiesta.com © 2002 Cavalcade Publishing – All Rights Reserved Percent Composition Worksheet - Solutions Find the percent compositions of all of the elements in the following compounds: 1) CuBr2 Cu: 28.4% Br: 71.6% 2) NaOH Na: 57.5% O: 40.0% H: 2.5% 3) (NH4)2S N: 41.1% H: 11.8% S: 47.1% 4) N2S2 N: 30.4% S: 69.6% For chemistry help, visit www.chemfiesta.com © 2002 Cavalcade Publishing – All Rights Reserved Percent Yield Calculations 1) Balance this equation and state which of the six types of reaction is taking place: ____ Mg + ____ HNO3 ! ____ Mg(NO3)2 + ____ H2 Type of reaction: __________________________ 2) If I start this reaction with 40 grams of magnesium and an excess of nitric acid, how many grams of hydrogen gas will I produce? 3) If 1.7 grams of hydrogen is actually produced, what was my percent yield of hydrogen? 4) Balance this equation and state what type of reaction is taking place: ____ NaHCO3 ! ____ NaOH + ____ CO2 Type of reaction: __________________________ 5) If 25 grams of carbon dioxide gas is produced in this reaction, how many grams of sodium hydroxide should be produced? 6) If 50 grams of sodium hydroxide are actually produced, what was my percent yield? For chemistry help, visit www.chemfiesta.com © 2007 Cavalcade Publishing, All Rights Reserved Percent Yield Calculation Answers 1) Balance this equation and state which of the six types of reaction is taking place: 1 Mg + 2 HNO3 ! 1 Mg(NO3)2 + 1 H2 Type of reaction: single displacement 2) If I start this reaction with 40 grams of magnesium and an excess of nitric acid, how many grams of hydrogen gas will I produce? • 3.3 grams (when Mg atomic mass = 24.3 grams) 3) If 1.7 grams of hydrogen is actually produced, what was my percent yield of hydrogen? • 52% 4) Balance this equation and state what type of reaction is taking place: 1 NaHCO3 ! 1 NaOH + 1 CO2 Type of reaction: decomposition 5) If 25 grams of carbon dioxide gas is produced in this reaction, how many grams of sodium hydroxide should be produced? 22.7 grams NaOH 6) If 50 grams of sodium hydroxide are actually produced, what was my percent yield? 50/22.7 x 100% = 220% Hopefully, you understand that this is not a reasonable answer to this question and indicates that something very wrong happened during this reaction. For chemistry help, visit www.chemfiesta.com © 2007 Cavalcade Publishing, All Rights Reserved Stoichiometry Review – Ch. 9 **YOUR ANSWERS MUST INCLUDE THE PROPER NUMBER OF SIG FIGS AND COMPLETE UNITS IN ORDER TO RECEIVE CREDIT FOR THE PROBLEM.** BALANCE THE FOLLOWING EQUATIONS TO USE IN QUESTIONS 5 – 14: 1. ____ Al + ____ O2 → ____ Al2O3 2. ____ Cu + ____ AgNO3 → ____ Ag + ____ Cu(NO3)2 3. ____ Zn + ____ HCl → ____ ZnCl2 + ____ H2 4. ____ Fe + ____ Cl2 → ____ FeCl3 PERFORM THE FOLLOWING STOICHIOMETRIC CALCULATIONS: 5. Zinc reacts with hydrochloric acid to produce zinc chloride and hydrogen. How many moles of HCl are required to produce 7.50 moles of ZnCl2? 6. Copper metal reacts with silver nitrate to form silver and copper(II) nitrate. How many grams of copper are required to form 250 g of silver? 7. When aluminum is burned in excess oxygen, aluminum oxide is produced. How many grams of oxygen are required to produce 0.75 moles of Al2O3? 8. How many grams of iron(III) chloride are produced when 15.3 g of iron react with excess chlorine gas? 9. Copper metal reacts with silver nitrate to form silver and copper(II) nitrate. How many moles of silver will be produced from 3.65 moles of silver nitrate? 10. Zinc reacts with hydrochloric acid to produce zinc chloride and hydrogen gas. How many milliters of 3.00M HCl are required to react with 12.35 g of zinc? 11. How many grams of iron are needed to react with 31.0 L of chlorine gas at STP to produce iron(III) chloride? 12. When 9.34 g of zinc react with excess hydrochloric acid how many grams of zinc chloride will be produced? 13. How many liters of oxygen gas at STP are required to react with 65.3 g of aluminum in the production of aluminum oxide? 14. Copper reacts with silver nitrate to form silver and copper(II) nitrate. How many grams of copper are required to react with 50.0 mL of 8.0M AgNO3? 