DRAFT/PROPOSED OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY AIR QUALITY DIVISION MEMORANDUM October 14, 2013 TO: Phillip Fielder, P.E., Permits and Engineering Group Manager, THROUGH: Kendal Stegmann, Senior Environmental Manager, Compliance and Enforcement THROUGH: Phil Martin, P.E., Existing Source Permit Section THROUGH: Peer Review FROM: Ellis Fischer, P.E., Existing Source Permit Section SUBJECT: Evaluation of Permit Application No. 2011-227-TVR2 ONEOK Field Services Company, L.L.C. Maysville Gas Plant Section 18, T4N, R2W, Garvin County Latitude 34.8171º, Longitude -97.4531º Located 2 miles west the intersection of Hwy 74 & Hwy 19 in Maysville SECTION I. INTRODUCTION ONEOK Field Services Company, L.L.C. (OFS) has submitted an application for the second renewal of the Title V permit for their Maysville Gas Plant, which currently operates under Permit No. 2004-163-TVR (M-5) issued on October 8, 2010. The plant is a PSD major source and is classified as a SIC 1321 facility. The facility is a cryogenic natural gas liquids (NGL) extraction plant with a gas processing capacity of 137 MMSCFD. Residue gas is delivered to a sales pipeline after the recovery of NGL. Current plant gas throughput is approximately 135 MMSCFD. The facility was originally constructed in 1948 by Warren Petroleum Company and consisted of 24 internal combustion engines and 5 gas-fired heaters in hot oil, steam generation, and regeneration-gas service. The plant inlet gas contains a small amount of H2S (up to 13.5 ppm), which is removed in amine units and flared in the acid gas flare. From 1985 to 1996, several plant modifications were permitted, in which engines were removed and added, a new cryogenic skid was constructed, and more furnace capacity was installed. The present facility consists of 20 grandfathered and 16 permitted internal combustion engines, 3 cryogenic skids, 5 heaters, 4 boilers, 1 glycol regeneration unit, 1 amine regeneration unit, 1 process/emergency flare, 1 VOC flare, 1 acid gas flare, 54 pressurized product storage tanks, 4 pressurized spheroid tanks, 2 methanol storage tanks, 2 scrubber oil tanks, 1 condensate tank, 1 PERMIT MEMORANDUM 2011-227-TVR2 DRAFT/PROPOSED 2 water/condensate pit tank, 1 gasoline storage tank, 1 Stoddard solvent tank, and miscellaneous smaller tanks. On June 4, 2004, OFS submitted three self-disclosures pertaining to (1) NAAQS for NOX emissions, (2) MAAC for formaldehyde, (3) NESHAP Subpart HH, (4) NSPS Subpart KKK, and (5) general control requirements for flares. The TVR application contained compliance plans to address each of these issues. OFS submitted quarterly progress reports to update the status of compliance during the Part 70 permit application review period, including the notifications required by NESHAP Subpart HH and NSPS Subpart KKK. A compliance plan to bring the facility in compliance with the NAAQS for NOX emissions was submitted to ODEQ and became a part of Consent Order 06-063. Consent Order 06-063 also placed some additional requirements on the facility. The TVR was issued with completion of the NAAQS for NOX compliance plan as a permit specific condition. The facility has made combustion modifications to engines in EUG-1 and in March of 2007 submitted air dispersion modeling which demonstrates compliance with the NAAQS for NOX. For modification (M-1), OFS requested that the procedure for monitoring the amount of H2S combusted in the acid gas flare be revised to allow calculations using either measurement of the amount of H2S concentration and flow of inlet gas streams, or using measurement of the amount of H2S concentration and flow of the total acid gas stream between the amine contactors and the acid gas flare. OFS also requested a change in the data collection procedures for Indicator No. 1, flare flame indicator for the CAM plan for the glycol dehydration unit. These proposed changes were minor and the application was processed under Tier I. For modification (M-2), OFS requested a federally enforceable condition to limit the horsepower for five generators so that they will be exempt from emissions and operating limitations under 40 CFR Part 63 Subpart ZZZZ (RICE MACT). OFS requested that emissions factors for engines in EUG-1 be revised as part of the compliance plan required by Consent Order 06-063 dated April 6, 2006, to demonstrate compliance with the NAAQS for NOX. OFS requested that language be included in the modified permit to clarify applicability of 40 CFR Part 60 Subpart NNN. Prior Permit History for the five 1948 vintage Ingersoll-Rand PKVG-6 engines Permit No. 2004-163-TVR (M-5), issued October 8, 2010 The five generator engines are 1948 vintage Ingersoll-Rand PKVG-6 four-stroke rich-burn engines that are factory rated at 660-hp. While designated as rich-burn engines, the engines run with oxygen exhaust concentrations ranging from near 3% down to 1%. It could be argued that the engines are actually existing lean-burn engines (defined in the RICE MACT as an engine that has 2% oxygen in the exhaust), which would exempt them from the RICE MACT. Also, the exhaust temperatures of the engines are typically less than 600°F and OFS has been unable to find a NSCR catalyst vendor who would guarantee the formaldehyde removal efficiency necessary to be in compliance with the RICE MACT. In addition, the RICE MACT requires compliance with a minimum catalyst inlet temperature of 750°F, which the engines do not obtain. In order to resolve the site specific problems for complying with the RICE MACT for these 50 year old engines, OFS requested and AQD (Permitting, Compliance, and Legal) agreed PERMIT MEMORANDUM 2011-227-TVR2 DRAFT/PROPOSED 3 to allow the source to take federally enforceable limitations on engine horsepower such that the site-rated horsepower would be considered less than 500-hp. This exempted the existing engines from the RICE MACT standards. The limit was enforced by placing a generator output limit of 330-KW on each engine. This power output is equivalent to an engine power output of less than 500-hp when considering the mechanical efficiency and shaft losses for the generator sets. AQD and OFS agreed to issuance of a Consent Order to make these limitations enforceable prior to the RICE MACT compliance date of June 15, 2007. All rich-burn engines with a site-rating less than 500 brake horsepower (C-19, G-1, G-2, G-3, G4, G-5, G-6 and G-7) are subject to emission and operating limitations in Subpart ZZZZ and will be required to comply with the standards by October 19, 2013. OFS now intends to remove generators G-1, G-2, G-3, G-4, and G-5 from service prior to the October 19, 2013 compliance date. OFS has contracted for purchase power to supply back up power when needed. For modification (M-5), OFS requested to: 1. 2. 3. 4. 5. 6. 7. 8. To install a new Western Oklahoma (WOK*) 16” inlet and condensate handling system along with, Installing a high-pressure inlet gas pre-heater in the North Amine System process unit. To install a vapor recovery system as inherent process equipment, which will recover working, breathing, and flashing vapors from the condensate tanks and re-compress the vapors into the inlet, except during downtime. This project increased the actual throughput by approximately 50 MMSCFD. At the time of the previous permit action, the daily was running between 80-90 MMSCFD. The new 16-inch inlet brought daily volumes up to around 115 MMSCFD. Change serial number of C-21 from 306599 to 306559. Renumber engine C-25.3 to C-25. Update Oklahoma Air Pollution Control Rules. Update Federal Regulations. *WOK is an acronym used to identify the Custer and Woodward operating areas as one. A portion of the WOK gas will be routed from the Custer area to Maysville Plant The three existing cryo skids remained unchanged. Therefore, no increase of plant capacity. The WOK 16” inlet and condensate handling process is subject to NSPS Subpart KKK and the North Amine System is currently subject to NSPS Subpart KKK. This application has been classified as Tier II based on the request for the second renewal of the Title V operating permit. SECTION II. PROCESS DESCRIPTION Maysville is a cryogenic natural gas liquids (NGL) extraction plant with a gas processing capacity of 137 MMSCFD. Residue gas is delivered to a sales pipeline after recovery of natural gas liquids (NGL). The facility currently consists of 20 grandfathered and 16 permitted internal combustion engines, three cryogenic process skids, five process heaters, four boilers, one glycol PERMIT MEMORANDUM 2011-227-TVR2 DRAFT/PROPOSED 4 dehydration unit, one amine regeneration unit, one process/emergency flare, one VOC flare, one acid gas flare, 54 pressurized product storage tanks, four pressurized spheroid tanks, two methanol storage tanks, two scrubber oil tanks, one condensate/bottom sediment (BS&W) tanks, one BS&W/condensate pit tank, one gasoline storage tank, one Stoddard solvent tank, and miscellaneous support tanks. Plant inlet wet gas consists of multiple low-pressure (LP) (~5 psig) and HP (~200 psig) streams. Inlet wet gas from the 16” WOK inlet has a pressure of ~700-800 psig. Therefore, the inlet wet gas does not require pre-compression for further processing. With the 16” WOK inlet, the wet gas flows through a HP separator, where condensate and water are removed. The wet gas is directed to the Anadarko HP inlet for further processing. The separated condensate and water flow to the HP condensate flash separator. From there, the condensate is separated from the water and flows to the condensate storage tanks (TK-9, -10, -11, and -12). The produced water flows to the water storage tanks. Flash gas from the HP flash tank separator is routed to the Anadarko HP inlet of the plant. All working, breathing, and flash vapors from the condensate storage and loading vapors are recovered by the VRU system, and then recompressed into the LP inlet of the plant. The VRU system consists of a primary VRU and a secondary VRU, which ascertains 100% vapor recovery during operation. The condensate tanks and VRU system comprise a closed system, with no emissions vented to atmosphere, except during downtime (maintenance, utility power outage, etc.). Water is separated from the condensate and stored in wastewater tanks until it is transported off site for disposal. Condensate will remain in the condensate tanks until transported by truck for sales. Three process skids operate in parallel. Approximately 30% of incoming gas flows through Skid #1, 10% through Skid #2, and 60% through Skid #3. Each of the three skids processes wet inlet gas for acid gas removal (sweetening), dehydration, and NGL removal. LP inlet scrubbers remove condensate/liquid oil and water from inlet wet gas before compression. LP scrubber fluids flow to condensate tank #19 (TK-1), which vents to the process/emergency flare. Liquid condensates in TK-1 are transported by truck to two scrubber oil tanks (TK-2, TK-3) for oil-water separation. Scrubber oils and drips collected from remote field sources also are transported to tanks TK-2 and TK-3 by truck. Separated scrubber oils and condensate are transported offsite by truck for sales. Overflow from tanks TK-2 and TK-3 is stored temporarily in wastewater open-top pit tank TK-4. BS&W from tank TK-4 and other open pits is emptied by vacuum truck for off-site disposal. Scrubbed LP wet inlet gas is compressed to approximately 730 psig before further processing. Compressor inter-stage scrubbers produce a condensate liquid that is lighter than that produced by LP inlet scrubbers. This lighter condensate flows to a condensate stabilizer system where light-end hydrocarbons are recovered and returned to the plant inlet. The stabilized heavier hydrocarbon liquids are stored in four pressurized bullet tanks awaiting transport off-site via pipeline. PERMIT MEMORANDUM 2011-227-TVR2 DRAFT/PROPOSED 5 Compressed wet inlet gas flows to the amine contactor towers (north amine unit and south amine unit) for removal of hydrogen sulfide (H2S) and partial removal of carbon dioxide (CO2). Rich amine from the contactors flows to rich amine flash tanks, which are vented to the acid gas flare. Rich amine from the flash tanks and from the amine contactor without a flash tank flows to the amine regeneration stills where acid gas is removed overhead and vented to the acid gas flare for incineration of H2S. The amine regenerator reboiler for Skid #3 is heated by a natural gas-fired furnace. Skids #1 and #2 share a reboiler heated by hot oil. The sweetened gas at Skid #1 and Skid #2 flows through molecular sieve beds for dehydration. Gas-fired heaters supply the heat for molecular sieve regeneration. Sweetened gas in Skid #3 flows through a glycol contactor for dehydration. Rich glycol from the contactor flows to the rich glycol flash tank, which vents to the low-pressure inlet gas stream. Rich glycol from the flash tank flows to the glycol regeneration still for removal of absorbed water. Vapors from the glycol still flow through a condenser. Any remaining vapors are recycled to the LP inlet gas stream, or vented to the process/emergency flare (PFL-1). Following dehydration, the sweetened and dried gas is processed through a cryogenic unit (demethanizer tower) on each skid. This process lowers the temperature sufficiently to condense ethane and heavier hydrocarbons, while leaving the methane fraction in gaseous form. The overhead methane stream (the residue gas) is recompressed to 650 psig and directed to the natural gas pipeline for distribution. The liquefied demethanizer bottoms are the raw natural gas liquids (NGL), and include ethane and heavier hydrocarbons. All of the raw NGL flows to a single NGL fractionation train for separation of NGL products. The fractionation train includes deethanizer, depropanizer, debutanizer, and deisobutanizer columns. The deethanizer column removes an ethane-propane mix (C2-C3), which leaves the plant via pipeline. The depropanizer removes the remaining propane. The debutanizer and deisobutanizer columns separate normal butane and iso-butane products (C4s), respectively. The remaining C5+ hydrocarbons are known as 14# gasoline. The propane, butane, and 14# gasoline products are stored in pressurized bullet and spheroid tanks awaiting outbound shipment via tank truck or pipeline. The bullet and spheroid tanks operate with working pressures between 5 and 200 psig. SECTION III. EQUIPMENT Emission units (EUs) have been arranged into Emission Unit Groups (EUGs) as follow. All fuelburning units at the station use pipeline-quality natural gas or field gas with a sulfur content of less than 343-ppmv. The engines operate continuously. DRAFT/PROPOSED PERMIT MEMORANDUM 2011-227-TVR2 6 EUG-1. Grandfathered Engines EU C-1 C-2 C-3(2) C-4(2) C-5(2) C-6(2) C-7 C-8(2) C-9(2) C-10(2) C-11(2) C-12 C-13(2) C-14 C-15 G-1(3) G-2(3) G-3(3) G-4(3) G-5(3) Point P-1 P-2 P-3 P-4 P-5 P-6 P-7 P-8 P-9 P-10 P-11 P-12 P-13 P-14 P-15 P-30 P-31 P-32 P-33 P-34 Make/Model Clark RA-8 Clark RA-8 Clark RA-8 Clark RA-6 Clark RA-6 Clark RA-8 Clark RA-8 Clark HRA-8 Clark HRA-8 Clark HRA-8 Clark HBA-8 Clark HBA-8 Clark HBA-8 Clark HBA-5 Clark HBA-5 Ingersoll-Rand PKVG-6 Ingersoll-Rand PKVG-6 Ingersoll-Rand PKVG-6 Ingersoll-Rand PKVG-6 Ingersoll-Rand PKVG-6 HP 800 800 800 600 600 800 800 880 880 880 1,760 --1,760 1,100 --<500 <500 <500 <500 <500 Serial # 25938 25937 25936 21133 21132 25927 25928 A25567 A25568 A25572 30269 --30271 35601 --6HZ131 6HZ132 6HZ134 6HZ136 6NZ182 Construction Date 1948 1948 1948 1948 1948 1948 1948 1948 1948 1948 1948 (1) 1948 1948 (1) 1948 1948 1948 1948 1948 1. Engine C-12 was permanently shutdown on July 19, 2003 per C.O. 03-165. Engine C-15 has been permanently removed from service. 2. These engines have modified pressure fuel systems installed per Consent Order 06-063, but are considered “existing engines” for purposes of MACT Subpart ZZZZ and permitting. See AD # 97-222-AD (M-3) dated June 20, 2005. 