Vacuum Gas Oil
Safety Data Sheet
Axeon Specialty Products
400 Grove Road
West Deptford, NJ 08066
MSDS No.
Revision Date
07-201
3-24-14
HAZARD RANKING
IMPORTANT: This MSDS is prepared in accordance with 29 CFR 1910.1200. Read this
MSDS before transporting, handling, storing or disposing of this product and forward this
information to employees, customers and users of this product.
Health Hazard
EMERGENCY OVERVIEW
HMIS NFPA
0
0
Fire Hazard
1
1
Reactivity
0
0
WARNING: Avoid repeated or prolonged skin contact.
This product is a mixture of hydrocarbons and may contain significant
amounts of polynuclear aromatic hydrocarbons which have been shown
to cause skin cancer after prolonged or frequent contact with the skin of
test animals. It must be assumed that cancer could also occur in
humans after repeated or prolonged skin contact, thus users must use
the appropriate skin protection when handling this product to reduce
exposure to a minimum. The International Agency for Research on
Cancer (IARC) has determined that there is sufficient evidence that
heavy vacuum distillates derived from refining crude oil cause cancer in
laboratory animals.
Protective Equipment
Minimum Recommended
See Section 8 for Details
This recommendation reflects
minimum PPE when product is at
elevated temperatures
SECTION 1. PRODUCTION IDENTIFICATION
Trade Name
Vacuum Gas Oil
Commodity Code
07-201
CAS Number
68955-27-1
Product Family
Petroleum Hydrocarbons
Technical Contact
24-Hour Contact
(856) 224-7409
(856) 224-7415
CHEMTREC EMERGENCY
U.S. and Canada only
Outside U.S and Canada
(800) 424-9300
(703) 527-3887
Synonyms: Vacuum Distillates, VGO, Cat Feed
SECTION 2. COMPOSITION
Component Name(s)
CAS Registry No.
(%)
Hazard Data
Vacuum Distillates*
68955-27-1
100
Oral LD50(rat): >5g/kg*
Drml LD50(rbt): >5g/kg*
Eyes, Draize (rbt): 0-0.33*/110 in 24 hr test.
*For similar product.
MSDS No. 07-201 (CIN #: 1473)
Revision Date: 3-24-14
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*A complex combination of hydrocarbons produced by the vacuum distillation of the residuum from the atmospheric distillation of crude
oil.
SECTION 3. HAZARD IDENTIFICATION
No
Carcinogen
Yes Animal Carcinogen*
No
Suspect Carcinogen
No
Mutagen
No
Highly Toxic
No
Toxic
Product Listed as Carcinogen or Potential Carcinogen by:
NTP: No
IARC: Yes*
*For Similar material
No
No
No
No
No
Corrosive
Irritant
Sensitizer
Teratogen
Target Organs
OSHA: No
Other: No
Also see Emergency Overview and Hazard Ratings on the top of Page 1 of this MSDS.
Physical State
Liquid
Mayor Route(s) Dermal contact. Eye contact. Inhalation. Ingestion.
of Entry
Eye Contact
Skin Contact
The eye irritation potential of this product has not been determined. However, based upon the
toxicology of similar products this product is not expected to cause prolonged or significant eye
irritation.
The dermal toxicity of this product has not been determined. However, based upon the
toxicology of similar products this product is not expected to cause prolonged or significant skin
irritation, but may produce mild transient skin irritation. It may be moderately toxic to internal
organs if it is absorbed through the skin. The severity of injury will depend on the amount
absorbed.
Inhalation
The inhalation toxicity of this product has not been determined. However, based on the toxicology of
similar products, breathing of fumes may cause central nervous system (CNS) effects and be
moderately toxic to internal organs. Signs and symptoms of CNS effects include one or more of the
following: dizziness, headache, loss of appetite, weakness and loss of coordination. This product
may also cause respiratory irritation and chemical pneumonitis when inhaled. Signs and symptoms
of respiratory irritation and pneumonitis may include coughing, shortness of breath, bronchial
irritation, chest discomfort and diminished pulmonary function.
Ingestion
The oral toxicity of this product has not been determined. However, based on the toxicology of similar
products, this product may be slightly toxic to internal organs if swallowed. The severity of injury will
depend upon the amount absorbed from the gut. Typical signs and symptoms from ingestion include
gastro-intestinal disturbances, vomiting and diarrhea, headache, and tiredness. This product may
present a moderate aspiration hazard.
