Testpapiere Seite 5 Mittwoch, 29. März 2006 1:56 13 Indicator and test papers pH papers · qualitative and semi-quantitative test papers and test sticks pH indicator papers and liquid indicators Test papers Indicator papers without colour scale Universal and special indicator papers DUOTEST and TRITEST indicator papers PEHANON® indicator papers pH-Fix indicator sticks – non-bleeding Liquid indicators UNISOL 6 7 8 9 10 11 Test papers for qualitative determinations Summary and ordering information Description of qualitative test papers in alphabetical order 12 – 13 14 – 20 Test sticks and test papers for semi-quantitative determinations QUANTOFIX® test sticks Summary and ordering information Description of QUANTOFIX® test sticks in alphabetical order 21 – 26 21 22 – 26 Other test sticks and test papers for semi-quantitative determinations Ordering information Description of test sticks / test papers in alphabetical order 27 27 – 30 Test sticks for microbiological diagnostics www.mn-net.com 31 – 32 MN 5 Testpapiere Seite 6 Mittwoch, 29. März 2006 1:56 13 pH indicator papers Indicator papers without colour scale For orientation and adjustment of pH values Test papers These products are simple, completely impregnated indicator papers, which do not allow exact pH determinations, but pH adjustments during special chemical procedures. For this reason, no colour scale is provided with these papers. Brilliant yellow paper Yellow paper, which changes colour to red near neutral (pH 6.7 – 7.9). Recommended application: demonstration of a specific alkali concentration, which is required for special reactions. Congo red paper Red paper, which changes colour to blue in the pH range 3.0 – 5.0. Congo paper is supplied in three versions of varying sensitivity: Congo paper MN 816 N normal sensitivity Congo paper MN 260 HE high sensitivity Congo paper MN 616 T medium sensitivity, between the above two types, recommended specifically for spot tests. Recommended application: Neutralisation analysis; detection of lactic acid in culture media, which contain lactic acid-producing strains of B. coli. Litmus papers Litmus paper is available in three modifications: Litmus paper blue: changes colour from blue to red when conditions change from alkaline to acidic. Litmus paper neutral: violet indicator paper which changes to red under acid conditions and to blue under alkaline conditions. Recommended application: neutralisation analyses Nitrazine yellow paper Yellow paper which changes to blue when the pH exceeds 6 towards alkaline conditions (greyish blue at pH 7; blue at pH > 8). Recommended application: neutralisation analyses Phenolphthalein paper White paper, which changes colour to red when the pH exceeds 8.3 towards alkaline conditions (red at pH > 10). Indicator paper Colour change, when pH changes from → to Brilliant yellow paper Congo paper MN 816 N Congo paper MN 616 T Congo paper MN 260 HE Litmus paper blue Litmus paper neutral Litmus paper red Nitrazine yellow paper Phenolphthalein paper yellow → red red → blue red → blue red → blue blue → red red ← violet → blue red → blue yellow → violet-blue white → red Presentation Reel: Refill pack: Booklet: Box: 6 Litmus paper red: changes colour from red to blue when conditions change from acidic to alkaline. Recommended application: General test for acidic or alkaline reaction: It serves in neutralisation reactions to check whether the change from acid to alkaline or vice versa has taken place. Litmus paper is the bestknown indicator paper. Chemistry: Litmus is not a single, chemically defined substance but a natural product containing a mixture of substances. It is extracted from lichen and probably represents the oldest known indicator dye. MN 6.7 – 7.9 5.0 – 3.0 5.0 – 3.0 5.0 – 3.0 8.0 – 5.0 5.0 – 8.0 5.0 – 8.0 6.0 – 7,0 8.3 – 10.0 Reel Cat. No. – 907 02 – – 911 06 911 07 911 08 – 907 12 Refill pack Cat. No. – 907 03 – – 911 16 911 17 911 18 – 907 13 Booklets Cat. No. – – – – 911 26 911 27 911 28 – – Box Cat. No. 907 01 – 907 04 907 05 – – – 907 11 – plastic dispenser with 1 reel 5 m long and 7 mm wide, packed in individual cardboard box. box with 3 reels 5 m long and 7 mm wide, each reel separately sealed in polyethylene 100 strips 10 x 70 mm 200 strips 20 x 70 mm www.mn-net.com Testpapiere Seite 7 Mittwoch, 29. März 2006 1:56 