3. Factory rating is 660-hp, but the engines are limited to <500-hp by limiting actual KW power production from each engine to 330-KW based on a 30-day rolling average. These engines will be removed from service prior to October 19, 2013 EUG-2. Permitted Engines EU C-16.2(1) C-17(1) C-18(1) C-19(1) C-20 C-21(2) C-22 C-23(1) C-24(1) C-25 Point P-16 P-17 P-18 P-19 P-20 P-21 P-22 P-23 P-24 P-25 Make/Model Waukesha L7042 GSIU Waukesha L7042 GSIU Waukesha L7042 GSIU Waukesha L5108 GU Superior 16GTLA Superior 16GTLA Superior 16GTLA Superior 8G825 Superior 6G825 Superior 8GTLA HP 922 922 922 492 2,078 2,078 2,078 800 600 1,039 Serial # 365714A 387563 387652 387653 306999 306559 291649 282349 292229 293109 Construction Date 12/13/84 12/14/84 12/15/84 1/11/85 ~12/12/85 ~10/12/85 ~7/91 ~12/91-1/92 12/82 03/05 DRAFT/PROPOSED PERMIT MEMORANDUM 2011-227-TVR2 EU Point Make/Model C-26.2 P-26 Superior 12GTLA C-27 P-27 Superior 12GTLA C-28 P-28 Superior 12GTLA C-29 P-29 Superior 12GTLA G-6(1) P-35 Waukesha L3711 (1) G-7 P-36 Waukesha L3711 1. With NSCR and AFRC. 2. Overhauled in 2003 per C.O. 03-165. HP 1,558 1,558 1,558 1,558 335 335 Serial # 310529 304979 304989 295909 48027 48028 7 Construction Date ~6/86 ~6/86 ~6/86 2/12/90 1990 1990 EUG-3. Tanks EU TK-1 TK-2 TK-3 TK-4 TK-5 TK-6 TK-7 TK-8 Point P-50 P-51 P-52 P-53 P-54 P-55 P-56 P-57 Contents Condensate / BS&W Scrubber Oil, North Scrubber Oil, South BS&W / Condensate Methanol Methanol Gasoline Solvent < 1.5 psia vapor pressure Gallons 23,400 23,200 22,000 4,200 8,820 1,730 3,000 580 Construction Date pre 1974 pre 1974 pre 1974 post 1974 pre 1974 post 1974 post 1974 post 1974 EUG-4. Fugitive Components (Not Subject to NSPS Subpart KKK, OOOO or MACT Subpart HH) EU FUG-1 Type of Equipment Connectors Valves Open Ended Lines Flanges Compressor Seals Pump Seals Relief Valves Estimated Number of Items 7,000 3,500 280 4,378 56 113 38 EUG-5. Fugitive Components (Subject to NSPS Subpart KKK) EU FUG-2 Type of Equipment Connectors Valves Open Ended Lines Flanges Compressor Seals Pump Seals Relief Valves Estimated Number Of Items 6,522 3,091 282 4,006 5 28 5 DRAFT/PROPOSED PERMIT MEMORANDUM 2011-227-TVR2 EUG-6. Heaters & Boilers EU H-1 H-2 H-3 H-4 H-5 H-6 H-7 B-1 B-2 Point Equipment P-37 P-38 P-39 P-40 P-41 P-42 P-43 P-44 P-45 MMBtu/hr Hot Oil Heater (West) Hot Oil Heater (East) Regen. Gas Heater (Plant #1) Regen. Gas Heater (Plant #2) Glycol Reboiler Amine Reboiler Regen. Gas Heater (Plant #3) Boiler #1 (North, OK36454) Boiler #2 (South, OK43476) 49.8 41.5 5.0 1.5 1.5 5.25 7.5 2.0 2.0 Serial# 617 620 75122 41593 0132 5991 1276 1740 9777 Construction Date 1997(1) 1948 1976 1985 1985 1985 1985 1976 1988 1. Modified in October 1997 with more efficient burners. EUG-7. Process/Emergency Flare EU Point MMBtu/hr PFL-1 FL-1 27,000 Diameter inches 24 Height feet 110 Construction Date 1948 Diameter inches 24 Height feet 110 Construction Date 1985 EUG-8. Acid Gas Flare EU Point MMBtu/hr AU-1 FL-1 1.5 Note: The acid gas flare runs up the side of the process/emergency flare. Equipment vented to the acid gas flare includes the DGA north amine treater (Plants 1 and 2) and the DEA south amine treater (Plant 3). EUG-9. VOC Flare EU Point MMBtu/hr FL-2 FL-2 40 Diameter inches 12 Height feet 15 Construction Date 1986 EUG-10. Glycol Dehydration Unit EU D-1 Point FL-1 Equipment Still Overhead Vent Construction Date 1986 8 DRAFT/PROPOSED PERMIT MEMORANDUM 2011-227-TVR2 9 EUG-11. Condensate/Scrubber Oil Truck Loading EU TL-1 Point TL-1 Equipment Truck Loading Construction Date 1948 EUG 12. Fugitive Components (Subject to NESHAP Subpart HH) EU FUG-3 Type of Equipment Connectors Valves Pressure Relief Valves Pump Seals Estimated Number of Items Natural Condensate Gasoline 2,187 10 625 325 19 19 5 4 EUG-13. Miscellaneous Venting Activities EU ID # VENT Point # VENT Emission Units Miscellaneous Process Vents Date Constructed 1948 EUG-14. WOK Condensate/Methanol Storage Tanks EU TK-9 TK-10 TK-11 TK-12 TK-13 Point P-58 P-59 P-60 P-61 P-62 Contents 400-bbl Condensate 400-bbl Condensate 400-bbl Condensate 400-bbl Condensate 210-bbl Methanol Gallons 16,800 16,800 16,800 16,800 8,820 Construction Date March 2010 March 2010 March 2010 March 2010 March 2010 EUG-15. WOK Condensate Truck Loading from EUG-14 EU TL-2 Point TL-2 Equipment Truck Loading Construction Date March 2010 EUG-FW. Facility-Wide Emissions Engine Stack Parameters EU C-1A, B* C-2A, B* C-3A, B* Source Clark RA-8 Clark RA-8 Clark RA-8 Height feet 40 40 40 Diameter inches 10 10 10 Flow ACFM 3,540 3,540 3,540 Temp F 725 725 725 DRAFT/PROPOSED PERMIT MEMORANDUM 2011-227-TVR2 EU C-4A, B* C-5A, B* C-6 C-7A, B* C-8 C-9 C-10 C-11 C-12 C-13 C-14 C-15 C-16 C-17 C-18 C-19 C-20 C-21 C-22 C-23 C-24 C-25 C-26 C-27 C-28 C-29 G-1** G-2** G-3** G-4** G-5** G-6 G-7 Source Clark RA-6 Clark RA-6 Clark RA-8 Clark RA-8 Clark HRA-8 Clark HRA-8 Clark HRA-8 Clark HBA-8 Clark HBA-8 (removed) Clark HBA-8 Clark HBA-5 Clark HBA-5 (removed) Waukesha L7042 GSIU Waukesha L7042 GSIU Waukesha L7042 GSIU Waukesha L5108 GU Superior 16GTLA Superior 16GTLA Superior 16GTLA Superior 8G825 Superior 6G825 Superior 8GTLA Superior 12GTLA Superior 12GTLA Superior 12GTLA Superior 12GTLA Ingersoll-Rand PKVG-6 Ingersoll-Rand PKVG-6 Ingersoll-Rand PKVG-6 Ingersoll-Rand PKVG-6 Ingersoll-Rand PKVG-6 Waukesha L3711 Waukesha L3711 Height feet 41 41 43 42 45 45 45 56 --56 24 --20 20 20 26 28 28 28 18 22 16 19 19 19 21 37 37 37 37 37 27 27 Diameter inches 10 10 10 10 14 14 14 18 --18 16 --8 8 8 8 16 16 16 12 12 14 18 18 18 18 10 10 10 10 10 8 8 * Dual stacks ** To be removed from service prior to October 19, 2013. SECTION IV. EMISSIONS All emission estimates are based on continuous operation. Flow ACFM 2,598 2,598 3,539 3,540 3,763 3,763 3,763 11,335 --11,335 6,917 --4,085 4,085 4,085 2,135 12,007 12,007 12,007 5,359 4,437 6,654 7,921 7,921 7,921 7,921 2,889 2,889 2,889 2,889 2,889 1,500 1,500 10 Temp F 700 700 725 725 675 675 675 875 --875 800 --1007 1007 1007 800 808 808 808 1,330 1,250 934 801 801 801 801 975 975 975 975 975 850 850 PERMIT MEMORANDUM 2011-227-TVR2 DRAFT/PROPOSED 11 A. Criteria Emissions NOX and CO emission factors for the Clark engines are based on stack tests and operating experience after combustion modifications. NOX and CO emission factors for the Ingersoll Rand engines are based on AP-42 (7/00) Table 3.2-3 and a horsepower of 499. VOC emission factors for all engines are based on AP-42 (7/00) Tables 3.2-1 and 3.2-3. Source Type Clark RA-8 and RA-6 Clark RA-8 and RA-6 (modified) Clark HRA-8 (modified) Clark HBA-8 (modified) Clark HBA-5 Ingersoll-Rand PKVG-6 2SLB 2SLB 2SLB 2SLB 2SLB 4SRB Emission Factor, g/hp-hr NOX CO VOC 22 3.5 0.49 14 3.5 0.49 14 2.0 0.49 14 6.0 0.49 22 6.0 0.49 8.0 13.5 0.11 Fuel HP Btu/hp-hr 9,000 800 9,000 600 9,000 880 9,000 1,760 9,000 1,100 8,000 <500 NOX, CO, and VOC emission factors for the permitted engines in EUG-2 are based on the permit limits of Permit No. 97-222-TV. Source Type Waukesha L7042 GSIU* Waukesha L5108 GU* Superior 16GTLA Superior 8G825* Superior 6G825* Superior 8GTLA Superior 12GTLA Waukesha L3711* 4SRB 4SRB 4SLB 4SRB 4SRB 4SLB 4SLB 4SRB * Fuel, HP Btu/hp-hr 8,000 922 8,000 492 8,500 2,080 8,000 800 8,000 600 8,500 1,040 8,500 1,560 8,000 335 Emission Factor, g/hp-hr NOX CO VOC 2.0 5.65 1.0 2.0 4.80 1.0 2.0 3.0 1.0 2.0 3.0 1.0 2.0 3.0 1.0 2.0 3.0 1.0 2.0 3.0 1.0 2.0 5.65 1.0 Equipped with NSCR and AFRC. EUG-1. Grandfathered Engines EU C-1 C-2 C-3 C-4 C-5 C-6 C-7 C-8 Engine Clark RA-8 Clark RA-8 Clark RA-8 Clark RA-6 Clark RA-6 Clark RA-8 Clark RA-8 Clark HRA-8 Criteria Emissions NOX lb/hr TPY 24.69 108.15 24.69 108.15 24.69 108.15 18.52 81.11 18.52 81.11 24.69 108.15 38.80 169.95 27.16 118.96 CO lb/hr 6.17 6.17 6.17 4.63 4.63 6.17 6.17 3.88 TPY 27.04 27.04 27.04 20.28 20.28 27.04 27.04 16.99 VOC lb/hr TPY 0.86 3.79 0.86 3.79 0.86 3.79 0.65 2.84 0.65 2.84 0.86 3.79 0.86 3.79 0.95 4.16 PERMIT MEMORANDUM 2011-227-TVR2 EU Engine C-9 C-10 C-11 C-12* C-13 C-14 C-15* G-1* G-2* G-3* G-4* G-5* * Clark HRA-8 Clark HRA-8 Clark HBA-8 Clark HBA-8 Clark HBA-8 Clark HBA-5 Clark HBA-5 Ingersoll-Rand PKVG-6 Ingersoll-Rand PKVG-6 Ingersoll-Rand PKVG-6 Ingersoll-Rand PKVG-6 Ingersoll-Rand PKVG-6 Total lb/hr 27.16 27.16 54.32 0 54.32 53.35 0 8.8 8.8 8.8 8.8 8.8 462.07 DRAFT/PROPOSED NOX TPY 118.96 118.96 237.93 0 237.93 233.68 0 39 39 39 39 39 2026.19 CO lb/hr TPY 3.88 16.99 3.88 16.99 23.28 101.97 0 0 23.28 101.97 15.55 63.73 0 0 15 66 15 66 15 66 15 66 15 66 188.86 824.40 12 VOC lb/hr TPY 0.95 4.16 0.95 4.16 1.90 8.33 0 0 1.90 8.33 1.19 5.20 0 0 0.12 0.60 0.12 0.60 0.12 0.60 0.12 0.60 0.12 0.60 14.04 61.97 C-12 was shutdown per Consent Order No. 03-165. Emissions decrease is not to be used for future PSD netting purposes. C-15 has been permanently removed from service. Generators G-1, G-2, G-3, G-4, and G-5 will be removed from service prior to October 19, 2013. Emissions decrease from removal of C-15 and generators may be used for PSD netting purposes. There are no catalytic converters for emission controls on grandfathered engines. EUG-2. Permitted Engines EU C-16(1) C-17(1) C-18(1) C-19(1)(2) C-20 C-21 C-22 C-23(1) C-24(1) C-25 C-26 C-27 C-28 C-29 G-6(1)(2) G-7(1)(2) Engine Waukesha L7042 GSIU Waukesha L7042 GSIU Waukesha L7042 GSIU Waukesha L5108 GU Superior 16GTLA Superior 16GTLA Superior 16GTLA Superior 8G825 Superior 6G825 Superior 8GTLA Superior 12GTLA Superior 12GTLA Superior 12GTLA Superior 12GTLA Waukesha L3711 Waukesha L3711 Criteria Emissions NOX lb/hr TPY 4.07 17.81 4.07 17.81 4.07 17.81 2.17 9.50 9.16 40.13 9.16 40.13 9.16 40.13 3.53 15.45 2.65 11.59 4.58 20.07 6.87 30.09 6.87 30.09 6.87 30.09 6.87 30.09 1.48 6.47 1.48 6.47 CO lb/hr 11.48 11.48 11.48 5.21 13.74 13.74 13.74 5.29 3.97 6.87 10.30 10.30 10.30 10.30 4.17 4.17 TPY 50.30 50.30 50.30 22.80 60.20 60.20 60.20 23.17 17.38 30.10 45.13 45.13 45.13 45.13 18.28 18.28 VOC lb/hr TPY 2.03 8.90 2.03 8.90 2.03 8.90 1.08 4.75 4.58 20.07 4.58 20.07 4.58 20.07 1.76 7.72 1.32 5.79 2.29 10.03 3.43 15.04 3.43 15.04 3.43 15.04 3.43 15.04 0.74 3.23 0.74 3.23 DRAFT/PROPOSED PERMIT MEMORANDUM 2011-227-TVR2 EU NOX lb/hr TPY 83.06 363.73 Engine Total CO lb/hr 146.54 TPY 642.03 13 VOC lb/hr TPY 41.48 181.82 (1) Equipped with NSCR and AFRC. (2) Subject to 40 CFR Part 64, CAM rule until October 19, 2013 when new requirements under 40 CFR 63, Subpart ZZZZ go into effect. EUG-3. Tanks Tank TK-1 is vented to the plant/emergency flare. All other tank emissions in EUG-3 are considered insignificant activities. EU Point Contents TK-1 TK-2 TK-3 TK-4 TK-5 TK-6 TK-7 TK-8 P-50 P-51 P-52 P-53 P-54 P-55 P-56 P-57 Condensate / BS&W Scrubber Oil, North Scrubber Oil, South BS&W / Condensate, Open Pit Methanol Methanol Gasoline, Unleaded Solvent < 1.5 psia vapor pressure Estimated throughput, gallons per year 5,735,000 487,200 462,630 218,400 --------- EUG-4 (Exempt from NSPS Subpart KKK, OOOO and MACT Subpart HH), EUG-5 (Subject to NSPS Subpart KKK), and EUG-12 (Subject to MACT Subpart HH) Fugitive Components Potential fugitive VOC emissions are estimated based on EPA’s 1995 Protocol for Equipment Leak Estimates (EPA-453/R-95-017), component count for each fugitive type, and VOC content of the process streams. Fugitive emissions from components monitored under an LDAR program are calculated with appropriate reduction credits claimed. Equipment Wet Gas [24 wt% VOC] Components VOC 2,496 12.80 3,203 2.90 5,172 2.40 Valves Flanges Connectors Open Ended Lines Compressor Seals Relief Valves Pump Seals Subtotal (TPY) * Fugitive Emissions, TPY (Component Count)* Residue Gas Light Liquids Propane [10 wt% VOC] [100 wt% VOC] [100 wt% VOC] Components VOC Components VOC Components VOC 250 1.09 3,611 66.82 235 7.44313 0.12 4,574 4.86 294 1.11 500 0.10 7,382 14.97 470 0.91 226 0.42 2115 1.91 298 45 0.91 10 0.08 --38 5 0.10 --- --- --- --19.53 --- --68 3.30 Total = 133.10 TPY 2.81 Heavy Liquids [100 wt% VOC] Components VOC ------------- 19 0.23 --- --- 6 0.51 --- --- 2.75 --- --- 73 0.36 7.50 99.71 --- --10.20 --- --0.36 --- Fugitive emissions and component counts are best estimates DRAFT/PROPOSED PERMIT MEMORANDUM 2011-227-TVR2 14 EUG-6. Heaters & Boilers Estimated NOX, CO, and VOC emissions for the heaters and boilers are based on AP-42 (7/98), Tables 1.4-1 and 1.4-2 and a fuel gas HHV of 1,000 Btu/scf. EU Equipment H-1 H-2 H-3 H-4 H-5 H-6 H-7 B-1 B-2 Hot Oil Heater (West) Hot Oil Heater (East) Regen. Gas Heater (Plant #1) Regen. Gas Heater (Plant #2) Glycol Reboiler Amine Reboiler Regen. Gas Heater (Plant #3) Boiler #1 (North, OK36454) Boiler #2 (South, OK43476) Total NOX lb/hr TPY 4.98 21.8 4.15 18.2 0.50 2.19 0.15 0.66 0.25 1.10 0.60 2.63 0.75 3.29 0.20 0.86 0.20 0.86 11.78 51.6 CO lb/hr TPY 4.18 18.3 3.49 15.3 0.42 1.84 0.13 0.55 0.21 0.92 0.50 2.21 0.63 2.76 0.16 0.72 0.16 0.72 9.88 43.3 VOC lb/hr TPY 0.28 1.2 0.23 1.0 0.03 0.13 0.01 0.04 0.02 0.09 0.03 0.13 0.04 0.18 0.02 0.09 0.02 0.09 0.70 3.0 EUG-7. Process/Emergency Flare (Subject to NSPS Subpart A) Short-term emission estimates are based on a main plant upset where 90 MMscf of gas would be released in 4 to 6 hours. The maximum per hour rate would be about 22.5 MMscf, diminishing as valves are closed and gas is routed elsewhere. Emission estimates of SO2 and H2S are based on an H2S maximum concentration of 13.5 ppm in the inlet gas, a mass balance, and a conversion rate of 98%. NOX, CO, and VOC emission estimates are based on AP-42 (9/91), Table 13.5-1, the gas rate of 22.5 MMscf/hr, and a heating value of 1,200 Btu/scf. EUG-7 Process / Emergency Flare Unit lb/hr NOX 1,840 CO 9,990 VOC 3,860 SO2 50.3 H2 S 0.55 Annual emission estimates of NOX, CO, and VOC from process flaring are based on AP-42 (9/91), Table 13.5-1, an estimated flare throughput of 16.2 MMscf/yr for the glycol regeneration overhead vent stream, propane refrigerant compressor blowdowns, and Tank #19 vent, and propane properties. Flare pilot emissions are based on a pilot gas rate of 0.1 MMBtu/hr and a heating value of 1,000 Btu/scf. EUG-7 Process / Emergency Flare Unit TPY NOX 1.31 CO 7.12 VOC 19.3 EUG-8. Acid Gas Flare (Subject to NSPS Subpart A) Acid gases from the rich amine flash tank and the amine regeneration still are vented to the acid gas flare for conversion of H2S to SO2. Emission estimates of SO2 and H2S are based on an inlet DRAFT/PROPOSED PERMIT MEMORANDUM 2011-227-TVR2 15 gas rate of 137 MMSCFD, an H2S concentration of 13.5 ppmv in the inlet gas, a mass balance, and a conversion rate of 98%. NOX, CO, and VOC emission estimates are based on AP-42 (9/91), Table 13.5-1, and a flare heat rate of 1.5 MMBtu/hr. EUG-8 Acid Gas Flare Unit lb/hr TPY NOX 0.10 0.45 CO 0.56 2.45 VOC 1.70 7.45 SO2 12.8 55.9 H2 S 0.14 0.61 EUG-9. VOC Flare (Subject to NSPS Subpart A) NOX, CO, and VOC emission estimates are based on AP-42 (9/91), Table 13.5-1 and Table 13.52 and a maximum flare heat rate of 40 MMBtu/hr. EUG-9 Unit lb/hr TPY VOC Flare NOX 2.7 12 CO 15 66 VOC 2.5 11 EUG-10. Glycol Dehydration Unit Emissions from the dehydration regenerator still are vented through a condenser and any remaining vapors are either recycled to the low-pressure inlet gas stream or vented to the process/emergency flare. Flash vapors from the rich glycol flash tank are recycled to the lowpressure inlet gas stream. Therefore, there are no significant pollutant emissions. EUG-11. Condensate/Scrubber Oil Truck Loading Emissions from the loading of condensate are based on AP-42 (1/95), Section 5.2-5, Equation 1. ID# TL-1 Throughput Loading Loss, lb/1000 VOC bbl/yr 164,363 gallons 5.11 TPY 17.7 EUG-13. Miscellaneous Venting Activities Emissions from miscellaneous venting activities (i.e., compressor blowdowns) are based on 1,200,000 scf/yr of blowdown volume and VOC content of the inlet gas. EU ID# Blowdown Volume (scf/yr) VENT 1,200,000 VOC (TPY) 7.8 DRAFT/PROPOSED PERMIT MEMORANDUM 2011-227-TVR2 16 EUG-14. WOK Condensate/Methanol Storage Tanks Emission from the WOK condensate tanks are based on EPA TANKS 4.0.9d software. Rather than an individual limit on each condensate storage tank, OFS requests a combined throughput limit for tanks TK-9 through TK-12. The condensate tanks have a closed vapor recovery system (VRU) that collects 100% of emissions when operating. However, OFS requests to permit 100 hours of VOC working, breathing and flashing emissions to occur when VRU equipment is not operating. EU Point Estimated throughput gallons per year 383,250 383,250 383,250 383,250 1,533,000 210,000 Contents TK-9 P-58 Condensate TK-10 P-59 Condensate TK-11 P-60 Condensate TK-12 P-61 Condensate Combined Condensate Throughput TK-13 P-62 Methanol VOC Emissions EU Point Emission Type TK-9 – TK-12 P-58 – P-61 Working and Breathing Flashing TOTAL Pre-VRU TPY 22.92 534.91 557.83 Post-VRU TPY 0.28 6.11 6.39 EUG-15. WOK Condensate Truck Loading from EUG-14 Emissions from the loading of condensate are based on AP-42 (1/95), Section 5.2-5, Equation 1. Loading loss (lb/1000 gal loaded) = 12.46*S*P*M/T, where: S (Saturation factor, submerged fill P (True vapor pressure of liquid loaded, average psia) M (Molecular weight of vapor, lb/lb-mol) T (Temperature of bulk liquid, average °F + 460 = °R) ID # TL-2 0.6 11.3345 54.1086 59.96 Throughput Loading Loss, lb/1000 VOC gal/yr 1,533,000 gallons 8.82 TPY 6.76 DRAFT/PROPOSED PERMIT MEMORANDUM 2011-227-TVR2 17 EUG-FW. Facility-Wide Emissions Total Criteria Pollutant Emissions Source EUG NOX lb/hr Engines-1 (4) 462.07 (4) Engines-2 83.06 Tanks(1) Fugitives Not Subject to 4 & 12 NSPS Subpart KKK Fugitives Subject to NSPS 5(6) Subpart KKK 6 Heaters/Boilers 11.38 7 Process/Emergency Flare (2) 8 Acid Gas Flare 0.10 9 VOC Flare 2.74 (3) 10 Glycol Unit 11 Truck Loading 13 Misc. Venting (6) 14 Condensate Tanks 14(6) Methanol Tank Condensate Truck Loading 15(6) from EUG-14 Total (5) 559.35 1 2 3 1. 2. 3. 4. 5. 6. SO2 lb/hr TPY 2026.19 188.86 824.40 14.04 61.97 0.08 0.34 363.73 146.54 642.03 41.48 181.82 0.09 0.41 0 TPY lb/hr CO TPY VOC lb/hr TPY 23.99 105.07 - - - 6.38 27.95 - - 49.83 1.31 0.45 12.02 - 9.56 0.52 14.93 - 41.86 7.12 2.45 65.39 - 0.63 1.70 2.54 - 2.74 19.31 7.45 12.75 55.85 11.13 0 17.65 7.79 6.37 0.17 6.76 2453.53 360.41 1583.25 90.76 456.18 12.92 56.60 Tank emissions are either 100% controlled or insignificant. The process/emergency flare is for process and emergency use and its short-term emissions estimates are for ambient air modeling purposes only and are not counted for facility emission estimates. Glycol regenerator still vent is controlled by the process/emergency flare. Rich glycol flash tank off-gases are recycled back to the low-pressure inlet gas stream. SO2 emissions added for engines by applicant. After fuel system modifications to grandfathered engines and shutdown of engine C-12 and removal of engine C-15. Modifications associated with WOK 16” line installation. B. HAP Emissions Engines The internal combustion engines have emissions of HAP, the most significant being formaldehyde and acrolein. The following table presents emission factors for formaldehyde and acrolein. Emission factors for formaldehyde are based as noted. Emission factors for acrolein are based on AP-42 (7/00) Tables 3.2-1 and 3.2-3, except as noted. PERMIT MEMORANDUM 2011-227-TVR2 DRAFT/PROPOSED Formaldehyde and Acrolein Emission Factors Fuel, EF, lb/MMBtu Source Type HP Btu/hp-hr Formaldehyde Acrolein Clark RA-8 2SLB 9,000 800 0.24 (g/hp-hr)(1) 0.00778 Clark RA-6 2SLB 9,000 600 0.24 (g/hp-hr)(1) 0.00778 (1) Clark HRA-8 2SLB 9,000 880 0.27 (g/hp-hr) 0.00778 (1) Clark HBA-8 2SLB 9,000 1,760 0.38 (g/hp-hr) 0.00778 Clark HBA-5 2SLB 9,000 1,100 0.24 (g/hp-hr)(1) 0.00778 (2) Waukesha L7042 GSIU 4SRB 8,000 922 0.0103 0.00132(2) (2) Waukesha L5108 GU 4SRB 8,000 492 0.0103 0.00132(2) Superior 16GTLA 4SLB 8,500 2,078 0.1 (g/hp-hr)(3) 0.00514 (2) Superior 8G825 4SRB 8,000 800 0.0103 0.00132(2) Superior 6G825 4SRB 8,000 600 0.0103(2) 0.00132(2) (3) Superior 8GTLA 4SLB 8,500 1,039 0.1 (g/hp-hr) 0.00514 Superior 12GTLA 4SLB 8,500 1,558 0.1 (g/hp-hr)(3) 0.00514 (4) Ingersoll-Rand PKVG-6 4SRB 8,000 660 0.0205 0.00263 (2) Waukesha L3711 4SRB 8,000 335 0.0103 0.00132(2) 1. 2. 3. 