15. Nickel nitrate and potassium carbonate react to form nickel carbonate and potassium nitrate. How many milliliters of 0.55M Ni(NO3)2 are needed to react with 85 mL of 0.25M K2CO3? First, write a balanced equation. C. Johannesson 16. Zinc metal reacts with chromium(III) nitrate in a single replacement reaction. How many grams of zinc are required to react with 425 mL of 0.25M Cr(NO3)3? First, write a balanced equation. PERFORM THE FOLLOWING LIMITING REACTANT PROBLEMS: 17. When 16.3 g of magnesium and 4.52 g of oxygen gas react, how many grams of magnesium oxide will be formed? Identify the limiting and excess reactants. 2 Mg + O2 → 2 MgO 18. If 25.3 g of aluminum reacts with 25.3 g of copper(II) sulfate, how many grams of copper are formed? Identify the limiting and excess reactants in this single replacement reaction. 2 Al + 3 CuSO4 → 3 Cu + Al2(SO4)3 19. Identify the limiting and excess reactants when 1.00 g of zinc reacts with 150 mL of 0.250M Pb(NO3)2. How many grams of lead are formed in this single replacement reaction? Zn + Pb(NO3)2 → Pb + Zn(NO3)2 20. If 24.5 g of iron are placed in 1.00 L of 0.25M HCl, how many grams of FeCl2 are obtained? Identify the limiting and excess reactants in this single replacement reaction. Fe + 2 HCl → FeCl2 + H2 PERFORM THE FOLLOWING PERCENT YIELD CALCULATIONS: 21. If 12.5 g of copper react with excess chlorine gas, then 25.4 g of copper(II) chloride are produced. Find the theoretical and percent yields. Cu + Cl2 → CuCl2 22. If 6.57 g of iron react with an excess of hydrochloric acid, HCl, then 11.2 g of iron(II) chloride are obtained in addition to hydrogen gas. Find the theoretical and percent yields. Fe + 2 HCl → FeCl2 + H2 23. If 5.45 g of potassium chlorate are decomposed to form potassium chloride, 1.75 g of oxygen gas are also given off. Find the theoretical and percent yields. 2 KClO3 → 2 KCl + 3 O2 C. Johannesson Stoichiometry Review – Ch. 9 ANSWER KEY BALANCED EQUATIONS 1. 4 Al + 3 O2 → 2 Al2O3 2. Cu + 2 AgNO3 → 2 Ag + Cu(NO3)2 3. Zn + 2 HCl → ZnCl2 + H2 4. 2 Fe + 3 Cl2 → 2 FeCl3 STOICHIOMETRIC CALCULATIONS 5. 15.0 mol HCl 6. 74 g Cu 7. 36 g O2 8. 44.4 g FeCl3 9. 3.65 mol Ag 10. 126 mL HCl 11. 51.5 g Fe 12. 19.5 g ZnCl2 13. 40.7 L O2 14. 13 g Cu 15. Ni(NO3)2 + K2CO3 → NiCO3 + 2 KNO3, 39 mL Ni(NO3)2 16. 3 Zn + 2 Cr(NO3)3 → 3 Zn(NO3)2 + 2 Cr, 10. g Zn LIMITING REACTANT 17. LR: O2 XS: Mg Product: 11.4 g MgO 18. LR: CuSO4 XS: Al Product: 10.0 g Cu 19. LR: Zn XS: Pb(NO3)2 Product: 3.17 g Pb 20. LR: HCl XS: Fe Product: 16 g FeCl2 PERCENT YIELD 21. Theoretical: 26.4 g CuCl2 Percent Yield: 96.2% 22. Theoretical: 14.9 g FeCl2 Percent Yield: 75.1% 23. Theoretical: 2.13 g O2 Percent Yield: 82.2% C. Johannesson Word Equations Worksheet Write the word equations for each of the following chemical reactions: 1) When dissolved beryllium chloride reacts with dissolved silver nitrate in water, aqueous beryllium nitrate and silver chloride powder are made. 2) When isopropanol (C3H8O) burns in oxygen, carbon dioxide, water, and heat are produced. 3) When dissolved sodium hydroxide reacts with sulfuric acid (H2SO4), aqueous sodium sulfate, water, and heat are formed. 4) When fluorine gas is put into contact with calcium metal at high temperatures, calcium fluoride powder is created in an exothermic reaction. 5) When sodium metal reacts with iron (II) chloride, iron metal and sodium chloride are formed. For chemistry help, visit www.chemfiesta.com © 2002 Cavalcade Publishing, All Rights Reserved Word Equations Worksheet - Solutions Write the word equations for each of the following chemical reactions: 1) When dissolved beryllium chloride reacts with dissolved silver nitrate in water, aqueous beryllium nitrate and silver chloride powder are made. BeCl2(aq) + 2 AgNO3(aq) ! Be(NO3)2(aq) + 2 AgCl(s) 2) When isopropanol (C3H8O) burns in oxygen, carbon dioxide, water, and heat are produced. 2 C3H8O(l) + 9 O2(g) ! 6 CO2(g) + 8 H2O(g) ΔH = negative 3) When dissolved sodium hydroxide reacts with sulfuric acid, aqueous sodium sulfate, water, and heat are formed. 2 NaOH(aq) + H2SO4(l) ! Na2SO4 + 2 H2O(l) ΔH = negative 4) When fluorine gas is put into contact with calcium metal at high temperatures, calcium fluoride powder is created in an exothermic reaction. Δ F2(g) + Ca(s) ! CaF2(s) ΔH = negative 5) When sodium metal reacts with iron (II) chloride, iron metal and sodium chloride are formed. 2 Na(s) + FeCl2(s) ! 2 NaCl(s) + Fe(s) For chemistry help, visit www.chemfiesta.com © 2002 Cavalcade Publishing, All Rights Reserved