MSDS No. 07-201 (CIN #: 1473)
Revision Date: 3-24-14
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Signs and
Symptoms of
Chronic
Exposure
Inhalation:
The prolonged or repeated inhalation exposure may cause cancer and chemical
pneumonitis.
Skin Contact: Prolonged or repeated exposure may cause skin cancer. Repeated and
prolonged exposure may also cause drying, cracking, dermatitis, or folliculitis.
Eye Contact: Symptoms of chronic eye contact are believed to be similar to those discussed
above.
Ingestion:
Symptoms of chronic ingestion are believed to be similar to those discussed
above.
SECTION 4. FIRST AID MEASURES
Take proper precautions to ensure your own health and safety before attempting rescue or providing first aid.
For more specific information, refer to Exposure Controls and Personal Protection in Section 8 of this MSDS.
Inhalation
Remove individual to fresh air immediately. Do not attempt to rescue the victim unless proper
respiratory protection is worn. Seek medical attention if symptoms continue.
Eye Contact
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting upper and
lower eyelids. Remove contact lenses if worn. Seek medical attention if irritation persists.
Skin Contact
Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap
and water. If irritation develops, consult a physician. Contaminated clothing should be promptly
laundered before reuse. Contaminated leather goods should be discarded.
Ingestion
This product may be harmful or fatal if swallowed. This product may cause nausea, vomiting,
diarrhea, and restlessness. DO NOT INDUCE VOMITING. Aspiration into the lungs can cause
severe chemical pneumonitis or pulmonary edema/hemorrhage, which can be fatal. If swallowed
give milk or water to drink and telephone for medical advice. If medical advice cannot be obtained,
take the victim to the closest medical emergency center or hospital.
Notes to
Physician
Dilute with milk, water or demulcents and remove by lavage to extent possible. The Saybolt
viscosity of this material is approximately 350 SUS at 100°F, thus aspiration into the lungs following
ingestion is unlikely to occur. Remove all residues as this product contains potential human
carcinogens.
Aggravated by
Exposure
Individuals with chronic skin or respiratory problems may have these conditions aggravated by
exposure to this product.
SECTION 5. FIRE FIGHTING MEASURES
Clear Fire Area of all Non-emergency Personnel
Flash Point,
Lower Flammable Limit
>150°C (>300°F)
No data.
COC
Auto-ignition
Upper Flammable Limit
Not available
No data.
Temperature
CO2, Dry Chemical, Foam
Extinguishing
Media
Special
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus
Protective
(SCBA) with a full face-piece operated in positive pressure mode when in confined area. Avoid
MSDS No. 07-201 (CIN #: 1473)
Revision Date: 3-24-14
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Equipment for
Fire Fighters
Special
Remarks on
Fire Hazards
inhalation of fumes.
Water or foam may cause frothing.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Take proper precautions to ensure your own health and safety before attempting spill control or clean up. For more specific information, refer to the Emergency Overview on Page 1, Exposure Controls and
Personal Protection in Section 8 and Disposal Considerations in Section 11 of this MSDS.
For small liquid spills (< 1 drum), transfer by mechanical means to a labeled, sealable
container for product recovery or safe disposal. Allow residues to evaporate or soak up with an
appropriate absorbent material and dispose of safely. Remove contaminated soil and dispose
of safely.
Clean Up
Methods
Additional
Advice
For large spills (> 1 drum), transfer by mechanical means to a labeled container such as
vacuum truck to a salvage tank for recovery or safe disposal. Do not flush away residues with
water. Retain as contaminated waste. Allow residues to evaporate or soak up with an
appropriate absorbent material ad dispose of safely. Remove contaminated soil and dispose of
safely. Control ignition sources in the area of the spill.
It is the responsibility of the user to determine if the material is a hazardous waste at the time
of disposal. Check prior to disposing to ensure compliance will all applicable laws and
regulations
RCRA Hotline Number: 800-424-9346
SECTION 7. HANDLING AND STORAGE
Material is classified as a NFPA Class III B combustible liquid. Store distant from fire and ignition
sources.
Storage
Consult appropriate Federal, State and Local authorities before reusing, reconditioning, reclaiming,
recycling or disposing of empty containers and/or waste residues of this product.
SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
Occupational Exposure Guidelines
Substance
Oils, mist
OSHA PEL
Applicable Workplace Exposure Levels
TWA: 5 mg/m
3
3
3
3
3
ACGIH TLV
TWA: 5 mg/m ; STEL 10 mg/m 15-min max (Max 4 STEL/day; separated
by 60-min)
NIOSH REL
TWA: 5 mg/m ; STEL 10 mg/m
Exposure
Controls
The level of protection and types of controls necessary will vary depending upon potential exposure
conditions. Select controls based on a risk assessment of local circumstances.
Appropriate
Measures
Ventilation: As required to maintain personnel exposure below workplace exposure limits.
MSDS No. 07-201 (CIN #: 1473)
Revision Date: 3-24-14
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Respiratory
Protection
Normally none is required. However, if high vapor pressure concentrations or mists are expected,
use only NIOSH/MSHA approved organic respirator self-contained breathing apparatus.
Eye
Use Chemical Splash goggles if splashing is anticipated.
Skin
Body covering protection should be worn when handling liquid. Use protective covering and gloves
made of Buna-N and Poly-D.
Personal Protection in Case of a Large Spill
Respiratory
Protection
Personal Protective Equipment
If garments become soaked with hydrocarbon liquids, they must be immediately changed. Shower
with soap and water to remove hydrocarbon residues from the skin. Wash exposed skin with soap
and water to remove residues. Material is potential carcinogen.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES (TYPICAL)
No
No
No
Combustible
Compressed Gas
Explosive
No
No
No
Flammable
Organic Peroxide
Oxidizer
No Pyrophoric
No Reactivity
Yes Stable
Physical State
Liquid
Specific Gravity (60/60°F)
Appearance
Straw colored to dark brown Water Solubility
Odor
Petroleum odor
Evaporation Rate
NA
Boiling Point (760 mmHg)
>249°C (>480°F) (wide
range)
Vapor Pressure, mmHg,
25°C
<0.01 (mmHg, 15°C)
Molecular Weight
ND
Percent Volatile by Volume
None
Vapor Density
>1 (Air = 1)
Melting Point
ND
Flash Point, COC, °C(°F)
Flash Point, PM, °C(°F)
Fire Point, COC, °C(°F)
Flammable Limits (% by volume in air)
Auto-ignition Temperature, °C(°F)
Flammability Class
Extinguishing Media
Special Fire Fighting Procedure
0.91-0.93 (H2O = 1)
Not soluble
>149 (>300)
ND
ND
Lower: NA Upper: NA
~370 (~700)
IIIB
CO2, dry chemical, foam
Wear self-contained breathing apparatus when in a
confined area. Avoid inhalation of fumes. Water or foam
may cause frothing.
Water may be ineffective.
Unusual Fire or Explosion Hazard
SECTION 10. STABILITY AND REACTIVITY
MSDS No. 07-201 (CIN #: 1473)
Revision Date: 3-24-14
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Stability
This material is stable under normal conditions. Hazardous polymerization will not occur.
Conditions to
Avoid
Materials to
Avoid
Hazardous
Decomposition
Avoid heat, sparks, open flames and excessive heat.
Strong oxidizers
May release hydrogen sulfide gas when agitated. Overheating or incomplete combustion may
result in carbon dioxide, carbon monoxide, acrid fumes of decomposition and oxides of sulfur.
Thermal decomposition is highly dependent on conditions. A complex mixture of airborne
solids, liquids and gases including carbon monoxide, carbon dioxide, sulfur oxides, and
unidentified organic compounds will be evolved when this material undergoes combustion or
thermal or oxidative degradation.
SECTION 11. DISPOSAL CONSIDERATIONS
Waste Disposal
Material Disposal
The generation of waste should be avoided or minimized wherever possible. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains, and
sewers. Disposal of this product, solutions and any by-products should at all times
comply with the requirements of federal, provincial and local regulations.
Recover or recycle if possible. It is the responsibility of the waste generator to determine
the toxicity and physical properties of the material generated to determine the proper
waste classification and disposal methods in compliance with applicable regulations. Do
not dispose into the environment, in drains, or in water courses. Waste product should
not be allowed to contaminate soil or water.
SECTION 12. TRANSPORT INFORMATION
The shipping description below may not represent requirements for all modes of transportation, shipping
methods or locations outside of the United States.