4. Based on stack tests for Clark 2SLB engines, factors shown in g/hp-hr. Based on AP-42 (7/00), Table 3.2-3 with 50% catalytic reduction. Based on stack tests for White Superior 4SLB engines, factors shown in g/hp-hr. Based on AP-42, Table 3.2-3. EU C-1A, B C-2A, B C-3A, B C-4A, B C-5A, B C-6 C-7A, B C-8 C-9 C-10 C-11 C-12 C-13 C-14 C-15 C-16 C-17 C-18 C-19 Formaldehyde and Acrolein Emissions Formaldehyde Source lb/hr TPY Clark RA-8 0.42 1.86 Clark RA-8 0.42 1.86 Clark RA-8 0.42 1.86 Clark RA-6 0.32 1.39 Clark RA-6 0.32 1.39 Clark RA-8 0.42 1.86 Clark RA-8 0.42 1.86 Clark HRA-8 0.52 2.29 Clark HRA-8 0.52 2.29 Clark HRA-8 0.52 2.29 Clark HBA-8 1.47 6.46 Clark HBA-8 (removed) 0 0 Clark HBA-8 1.47 6.46 Clark HBA-5 0.58 2.55 Clark HBA-5 (removed) 0 0 Waukesha L7042 GSIU 0.08 0.33 Waukesha L7042 GSIU 0.08 0.33 Waukesha L7042 GSIU 0.08 0.33 Waukesha L5108 GU 0.04 0.18 Acrolein lb/hr TPY 0.056 0.25 0.056 0.25 0.056 0.25 0.042 0.18 0.042 0.18 0.056 0.25 0.056 0.25 0.062 0.27 0.062 0.27 0.062 0.27 0.123 0.54 0 0 0.123 0.54 0.077 0.34 0 0 0.01 0.04 0.01 0.04 0.01 0.04 0.005 0.02 18 DRAFT/PROPOSED PERMIT MEMORANDUM 2011-227-TVR2 EU C-20 C-21 C-22 C-23 C-24 C-25 C-26 C-27 C-28 C-29 G-1* G-2* G-3* G-4* G-5* G-6 G-7 Source Superior 16GTLA Superior 16GTLA Superior 16GTLA Superior 8G825 Superior 6G825 Superior 8GTLA Superior 12GTLA Superior 12GTLA Superior 12GTLA Superior 12GTLA Ingersoll-Rand PKVG-6 Ingersoll-Rand PKVG-6 Ingersoll-Rand PKVG-6 Ingersoll-Rand PKVG-6 Ingersoll-Rand PKVG-6 Waukesha L3711 Waukesha L3711 Total Formaldehyde lb/hr TPY 0.46 2.01 0.46 2.01 0.46 2.01 0.07 0.29 0.05 0.22 0.23 1.00 0.34 1.50 0.34 1.50 0.34 1.50 0.34 1.50 0.11 0.47 0.11 0.47 0.11 0.47 0.11 0.47 0.11 0.47 0.03 0.12 0.03 0.12 11.82 51.72 19 Acrolein lb/hr TPY 0.091 0.40 0.091 0.40 0.091 0.40 0.008 0.04 0.006 0.03 0.045 0.20 0.068 0.30 0.068 0.30 0.068 0.30 0.068 0.30 0.014 0.06 0.014 0.06 0.014 0.06 0.014 0.06 0.014 0.06 0.0035 0.02 0.0035 0.02 1.589 6.99 * To be removed from service prior to October 19, 2013. The facility is a major source of formaldehyde emissions. Glycol Dehydration Unit Glycol dehydration units in natural gas service typically emit benzene, toluene, ethyl benzene, xylene, and n-hexane from the rich glycol flash tank and the regenerator still vent. These compounds are regulated as HAP. Emission estimates for the glycol unit are based on GRIGLYCalc 3.0, a wet gas extended analysis dated December 17, 2004, a lean glycol circulation rate of 13 gpm, and a dry gas rate of 70 MMSCFD. Vapors from the rich glycol flash tank are recycled back to the low-pressure inlet gas stream. Uncontrolled emissions from the glycol regenerator still vent are listed in the table below. Pollutant Benzene Toluene Ethyl benzene Xylene n-Hexane Total Uncontrolled HAP CAS Emissions Number lb/hr TPY 71432 4.04 17.7 108883 4.06 17.8 100414 0.21 0.93 1330207 2.15 9.40 110543 1.83 8.0 12.29 53.8 PERMIT MEMORANDUM 2011-227-TVR2 DRAFT/PROPOSED 20 The glycol regenerator still vent emissions are vented to a condenser. Any uncondensed vapors are then vented to the plant’s process/emergency flare or are recycled to the low-pressure inlet gas stream. Controlled emissions are listed in the table below. Pollutant Benzene Toluene Ethyl benzene Xylene n-Hexane Total Controlled HAP CAS Emissions Number lb/hr TPY 71432 0.08 0.35 108883 0.08 0.36 100414 <0.01 0.02 1330207 0.04 0.19 110543 0.04 0.16 0.25 1.08 Greenhouse Gases The applicant has presented estimates of PTE for greenhouse gases (CO2-equivalent) at this site, demonstrating that the facility is above the PSD-major source threshold (100,000 TPY CO2e, 250 TPY mass basis) for this pollutant. Therefore the facility is an existing PSD source for greenhouse gases. Potential GHG Emission Summary Table follows. PERMIT MEMORANDUM 2011-227-TVR2 DRAFT/PROPOSED 21 Potential GHG Emission Summary Table EUG# Source EUG-1 EUG-2 EUG-3 EUG-4 EUG-5 EUG-6 EUG-7 EUG-8 EUG-9 EUG-10 EUG-11 EUG-13 EUG-14 EUG-14 EUG-15 TOTAL Grandfathered Engines and Generators (18) Permitted Engines and Generators (16) Tanks (8) Fugitive Components Not Subject to NSPS Subpart KKK Fugitive Components Subject to NSPA Subpart KKK Heaters and Boilers (9) Process/Emergency Flare Gas Sweetening Units/Acid Gas Flaring VOC Flare Glycol Dehydration Unit Condensate/Scrubber Oil Truck Loading (TL-1) Miscellaneous Venting Activities New (4) Condensate Tanks (TK-8, TK-10, TK-11, TK-12) New Methanol Storage Tank (TK-13) Condensate Truck Loading from EUG-14 (TL-2) Carbon Dioxide (CO2) lb/hr TPY 15,441.03 67,631.71 18,400.25 80,593.09 ----0.01 0.01 0.01 0.04 12,590.21 55,145.12 513.28 2,248.15 176.37 772.52 30.84 135.08 ----------0.01 0.07 0.31 --------47,152.06 206,526.04 Methane (CH4) as CO2 Eq. lb/hr TPY 6.12 26.79 7.29 31.92 ----111.82 489.77 383.30 1,678.85 4.99 21.84 0.20 0.89 0.07 0.31 0.01 0.05 ------1.04 --402.01 30.78 134.82 ------0.23 544.58 2,788.62 Nitrous Oxide (N2O) as CO2 Eq. lb/hr TPY 9.03 39.54 10.76 47.12 ------------7.36 32.24 0.30 1.31 0.10 0.45 0.02 0.08 ------------------------27.57 120.75 Total CO2 + CO2 Eq. lb/hr 15,456.17 18,418.30 --111.82 383.31 12,602.56 513.78 176.55 30.87 ------30.85 ----47,724.21 TPY 67,698.04 80,672.14 --489.78 1,678.89 55,199.20 2,250.36 773.28 135.22 --1.04 402.01 135.13 --0.23 209,435.32 PERMIT MEMORANDUM 2011-227-TVR2 DRAFT/PROPOSED 22 SECTION V. INSIGNIFICANT ACTIVITIES The insignificant activities identified and justified in the application are duplicated below. Records are available to confirm the insignificance of the activities. Appropriate recordkeeping of activities indicated below with “*” is specified in the Specific Conditions. 1. Space heaters, boilers, process heaters and emergency flares less than or equal to 5 MMBtu/hr heat input fired by commercial natural gas. The facility has several portable space heaters for the office buildings and various plant buildings. All are rated less than 5 MMBtu/hr. The 2.0 MMBtu/hr boilers (B-1 and B-2) are also in this category. 2. * Emissions from condensate tanks with a design capacity of 400 gallons or less in ozone attainment areas. None identified, but may be added in the future. 3. Surface coating operations which do not exceed a combined total usage of more than 60 gallons/month of coatings, thinners, and clean-up solvents at any one emissions unit. The facility conducts painting operations and engine cleaning exclusively for maintenance purposes, which is a trivial activity; therefore, no records are required. 4. * Activities having the potential to emit no more than 5 TPY (actual) of any criteria pollutant. The methanol and ethylene glycol tanks and compressor blowdowns fit in this category. Also included are the three regeneration-gas heaters (H-3, H-4, and H-7), the glycol reboiler (H-5), and the amine reboiler (H-6). SECTION VI. OKLAHOMA AIR POLLUTION CONTROL RULES OAC 252:100-1 (General Provisions) Subchapter 1 includes definitions but there are no regulatory requirements. [Applicable] OAC 252:100-2 (Incorporation by Reference) [Applicable] This subchapter incorporates by reference applicable provisions of Title 40 of the Code of Federal Regulations. These requirements are addressed in the “Federal Regulations” section. OAC 252:100-3 (Air Quality Standards and Increments) [Applicable] Subchapter 3 enumerates the primary and secondary ambient air quality standards and the significant deterioration increments. At this time, all of Oklahoma is in attainment of these standards. OAC 252:100-5 (Registration, Emission Inventory, and Annual Operating Fees) [Applicable] Subchapter 5 requires sources of air contaminants to register with Air Quality, file emission inventories annually, and pay annual operating fees based upon total annual emissions of regulated pollutants. An emissions inventory has been submitted and fees paid for prior years as required. PERMIT MEMORANDUM 2011-227-TVR2 DRAFT/PROPOSED 23 OAC 252:100-8 (Permits for Part 70 Sources) [Applicable] Part 5 includes the general administrative requirements for Part 70 permits. Any planned changes in the operation of the facility which result in emissions not authorized in the permit and which exceed the “Insignificant Activities” or “Trivial Activities” thresholds require prior notification to AQD and may require a permit modification. Insignificant activities mean individual emission units that either are on the list in Appendix I (OAC 252:100), or whose actual calendar year emissions do not exceed the following limits: 5 TPY of any one criteria pollutant 2 TPY of any one hazardous air pollutant (HAP) or 5 TPY of multiple HAP or 20% of any threshold less than 10 TPY for single HAP that the EPA may establish by rule Emission limitations and operational requirements necessary to assure compliance with all applicable requirements for all sources are taken from the operating permit application, or developed from the applicable requirements. Part 7 summarizes Prevention of Significant Deterioration (PSD) requirements. See the “Federal Regulations” section for a discussion of PSD regulations. OAC 252:100-9 (Excess Emission Reporting Requirements) [Applicable] Except as provided in OAC 252:100-9-7(a)(1), the owner or operator of a source of excess emissions shall notify the Director as soon as possible but no later than 4:30 p.m. the following working day of the first occurrence of excess emissions in each excess emission event. No later than thirty (30) calendar days after the start of any excess emission event, the owner or operator of an air contaminant source from which excess emissions have occurred shall submit a report for each excess emission event describing the extent of the event and the actions taken by the owner or operator of the facility in response to this event. Request for affirmative defense, as described in OAC 252:100-9-8, shall be included in the excess emission event report. Additional reporting may be required in the case of ongoing emission events and in the case of excess emissions reporting required by 40 CFR Parts 60, 61, or 63. OAC 252:100-13 (Open Burning) [Applicable] Open burning of refuse and other combustible material is prohibited except as authorized in the specific examples and under the conditions listed in this subchapter. OAC 252:100-19 (Control of Emission of Particulate Matter) [Applicable] Section 19-4 regulates emissions of particulate matter (PM) from new and existing fuel-burning equipment, with emission limits based on maximum design heat input rating. Fuel-burning equipment is defined in OAC 252:100-1 as “combustion devices used to convert fuel or wastes to usable heat or power.” Thus, the gas-fired heaters and reboilers and engines are subject to the requirements of this subchapter. The facility’s flares are not subject since they do not produce any “usable heat or power.” Appendix C specifies a PM emission limitation range of 0.6 lb/MMBtu to 0.35 for fuel-burning equipment with a rated heat input range of 10 MMBtu/hr or less up to 100 MMBtu/hr. AP-42 (7/98) Table 1.4-2 lists total PM emissions as 0.0076 lb/MMBtu for natural gas combustion. AP-42 (7/00) Section 3.2 lists total PM emissions from natural gas-fired reciprocating internal combustion engines as about 0.01 lb/MMBtu. This PERMIT MEMORANDUM 2011-227-TVR2 DRAFT/PROPOSED 24 permit requires the use of natural gas for all fuel-burning units to ensure compliance with Subchapter 19. OAC 252:100-25 (Visible Emissions and Particulates) [Applicable] No discharge of greater than 20% opacity is allowed except for short-term occurrences that consist of not more than one six-minute period in any consecutive 60 minutes, not to exceed three such periods in any consecutive 24 hours. In no case shall the average of any six-minute period exceed 60% opacity. There is little possibility of exceeding these standards when burning natural gas. This permit requires the use of natural gas for all fuel-burning units to ensure compliance with Subchapter 25. OAC 252:100-29 (Control of Fugitive Dust) [Applicable] No person shall cause or permit the discharge of any visible fugitive dust emissions beyond the property line on which the emissions originate in such a manner as to damage or to interfere with the use of adjacent properties, or cause air quality standards to be exceeded, or interfere with the maintenance of air quality standards. Under normal operating conditions, this facility has negligible potential to violate this requirement; therefore, it is not necessary to require specific precautions to be taken. OAC 252:100-31 (Sulfur Compounds) [Applicable] Part 2 limits the ambient air impact of hydrogen sulfide emissions from any new or existing source to 0.2 ppm for a 24-hour average (equivalent to 280 g/m3). For the acid gas flare, EPA SCREEN3 dispersion modeling was conducted based on the stack parameters listed below and emissions rates of 0.14 lb/hr of H2S. The SCREEN3 results are tabulated in the following table. Acid Gas Flare Stack Height: Stack Diameter: Heat Release: 110 ft 24 inch 0.50 MMBtu/hr (A lower heat release than the 1.5 MMBtu/hr maximum rate was used for a conservative estimate) Ambient Impacts of H2S (0.14 lb/hr) Standard Ground Level Concentration Averaging Time 3 g/m g/m3 24-hour 280 0.41 For the process/emergency flare, EPA SCREEN3 dispersion modeling was conducted based on the stack parameters listed below and emissions rates of 0.55 lb/hr of H2S. The SCREEN3 results are tabulated in the following table. PERMIT MEMORANDUM 2011-227-TVR2 DRAFT/PROPOSED 25 Process/Emergency Flare Stack Height: Stack Diameter: Heat Release: 110 ft 24 inches 40 MMBtu/hr (a lower heat release than the 27,000 MMBtu/hr maximum rate was used for a conservative estimate) Ambient Impacts of H2S (0.55 lb/hr) Standard Ground Level Concentration Averaging Time 3 g/m g/m3 24-hour 280 0.1 Part 5 limits sulfur dioxide emissions from new equipment (constructed after July 1, 1972). For gaseous fuels, the limit is 0.2 lb/MMBtu heat input. This is equivalent to approximately 0.2weight percent sulfur in the fuel gas, which is equivalent to 2,000-ppmw sulfur. Thus, a limitation of 343-ppmv sulfur in a field gas supply will be in compliance. The permit requires the use of pipeline-grade natural gas or field gas with a maximum sulfur content of 343-ppmv for all fuel-burning equipment to ensure compliance with Subchapter 31. Part 5 also limits hydrogen sulfide emissions from new equipment (constructed after July 1, 1972). Removal of hydrogen sulfide in the exhaust stream, or oxidation to sulfur dioxide, is required unless hydrogen sulfide emissions would be less than 0.3 lb/hr for a two-hour average. Hydrogen sulfide emissions shall be reduced by a minimum of 95% of the hydrogen sulfide in the exhaust gas. Direct oxidation of hydrogen sulfide is allowed for units whose emissions would be less than 100 lb/hr of sulfur dioxide for a two-hour average. Acid gas from the amine treater rich amine flash tanks and the amine regenerator still vents are vented to the acid gas flare, which has a conversion efficiency of 98%. OAC 252:100-33 (Nitrogen Oxides) [Not Applicable] This subchapter limits new gas-fired fuel-burning equipment with rated heat input greater than or equal to 50 MMBtu/hr to emissions of 0.2 lb of NOX per MMBtu, three-hour average. There are no equipment items that equal or exceed the 50 MMBtu/hr threshold. OAC 252:100-35 (Carbon Monoxide) [Not Applicable] None of the following affected processes are located at this facility: gray iron cupola, blast furnace, basic oxygen furnace, petroleum catalytic cracking unit, or petroleum catalytic reforming unit. OAC 252:100-37 (Volatile Organic Compounds) [Applicable] Part 3 requires storage tanks constructed after December 28, 1974, with a capacity of 400 gallons or more and storing a VOC with a vapor pressure greater than 1.5 psia to be equipped with a permanent submerged fill pipe or with an organic vapor recovery system. Tanks TK-1, TK-2, TK3, and TK-5 were constructed prior to 1974 and are exempt from this requirement. Tanks TK-4, TK-6, and TK-7 are subject to this requirement and are equipped with submerged fill pipes. Tank TK-8 stores material with a vapor pressure less than 1.5 psia and is exempt from this requirement. Tanks TK-9, TK-10, TK-11, and TK-12 are subject to this requirement. PERMIT MEMORANDUM 2011-227-TVR2 DRAFT/PROPOSED 26 Part 3 requires loading facilities with a throughput equal to or less than 40,000 gallons per day to be equipped with a system for submerged filling of tank trucks or trailers if the capacity of the vehicle is greater than 200 gallons. This facility does not have the physical equipment (loading arm and pump) to conduct this type of loading. Therefore, this requirement is not applicable. Part 7 requires fuel-burning equipment to be operated and maintained to minimize emissions of VOC. All fuel-burning equipment at this location is subject to this requirement. Part 7 regulates VOC/water separators that receive water containing more than 200 gallons per day of VOC. There is no VOC/water separator at this location. Tank T-4 and five open pits recover water from the condensate tank area, rainwater runoff, and the plant drain system. Most of the oil/water mixtures captured by these units are removed by vacuum truck for off-site disposal. A small amount of the skimmed oil is sold occasionally. OAC 252:100-42 (Toxic Air Contaminants (TAC)) [Applicable] This subchapter regulates toxic air contaminants (TAC) that are emitted into the ambient air in areas of concern (AOC). Any work practice, material substitution, or control equipment required by the Department prior to June 11, 2004, to control a TAC, shall be retained unless a modification is approved by the Director. Since no AOC has been designated anywhere in the state, there are no specific requirements for this facility at this time. OAC 252:100-43 (Testing, Monitoring, and Recordkeeping) [Applicable] This subchapter provides general requirements for testing, monitoring and recordkeeping and applies to any testing, monitoring or recordkeeping activity conducted at any stationary source. To determine compliance with emissions limitations or standards, the Air Quality Director may require the owner or operator of any source in the state of Oklahoma to install, maintain and operate monitoring equipment or to conduct tests, including stack tests, of the air contaminant source. All required testing must be conducted by methods approved by the Air Quality Director and under the direction of qualified personnel. A notice of intent to test and a testing protocol shall be submitted to Air Quality at least 30 days prior to any EPA Reference Method stack tests. Emissions and other data required to demonstrate compliance with any federal or state emission limit or standard, or any requirement set forth in a valid permit shall be recorded, maintained, and submitted as required by this subchapter, an applicable rule, or permit requirement. Data from any required testing or monitoring not conducted in accordance with the provisions of this subchapter shall be considered invalid. Nothing shall preclude the use, including the exclusive use, of any credible evidence or information relevant to whether a source would have been in compliance with applicable requirements if the appropriate performance or compliance test or procedure had been performed. PERMIT MEMORANDUM 2011-227-TVR2 DRAFT/PROPOSED 27 The following Oklahoma Air Quality Rules are not applicable to this facility: OAC 252:100-11 OAC 252:100-15 OAC 252:100-17 