13 pH indicator papers Universal and special indicator papers Indicator paper Gradation Test papers These products are produced by total impregnation of the paper with a pH indicator or a mixture of several indicator dyes. MACHEREY-NAGEL universal indicator paper covers the pH renges 1 – 11 and 1 – 14; gradation of the colour scale is in steps of 1.0 pH units or 1.0/2.0 units, respectively. MACHEREY-NAGEL special indicator papers (narrow range papers) usually cover a range of about 2 – 5 pH units in gradations of 0.2/0.3 or 0.5 units. Please note that indicator papers measure the pH of unbuffered or only weakly buffered solutions less accurately than do indicator solutions. When dealing with buffered solutions, however, indicator papers work with the same degree of accuracy. For pH measurements in weakly buffered or unbuffered solutions we recommend pH-Fix indicator sticks. The following procedure is recommended when you attempt to measure the pH value of unbuffered or weakly buffered solutions with universal or special indicator papers: a strip of indicator paper is placed against the wall of a test tube which is then filled to the brim with the solution to be tested. The indicator paper is left in the test tube and its colour, viewed through the glass, is compared with the colour scale after about 1 minute. Reel Cat. No. Refill pack Cat. No. Booklet Cat. No. 902 01 902 04 902 02 902 24 902 03 – 902 05 902 06 902 07 902 08 902 09 902 10 902 11 902 12 902 13 902 14 902 25 902 26 902 27 902 28 902 29 902 30 902 31 902 32 902 33 902 34 – – – – – – – – – – Universal-Indikatorpapiere pH 1 – 11 pH 1 – 14 1 – 2 – 3 – 4 – 5 – 6 – 7 – 8 – 9 – 10 – 11 1 – 2 – 3 – 5 – 6 – 7 – 8 – 9 – 10 – 12 – 14 Special indicator papers pH 0.5 – 5.5 pH 3.8 – 5.8 pH 4.0 – 7.0 pH 5.4 – 7.0 pH 5.5 – 9.0 pH 6.4 – 8.0 pH 7.2 – 9.7 pH 8.0 – 10.0 pH 9.0 – 13.0 pH 12.0 – 14.0 0.5 – 1.0 – 1.5 – 2.0 – 2.5 – 3.0 – 3.5 – 4.0 – 4.5 – 5.0 – 5.5 <3.8 – 3.8 – 4.1 – 4.3 – 4.5 – 4.7 – 4.9 – 5.2 – 5.5 – 5.8 – >5.8 4.0 – 4.3 – 4.6 – 4.9 – 5.2 – 5.5 – 5.8 – 6.1 – 6.4 – 6.7 – 7.0 <5.4 – 5.4 – 5.7 – 6.0 – 6.2 – 6.4 – 6.7 – 7.0 – >7.0 5.5 – 6.0 – 6.5 – 7.0 – 7.5 – 8.0 – 8.5 – 9.0 <6.4 – 6.4 – 6.6 – 6.8 – 7.0 – 7.2 – 7.4 – 7.6 – 7.8 – 8.0 – >8.0 <7.2 – 7.2 – 7.5 – 7.8 – 8.1 – 8.4 – 8.7 – 9.0 – 9.3 – 9.7 – >9.7 8.0 – 8.2 – 8.4 – 8.7 – 9.0 – 9.2 – 9.6 – 10.0 9.0 – 9.5 – 10.0 – 10.5 – 11.0 – 11.5 – 12.0 – 12.5 – 13.0 12.0 – 12.5 – 13.0 – 13.5 – 14.0 Collections of universal and special indicator papers pH-Set U-10 TRI-BOX Presentation Reel: Refill pack: Booklet: www.mn-net.com box with 10 different reels of pH indicator paper (2 reels of universal indicator paper and 8 reels of different special indicator papers) plastic dispenser with 3 reels of special indicator paper each 5 m long and 7 mm wide (1 reel each of pH 0.5 – 5.5, pH 5.5 – 9.0, pH 9.0 – 13.0, gradation 0.5 pH units) and 3 colour scales 902 19 902 18 plastic dispenser with colour scale and 1 reel 5 m long and 7 mm wide, packed in individual cardboard box box with 3 reels 5 m long and 7 mm wide, each reel separately sealed in polyethylene 100 strips 10 x 70 mm with colour scale MN 7 Testpapiere Seite 8 Mittwoch, 29. März 2006 1:56 13 pH indicator papers DUOTEST double-zone indicator papers TRITEST triple-zone indicator papers Test papers TRITEST paper is an indicator paper combining highes accuracy with greatest ease of reading. Three complementary indicator zones on a single strip guarantee clear colour differentiation and the possibility to estimate in-between values. The gradation is 1.0 pH unit. TRITEST is available for the range pH 1–11, but in two types: DUOTEST papers are indicator papers with greater accuracy and increased ease of reading. Two complementary indicator zones on one strip – separated by a white centre band – guarantee clear colour differentiation and a more accurate estimate of intermediate values. The white centre band is hydrophobic and prevents that colours of the two indicator zones run into one another, thus increasing accuracy. In addition the white band forms a good contrast to the coloured test zones and furthermore adds mechanical strength to the wet strip, because it repels water. a) TRITEST in reel form (without hydrophobic zone) paper strip of 10 mm width to which three adjoining indicator zones (1 main indicator