Storage: Material is classified as NFPA Class III B combustible liquid. Store distant from fire and ignition sources
US Department of Transportation Information
Proper Shipping Name: Petroleum Oil, NOS
Hazard Class: Non-hazardous
Hazard Identification Number: NA
DOT Placard: Not required
SECTION 13. ENVIRONMENTAL DATA
US Federal Regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpart D)
Not regulated.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Polycyclic Aromatic Hydrocarbons (CAS 130498-29-2)
US EPCRA (SARA Title III) Section 302 – Extremely Hazardous Spill: Reportable Quantity
Hydrogen Sulfide (CAS 7783-06-4)
100 LBS
US EPCRA (SARA Title III) Section 302 – Extremely Hazardous Substance: Threshold Planning Qty.
Hydrogen Sulfide (CAS 7783-06-4)
500 LBS
US EPCRA (SARA Title III) Section 313 – Toxic Chemical: De minimis concentration
Polycyclic Aromatic Hydrocarbon (CAS 130498-29-2) 0.1% N590 Substance is not eligible for the
de minimis exemption except for the
purposes of supplier notification requirement
US EPCRA (SARA Title III) Section 313 – Toxic Chemical: Reportable Threshold
Polycyclic Aromatic Hydrocarbons (CAS 130498-29-2) 100 LBS N590
US EPCRA (SARA Title III) Section 313 – Toxic Chemical: Listed Substance
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Revision Date: 3-24-14
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Polycyclic Aromatic Hydrocarbons (CAS 130498-29-2) N590 Listed
CERCLA (Superfund) reportable quantity (LBS) (40 CFR 302.4)
Hydrogen Sulfide: 100
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard Categories
Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard – No
Pressure Hazard - No
Reactivity Hazard – No
Section 302 extremely
No
hazardous substance (40
CFR 355, Appendix A)
SECTION 14. OTHER INFORMATION
WARNING: Cancer Suspect Agent
Similar products have been shown to cause cancer in laboratory animals. Avoid
prolonged or repeated skin contact with this material
Label
Requirements
Note:
Skin painting studies of petroleum products of similar compositions and processing
have shown weak carcinogenic activity in laboratory animals. Therefore, in the absence
of good personal hygiene, there may be potential risk of skin cancer from prolonged or
repeated contact. Occasional skin contact with this product is not expected to have
serious side effects. However, good personal hygiene should be practiced and repeated
skin contact limited to avoid the possibility of skin irritation. Personal hygiene measures
taken to prevent skin irritation are expected to be adequate to prevent risk of cancer.
REVISION INFORMATION
Version Number
3.0
Revision Date
3-24-14
ABBREVIATIONS
AP: Approximately EQ: Equal >: Greater Than <: Less Than NA: Not applicable ND: No Data
NE: Not Established
ACGIH: American Conference of Governmental Industrial Hygienists
IARC: International Agency for Research on Cancer
NIOSH: National Institute of Occupational Safety and Health
NFPA: National Fire Protection Association
AIHA: American Industrial Hygiene Association
NTP: National Toxicology Program
OSHA: Occupational Safety and Health Administration
HMIS: Hazardous Materials Information System
EPA: US Environmental Protection Agency
MSDS No. 07-201 (CIN #: 1473)
Revision Date: 3-24-14
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DISCLAIMER OF LIABILITY
VACUUM GAS OIL
ALL STATEMENTS, INFORMATION, AND DATA PROVIDED IN THIS MATERIAL SAFETY DATA SHEET ARE
BELIEVED TO BE ACCURATE AND RELIABLE, BUT ARE PRESENTED WITHOUT GUARANTEE,
REPRESENTATION, WARRANTY, OR RESPONSIBILITY OF ANY KIND, EXPRESSED OR IMPLIED. ANY AND ALL
REPRESENTATIONS AND/OR WARRANTIES OF MERCHANTIBITY OR FITNESS FOR A PARTICULAR PURPOSE
ARE SPECFICALLY DISCLAIMED. USERS SHOULD MAKE THEIR OWN INVESTIGATION TO DETERMINE THE
SUITABILITY OF THE INFORMATION OR PRODUCTS FOR THEIR PARTICULAR PURPOSE. NOTHING
CONTAINED HERIN IS INTENTED AS PERMISSION, INDUCEMENT, OR RECOMMENDATION TO VIOLATE ANY
LAWS OR TO PRACTICE ANY INVENTION COVERED BY EXISTING PATENTS, COPYRIGHTS OR INVENTIONS.
MSDS No. 07-201 (CIN #: 1473)
Revision Date: 3-24-14
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