OAC 252:100-23 OAC 252:100-24 OAC 252:100-39 OAC 252:100-47 Alternative Emissions Reduction Mobile Sources Incinerators Cotton Gins Grain, Feed, or Seed Facility Non-attainment Areas Municipal Solid Waste Landfills not eligible not in source category not type of emission unit not type of emission unit not in source category not in a subject area not type of source category SECTION VII. FEDERAL REGULATIONS PSD, 40 CFR Part 52 [Not Applicable] Total potential emissions of NOX, CO, and VOC are greater than the threshold level of 250 TPY. Any future increases of emissions must be evaluated for PSD if they exceed a significance level (100 TPY CO, 40 TPY NOX, 40 TPY SO2, 40 TPY VOC, 15 TPY PM10, 10 TPY H2S). NSPS, 40 CFR Part 60 [Subparts A, Dc, KKK, OOOO and LLL Applicable] Subpart A, General Provisions. The VOC flare (FL-2) is used to control emissions from relief valves within the gas liquids extraction equipment that are subject to NSPS Subpart KKK and to control emissions from the seal degassing systems of compressors C-19, C-24 and C-25. The plant process/emergency flare (FL-1) is used to control emissions from the TEG dehydration still vent and from relief valves that are subject to NSPS Subpart KKK. The VOC flare and the plant process/emergency flare are subject to Subpart A and shall comply with all applicable requirements for flares in §60.18. The acid gas flare is used to control the acid gas from the DGA and DEA units. However, it is not used to comply with NSPS Subpart LLL even though the DGA and DEA are both subject to NSPS Subpart LLL because the H2S design capacity of both amine units is less than 2 LT/D. Therefore, the control requirements of Subpart LLL are not applicable. Subpart Dc, Small Industrial-Commercial-Institutional Steam Generating Units. This subpart affects steam generating units constructed after June 9, 1989, and with capacity between 10 and 100 MMBtu/hr. Hot oil heaters H-1 and H-2 are “Steam Generating Units” as that term is defined in this subpart. The heaters were constructed prior to June 9, 1989; however, new burners were installed in H-1 in 1997 that would reduce NOX and CO emissions, but allowed for a very slight increase in SO2 emissions that triggered Subpart Dc. Since H-1 is fired with natural gas, only initial notification and records of the type of fuel and amount combusted each day is required. Subparts K, Ka, Kb, Volatile Organic Liquid (VOL) Storage Vessels. All tanks were either constructed prior to the effective date of these subparts or are below the 19, 813 gallon threshold for Subpart Kb. Subpart GG, Stationary Gas Turbines. There are no stationary gas turbines at this facility. Subpart KKK, Equipment Leaks of VOC from Onshore Natural Gas Processing Plants PERMIT MEMORANDUM 2011-227-TVR2 DRAFT/PROPOSED 28 constructed, reconstructed, or modified after January 20, 1984. This subpart sets standards for natural gas processing plants, which are defined as any site engaged in the extraction of natural gas liquids from field gas, fractionation of natural gas liquids, or both. Compressors C-16 through C-23 and C-25 through C-29 are affected facilities since they were constructed/modified after January 20, 1984. Subpart KKK specifically exempts reciprocating compressors in wet gas service, and compressors that are not in VOC service, from all but notification and recordkeeping requirements. Compressors C-20, C-21, C-22, and C-23 are in wet gas service and all must meet the notificationand recordkeeping requirements of §60.486(j) and §60.635(a) and (c). Compressors C-16, C-17, C-18, C-26, C-27, C-28 and C-29 are in wet gas/residue gas service. Compressors C19, C-24 and C-25 are in propane refrigeration service and subject to §60.482-3 control requirements. The permittee will be required to maintain a leak detection and repair (LDAR) program for C-19, C-24, C-25, and associated equipment. EUG-5 includes the WOK 16” inlet and condensate handling process and will be subject to this subpart. The TEG dehydrator unit (Plant 3 TEG System) was constructed in 1986 and is an affected facility. The amine units (Plants 1 & 2 DGA North Amine Treater and Plant 3 DEQ South Amine Treater) were constructed/reconstructed after 1984 and are affected facilities. Multiple inlet gas streams (Inlet Gas South Low, Inlet Gas South High, Anadarko Inlet and Waukesha Inlet) are affected facilities. Other process units have some equipment components constructed or modified after January 20, 1984. EUG-5 contains those equipment components subject to Subpart KKK. The permittee will be required to maintain an LDAR program for those components. Subpart LLL sets standards for natural gas sweetening units, and sweetening units followed by a sulfur recovery unit, which commenced construction or modification after January 20, 1984. The north amine unit (DGA) was reconstructed after the applicability date of Subpart LLL. The south amine unit (DEA) was constructed in 1985. Both are subject to this subpart. However, facilities with a design capacity of less than 2 long tons per day (LT/D) of H2S in the acid gas, expressed as sulfur, are exempted from the control requirements of the standard. The applicant has provided an analysis demonstrating that the amine units at this facility have a design capacity of less than 2 LT/D of sulfur. Therefore, the north and south amine units are subject only to §60.647 (c), which requires the facility to keep, for the life of the facility, an analysis demonstrating that the amine units’ design capacities are less than 2 LT/D of H2S, expressed as sulfur. Subpart NNN, VOC Emissions from SOCMI Distillation Operations. This subpart applies to each affected facility (distillation units and recovery systems) that is part of a process unit that produces any of the chemicals listed in §60.667 as a product, co-product, by-product, or intermediate. The affected facilities are (1) each distillation unit not discharging its vent stream into a recovery system, (2) each combination of distillation unit and the recovery system into which its vent stream is discharged, or (3) each combination of two or more distillation units and the common recovery system into which their vent streams are discharged. The definition of “vent stream” excludes relief valves and fugitive equipment leaks. Propane, butane, and isobutane are listed chemicals in §60.667 and an Applicability Determination from EPA Region VI dated December 14, 2006 states that Subpart NNN applied to distillation operations at a natural gas processing plant operated by ConocoPhillips Company. However, OFS has determined that only relief PERMIT MEMORANDUM 2011-227-TVR2 DRAFT/PROPOSED 29 valves and fugitive leaks are vented to the atmosphere at this facility’s depropanizer and debutanizer columns; therefore, there are no applicable requirements under Subpart NNN. Subpart IIII, Standards of Performance for Stationary Compression Ignition Internal Combustion Engines, affects stationary compression ignition (CI) internal combustion engines (ICE) based on power and displacement ratings, depending on date of construction, beginning with those constructed after July 11, 2005. For the purposes of this subpart, the date that construction commences is the date the engine is ordered by the owner or operator. The facility does not presently operate any engines subject to this subpart since all engines were constructed prior to July 11, 2005. Subpart JJJJ, Standards of Performance for Stationary Spark Ignition Internal Combustion Engines, was proposed in the Federal Register on June 12, 2006. It will affect all new engines and those modified or reconstructed after June 6, 2006. It will impose categories of standards for NOX, CO, NMHC, based on engine power rating, lean-burn or rich-burn, fuel type, and manufacture date. The facility does not presently operate any engines subject to this subpart since all engines were constructed prior to June 12, 2006. Subpart KKKK, Standards of Performance for Stationary Combustion Turbines, establishes emission standards and compliance schedules for the control of emissions from stationary combustion turbines with a heat input at peak load equal to or greater than 10 MMBtu per hour, based on the higher heating value of the fuel, which commenced construction, modification, or reconstruction after February 18, 2005. Stationary combustion turbines regulated under this subpart are exempt from the requirements of Subpart GG of this part. Heat recovery steam generators and duct burners regulated under this subpart are exempted from the requirements of subparts Da, Db, and Dc of this part. There are no turbines at this facility. Subpart OOOO, Crude Oil and Natural Gas Production, Transmission, and Distribution. This subpart was promulgated on August 16, 2012, and affects the following sources that commence construction, reconstruction, or modification after August 23, 2011: 1. Each single gas well; 2. Single centrifugal compressors using wet seals that are located between the wellhead and the point of custody transfer to the natural gas transmission and storage segment; 3. Reciprocating compressors which are single reciprocating compressors located between the wellhead and the point of custody transfer to the natural gas transmission and storage segment; 4. Single continuous bleed natural gas driven pneumatic controllers with a natural gas bleed rate greater than 6 SCFH, which commenced construction after August 23, 2011, located between the wellhead and the point of custody transfer to the natural gas transmission and storage segment and not located at a natural gas processing plant; 5. Single continuous bleed natural gas driven pneumatic controllers which commenced construction after August 23, 2011, and is located at a natural gas processing plant; 6. Single storage vessels located in the oil and natural gas production segment, natural gas processing segment, or natural gas transmission and storage segment; PERMIT MEMORANDUM 2011-227-TVR2 DRAFT/PROPOSED 30 7. All equipment, except compressors, within a process unit at an onshore natural gas processing plant; 8. Sweetening units located at onshore natural gas processing plants. The only affected facilities at this time are reciprocating compressors added, modified or reconstructed after August 23, 2011. NESHAP, 40 CFR Part 61 [Not Applicable] There are no emissions of any of the regulated pollutants: arsenic, asbestos, beryllium, benzene, coke oven emissions, mercury, radionuclides, or vinyl chloride except for trace amounts of benzene. Subpart J (Equipment Leaks of Benzene) concerns only process streams, which contain more than 10% benzene by weight. All process streams at this facility are below this threshold. NESHAP, 40 CFR Part 63 [Subparts A, HH, ZZZZ, and DDDDD are Applicable] Subpart A, General Provisions. The facility is subject to the reporting requirements of 40 CFR §60.9, but is not subject to the flare requirements of 40 CFR §63.11. Neither of the two flares (FL-1 nor FL-2) at the plant is used to comply with MACT Subpart HH. The General Standards require compliance with 40 CFR §63.771 or 40 CFR §63.11 for “flares that are used to comply with Subpart HH.” GLYCOL UNITS: The process/emergency flare (FL-1) was used to control emissions from the TEG dehydration still vent prior to June 17, 2002 and the requirement to recycle or flare the glycol vent gas was a federally enforceable permit limit prior to June 17, 2002. Because the benzene from that flare is < 0.90 megagrams per year, the glycol unit and flare are exempt under 40 CFR §63.764(e)(1)(ii). ANCILLARY EQUIPMENT: 40 CFR §63.769(b) exempts sources “meeting the requirements specified in 40 CFR Part 60, subpart KKK” from 40 CFR §63.769, which includes 40 CFR §63.11(b). Subpart HH, Oil and Natural Gas Production Facilities. This subpart applies to affected emission points that are located at facilities which are major sources of HAP, or TEG dehydration units only located at an area source, and either process, upgrade, or store hydrocarbons prior to the point of custody transfer or prior to the point at which the natural gas enters the natural gas transmission and storage source category. Subpart HH affects glycol dehydration unit process vents, storage vessels with potential for flash emissions, and compressors and ancillary equipment (valves, flanges, etc.) in VHAP service (i.e., more than 10% by weight HAP) that are located at gas processing plants. This facility is a major source of HAP and must meet the compliance, reporting, and recordkeeping requirements of Subpart HH. Emissions from the glycol dehydrator still vent are controlled by a condenser and by recycle or combustion in the plant’s process/emergency flare. The applicant has stated and demonstrated that the glycol unit is subject to the control requirements of §63.764 and §63.765. The natural gasoline system, equipment handling condensate, and the engine jacket cooling water systems (using ethylene glycol) have ancillary equipment components in VHAP service. The facility has implemented and will maintain a leak detection and repair program (LDAR) for those equipment components in VHAP service. PERMIT MEMORANDUM 2011-227-TVR2 DRAFT/PROPOSED 31 All condensate and scrubber oil storage tanks are exempt from the standards of this subpart as none have a throughput above 21,000 gallons per day. None of the facility’s compressors are in VHAP service. Recordkeeping is required for notifications required by 40 CFR §63.9, for the LDAR monitoring, for the records required by 40 CFR §63.772(a) that demonstrate which streams are in VHAP service and which streams are not in VHAP service, and for the exemptions documented according to 40 CFR §63.764(e)(1)(ii), §63.774(d)(1)(ii) and §63.774(d)(2). Subpart ZZZZ, Reciprocating Internal Combustion Engines (RICE). This subpart previously affected only RICE with a site-rating greater than 500 brake horsepower located at a major source of HAP emissions. On January 18, 2008, the EPA published a final rule that promulgates standards for new and reconstructed engines (after June 12, 2006) with a site-rating less than or equal to 500 HP located at major sources, and for new and reconstructed engines (after June 12, 2006) located at area sources. The existing lean-burn engines are exempt from any standards in Subpart ZZZZ. All existing rich-burn engines with a site-rating greater than 500 brake horsepower are subject to emission and operating limitations in Subpart ZZZZ and were required to comply with the standards by June 15, 2007. The permit will require compliance with this subpart. As previously explained, OFS took a federally enforceable limit on the horsepower output for the engines driving generators G-1, G-2, G-3, G-4, and G-5 in order to delay applicability to the RICE MACT. OFS has now decided to remove these units from service prior to the October 19, 2013 compliance deadline. All remaining rich-burn engines with a site-rating less than 500 brake horsepower (C19, G-6 and G-7) are subject to emission and operating limitations in Subpart ZZZZ and will be required to comply with the standards by October 19, 2013. Subpart DDDDD, Industrial, Commercial and Institutional Boilers and Process Heaters at major sources of HAP. On January 31, 2013, the EPA took final action on its reconsideration of certain issues in the emission standards for the control of HAP from new and existing industrial, commercial, and institutional boilers and process heaters at major sources of HAP. The compliance dates for the rule are January 31, 2016, for existing sources and, January 31, 2013, or upon startup, whichever is later, for new sources. New sources are defined as sources that began operation on or after June 4, 2010. Hot oil heaters H-1 and H-2 are process heaters are affected units. Both of these units are existing sources in the unit designed to burn gas 1 subcategory and are rated greater than 10 MMBTUH. Units with a continuous oxygen trim system that maintains an optimum air to fuel ratio are required to conduct a tune-up of the boiler initially and then every 5 years thereafter as specified in § 63.7540. Units without a continuous oxygen trim system are required to conduct a tune-up of the boiler initially and then every 5 years thereafter as specified in § 63.7540. Units greater than 10 MMBTUH without a continuous oxygen trim system will conduct this tune-up as a work practice for all regulated emissions under this subpart. These affected units must conduct the required initial tune-up by January 31, 2016. Heaters H-3, H-4, H-5, H-6, H-7, B-1, and B-2 were considered small gaseous fuel heaters (less than 10 MMBtu/hr heat rating) that were not subject to any standards, recordkeeping, or PERMIT MEMORANDUM 2011-227-TVR2 DRAFT/PROPOSED 32 notifications under Subpart DDDDD. CAM, 40 CFR Part 64 [Applicable] Compliance Assurance Monitoring (CAM) applies to any pollutant specific emission unit at a major source that is required to obtain a Title V permit, if it meets all of the following criteria: 1. It is subject to an emission limit or standard for an applicable regulated air pollutant. 2. It uses a control device to achieve compliance with the applicable emission limit or standard. 