and 2 auxiliary indicators) have been applied b) TRITEST L in reel form (with 2 hydrophobic zones) paper strip of 6 m length and 14 mm width to which three indicator zones (1 main indicator and 2 auxiliary indicators) have been applied. The indicator zones are separated by hydrophobic barriers. This guarantees a sharp separation of the indicator zones which is of particular advantage in pH determinations in the highly alkaline range. Indicator paper Gradation Reel Cat. No. Refill pack Cat. No. 903 01 903 02 903 03 903 04 903 05 903 06 903 11 903 12 903 13 903 14 903 15 903 16 DUOTEST pH 1 – 12 pH 1.0 – 4.3 pH 3.5 – 6.8 pH 5.0 – 8.0 pH 7.0 – 10.0 pH 9.5 – 14.0 1 – 2 – 3 – 4 – 5 – 6 – 7 – 8 – 9 – 10 – 11 – 12 1.0 – 1.3 – 1.6 – 1.9 – 2.2 – 2.5 – 2.8 – 3.1 – 3.4 – 3.7 – 4.0 – 4.3 3.5 – 3.8 – 4.1 – 4.4 – 4.7 – 5.0 – 5.3 – 5.6 – 5.9 – 6.2 – 6.5 – 6.8 5.0 – 5.3 – 5.6 – 5.9 – 6.2 – 6.5 – 6.8 – 7.1 – 7.4 – 7.7 – 8.0 7.0 – 7.3 – 7.6 – 7.9 – 8.2 – 8.5 – 8.8 – 9.1 – 9.4 – 9.7 – 10.0 9.5 – 10.0 – 10.5 – 11.0 – 11.5 – 12.0 – 12.5 – 13.0 – 13.5 – 14.0 Collection of DUOTEST indicator papers pH-Set D 10 10 reels of DUOTEST (2 reels each of pH 1 – 12; 3.5 – 6.8; 5.0 – 8.0; 7.0 – 10.0; 1 reel each of pH 1.0 – 4.3 and 9.5 – 14.0) 903 19 1 – 2 – 3 – 4 – 5 – 6 – 7 – 8 – 9 – 10 – 11 1 – 2 – 3 – 4 – 5 – 6 – 7 – 8 – 9 – 10 – 11 905 02 905 11 TRITEST TRITEST pH 1 – 11 TRITEST L pH 1 – 11 Presentation Reel: Reel size: Refill pack: 8 MN 905 01 905 10 plastic dispenser with colour scale and 1 reel, packed in individual cardboard box. DUOTEST and TRITEST: 5 m long and 10 mm wide, TRITEST L: 6 m long and 14 mm wide box with 3 reels, each reel separately sealed in polyethylene www.mn-net.com Testpapiere Seite 9 Mittwoch, 29. März 2006 1:56 13 pH indicator papers PEHANON® indicator papers for pH measurement in coloured solutions The indicator zone (unprinted field of about 6 mm width) is in the middle of the strip, the comparison fields (4 mm wide) are arranged above and below. The strip is submerged in the solution for about three seconds so that all colour zones are wetted. The indicator zone (unprinted centre field) changes colour according to the pH value of the solution and is then compared against the colour fields on the strip. The pH value is read from the closest matching field. An invisible hydropho- Test papers PEHANON® is a series of pH indicator papers where the indicator and colour scale are combined on a single strip. They permit a fast, convenient and accurate determination of the pH value since they eliminate the necessity to compare the colour field against a separate scale. pH values are imprinted on the strips. This presentation also permits the pH measurement of coloured solutions and suspensions, since the colour of the test solution acts on the colour scale in the same manner as on the indicator field, resulting in a comparison of mixed colours. The individual colour zones are separated by hydrophobic barriers. bic silicone barrier just above the top colour field prevents capillary action of the test solution beyond that point and allows safe and clean handling with corrosive, toxic or otherwise noxious liquids. The PEHANON® series covers the entire pH range from 0 to 14 with one universal paper and thirteen narrow ranges which overlap to permit utmost selectivity for the range suited to each particular need. The pH gradations within each strip have been established to offer maximum colour differentiation from one comparison field to the next depending on the individual indicator. PEHANON® papers guarantee highest accuracy even when testing coloured solutions! Again – as with universal and special indicator papers – best results are obtained for buffered solutions and suspensions (see page 7). PEHANON® range Gradation pH 1 – 12 1 – 2 – 3 – 4 – 5 – 6 – 7 – 8 – 9 – 10 – 11 – 12 pH 0 – 1.8 0 – 0.3 – 0.6 – 0.8 – 1.0 – 1.2 – 1.5 – 1.8 pH 1.0 – 2.8 1.0 – 1.3 – 1.6 – 1.8 – 2.0 – 2.2 – 2.5 – 2.8 pH 1.8 – 3.8 1.8 – 2.1 – 2.4 – 2.7 – 3.0 – 3.2 – 3.5 – 3.8 pH 2.8 – 4.6 2.8 – 3.1 – 3.4 – 3.6 – 3.8 – 4.0 – 4.3 – 4.6 pH 3.8 – 5.5 3.8 – 4.0 – 4.2 – 4.4 – 4.6 – 4.9 – 5.2 – 5.5 pH 4.0 – 9.0 4.0 – 4.5 – 5.0 – 5.5 – 6.0 – 6.5 – 7.0 – 7.5 – 8.0 – 8.5 – 9.0 pH 5.2 – 6.8 5.2 – 5.5 – 5.7 – 5.9 – 6.1 – 6.3 – 6.5 – 6.8 pH 6.0 – 8.1 6.0 – 6.3 – 6.6 – 6.9 – 7.2 – 7.5 – 7.8 – 8.1 pH 7.2 – 8.8 7.2 – 7.4 – 7.6 – 7.8 – 8.0 – 8.2 – 8.5 – 8.8 pH 8.0 – 9.7 8.0 – 8.2 – 8.4 – 8.6 – 8.8 – 9.1 – 9.4 – 9.7 pH 9.5 – 12.0 9.5 – 10.0 – 10.5 – 11.0 – 11.5 – 12.0 pH 10.5 – 13.0 10.5 – 11.0 – 11.5 – 12.0 – 12.5 – 13.0 pH 12.0 – 14.0 12.0 – 12.5 – 13.0 – 13.5 – 14.0 Presentation: plastic box containing 200 strips 11 x 100 mm www.mn-net.com Cat. No. 904 01 904 11 904 12 904 13 904 14 904 15 904 24 904 16 904 17 904 19 904 20 904 21 904 22 904 23 MN 9 Testpapiere Seite 10 Mittwoch, 29. März 2006 1:56 13 pH indicator papers pH-Fix indicator sticks – non-bleeding – Recommended for pH measurement in weakly buffered or strongly alkaline solutions Test papers pH-Fix indicator sticks are for the rapid measurement of the pH of a water sample. In contrast to standard test papers, the pH-Fix indicator is chemically bound to the cellulose fibres, avoiding bleeding even in strongly alkaline samples. Furthermore there are the following advantages: Measurement of pH values is possible even in unbuffered solutions, since the sticks can be left in the solution until the final reaction colour is obtanined. Test samples are not contaminated by the indicator dyes. Thus solutions can be used for further investigations. Colours of the individual colour fields cannot run into each other. This allows a more precise comparison the the colour scale. Specially developed indicator dyes guarantee a sharp differentiation between the individual pH values and a clear and easy comparison with the colour scale. Length and stability of the plastic strips protect fingers from contact with the test solution. pH-Fix range Gradation pH 0 – 14 0 – 1 – 2 – 3 – 4 – 5 – 6 – 7 – 8 – 9 – 10 – 11 – 12 – 13 – 14 pH 0.0 – 6.0 0 – 0.5 – 1.0 – 1.5 – 2.0 – 2.5 – 3.0 – 3.5 – 4.0 – 4.5 – 5.0 – 5.5 – 6.0 pH 2.0 – 9.0 2.0 – 2.5 – 3.0 – 3.5 – 4.0 – 4.5 – 5.0 – 5.5 – 6.0 – 6.5 – 7.0 – 7.5 – 8.0 – 8.5 – 9.0 pH 4.5 – 10.0 4.5 – 5.0 – 5.5 – 6.0 – 6.5 – 7.0 – 7.5 – 8.0 – 8.5 – 9.0 – 9.5 – 10.0 pH 6.0 – 10.0 6.0 – 6.4 – 6.7 – 7.0 – 7.3 – 7.6 – 7.9 – 8.2 – 8.4 – 8.6 – 8.8 – 9.1 – 9.5 – 10.0 pH 7.0 – 14.0 7.0 – 7.5 – 8.0 – 8.5 – 9.0 – 9.5 – 10.0 – 10.5 – 11.0 – 11.5 – 12.0 – 12.5 – 13.0 – 13.5 – 14.0 pH 0.3 – 2.3 0.3 – 0.7 – 1.0 – 1.3 – 1.6 – 1.9 – 2.3 pH 1.7 – 3.8 1.7 – 2.0 – 2.3 – 2.6 – 2.9 – 3.2 – 3.5 – 3.8 pH 3.6 – 6.1 3.6 – 4.1 – 4.4 – 4.7 – 5.0 – 5.3 – 5.6 – 6.1 pH 5.1 – 7.2 5.1 – 5.4 – 5.7 – 6.0 – 6.3 – 6.6 – 6.9 – 7.2 pH 6.0 – 7.7 6.0 – 6.4 – 6.7 – 7.0 – 7.3 – 7.7 pH 7.5 – 9.5 7.5 – 7.9 – 8.2 – 8.4 – 8.6 – 8.8 – 9.1 – 9.5 pH 7.9 – 9.8 7.9 – 8.3 – 8.6 – 8.9 – 9.1 – 9.4 – 9.8 Presentation: box with 100 sticks 6 x 85 mm : CE-marked according to the IvD-directive 98/79/EC 10 MN Cat. No. 921 10 921 15 921 18 921 20 921 22 921 25 921 80 921 90 921 30 921 40 921 50 921 60 921 70 www.mn-net.com Testpapiere Seite 11 Mittwoch, 29. März 2006 1:56 13 Liquid indicators UNISOL indicator solutions for pH measurement in liquids For pH measurement in pure water, in surface waters, in very diluted acids or bases – i. e. in weakly buffered solutions – indicator papers find their limit of applicability (acid-base error). For these applicaitons indicator solutions are used, which are added to the analyte fluid. The resulting colour is directly compared with the colour scale (UNISOL, VISOCOLOR® ). UNISOL indicator solutions are available for measurements in different pH ranges. UNISOL 113 covers the pH range from 1 to 13 and shows several colour changes within this range. Starting on the acid side the colour changes from red via yellow and green to blue-violet, when the pH of the solution is increased successively. The gradation of the printed colour scale is in 1.0 pH units. UNISOL 410 covers the more narrow range pH 4 – 10 with a gradation of 0.5 units on the colour scale. Fields of application: pure water and waste water water for aquariums unbuffered solutions surfaces of paper and similar products UNISOL indicator solutions offer simple and convenient handling. With UNISOL 113 one drop of the indicator solution, with UNISOL 410 two drops are added to 5 ml of the colourless Test papers aqueous solution to be tested. The resulting colour is compared with the corresponding colour scale. One has to pay attention, however, to the fact that the colour intensity depends on the indicator concentration and the thickness of the coloured layer