3. It has potential emissions, prior to the control device, of the applicable regulated air pollutant of 100 TPY for a criteria pollutant, 10 TPY for an individual HAP, or 25 TPY for all HAP. Pre-control emissions from the glycol regenerator still vent are above 100 TPY for VOC and a control device is used to meet the permit emission limits. Therefore, since the glycol dehydration unit is subject to the control standards of Subpart HH, the unit and its controls are not subject to CAM. Engines C-16, C-17, C-18, and C-23, have pre-control emissions above major source levels and are equipped with catalytic converters (NSCR) to meet permit emission limits. Therefore, all these engines and their control components were previously determined to be subject to CAM. All of these engines became subject to emission limitations in 40 CFR Part 63, Subpart ZZZZ and were required to demonstrate compliance with those MACT standards by June 15, 2007. Therefore, the monitoring required by Subpart ZZZZ is presumptively acceptable as monitoring for CAM. Chemical Accident Prevention Provisions, 40 CFR Part 68 [Applicable] This facility handles naturally occurring hydrocarbon mixtures at a natural gas processing plant and is subject to this Subpart (Section 112r of the Clean Air Act 1990 Amendments). A Risk Management Plan was submitted to EPA Region 6 on June 14, 1999 and deemed complete on June 16, 1999. An update to the RMP was received on September 23, 1999 and judged complete on September 28, 1999. Renewals to the RMP were submitted on September 16, 2004 and September 16, 2009. EPA Notice of Confirmation was dated September 24, 2004. More information on this federal program is available on the web page: www.epa.gov/ceppo Stratospheric Ozone Protection, 40 CFR Part 82 [Subpart A and F Applicable] These standards require phase out of Class I & II substances, reductions of emissions of Class I & II substances to the lowest achievable level in all use sectors, and banning use of nonessential products containing ozone-depleting substances (Subparts A & C); control servicing of motor vehicle air conditioners (Subpart B); require Federal agencies to adopt procurement regulations which meet phase out requirements and which maximize the substitution of safe alternatives to Class I and Class II substances (Subpart D); require warning labels on products made with or containing Class I or II substances (Subpart E); maximize the use of recycling and recovery upon disposal (Subpart F); require producers to identify substitutes for ozone-depleting compounds under the Significant New Alternatives Program (Subpart G); and reduce the emissions of halons (Subpart H). PERMIT MEMORANDUM 2011-227-TVR2 33 DRAFT/PROPOSED Subpart A identifies ozone-depleting substances and divides them into two classes. Class I controlled substances are divided into seven groups; the chemicals typically used by the manufacturing industry include carbon tetrachloride (Class I, Group IV) and methyl chloroform (Class I, Group V). A complete phase-out of production of Class I substances is required by January 1, 2000 (January 1, 2002, for methyl chloroform). Class II chemicals, which are hydrochlorofluorocarbons (HCFCs), are generally seen as interim substitutes for Class I CFCs. Class II substances consist of 33 HCFCs. A complete phase-out of Class II substances, scheduled in phases starting by 2002, is required by January 1, 2030. This facility does not produce, consume, recycle, import, or export any controlled substances or controlled products as defined in this part, nor does this facility perform service on motor (fleet) vehicles that involves ozone-depleting substances. Therefore, as currently operated, this facility is not subject to these requirements. To the extent that the facility has air-conditioning units that apply, the permit requires compliance with Part 82. SECTION VIII. COMPLIANCE Inspection On May 30, 2012, from 10:00 hours to 13:00 hours, an announced air quality FCE was conducted at ONEOK Maysville Gas Plant. Austin Hawkins and Patrick Frisby, Environmental Programs Specialists for the Oklahoma Department of Environmental Quality, Air Quality Division (“Department”) conducted the evaluation. Berry Mantooth, Environmental Specialist, represented ONEOK. The Exit Interview/Summary states: The Facility appears to be in compliance with the requirements and conditions of Permit No. 2004-163-TVR (M-5) as well as state and federal regulations. However, the missing plate on the generator engine designated G5 should be considered an area of concern. As previously stated, the plate is missing, and is apparently lost. ONEOK personnel state that they would like to find the original plate since the unit is an antique but will fabricate a new plate if the original cannot be found. Since the May 30, 2012 FCE, there are no open compliance/enforcement issues involving this facility. A facility inspection is not needed for this permit renewal. Testing EU C-16 C-17 C-18 Permitted Engine Testing NOX CO Engine Limit Test Limit Test lb/hr lb/hr lb/hr lb/hr Waukesha L7042 GSIU 4.06 3.87 11.5 5.02 Waukesha L7042 GSIU 4.06 1.01 11.5 0.25 Waukesha L7042 GSIU 4.06 1.97 11.5 2.89 Testing Date 07/16/2013 08/28/2013 07/16/2013 PERMIT MEMORANDUM 2011-227-TVR2 EU C-19 C-20 C-21 C-22 C-23 C-24 C-25 C-26 C-27 C-28 C-29 G-6 G-7 Engine Waukesha L5108 GU Superior 16GTLA Superior 16GTLA Superior 16GTLA Superior 8G825 Superior 6G825 Superior 8GTLA Superior 12GTLA Superior 12GTLA Superior 12GTLA Superior 12GTLA Waukesha L3711 Waukesha L3711 NOX Limit Test lb/hr lb/hr 2.17 0.09 9.15 4.90 9.15 7.75 9.15 1.76 3.52 0.30 2.64 0.01 4.58 0.48 6.86 6.27 6.86 6.66 6.86 4.54 6.86 0.75 1.48 0.60 1.48 0.08 34 DRAFT/PROPOSED CO Limit Test lb/hr lb/hr 5.23 1.11 13.7 7.81 13.7 6.02 13.7 8.75 5.29 0.79 3.96 0.68 6.87 2.70 10.3 5.08 10.3 6.35 10.3 5.51 10.3 6.54 4.17 0.35 4.17 0.28 Testing Date 07/16/2013 07/16/2013 04/03/2013 07/16/2013 07/18/2013 08/28/2013 07/16/2013 08/28/2013 07/16/2013 07/16/2013 09/17/2013 08/28/2013 08/28/2013 Tier Classification and Public Review This application has been classified as Tier II based on the request for the second renewal of the Title V operating permit. Public and EPA review of the application and permit are required. The permit will be reviewed by EPA Region VI for review for a period of 45 days which will be concurrent with the 30 day public review required by Tier II permits. The applicant has submitted a signed affidavit from Garvin County News Star, a weekly publication that is a “legal newspaper” for the City of Maysville, in Garvin county, that a “Notice of Filing a Tier II Application” was published on April 28, 2011. The Notice stated that the application was available for public review at the Elliott Lasater Maysville library or at the Air Quality Division’s main office. No comments were received from the public. The applicant will be required to publish a “Notice of Tier II Draft Permit” when this draft permit is issued. The facility is not located within 50 miles of the Oklahoma State border. The permittee has submitted an affidavit that they are not seeking a permit for land use or for any operation upon land owned by others without their knowledge. The affidavit certifies that the applicant owns the land. Information on all permit actions is available for review by the public in the Air Quality section of the DEQ Web Page: www.deq.state.ok.us. PERMIT MEMORANDUM 2011-227-TVR2 DRAFT/PROPOSED 35 Fees Paid A renewal to a Part 70 permit application fee of $1,000 has been paid. SECTION IX. SUMMARY The facility is constructed and operated as described in the permit application. Ambient air quality standards are not threatened at this site and OFS has submitted modeling demonstrating that the facility is in compliance with the NAAQS for NO2, There are no active compliance or enforcement Air Quality issues that affect the issuance of this permit. Issuance of this permit is recommended, contingent on public and EPA review. DRAFT/PROPOSED PERMIT TO OPERATE AIR POLLUTION CONTROL FACILITY SPECIFIC CONDITIONS ONOEK Field Services Company, L.L.C. Maysville Gas Plant Permit Number 2011-227-TVR2 The permittee is authorized to operate in conformity with the specifications submitted to Air Quality on February 23, 2010, and at various other times as requested. The Evaluation Memorandum dated October 14, 2013 explains the derivation of applicable permit requirements and estimates of emissions; however, it does not contain operating limitations or permit requirements. Operating under this permit constitutes acceptance of, and consent to, the conditions contained herein: 1. Points of emissions and emissions limitations for each point: [OAC 252:100-8-6(a)(1)] EUG 1 and EUG 2. Grandfathered Engines and Permitted Engines EUG 1. Grandfathered Engines - no emission limits are applied to these engines under Title V, but emissions are limited to the existing equipment as it is. EU C-1 C-2 C-3 C-4 C-5 C-6 C-7 C-8 C-9 C-10 C-11 C-13 C-14 Engine Clark RA-8 Clark RA-8 Clark RA-8 Clark RA-6 Clark RA-6 Clark RA-8 Clark RA-8 Clark HRA-8 Clark HRA-8 Clark HRA-8 Clark HBA-8 Clark HBA-8 Clark HBA-5 Hp 800 800 800 600 600 800 800 880 880 880 1,760 1,760 1,100 Serial # 25938 25937 25936 21133 21132 25927 25928 A25567 A25568 A25572 30269 30271 35601 SPECIFIC CONDITIONS 2011-227-TVR2 DRAFT/PROPOSED 2 EUG 2. Permitted engines - emissions for these units are limited as follows. EU Engine Serial # C-16.2 C-17 C-18 C-19 C-20 C-21 C-22 C-23 C-24 C-25 C-26.2 C-27 C-28 C-29 G-6 G-7 Waukesha L7042 GSIU Waukesha L7042 GSIU Waukesha L7042 GSIU Waukesha L5108 GU Superior 16GTLA Superior 16GTLA Superior 16GTLA Superior 8G825 Superior 6G825 Superior 8GTLA Superior 12GTLA Superior 12GTLA Superior 12GTLA Superior 12GTLA Waukesha L3711 Waukesha L3711 365714A 387563 387652 387653 306999 306599 291649 282349 292229 293109 310529 304979 304989 295909 48027 48028 NOX lb/hr TPY 4.07 17.8 4.07 17.8 4.07 17.8 2.17 9.5 9.16 40.1 9.16 40.1 9.16 40.1 3.53 15.5 2.65 11.6 4.58 20.1 6.87 30.1 6.87 30.1 6.87 30.1 6.87 30.1 1.48 6.47 1.48 6.47 CO lb/hr 11.5 11.48 11.48 5.21 13.7 13.7 13.7 5.29 3.97 6.87 10.3 10.3 10.3 10.3 4.17 4.17 TPY 50.3 50.3 50.3 22.8 60.0 60.0 60.0 23.2 17.4 30.1 45.1 45.1 45.1 45.1 18.3 18.3 VOC lb/hr TPY 2.03 8.90 2.03 8.90 2.03 8.90 1.08 4.75 4.58 20.1 4.58 20.1 4.58 20.1 1.76 7.72 1.32 5.79 2.29 10.0 3.43 15.0 3.43 15.0 3.43 15.0 3.43 15.0 0.74 3.2 0.74 3.2 2. Each engine at the facility shall have a permanent identification plate attached, which shows the make, model number, and serial number. [OAC 252:100-43] 3. The permittee shall at all times properly operate and maintain all engines in a manner that will minimize emissions of hydrocarbons or other organic materials. [OAC 252:100-37-36] 4. The permittee shall keep operation and maintenance (O&M) records for the grandfathered engines (EUG 1) and for each permitted engine (EUG 2) that is not tested in a quarter. Such records shall at a minimum include the dates of operation and maintenance, type of work performed, and the increase, if any, in emissions as a result. [OAC 252:100-8-6 (a)(3)(B)] 5. At least once per calendar quarter, the permittee shall conduct tests of NOX and CO emissions in exhaust gases from each engine in EUG 2 and from each replacement engine/turbine when operating under representative conditions for that period. Testing is required for each engine in EUG 2 or any replacement engine/turbine that runs for more than 220 hours during that calendar quarter. A quarterly test may be conducted no sooner than 20 calendar days after the most recent test. Testing shall be conducted using a portable analyzer in accordance with a protocol meeting the requirements of the latest AQD Portable Analyzer Guidance document, or an equivalent method approved by Air Quality. When four consecutive quarterly tests show the engine/turbine to be in compliance with the emissions limitations shown in the permit, then the testing frequency may be reduced to semi-annual testing. A semi-annual test may be conducted no sooner than 60 calendar days SPECIFIC CONDITIONS 2011-227-TVR2 DRAFT/PROPOSED 3 nor later than 180 calendar days after the most recent test. Likewise, when the following two consecutive semi-annual tests show compliance, the testing frequency may be reduced to annual testing. An annual test may be conducted no sooner than 120 calendar days nor later than 365 calendar days after the most recent test. Upon any showing of noncompliance with emissions limitations or testing that indicates that emissions are within 10% of the emission limitations, the testing frequency shall revert to quarterly. Reduced testing frequency does not apply to engines with catalytic converters. Any reduction in the testing frequency shall be noted in the next required compliance certification. [OAC 252:100-8-6 (a)(3)(A)] 6. When periodic compliance testing shows exhaust emissions from the engines in excess of the lb/hr limits in Specific Condition No. 1, the permittee shall comply with the provisions of OAC 252:100-9. Requirements of OAC 252:100-9 include immediate notification and written notification of Air Quality and demonstrations that the excess emissions meet the criteria specified in OAC 252:100-9. [OAC 252:100-9] 7. Replacement (including temporary periods of 6 months or less for maintenance purposes), of the internal combustion engines with emissions specified in this permit with engines/turbines of lesser or equal emissions of each pollutant (in lbs/hr and TPY) is authorized under the following conditions. a. b. c. d. 8. The permittee shall notify AQD in writing no later than 7 days in advance of the start-up of the replacement engine(s)/turbine(s). Said notice shall identify the equipment removed and shall include the new engine/turbine make, model, and horsepower; date of the change, and any change in emissions. Quarterly emissions tests for the replacement engine(s)/turbine(s) shall be conducted to confirm continued compliance with NOX and CO emissions limitations. A copy of the first quarter testing shall be provided to AQD within 60 days of start-up of each replacement or additional engine/turbine. The test report shall include the engine/turbine fuel usage, stack flow (ACFM), stack temperature (oF), stack height (feet), stack diameter (inches), and pollutant emissions rates (g/hp-hr, lbs/hr, and TPY) at maximum rated horsepower for the altitude/location. Replacement equipment and emissions are limited to equipment and emissions that are not a modification under NSPS, NESHAP, or a significant modification under PSD. [OAC 252:100-8-6(f)] Engines installed as allowed under the replacement allowance in this Specific Condition that are subject to 40 CFR Part 63, Subpart ZZZZ and/or 40 CFR Part 60, Subpart JJJJ shall comply with all applicable requirements. By the initial compliance date of October 19, 2013, the owner/operator shall comply with all applicable requirements of the NESHAP: Reciprocating Internal Combustion Engines, Subpart ZZZZ, for each affected facility including but not limited to the provisions listed below. [40 CFR 63 Subpart ZZZZ] SPECIFIC CONDITIONS 2011-227-TVR2 DRAFT/PROPOSED 4 What This Subpart Covers a. § 63.6580 What is the purpose of subpart ZZZZ? b. § 63.6585 Am I subject to this subpart? c. § 63.6590 What parts of my plant does this subpart cover? d. § 63.6595 When do I have to comply with this subpart? Emission and Operating Limitations e. § 63.6603 What emission limitations and operating limitations must I meet if I own or operate an existing stationary RICE located at an area source of HAP emissions? General Compliance Requirements f. § 63.6605 What are my general requirements for complying with this subpart? Testing and Initial Compliance Requirements g. § 63.6625 What are my monitoring, installation, operation, and maintenance requirements? h. § 63.6630 How do I demonstrate initial compliance with the emission limitations and operating limitations? Continuous Compliance Requirements i. § 63.6640 How do I demonstrate continuous compliance with the emission limitations and operating limitations? Notifications, Reports, and Records j. § 63.6650 What reports must I submit and when? k. § 63.6655 What records must I keep? l. § 63.6660 In what form and how long must I keep my records? Other Requirements and Information m. § 63.6665 What parts of the General Provisions apply to me? n. § 63.6670 Who implements and enforces this subpart? o. § 63.6675 What definitions apply to this subpart? 9. The permittee shall comply with the Standards of Performance for Equipment Leaks of VOC from Onshore Natural Gas Processing Plants, NSPS 40 CFR Part 60, Subpart KKK including, but not limited to, the following: [40 CFR §60.630 to §60.636] a. b. c. d. Information and data used to demonstrate that a reciprocating compressor is in wet gas service to apply for the exemption in §60.633(f) shall be recorded in a log that is kept in a readily accessible location as per §60.635(c). Information and data used to demonstrate that a reciprocating compressor is not in VOC service shall be recorded in a log that is kept in a readily accessible location as per §60.486(j). C-19, C-24, and C-25 shall be equipped with a VOC leakage capture system operated and maintained in proper working order per §60.482-3 (h). As an alternative to iii above, for each compressor subject to the control standards of 40 CFR §§60.482-3(a) thru (h), the permittee may choose to apply the exemption of 40 CFR §60.482-3(i) (no detectable emissions, as indicated by an instrument reading of less than 500 ppm above background) by monitoring the compressor initially, annually, and at any other time requested by AQD. The permittee shall keep records as DRAFT/PROPOSED SPECIFIC CONDITIONS 2011-227-TVR2 5 required by 40 CFR §60.486(e) (1) and (2). 10. While in service the engines for generators G-1, G-2, G-3, G-4, and G-5 are each limited to an output of less than 500-hp. The permittee shall demonstrate compliance by limiting the power output from each generator to no more than 330-KW based on the average KW generated for the hours that each generator operates during a calendar month. Once each day, the permittee shall record the KW output from each generator during normal operation. EUG 3. Tanks 11. Total throughput is limited as follows: EU TK-1 Content Condensate / BS&W [OAC 252:100-8-6(a)(1)] Throughput, gallons per day 19,000 12. The throughput limit shall be based on a daily average calculated by dividing a rolling 12month total by 365 days. 13. Emissions from TK-1 shall be vented to the plant process/emergency flare. 