of the test solution. Spot plates or ordinary test tubes may be used, but we recommend to use square measuring cells since the thickness of the layer is always constant and permits accurate readings. Measuring cuvettes made from glass or quartz are very expensive and, due to the danger of breakage, too valuable for rapid pH measurements outside the laboratory. Precise pH results can be obtained by using the included plastic cuvette MN 13/72, because it was used to balance colours for printing the colour scales. Type Range Gradiation Cat. No. UNISOL indicator solutions UNISOL 410 pH 4.0 – 10.0 0.5 910 02 UNISOL 113 pH 1.0 – 13.0 1.0 910 31 Presentation: 1 x 100 ml in drop bottle + colour scale + 1 plastic cuvette MN 13/72 UNISOL accessories Plastic cuvettes MN 13/72 (pack of 5) 910 39 Other products for pH measurement colorimetric determination photometric determination Colorimetric pH measurement is based on colour comparison in a comparator. The transparent coloured solution allows an unambiguous assignment of the pH value even for inexperienced eyes. These products are especially recommended for the pH measurement in unbuffered solutions, e. g. of surface waters (see page 50). The efficient NANOCOLOR® photometers, too, allow pH measurements independent of the human eye (see page 73, 86). www.mn-net.com MN 11 Testpapiere Seite 12 Mittwoch, 29. März 2006 1:56 13 Test papers for qualitative determinations Summary Test papers Test papers allow the qualitative detection of ions and chemical substances. They provide the information, whether a given component is present above the defined limit of detection. Determination of Test paper Presentation Alkaline phosphatase in milk Phosphatesmo MI box of 50 test sticks 10 x 95 mm 906 12 Aluminium test paper Ammonium test paper box of 100 strips 20 x 70 mm box of 200 strips 20 x 70 mm 907 21 907 22 Antimony test paper Arsenic test paper = mercury bromide paper Bismuth test paper Peroxtesmo KM turmeric paper box of 200 strips 20 x 70 mm box of 200 strips 20 x 70 mm 907 23 907 62 box of 200 strips 20 x 70 mm box of 25 sheets 15 x 30 mm box of 200 strips 20 x 70 mm 907 33 906 05 907 47 (Al3+) Aluminium ions Ammonia, ammonium ions (NH3, NH4+) Antimony ions (Sb3+) Arsenic, arsine (As, AsH3) Bismuth ions (Bi3+) Blood traces (peroxidase) Boric acid, borates (H3BO3, BO33–) 12 Some test papers can also be used for the non-destructive testing of materials. MN Cat. No. www.mn-net.com Testpapiere Seite 13 Mittwoch, 29. März 2006 1:56 13 Test papers for qualitative determinations Application of test papers for qualitative determinations Determination of Chlorine, free halogens Iron(II) ions (Fe2+) Iron ions (Fe2+, Fe3+) Lactoperoxidase in milk Lead, lead ions (Pb, Pb2+) Mastitis Nickel(II) ions (Ni2+) Nitrate and nitrite (NO3–, NO2–) Nitrite ions (NO2–), nitrous acid(HNO2), ozone (O3) Oil in water and soil Oil, thickness of layer in oil separators Peroxidase in foodstuffs Peroxidase in milk Potassium ions (K+) Protein residues Reducing agents, SO2, sulphite ions Sulphur dioxide (SO2), sulphite ions Silver ions (Ag+) Sperm, acid phosphatase Vat dyes, end-point of conversion Water on the bottom of fuel tanks Water in org. solvents Water distribution in butter Zirconium ions (Zr4+) www.mn-net.com Sulphide test paper dipyridyl paper Iron test paper Peroxtesmo MI Plumbtesmo udder test paper Nickel test paper Nitratesmo potassium iodide starch paper MN 816 N (normal sensitivity) potassium iodide starch paper MN 616 T (for spot tests) Oil test paper AQUATEC test sticks Peroxtesmo KO Peroxtesmo MI Potassium test paper INDIPRO potassium iodate starch paper Sulphite test paper Silver test paper Phosphatesmo KM indanthrene yellow paper AQUATEC test sticks Watesmo Wator Zirconium test paper Presentation box of 200 strips 20 x 70 mm Cat. No. 906 03 box of 200 strips 20 x 70 mm box of 100 strips 20 x 70 mm box of 40 sheets 40 x 25 mm box of 200 strips 20 x 70 mm reel of 5 m length box of 200 strips 20 x 70 mm box of 200 strips 20 x 70 mm reel of 5 m length reel of 5 m length refill pack à 3 reels booklet with 100 strips 10 x 75 mm reel of 5 m length box of 200 strips 20 x 70 mm box of 100 strips 20 x 70 mm box of 100 sheets 15 x 15 mm box of 40 sheets 40 x 25 mm PE bag with 20 sheets box of 200 strips 20 x 70 mm reel of 5 m length reel of 5 m length refill pack of 3 reels booklet with 100 strips 10 x 75 mm box of 200 strips 20 x 70 mm 907 24 907 28 906 01 907 29 906 04 907 50 906 03 906 04 907 44 907 45 907 46 907 61 907 25 907 26 906 27 906 02 907 48 907 30 906 11 907 54 907 55 907 56 907 58 box of 100 strips 20 x 70 mm box of 100 test sticks 10 x 200 mm box of 100 sheets 15 x 15 mm box of 100 sheets 15 x 15 mm box of 200 strips 20 x 70 mm box of 60 test sticks 10 x 95 mm reel of 5 m length box of 100 strips 20 x 70 mm box of 200 strips 20 x 70 mm box of 25 sheets 15 x 30 mm box of 200 strips 20 x 70 mm box of 100 test sticks 10 x 200 mm reel of 5 m length box of 50 sheets 78 x 40 mm box of 100 strips 20 x 70 mm 907 60 907 42 906 06 906 27 907 27 907 65 907 53 907 63 907 32 906 07 907 51 907 42 906 09 906 10 907 21 MN Test papers Test paper Chlortesmo potassium iodide starch paper (see below) Chromium, chromate (Cr(VI), CrO42–) Chromium test paper Cobalt test paper Cobalt ions (Co2+) + 2+ Copper, copper ions (Cu, Cu , Cu ) Cuprotesmo Copper test paper Copper(II) ions (Cu2+) Cyanides, hydrocyanic acid (CN–, HCN) Cyantesmo Fluorides, hydrogen fluoride (F–, H2F2) Fluoride test paper Halogens, especially free chlorine Chlortesmo Hydrocyanic acid, cyanides (HCN, CN–) Cyantesmo Hydrogen sulphide (H2S), lead acetate paper sulphide ions (S2–) 13 Testpapiere Seite 14 Mittwoch, 29. März 2006 1:56 13 Test papers for qualitative determinations Description of qualitative test papers in alphabetical order Aluminium test paper Cat. No. 907 21 Test papers This test paper shows bright red spots on a yellow background in the presence of aluminium ions (Al3+). Fe, Zn, Cu and Mn interfere with the determination of aluminium. Under certain reaction conditions aluminium test paper can be used for the determination of zirconium. Limit of sensitivity: 10 mg/l Al3+ Ammonium test paper Cat. No. 907 22 This test paper can be used for the detection of ammonium ions as well as for gaseous ammonia. The white paper turns brownish-yellow in the presence of ammonium ions or NH3. This test paper is specific for the determination of NH4+. Limit of sensitivity: 10 mg/l NH4+ Antimony test paper Cat. No. 907 23 This test paper shows orange-red spots on a yellow background in the presence of antimony ions [Sb(III)]. Pentavalent antimony, i.e. Sb(V), has to be reduced to Sb(III) with metallic magnesium. This test paper is specific for antimony. Limit of sensitivity: 5 mg/l Sb3+ AQUATEC test sticks the lower ends coincide. The test stick is then lowered into the tank by means of a thin cord or wire until it reaches the bottom. Any water present beneath the fuel will dissolve the blue layer (testing tim about 15 – 20 seconds). If the test stick was lowered vertically to the bottom of the tank, the level of dissolved layer corresponds to the level of water present. For the determination of oil layers in oil separators, the part of the AQUATEC paper, which remains blue, indicates the thickness of the oil layer. Arsenic test paper (mercury bromide paper) Cat. No. 907 62 This test paper is used for the determination of arsenic or arsine. It is based on the fact that arsine forms a coloured coordination compound with mercury compounds. The test paper is exposed to AsH3, liberated with zinc/hydrochloric acid, by holding the paper either over the test tube or over the end of a gas exhaust tube. Colour reaction: white → brown-black. The colour reaction is faster, when the paper is first moistened before being used to test for AsH3 in air. Limit of sensitivity: 0.5 µg As Recommended application: determination of arsenic in grape must and wine, determination of arsine in air. In the latter case the test paper should first be moistened with acetic anhydride. Cat. No. 907 42 Test sticks for the determination of water in petrol and fuel oil tanks or for the determination of the thickness of oil layers in oil separators Bismuth test paper Cat. No. 907 33 In the presence of bismuth ions (Bi3+) this paper shows an orange-red discoloration on a pale-yellow background. A number of metal ions produce yellow spots. These do not, however, interfere with the determination of Bi. Limit of sensitivity: 60 mg/l Bi3+ Sensitivity is reduced in the presence of nitric acid. The test solution should not contain more than 2 to 3 percent HNO3. Chlortesmo Cat. No. 906 