14. Emissions from the tanks listed below are considered insignificant because emissions are less than 5 TPY; therefore, these units do not have any specific emission limitations. EU TK-2 TK-3 TK-4 TK-5 TK-6 TK-7 TK-8 15. Contents Scrubber Oil, North Scrubber Oil, South BS&W / Condensate Methanol Methanol Gasoline Solvent < 1.5 psia vapor pressure Gallons 23,200 22,000 4,200 8,820 1,730 3,000 580 Tanks TK-4, TK-5, TK-6, and TK-7 shall be equipped with a submerged fill pipe. [OAC 252:100-37-15(b)] EUG-4. Fugitive Components (Not subject to NSPS Subpart KKK or MACT Subpart HH) 16. No emission limits are applied to this EUG under Title V, but emissions are limited to the existing equipment as it is. EU FUG-1 Type of Equipment Connectors Valves Open Ended Lines Estimated Number of Items 7,000 3,500 280 SPECIFIC CONDITIONS 2011-227-TVR2 DRAFT/PROPOSED Flanges Compressor Seals Pump Seals Relief Valves * 6 4,378 56 113 38 Estimated only, not a permit limit. EUG-5. Fugitive Components (Subject to NSPS Subpart KKK) 17. No emission limits are applied to this EUG under Title V, but emissions are limited to the existing equipment as it is. EU Type of Equipment Connectors Valves Open Ended Lines Flanges Compressor Seals Pump Seals Relief Valves FUG-2 * 18. Estimated Number of Items 6,522 3,091 282 4,006 5 28 5 Estimated only, not a permit limit. New, modified or reconstructed Process Units at the Maysville Gas Plant are subject to NSPS 40 CFR Part 60, Subpart KKK. These include, but are not limited to, the two liquids extraction units (Plant 3 cryo and South Refrigeration System), four inlet headers (Inlet Gas South Low and High, Anadarko Inlet, and Waukesha Inlet), the glycol dehydration unit (TEG System), the demethanizer system, Plant 3 regeneration system, the two amine units that are in VOC service (DGA North Amine Treater and DEA South Amine Treater), compressors C19, C-24 and C-25, and the WOK 16” inlet and condensate handling process. The permittee shall comply with this subpart including, but not limited to, the following requirements: [40 CFR 60.630-636] a. b. c. d. e. §60.632: Standards. §60.635: Recordkeeping requirements. §60.636: Reporting requirements. Information and data used to demonstrate that ancillary equipment is not in VOC service shall be recorded in a log that is kept in a readily accessible location as per §60.486(j). Any new construction, reconstruction or modification will be subject to 40 CFR Part 60, Subpart KKK for affected components in VOC service. EUG 6. Heaters & Boilers 19. No emission limits are applied to the grandfathered heater H-2 under Title V, but emissions are limited to the existing equipment as it is. Emissions from heater H-1 are limited as DRAFT/PROPOSED SPECIFIC CONDITIONS 2011-227-TVR2 7 follows. EU H-1 H-2 NOX lb/hr TPY 4.98 21.8 - Equipment Hot Oil Heater (West) Hot Oil Heater (East) CO lb/hr TPY 4.18 18.3 - VOC lb/hr TPY 0.28 1.2 - 20. Compliance with the emissions limits for H-1 is demonstrated by the heater’s design heat input rating of 50 MMBtu/hr and by firing natural gas. [OAC 252:100-43] 21. Heater H-1 is subject to NSPS Subpart Dc, but must comply only with the initial notification requirements of 40 CFR §60.48c (a)(1) and the recordkeeping requirements of 40 CFR §60.48c (g). [40 CFR Part 60 Subpart Dc] 22. Emissions from the units listed below are considered insignificant because emissions are less than 5 TPY; therefore, these units do not have any specific emission limitations. EU H-3 H-4 H-5 H-6 H-7 B-1 B-2 23. Equipment Regen. Gas Heater (Plant #1) Regen. Gas Heater (Plant #2) Glycol Reboiler Amine Reboiler Regen. Gas Heater (Plant #3) Boiler #1 (North, OK36454) Boiler #2 (South, OK43476) MMBtu/hr 5.0 1.5 2.5 6.0 7.5 2.0 2.0 Serial # 75122 41593 0132 5991 1276 1740 9777 The heaters and boilers in EUG6 are subject to 40 CFR 63, Subpart DDDDD. The affected source under Subpart DDDDD is the collection of all existing industrial, commercial and institutional boilers and process heaters within a subcategory as defined in §63.7575. All heaters and boilers in EUG6 are existing units in the subcategory designed to burn gas 1 fuel. As such the affected units in EUG6 will be subject only to the work practice standards in Table 3 of Subpart DDDDD and other applicable monitoring recordkeeping, and reporting requirements. EUG-7. Process/Emergency Flare 24. 25. No emission limits are applied to this unit under Title V, but emissions are limited to the existing equipment as it is. EU MMBtu/hr PFL-1 27,000 Diameter, inches 24 Height, feet 110 The process/emergency flare is subject to 40 CFR §60.18 General Control Requirements and the permittee shall comply with all requirements, including, but not limited to, the SPECIFIC CONDITIONS 2011-227-TVR2 DRAFT/PROPOSED following: a. b. 8 [40 CFR §60.18] The flare shall be operated at all times when emissions may be vented to it. The presence of a pilot flame shall be monitored using a thermocouple or any other equivalent device to detect the presence of a flame. EUG-8. Acid Gas Flare 26. Emissions are limited as follows: EUG-8 Acid Gas Flare Unit lb/hr TPY NOX 0.10 0.45 CO 0.56 2.45 VOC 1.70 7.45 SO2 12.8 55.9 H2 S 0.14 0.61 27. Emissions of NOX, CO, and VOC are limited by the Acid Gas Flare’s design heat rating of 1.5 MMBtu/hr. [OAC 252:100-43] 28. H2S concentration and/or the flow rate of the plant inlet gas streams or the acid gas stream(s) shall be limited to ensure that the emission limits for SO2 are not exceeded. [OAC 252:100-31-7 (a) and (b)] a. b. 29. The daily sulfur feed rate from the north amine unit and the south amine unit (i.e., the H2S in the acid gas), expressed as sulfur, shall be no more than 0.071 LT/D. H2S concentration and/or the flow rate of the plant inlet gas streams or the acid gas stream(s) shall be limited to ensure compliance with this daily sulfur feed rate limit. The daily rate shall be calculated based on daily gas flow rate(s) and a quarterly measured H2S concentration. Flow and H2S concentration shall be measured at one of the following locations: (1) plant inlet gas streams, or (2) total acid gas stream prior to the acid gas flare. Compliance with the annual emission limits of SO2 shall be based on a 12-month rolling total. The permittee shall calculate the total SO2 emissions from the acid gas flare stack based on 98% conversion of H2S. The calculations shall be based on a quarterly tested H2S concentration and the daily average gas flow rate for that month measured at one of the following locations: (1) plant inlet gas streams, or (2) total acid gas stream prior to the acid gas flare. These calculations will be submitted with the semiannual monitoring and deviation report. The flare shall have installed, calibrated, maintained, and operated an alarm system that will signal non-combustion of the gas. [OAC 252:100-31-26(c)] EUG-9. VOC Flare 30. Emissions are limited as follows: SPECIFIC CONDITIONS 2011-227-TVR2 EUG-9 VOC Flare Unit lb/hr TPY DRAFT/PROPOSED NOX 2.7 12 CO 15 66 9 VOC 2.5 11 31. Emissions of NOX, CO, and VOC are limited by the flare’s design heat rating of 40 MMBtu/hr. [OAC 252:100-43] 32. The VOC flare is subject to 40 CFR §60.18 General Control Requirements and the permittee shall comply with all requirements, including, but not limited to, the following: [40 CFR §60.18] a. b. The flare shall be operated at all times when emissions may be vented to it. The presence of a pilot flame shall be monitored using a thermocouple or any other equivalent device to detect the presence of a flame. EUG-10. Glycol Dehydration Unit 33. The dehydration unit shall be operated in such a way that benzene emissions are less than 1.0 tpy. 34. Vapors from the rich glycol flash tank shall be vented to the plant inlet gas stream. 35. The glycol dehydration unit in EUG-10 shall be equipped with a condenser and uncondensed regenerator vent vapors shall be routed either to the plant inlet gas stream or to the process/emergency flare for combustion. The unit is subject to NESHAP Subpart HH and must meet the compliance, reporting, and recordkeeping requirements of Subpart HH. [40 CFR §63 Subpart HH] 36. The permittee shall determine actual average benzene emissions using the model GRIGLYCalc™ Version 3.0 or higher, as required by MACT Subpart HH. Inputs to the model shall be representative of actual operating conditions. The permittee shall also maintain records as required by MACT Subpart HH to document compliance with the benzene limit. 37. The glycol dehydrator is subject to NESHAP, 40 CFR Part 63, Subpart HH and all affected equipment shall comply with all applicable requirements. [40 CFR 63, NESHAP, Subpart HH] a. § 63.760 Applicability and designation of affected source. b. § 63.761 Definitions. c. § 63.762 Startups, shutdowns, and malfunctions. d. § 63.764 General standards. e. § 63.765 Glycol dehydration unit process vent standards. f. § 63.766 Storage vessel standards. g. § 63.769 Equipment leak standards. h. § 63.771 Control equipment requirements. i. § 63.772 Test methods, compliance procedures, and compliance determinations. SPECIFIC CONDITIONS 2011-227-TVR2 j. k. l. m. n. DRAFT/PROPOSED 10 § 63.773 Inspection and monitoring requirements. § 63.774 Recordkeeping requirements. § 63.775 Reporting requirements. § 63.776 Delegation of authority. § 63.777 Alternative means of emission limitation. EUG-11. Condensate/Scrubber Oil Truck Loading 38. Emissions and throughput are limited as follows. ID # TL-1 39. Throughput VOC bbl/yr 164,363 TPY 17.7 The throughput limit is based on a 12-month rolling total. Compliance with the throughput limit demonstrates compliance with the emissions limit. EUG-12. Fugitive Components (subject to NESHAP Subpart HH) 40. No emission limits are applied to this EUG under Title V, but emissions are limited to the existing equipment as it is. EU Type of Equipment FUG-1 Connectors Valves Pressure Relief Valves Pump Seals * Number of Components * 2,197 950 38 9 Estimated only, not a permit limit. EUG 13. Miscellaneous Process Vent 41. VOC emissions are estimated based on existing equipment items but do not have a specific limitation. EU ID # VENT Point # VENT Emission Units Miscellaneous Process Vents Date Constructed 1948 EUG 14. WOK Condensate Tanks 42. Total throughput is limited as follows: [OAC 252:100-8-6(a)(1)] SPECIFIC CONDITIONS 2011-227-TVR2 43. EU Content TK-9, TK-10, TK-11, TK-12 Condensate EU Content TK-9, TK-10, TK-11, TK-12 Condensate DRAFT/PROPOSED Throughput during normal operation, gallons per yr 1,533,000 Throughput during VRU downtime, gallons per yr 17,500 Condensate tanks shall have the following operating conditions: a. b. c. 11 [OAC 252:100-37-15(b)] The throughput limits shall be based on a rolling 12-month total. Emissions from EUG-14 shall be vented to a closed vapor recovery system with 100% efficiency, except during VRU downtime. Tanks in EUG-14 shall be equipped with a submerged fill pipe. EUG-15. WOK Condensate Truck Loading from EUG-14 44. Emissions and throughput are limited as follows. EU TL-2 45. Throughput VOC gal/yr 1,533,000 TPY 6.76 The throughput limit is based on a 12-month rolling total. Compliance with the throughput limit demonstrates compliance with the emissions limit. Facility-Wide General Specific Conditons 46. The fuel-burning equipment shall be fired with pipeline grade natural gas or other gaseous fuel with a sulfur content less than 343 ppmv. Compliance can be shown by the following methods: for gaseous fuel, a current gas company bill, a current lab analysis, stain-tube analysis, gas contract, tariff sheet, or other approved methods. Compliance shall be demonstrated at least once annually. 47. The permittee shall be authorized to operate this facility continuously (24 hours per day, every day of the year). [OAC 252:100-8-6(a)] 48. Fugitive components: a. The fugitive components of EUG 12 and the glycol dehydrator of EUG 10 are subject to CFR 40 Part 63, Subpart HH provided that they are affected components in VHAP service (defined as HAP content greater than 10% by weight) and shall comply with all applicable requirements including, but not limited to, the following. [40 CFR §63.760 to §63.779] SPECIFIC CONDITIONS 2011-227-TVR2 i. ii. iii. iv. v. vi. vii. viii. ix. x. DRAFT/PROPOSED 12 40 CFR 63.762: Startup, shutdowns, and malfunctions. 40 CFR 63.764: General standards. 40 CFR 63.765: Glycol dehydration unit process vents standards. Emissions from the rich glycol flash tank and the glycol regenerator still vent are subject to Subpart HH, but are exempt from the standards per §63.764(e)(1)(ii). The permittee shall maintain records per §63.774(d)(1) demonstrating that actual benzene emissions are below 0.90 megagram (1.0 TPY) using the methods outlined in §63.772(b)(2). 40 CFR 63.766: Storage vessel standards. Tank TK-1 is not an affected source since it has a federally enforceable throughput limit of 19,000 gallons per day based on a daily average. 40 CFR 63.769: Equipment leak standards. All components in vapor service and light liquid service are below the 10% by weight threshold except those components in natural gasoline service, condensate service, and the engine jacket water systems, which use ethylene glycol. Documentation of those components exempt from the standards must be made per §63.764(e)(2) and records kept per §63.774(d)(1). 40 CFR 63.772: Test methods, compliance procedures, and compliance demonstrations. 40 CFR 63.774: Recordkeeping requirements. 40 CFR 63.775: Reporting requirements. 40 CFR 63.776: Delegation of authority. 40 CFR 63.777: Alternate means of emission limitation. 49. Quarterly visual inspections of equipment in ethylene glycol VHAP service may be used as a monitoring alternative to Method 21. [40 CFR §63.8(b)(ii)] 50. Ancillary equipment and compressors that are subject to this subpart (40 CFR Part 63, Subpart HH) and are also subject to 40 CFR Part 60, Subpart KKK, are only required to comply with the requirements of 40 CFR Part 60, Subpart KKK as an approved monitoring alternative. The permittee shall document that they are complying with 40 CFR Part 60, Subpart KKK by keeping the records specified in 40 CFR 63.774(b)(9). 51. The north (DGA) and south (DEA) amine units are subject to 40 CFR Part 60, Subpart LLL, but are exempt from any control standards. The permittee shall comply with §60.647 (c), which requires the facility to keep, for the life of the facility, an analysis demonstrating that the facility’s design capacity is less than 2 long tons per day (LT/D) of H2S in the acid gas (expressed as sulfur). [40 CFR §60.40 to §60.648] 52. The following records shall be maintained on-site to verify Insignificant Activities. No recordkeeping is required for those operations that qualify as Trivial Activities. [OAC 252:100-8-6 (a)(3)(B)] a. For emissions from condensate tanks with a design capacity of 400 gallons or less in SPECIFIC CONDITIONS 2011-227-TVR2 b. c. 53. DRAFT/PROPOSED 13 ozone attainment areas: the tank capacity and contents. For surface coating operations which do not exceed a combined total usage of more than 60 gallons/month of coatings, thinners, and clean-up solvents at any one emissions unit: the total gallons used (monthly). For activities having the potential to emit no more than 5 TPY (actual) of any criteria pollutant: the type of activity and the amount of emissions from that activity (annual). The permittee shall maintain records of operations as listed below. These records shall be maintained on-site for at least five years after the date of recording and shall be provided to regulatory personnel upon request. [OAC 252:100-43] a. b. c. d. e. f. g. h. i. j. k. l. m. n. o. For the fuel burned, the appropriate document(s) as described in Specific Condition No. 2. O&M records for each “grandfathered” engine in EUG-1. O&M records for any engine in EUG-2, if operated less than 220 hours per quarter and not tested. Periodic testing for NOX and CO for each engine in EUG-2. Monthly records of the average KW output from generators G-1, G-2, G-3, G-4, and G-5. Records required by 40 CFR §60.647 (c) demonstrating that both the north (DGA) and south (DEA) amine units have a design capacity less than 2 long tons per day (LT/D) of H2S in the acid gas (expressed as sulfur). Throughput of tank TK-1 (rolling 12-month total). Throughput of EUG-14 condensate tanks for normal operation and for VRU downtime (rolling 12-month total). Records of quarterly tested H2S concentration and the daily average gas flow rate(s) measured at one of the following locations: (1) plant inlet gas streams, or (2) total acid gas stream prior to the acid gas flare. And calculations of SO2 emissions from the acid gas flare (12-month rolling total). Records required by 40 CFR §60, Subpart KKK. Records required by 40 CFR §60, Subpart JJJJ. Records required by 40 CFR §63, Subpart HH. Records required by 40 CFR §63, Subpart ZZZZ. Records required by 40 CFR §64, CAM. Records required by 40 CFR §60, Subpart OOOO. 54. No later than 30 days after each anniversary date of the issuance of the original Part 70 permit (December 8, 1999), the permittee shall submit to Air Quality Division of DEQ, with a copy to the US EPA, Region 6, a certification of compliance with the terms and conditions of this permit. For this permit, the semiannual reporting periods are defined as May 30 through November 29 and November 30 through May 29. [OAC 252:100-8-6 (c)(5)(A), (C) & (D)] 55. This permit supersedes all previous air quality operating permits for this facility, which are now null and void. MAJOR SOURCE AIR QUALITY PERMIT STANDARD CONDITIONS (July 21, 2009) SECTION I. DUTY TO COMPLY A. This is a permit to operate / construct this specific facility in accordance with the federal Clean Air Act (42 U.S.C. 7401, et al.) and under the authority of the Oklahoma Clean Air Act and the rules promulgated there under. [Oklahoma Clean Air Act, 27A O.S. § 2-5-112] B. The issuing Authority for the permit is the Air Quality Division (AQD) of the Oklahoma Department of Environmental Quality (DEQ). The permit does not relieve the holder of the obligation to comply with other applicable federal, state, or local statutes, regulations, rules, or ordinances. [Oklahoma Clean Air Act, 27A O.S. § 2-5-112] C. The permittee shall comply with all conditions of this permit. Any permit noncompliance shall constitute a violation of the Oklahoma Clean Air Act and shall be grounds for enforcement action, permit termination, revocation and reissuance, or modification, or for denial of a permit renewal application. All terms and conditions are enforceable by the DEQ, by the Environmental Protection Agency (EPA), and by citizens under section 304 of the Federal Clean Air Act (excluding state-only requirements). This permit is valid for operations only at the specific location listed. [40 C.F.R. §70.6(b), OAC 252:100-8-1.3 and OAC 252:100-8-6(a)(7)(A) and (b)(1)] D. It shall not be a defense for a permittee in an enforcement action that it would have been necessary to halt or reduce the permitted activity in order to maintain compliance with the conditions of the permit. However, nothing in this paragraph shall be construed as precluding consideration of a need to halt or reduce activity as a mitigating factor in assessing penalties for noncompliance if the health, safety, or environmental impacts of halting or reducing operations would be more serious than the impacts of continuing operations. [OAC 252:100-8-6(a)(7)(B)] SECTION II. REPORTING OF DEVIATIONS FROM PERMIT TERMS A. Any exceedance resulting from an emergency and/or posing an imminent and substantial danger to public health, safety, or the environment