03 This test paper is used for the qualitative determination of free halogens (chlorine, bromine, iodine). In the presence of these compounds the pale yellow paper turns blue. Free nitrous acid HNO2 (not nitrite ions) interferes, but can be destroyed by additions of amidosulphuric acid. Limit of sensitivity: 1 mg/l chlorine In the course of time frequently water accumulates in petrol and fuel oil storage tanks forming a layer underneath the fuel. We recommend a special test stick to determine the depth of this water layer.To ensure the proper function of oil separators, accumulated oil layers must be removed frequently. The thickness of such oil layers can also be determined with AQUATEC paper. The test stick consists of a polyester film 0.2 mm thick and 10 x 200 mm coated on one side with a dark blue, water-soluble layer, which is insoluble in petrol and fuel oil. In order to determine the presence of water beneath the petrol or fuel oil, the test stick is fixed to a flat stainless steel sheet (approx. 25 cm long, 3 cm wide and 3 mm thick) so that 14 MN Chromium test paper Cat. No. 907 24 This test paper shows violet spots on a white background upon application of solutions containing chromium. The reaction is based on the presence of chromium as chromate. Cr3+ ions must be converted to chromate. Interferences caused by mercury salts or molybdates are readily circumvented. Limit of sensitivity: 2 mg/l Cr3+ corresponding to 5 mg/l CrO42– www.mn-net.com Testpapiere Seite 15 Mittwoch, 29. März 2006 1:56 13 Test papers for qualitative determinations Description of qualitative test papers in alphabetical order Cobalt test paper Cat. No. 907 29 This test paper shows green spots on a white background in the presence of copper (Cu). It is specific for Cu. Limit of sensitivity: 20 mg/l Cu2+ Note: For the determination of copper on surfaces and in alloys, checking for pores in metallic coatings on copper, for criminal trace investigations (projectiles), and for the detection of copper-containing pesticides on plants, fruit or vegetables we recommend the specific and highly sensitive Cuprotesmo paper (sensitivity to 0.05 µg). Cuprotesmo Cat. No. 906 04 Cyantesmo is a test paper for the determination of hydrocyanic acid and cyanides in aqueous solutions and extracts. In the presence of HCN, the pale green paper turns blue. It does not react with alkaline cyanide solutions, but is very sensitive to cyanide solutions weakly acidified with sulphuric acid. Cyantesmo reacts intensively in the gas zone just above the level of the solution to be tested. Hexacyanoferrate(II), hexacyanoferrate(III), thiocyanate, thiosulphate and free chlorine interfere. For further information refer to the instructions for use supplied with the paper. Limit of sensitivity: 0.2 mg/l hydrocyanic acid (HCN) Cat. No. 907 28 The white test paper turns blue upon application of cobalt ions (Co2+). Interferences caused by iron or copper ions can be circumvented (see instructions for use supplied with the paper). Limit of sensitivity: 25 mg/l Co2+ Note: Non-destructive tests for the detection of cobalt in alloys are carried out as follows: apply 2 drops of acid solution (= 50 ml hydrogen peroxide 3 % + 7.5 ml o-phosphoric acid 85 % + 5 ml hydrochloric acid 37 %) to the degreased steel surface. After 30 to 60 seconds, absorb the liquid with the cobalt test paper. The presence of cobalt is indicated by a blue colour, the intensity of which varies according to the Co content. Limit of sensitivity: 0.5 % Co Copper test paper Cyantesmo Test papers Note: Non-destructive tests for the detection of chromium in metal alloys are carried out as follows: Apply a drop of a proper acid solution (1 part hydrochloric acid 37 % + 4 parts hydrogen peroxide 3 %) to the degreased steel surface, wait 10 – 30 seconds, add some drops of sodium hydroxide solution and cover the precipitate with filter paper. Press the chromium test paper on top of the filter paper. In the presence of chromium, a violet spot appears when the test paper is bathed in dilute sulphuric acid. Limit of sensitivity: 0.1 % Cr Dipyridyl paper Cat. No. 907 25 Impregnated with α,α’-dipyridyl (= 2,2’-bipyridine), the paper reacts when Fe2+ ions are present in mineral acid solutions, yielding a deep red very stable complex cation. Dipyridyl paper is