shall be reported in accordance with Section XIV (Emergencies). [OAC 252:100-8-6(a)(3)(C)(iii)(I) & (II)] B. Deviations that result in emissions exceeding those allowed in this permit shall be reported consistent with the requirements of OAC 252:100-9, Excess Emission Reporting Requirements. [OAC 252:100-8-6(a)(3)(C)(iv)] C. Every written report submitted under this section shall be certified as required by Section III (Monitoring, Testing, Recordkeeping & Reporting), Paragraph F. [OAC 252:100-8-6(a)(3)(C)(iv)] TITLE V PERMIT STANDARD CONDITIONS SECTION III. July 21, 2009 2 MONITORING, TESTING, RECORDKEEPING & REPORTING A. The permittee shall keep records as specified in this permit. These records, including monitoring data and necessary support information, shall be retained on-site or at a nearby field office for a period of at least five years from the date of the monitoring sample, measurement, report, or application, and shall be made available for inspection by regulatory personnel upon request. Support information includes all original strip-chart recordings for continuous monitoring instrumentation, and copies of all reports required by this permit. Where appropriate, the permit may specify that records may be maintained in computerized form. [OAC 252:100-8-6 (a)(3)(B)(ii), OAC 252:100-8-6(c)(1), and OAC 252:100-8-6(c)(2)(B)] B. Records of required monitoring shall include: (1) the date, place and time of sampling or measurement; (2) the date or dates analyses were performed; (3) the company or entity which performed the analyses; (4) the analytical techniques or methods used; (5) the results of such analyses; and (6) the operating conditions existing at the time of sampling or measurement. [OAC 252:100-8-6(a)(3)(B)(i)] C. No later than 30 days after each six (6) month period, after the date of the issuance of the original Part 70 operating permit or alternative date as specifically identified in a subsequent Part 70 operating permit, the permittee shall submit to AQD a report of the results of any required monitoring. All instances of deviations from permit requirements since the previous report shall be clearly identified in the report. Submission of these periodic reports will satisfy any reporting requirement of Paragraph E below that is duplicative of the periodic reports, if so noted on the submitted report. [OAC 252:100-8-6(a)(3)(C)(i) and (ii)] D. If any testing shows emissions in excess of limitations specified in this permit, the owner or operator shall comply with the provisions of Section II (Reporting Of Deviations From Permit Terms) of these standard conditions. [OAC 252:100-8-6(a)(3)(C)(iii)] E. In addition to any monitoring, recordkeeping or reporting requirement specified in this permit, monitoring and reporting may be required under the provisions of OAC 252:100-43, Testing, Monitoring, and Recordkeeping, or as required by any provision of the Federal Clean Air Act or Oklahoma Clean Air Act. [OAC 252:100-43] F. Any Annual Certification of Compliance, Semi Annual Monitoring and Deviation Report, Excess Emission Report, and Annual Emission Inventory submitted in accordance with this permit shall be certified by a responsible official. This certification shall be signed by a responsible official, and shall contain the following language: “I certify, based on information and belief formed after reasonable inquiry, the statements and information in the document are true, accurate, and complete.” [OAC 252:100-8-5(f), OAC 252:100-8-6(a)(3)(C)(iv), OAC 252:100-8-6(c)(1), OAC TITLE V PERMIT STANDARD CONDITIONS July 21, 2009 3 252:100-9-7(e), and OAC 252:100-5-2.1(f)] G. Any owner or operator subject to the provisions of New Source Performance Standards (“NSPS”) under 40 CFR Part 60 or National Emission Standards for Hazardous Air Pollutants (“NESHAPs”) under 40 CFR Parts 61 and 63 shall maintain a file of all measurements and other information required by the applicable general provisions and subpart(s). These records shall be maintained in a permanent file suitable for inspection, shall be retained for a period of at least five years as required by Paragraph A of this Section, and shall include records of the occurrence and duration of any start-up, shutdown, or malfunction in the operation of an affected facility, any malfunction of the air pollution control equipment; and any periods during which a continuous monitoring system or monitoring device is inoperative. [40 C.F.R. §§60.7 and 63.10, 40 CFR Parts 61, Subpart A, and OAC 252:100, Appendix Q] H. The permittee of a facility that is operating subject to a schedule of compliance shall submit to the DEQ a progress report at least semi-annually. The progress reports shall contain dates for achieving the activities, milestones or compliance required in the schedule of compliance and the dates when such activities, milestones or compliance was achieved. The progress reports shall also contain an explanation of why any dates in the schedule of compliance were not or will not be met, and any preventive or corrective measures adopted. [OAC 252:100-8-6(c)(4)] I. All testing must be conducted under the direction of qualified personnel by methods approved by the Division Director. All tests shall be made and the results calculated in accordance with standard test procedures. The use of alternative test procedures must be approved by EPA. When a portable analyzer is used to measure emissions it shall be setup, calibrated, and operated in accordance with the manufacturer’s instructions and in accordance with a protocol meeting the requirements of the “AQD Portable Analyzer Guidance” document or an equivalent method approved by Air Quality. [OAC 252:100-8-6(a)(3)(A)(iv), and OAC 252:100-43] J. The reporting of total particulate matter emissions as required in Part 7 of OAC 252:100-8 (Permits for Part 70 Sources), OAC 252:100-19 (Control of Emission of Particulate Matter), and OAC 252:100-5 (Emission Inventory), shall be conducted in accordance with applicable testing or calculation procedures, modified to include back-half condensables, for the concentration of particulate matter less than 10 microns in diameter (PM10). NSPS may allow reporting of only particulate matter emissions caught in the filter (obtained using Reference Method 5). K. The permittee shall submit to the AQD a copy of all reports submitted to the EPA as required by 40 C.F.R. Part 60, 61, and 63, for all equipment constructed or operated under this permit subject to such standards. [OAC 252:100-8-6(c)(1) and OAC 252:100, Appendix Q] SECTION IV. COMPLIANCE CERTIFICATIONS A. No later than 30 days after each anniversary date of the issuance of the original Part 70 operating permit or alternative date as specifically identified in a subsequent Part 70 operating permit, the permittee shall submit to the AQD, with a copy to the US EPA, Region 6, a certification of compliance with the terms and conditions of this permit and of any other TITLE V PERMIT STANDARD CONDITIONS July 21, 2009 4 applicable requirements which have become effective since the issuance of this permit. [OAC 252:100-8-6(c)(5)(A), and (D)] B. The compliance certification shall describe the operating permit term or condition that is the basis of the certification; the current compliance status; whether compliance was continuous or intermittent; the methods used for determining compliance, currently and over the reporting period. The compliance certification shall also include such other facts as the permitting authority may require to determine the compliance status of the source. [OAC 252:100-8-6(c)(5)(C)(i)-(v)] C. The compliance certification shall contain a certification by a responsible official as to the results of the required monitoring. This certification shall be signed by a responsible official, and shall contain the following language: “I certify, based on information and belief formed after reasonable inquiry, the statements and information in the document are true, accurate, and complete.” [OAC 252:100-8-5(f) and OAC 252:100-8-6(c)(1)] D. Any facility reporting noncompliance shall submit a schedule of compliance for emissions units or stationary sources that are not in compliance with all applicable requirements. This schedule shall include a schedule of remedial measures, including an enforceable sequence of actions with milestones, leading to compliance with any applicable requirements for which the emissions unit or stationary source is in noncompliance. This compliance schedule shall resemble and be at least as stringent as that contained in any judicial consent decree or administrative order to which the emissions unit or stationary source is subject. Any such schedule of compliance shall be supplemental to, and shall not sanction noncompliance with, the applicable requirements on which it is based, except that a compliance plan shall not be required for any noncompliance condition which is corrected within 24 hours of discovery. [OAC 252:100-8-5(e)(8)(B) and OAC 252:100-8-6(c)(3)] SECTION V. REQUIREMENTS THAT BECOME APPLICABLE DURING THE PERMIT TERM The permittee shall comply with any additional requirements that become effective during the permit term and that are applicable to the facility. Compliance with all new requirements shall be certified in the next annual certification. [OAC 252:100-8-6(c)(6)] SECTION VI. PERMIT SHIELD A. Compliance with the terms and conditions of this permit (including terms and conditions established for alternate operating scenarios, emissions trading, and emissions averaging, but excluding terms and conditions for which the permit shield is expressly prohibited under OAC 252:100-8) shall be deemed compliance with the applicable requirements identified and included in this permit. [OAC 252:100-8-6(d)(1)] B. Those requirements that are applicable are listed in the Standard Conditions and the Specific Conditions of this permit. Those requirements that the applicant requested be determined as not TITLE V PERMIT STANDARD CONDITIONS July 21, 2009 applicable are summarized in the Specific Conditions of this permit. SECTION VII. 5 [OAC 252:100-8-6(d)(2)] ANNUAL EMISSIONS INVENTORY & FEE PAYMENT The permittee shall file with the AQD an annual emission inventory and shall pay annual fees based on emissions inventories. The methods used to calculate emissions for inventory purposes shall be based on the best available information accepted by AQD. [OAC 252:100-5-2.1, OAC 252:100-5-2.2, and OAC 252:100-8-6(a)(8)] SECTION VIII. TERM OF PERMIT A. Unless specified otherwise, the term of an operating permit shall be five years from the date of issuance. [OAC 252:100-8-6(a)(2)(A)] B. A source’s right to operate shall terminate upon the expiration of its permit unless a timely and complete renewal application has been submitted at least 180 days before the date of expiration. [OAC 252:100-8-7.1(d)(1)] C. A duly issued construction permit or authorization to construct or modify will terminate and become null and void (unless extended as provided in OAC 252:100-8-1.4(b)) if the construction is not commenced within 18 months after the date the permit or authorization was issued, or if work is suspended for more than 18 months after it is commenced. [OAC 252:100-8-1.4(a)] D. The recipient of a construction permit shall apply for a permit to operate (or modified operating permit) within 180 days following the first day of operation. [OAC 252:100-8-4(b)(5)] SECTION IX. SEVERABILITY The provisions of this permit are severable and if any provision of this permit, or the application of any provision of this permit to any circumstance, is held invalid, the application of such provision to other circumstances, and the remainder of this permit, shall not be affected thereby. [OAC 252:100-8-6 (a)(6)] SECTION X. PROPERTY RIGHTS A. This permit does not convey any property rights of any sort, or any exclusive privilege. [OAC 252:100-8-6(a)(7)(D)] B. This permit shall not be considered in any manner affecting the title of the premises upon which the equipment is located and does not release the permittee from any liability for damage to persons or property caused by or resulting from the maintenance or operation of the equipment for which the permit is issued. [OAC 252:100-8-6(c)(6)] TITLE V PERMIT STANDARD CONDITIONS SECTION XI. July 21, 2009 6 DUTY TO PROVIDE INFORMATION A. The permittee shall furnish to the DEQ, upon receipt of a written request and within sixty (60) days of the request unless the DEQ specifies another time period, any information that the DEQ may request to determine whether cause exists for modifying, reopening, revoking, reissuing, terminating the permit or to determine compliance with the permit. Upon request, the permittee shall also furnish to the DEQ copies of records required to be kept by the permit. [OAC 252:100-8-6(a)(7)(E)] B. The permittee may make a claim of confidentiality for any information or records submitted pursuant to 27A O.S. § 2-5-105(18). Confidential information shall be clearly labeled as such and shall be separable from the main body of the document such as in an attachment. [OAC 252:100-8-6(a)(7)(E)] C. Notification to the AQD of the sale or transfer of ownership of this facility is required and shall be made in writing within thirty (30) days after such sale or transfer. [Oklahoma Clean Air Act, 27A O.S. § 2-5-112(G)] SECTION XII. REOPENING, MODIFICATION & REVOCATION A. The permit may be modified, revoked, reopened and reissued, or terminated for cause. Except as provided for minor permit modifications, the filing of a request by the permittee for a permit modification, revocation and reissuance, termination, notification of planned changes, or anticipated noncompliance does not stay any permit condition. [OAC 252:100-8-6(a)(7)(C) and OAC 252:100-8-7.2(b)] B. The DEQ will reopen and revise or revoke this permit prior to the expiration date in the following circumstances: [OAC 252:100-8-7.3 and OAC 252:100-8-7.4(a)(2)] (1) Additional requirements under the Clean Air Act become applicable to a major source category three or more years prior to the expiration date of this permit. No such reopening is required if the effective date of the requirement is later than the expiration date of this permit. (2) The DEQ or the EPA determines that this permit contains a material mistake or that the permit must be revised or revoked to assure compliance with the applicable requirements. (3) The DEQ or the EPA determines that inaccurate information was used in establishing the emission standards, limitations, or other conditions of this permit. The DEQ may revoke and not reissue this permit if it determines that the permittee has submitted false or misleading information to the DEQ. (4) DEQ determines that the permit should be amended under the discretionary reopening provisions of OAC 252:100-8-7.3(b). C. The permit may be reopened for cause by EPA, pursuant to the provisions of OAC 100-87.3(d). [OAC 100-8-7.3(d)] TITLE V PERMIT STANDARD CONDITIONS July 21, 2009 7 D. The permittee shall notify AQD before making changes other than those described in Section XVIII (Operational Flexibility), those qualifying for administrative permit amendments, or those defined as an Insignificant Activity (Section XVI) or Trivial Activity (Section XVII). The notification should include any changes which may alter the status of a “grandfathered source,” as defined under AQD rules. Such changes may require a permit modification. [OAC 252:100-8-7.2(b) and OAC 252:100-5-1.1] E. Activities that will result in air emissions that exceed the trivial/insignificant levels and that are not specifically approved by this permit are prohibited. [OAC 252:100-8-6(c)(6)] SECTION XIII. INSPECTION & ENTRY A. Upon presentation of credentials and other documents as may be required by law, the permittee shall allow authorized regulatory officials to perform the following (subject to the permittee's right to seek confidential treatment pursuant to 27A O.S. Supp. 1998, § 2-5-105(18) for confidential information submitted to or obtained by the DEQ under this section): (1) enter upon the permittee's premises during reasonable/normal working hours where a source is located or emissions-related activity is conducted, or where records must be kept under the conditions of the permit; (2) have access to and copy, at reasonable times, any records that must be kept under the conditions of the permit; (3) inspect, at reasonable times and using reasonable safety practices, any facilities, equipment (including monitoring and air pollution control equipment), practices, or operations regulated or required under the permit; and (4) as authorized by the Oklahoma Clean Air Act, sample or monitor at reasonable times substances or parameters for the purpose of assuring compliance with the permit. [OAC 252:100-8-6(c)(2)] SECTION XIV. EMERGENCIES A. Any exceedance resulting from an emergency shall be reported to AQD promptly but no later than 4:30 p.m. on the next working day after the permittee first becomes aware of the exceedance. This notice shall contain a description of the emergency, the probable cause of the exceedance, any steps taken to mitigate emissions, and corrective actions taken. [OAC 252:100-8-6 (a)(3)(C)(iii)(I) and (IV)] B. Any exceedance that poses an imminent and substantial danger to public health, safety, or the environment shall be reported to AQD as soon as is practicable; but under no circumstance shall notification be more than 24 hours after the exceedance. [OAC 252:100-8-6(a)(3)(C)(iii)(II)] C. An "emergency" means any situation arising from sudden and reasonably unforeseeable events beyond the control of the source, including acts of God, which situation requires immediate corrective action to restore normal operation, and that causes the source to exceed a technology-based emission limitation under this permit, due to unavoidable increases in TITLE V PERMIT STANDARD CONDITIONS July 21, 2009 8 emissions attributable to the emergency. An emergency shall not include noncompliance to the extent caused by improperly designed equipment, lack of preventive maintenance, careless or improper operation, or operator error. [OAC 252:100-8-2] D. The affirmative defense of emergency shall be demonstrated through properly signed, contemporaneous operating logs or other relevant evidence that: [OAC 252:100-8-6 (e)(2)] (1) an emergency occurred and the permittee can identify the cause or causes of the emergency; (2) the permitted facility was at the time being properly operated; (3) during the period of the emergency the permittee took all reasonable steps to minimize levels of emissions that exceeded the emission standards or other requirements in this permit. E. In any enforcement proceeding, the permittee seeking to establish the occurrence of an emergency shall have the burden of proof. [OAC 252:100-8-6(e)(3)] F. Every written report or document submitted under this section shall be certified as required by Section III (Monitoring, Testing, Recordkeeping & Reporting), Paragraph F. [OAC 252:100-8-6(a)(3)(C)(iv)] SECTION XV. RISK MANAGEMENT PLAN The permittee, if subject to the provision of Section 112(r) of the Clean Air Act, shall develop and register with the appropriate agency a risk management plan by June 20, 1999, or the applicable effective date. [OAC 252:100-8-6(a)(4)] SECTION XVI. INSIGNIFICANT ACTIVITIES Except as otherwise prohibited or limited by this permit, the permittee is hereby authorized to operate individual emissions units that are either on the list in Appendix I to OAC Title 252, Chapter 100, or whose actual calendar year emissions do not exceed any of the limits below. Any activity to which a State or Federal applicable requirement applies is not insignificant even if it meets the criteria below or is included on the insignificant activities list. (1) 5 tons per year of any one criteria pollutant. (2) 2 tons per year for any one hazardous air pollutant (HAP) or 5 tons per year for an aggregate of two or more HAP's, or 20 percent of any threshold less than 10 tons per year for single HAP that the EPA may establish by rule. [OAC 252:100-8-2 and OAC 252:100, Appendix I] SECTION XVII. TRIVIAL ACTIVITIES Except as otherwise prohibited or limited by this permit, the permittee is hereby authorized to operate any individual or combination of air emissions units that are considered inconsequential and are on the list in Appendix J. Any activity to which a State or Federal applicable TITLE V PERMIT STANDARD CONDITIONS July 21, 2009 9 requirement applies is not trivial even if included on the trivial activities list. [OAC 252:100-8-2 and OAC 252:100, Appendix J] SECTION XVIII. OPERATIONAL FLEXIBILITY A. A facility may implement any operating scenario allowed for in its Part 70 permit without the need for any permit revision or any notification to the DEQ (unless specified otherwise in the permit). When an operating scenario is changed, the permittee shall record in a log at the facility the scenario under which it is operating. [OAC 252:100-8-6(a)(10) and (f)(1)] B. The permittee may make changes within the facility that: (1) result in no net emissions increases, (2) are not modifications under any provision of Title I of the federal Clean Air Act, and (3) do not cause any hourly or annual permitted emission rate of any existing emissions unit to be exceeded; provided that the facility provides the EPA and the DEQ with written notification as required below in advance of the proposed changes, which shall be a minimum of seven (7) days, or twenty four (24) hours for emergencies as defined in OAC 252:100-8-6 (e). The permittee, the DEQ, and the EPA shall attach each such notice to their copy of the permit. For each such change, the written notification required above shall include a brief description of the change within the permitted facility, the date on which the change will occur, any change in emissions, and any permit term or condition that is no longer applicable as a result of the change. The permit shield provided by this permit does not apply to any change made pursuant to this paragraph. [OAC 252:100-8-6(f)(2)] SECTION XIX. OTHER APPLICABLE & STATE-ONLY REQUIREMENTS A. The following applicable requirements and state-only requirements apply to the facility unless elsewhere covered by a more restrictive requirement: (1) Open burning of refuse and other combustible material is prohibited except as authorized in the specific examples and under the conditions listed in the Open Burning Subchapter. [OAC 252:100-13] (2) No particulate emissions from any fuel-burning equipment with a rated heat input of 10 MMBTUH or less shall exceed 0.6 lb/MMBTU. [OAC 252:100-19] (3) For all emissions units not subject to an opacity limit promulgated under 40 C.F.R., Part 60, NSPS, no discharge of greater than 20% opacity is allowed except for: [OAC 252:100-25] (a) Short-term occurrences which consist of not more than one six-minute period in any consecutive 60 minutes, not to exceed three such periods in any consecutive 24 hours. In no case shall the average of any six-minute period exceed 60% opacity; TITLE V PERMIT STANDARD CONDITIONS July 21, 2009 10 (b) Smoke resulting from fires covered by the exceptions outlined in OAC 252:100-13-7; (c) An emission, where the presence of uncombined water is the only reason for failure to meet the requirements of OAC 252:100-25-3(a); or (d) Smoke generated due to a malfunction in a facility, when the source of the fuel producing the smoke is not under the direct and immediate control of the facility and the immediate constriction of the fuel flow at the facility would produce a hazard to life and/or property. (4) No visible fugitive dust emissions shall be discharged beyond the property line on which the emissions originate in such a manner as to damage or to interfere with the use of adjacent properties, or cause air quality standards to be exceeded, or interfere with the maintenance of air quality standards. [OAC 252:100-29] (5) No sulfur oxide emissions from new gas-fired fuel-burning equipment shall exceed 0.2 lb/MMBTU. No existing source shall exceed the listed ambient air standards for sulfur dioxide. [OAC 252:100-31] (6) Volatile Organic Compound (VOC) storage tanks built after December 28, 1974, and with a capacity of 400 gallons or more storing a liquid with a vapor pressure of 1.5 psia or greater under actual conditions shall be equipped with a permanent submerged fill pipe or with a vapor-recovery system. [OAC 252:100-37-15(b)] (7) All fuel-burning equipment shall at all times be properly operated and maintained in a manner that will minimize emissions of VOCs. [OAC 252:100-37-36] SECTION XX. STRATOSPHERIC OZONE PROTECTION A. The permittee shall comply with the following standards for production and consumption of ozone-depleting substances: [40 CFR 82, Subpart A] (1) Persons producing, importing, or placing an order for production or importation of certain class I and class II substances, HCFC-22, or HCFC-141b shall be subject to the requirements of §82.4; (2) Producers, importers, exporters, purchasers, and persons who transform or destroy certain class I and class II substances, HCFC-22, or HCFC-141b are subject to the recordkeeping requirements at §82.13; and (3) Class I substances (listed at Appendix A to Subpart A) include certain CFCs, Halons, HBFCs, carbon tetrachloride, trichloroethane (methyl chloroform), and bromomethane (Methyl Bromide). Class II substances (listed at Appendix B to Subpart A) include HCFCs. B. If the permittee performs a service on motor (fleet) vehicles when this service involves an ozone-depleting substance refrigerant (or regulated substitute substance) in the motor vehicle air conditioner (MVAC), the permittee is subject to all applicable requirements. Note: The term “motor vehicle” as used in Subpart B does not include a vehicle in which final assembly of the TITLE V PERMIT STANDARD CONDITIONS July 21, 2009 11 vehicle has not been completed. The term “MVAC” as used in Subpart B does not include the air-tight sealed refrigeration system used as refrigerated cargo, or the system used on passenger buses using HCFC-22 refrigerant. [40 CFR 82, Subpart B] C. The permittee shall comply with the following standards for recycling and emissions reduction except as provided for MVACs in Subpart B: [40 CFR 82, Subpart F] (1) Persons opening appliances for maintenance, service, repair, or disposal must comply with the required practices pursuant to § 82.156; (2) Equipment used during the maintenance, service, repair, or disposal of appliances must comply with the standards for recycling and recovery equipment pursuant to § 82.158; (3) Persons performing maintenance, service, repair, or disposal of appliances must be certified by an approved technician certification program pursuant to § 82.161; (4) Persons disposing of small appliances, MVACs, and MVAC-like appliances must comply with record-keeping requirements pursuant to § 82.166; (5) Persons owning commercial or industrial process refrigeration equipment must comply with leak repair requirements pursuant to § 82.158; and (6) Owners/operators of appliances normally containing 50 or more pounds of refrigerant must keep records of refrigerant purchased and added to such appliances pursuant to § 82.166. SECTION XXI. TITLE V APPROVAL LANGUAGE A. DEQ wishes to reduce the time and work associated with permit review and, wherever it is not inconsistent with Federal requirements, to provide for incorporation of requirements established through construction permitting into the Source’s Title V permit without causing redundant review. Requirements from construction permits may be incorporated into the Title V permit through the administrative amendment process set forth in OAC 252:100-8-7.2(a) only if the following procedures are followed: (1) (2) (3) (4) (5) The construction permit goes out for a 30-day public notice and comment using the procedures set forth in 40 C.F.R. § 70.7(h)(1). This public notice shall include notice to the public that this permit is subject to EPA review, EPA objection, and petition to EPA, as provided by 40 C.F.R. § 70.8; that the requirements of the construction permit will be incorporated into the Title V permit through the administrative amendment process; that the public will not receive another opportunity to provide comments when the requirements are incorporated into the Title V permit; and that EPA review, EPA objection, and petitions to EPA will not be available to the public when requirements from the construction permit are incorporated into the Title V permit. A copy of the construction permit application is sent to EPA, as provided by 40 CFR § 70.8(a)(1). A copy of the draft construction permit is sent to any affected State, as provided by 40 C.F.R. § 70.8(b). A copy of the proposed construction permit is sent to EPA for a 45-day review period as provided by 40 C.F.R.§ 70.8(a) and (c). The DEQ complies with 40 C.F.R. § 70.8(c) upon the written receipt within the 45-day TITLE V PERMIT STANDARD CONDITIONS July 21, 2009 12 comment period of any EPA objection to the construction permit. The DEQ shall not issue the permit until EPA’s objections are resolved to the satisfaction of EPA. (6) The DEQ complies with 40 C.F.R. § 70.8(d). (7) A copy of the final construction permit is sent to EPA as provided by 40 CFR § 70.8(a). (8) The DEQ shall not issue the proposed construction permit until any affected State and EPA have had an opportunity to review the proposed permit, as provided by these permit conditions. (9) Any requirements of the construction permit may be reopened for cause after incorporation into the Title V permit by the administrative amendment process, by DEQ as provided in OAC 252:100-8-7.3(a), (b), and (c), and by EPA as provided in 40 C.F.R. § 70.7(f) and (g). (10) The DEQ shall not issue the administrative permit amendment if performance tests fail to demonstrate that the source is operating in substantial compliance with all permit requirements. B. To the extent that these conditions are not followed, the Title V permit must go through the Title V review process. SECTION XXII. CREDIBLE EVIDENCE For the purpose of submitting compliance certifications or establishing whether or not a person has violated or is in violation of any provision of the Oklahoma implementation plan, nothing shall preclude the use, including the exclusive use, of any credible evidence or information, relevant to whether a source would have been in compliance with applicable requirements if the appropriate performance or compliance test or procedure had been performed. [OAC 252:100-43-6] DRAFT/PROPOSED ONEOK Field Services Company, L.L.C. Ms. Deborah Perry Senior Environmental Engineer 100 West Fifth Street P.O. Box 871 Tulsa, OK 74102-0871 SUBJECT: Facility: Maysville Gas Plant Location: Garvin County Permit No. 2011-227-TVR2 Date Received: April 25, 2011 Dear Ms. Perry: Air Quality Division has completed the initial review of your permit application referenced above. This application has been determined to be a Tier II. In accordance with 27A O.S. § 2-14-302 and OAC 252:002-4-7-13(c) the enclosed draft permit is now ready for public review. The requirements for public review include the following steps which you must accomplish: 1. Publish at least one legal notice (one day) in at least one newspaper of general circulation within the county where the facility is located. (Instructions enclosed) 2. Provide for public review (for a period of 30 days following the date of the newspaper announcement) a copy of this draft permit and a copy of the application at a convenient public location within the county of the facility such as the public library in the county seat. 3. Send to AQD a copy of the proof of publication notice from Item #1 above together with any additional comments or requested changes which you may have on the draft permit. Thank you for your cooperation. If you have any questions, please refer to the permit number above and contact me or the permit writer at (405) 702-4100. Sincerely, Phillip Fielder, P.E. Permits and Engineering Group Manager AIR QUALITY DIVISION DRAFT/PROPOSED NOTICE OF DRAFT PERMIT TIER II or TIER III AIR QUALITY PERMIT APPLICATION APPLICANT RESPONSIBILITIES Permit applicants are required to give public notice that a Tier II or Tier III draft permit has been prepared by DEQ. The notice must be published in one newspaper local to the site or facility. Upon publication, a signed affidavit of publication must be obtained from the newspaper and sent to AQD. Note that if a public meeting is requested by either the applicant or the public, this must be arranged through the Customer Services Division of the DEQ. REQUIRED CONTENT (27A O.S. § 2-14-302 and OAC 252:4-7-13(c)) 1. 2. 3. 4. 5. 6. A statement that a Tier II or Tier III draft permit has been prepared by DEQ; Name and address of the applicant; Name, address, driving directions, legal description and county of the site or facility; The type of permit or permit action being sought; A description of activities to be regulated, including an estimate of emissions from the facility; Location(s) where the application and draft permit may be reviewed (a location in the county where the site/facility is located must be included); 7. Name, address, and telephone number of the applicant and DEQ contacts; 8. Any additional information required by DEQ rules or deemed relevant by applicant; 9. A 30-day opportunity to request a formal public meeting on the draft permit. SAMPLE NOTICE on page 2. DEQ FORM # 100-822 REVISED NOVEMBER 4, 2004 DRAFT/PROPOSED SAMPLE NOTICE (Italicized print is to be filled in by the applicant.): DEQ NOTICE OF TIER …II or III… DRAFT PERMIT A Tier …II or III… application for an air quality …type of permit or permit action being sought [e.g., Construction Permit for a Major Facility]… has been filed with the Oklahoma Department of Environmental Quality (DEQ) by applicant, …name and address. The applicant requests approval to …brief description of purpose of application… at the …site/facility name … …[proposed to be]… located at …physical address (if any), driving directions, and legal description including county….. In response to the application, DEQ has prepared a draft permit [modification] (Permit Number: …xx-xxx-x…), which may be reviewed at …locations (one must be in the county where the site/facility is located)… or at the Air Quality Division's main office (see address below). The draft permit is also available for review in the Air Quality Section of DEQ's Web Page: http://www.deq.state.ok.us/ This draft permit would authorize the facility to emit the following regulated pollutants (list each pollutant and amounts in tons per year (TPY)). This public notice shall include notice to the public that this permit is subject to Environmental Protection Agency (EPA) review, EPA objection, and petition to EPA, as provided by 40 CFR § 70.8; that the requirements of the construction permit will be incorporated into the Title V permit through the administrative amendment process; that the public will not receive another opportunity to provide comments when the requirements are incorporated into the Title V permit; and that EPA review, EPA objection, and petitions to EPA will not be available to the public when requirements from the construction permit are incorporated into the Title V permit. The public comment period ends 30 days after the date of publication of this notice. Any person may submit written comments concerning the draft permit to the Air Quality Division contact listed below. [Modifications only, add: Only those issues relevant to the proposed modification(s) are open for comment.] A public meeting on the draft permit [modification] may also be requested in writing at the same address. Note that all public meetings are to be arranged and conducted by DEQ/CSD staff. For additional information, contact …names, addresses and telephone numbers of contact persons for the applicant, or contact DEQ at: Chief Engineer, Permits Section, Air Quality Division, 707 N. Robinson, Suite 4100, P.O. Box 1677, Oklahoma City, OK, 73101-1677, (405) 702-4100. DEQ FORM # 100-822 REVISED NOVEMBER 4, 2004 DRAFT/PROPOSED PART 70 PERMIT AIR QUALITY DIVISION STATE OF OKLAHOMA DEPARTMENT OF ENVIRONMENTAL QUALITY 707 N. ROBINSON, SUITE 4100 P.O. BOX 1677 OKLAHOMA CITY, OKLAHOMA 73101-1677 Permit No. 2011-227-TVR2 ONEOK Field Service Company, L.L.C., having complied with the requirements of the law, is hereby granted permission to operate the Maysville Gas Plant, Section 18, T4N, R2W, Garvin County, Oklahoma subject to the Standard Conditions dated July 21, 2009 and Specific Conditions, both attached. This permit shall expire five years from the date of issuance, except as authorized under Section VIII of the Standard Conditions. _____________________________ Director Date Air Quality Division DEQ Form #100-890 Revised 10/20/06