specific for iron(II) (Fe2+) and permits the detection of minute quantities of Fe2+, even in the presence of substantial amounts of Fe3+. Limit of sensitivity: 2 mg/l Fe2+ Fluoride test paper Cat. No. 907 50 This paper is used for the determination of fluoride ions. The pinkish-red paper turns yellowish-white if fluorides are present in the test solution acidified with HCl. Substantial amounts of chlorates, bromates and sulphates cause white decolourations of the paper. These interferences are readily circumvented. Limit of sensitivity: 20 mg/l F– Indanthrene yellow paper Cat. No. 907 51 Indanthrene yellow paper is used to determine the end point in the conversion of vat dyes to the leuco form. In the presence of excess sodium hydrosulphite (sodium dithionite) and alkali the yellow paper turns blue. Because of the special purpose, indanthrene yellow paper is also called Hydrosulphite paper. Cat. No. 906 01 Preference should be given to this test paper for the detection of copper and copper salts on surfaces and in ash, for the detection of pores in metallic coatings on copper containing materials, in criminal trace investigations (projectiles), and for the detection of copper-containing pesticides on fruit and vegetables. The yellow-white paper turns pink to purple-red in the presence of copper or copper salts. It reacts with metallic copper as well as with Cu+ and Cu2+ ions. The test paper is specific for Cu. Limit of sensitivity: 0.05 µg Cu on surfaces as metallic Cu or Cu salt, 3 – 5 mg/l Cu ions Note: In addition to Cuprotesmo we supply a Copper test paper based on a different reaction (see above). www.mn-net.com MN 15 Testpapiere Seite 16 Mittwoch, 29. März 2006 1:56 13 Test papers for qualitative determinations Description of qualitative test papers in alphabetical order INDIPRO Cat. No. 907 65 Test papers Rapid test for determination of protein contamination on working surfaces in food industry. Rubb the wet paper on the surface to be tested, and add the colour reagent on the test pad. A colour change from yellow to green indicates protein residues. The surface should be cleaned then. Limit of sensitivity: 50 µg BSA (bovine serum albumin) cause a clear colour change to green. Presentation: The test kit contains a box with 60 test sticks and 2 reagents. Nickel test paper This test paper can be used for the determination of nickel in solutions as well as in materials containing nickel (non-destructive testing of alloys). In the presence of nickel ions (Ni2+) the white test paper turns red. Interferences caused by iron, cobalt or copper can be circumvented as described in the instructions for use supplied with the paper. Limit of sensitivity: 10 mg/l Ni2+ Note: For the determination of nickel in alloys, apply 1 drop nitric acid 3 % to the degreased surface. After about 1 minute absorb the liquid with the test paper. The presence of nickel is indicated by an intense red colour. The paper can also be used to test for nickel in consumer goods (zip fasteners, bracelets, buttons etc.). Limit of sensitivity: 0.5 % Ni Nitratesmo Iron test paper Cat. No. 907 26 This test paper is used for the rapid detection of iron ions (Fe2+ and Fe3+). These ions form brownish-red spots on a yellowish-white background. Mn, Mo, Ti and vanadium, if present as the cation, interfere. Interferences caused by Mn, Mo and Ti can be circumvented, however, not the interference caused by V. After prolonged storage the sensitivity may decrease. In this case wait 1 – 5 seconds for evaluation. Limit of sensitivity: 10 mg/l Fe2+ or Fe3+ Note: For specific detection of iron(II) (Fe2+) we recommend our dipyridyl paper. Lead acetate paper Cat. No. 907 44 Lead acetate paper is a filter paper impregnated with lead acetate. In the presence of H2S (hydrogen sulphide) the white paper turns brownish-black. Lead acetate reacts with H2S to form black lead sulphide. With lower H2S concentrations, however, the white paper assumes only a brown colour. Limit of sensitivity: 1 drop of a solution with 5 mg/l sulphide (S2–) gives a brown ring which is just visible. Cat. No. 907 30 Cat. No. 906 11 This test paper is suited for the simultaneous detection of nitrate and nitrite. It is based on a colour reaction of nitrate and nitrite ions in the presence of concentrated sulphuric acid or 5 mol/l hydrochloric acid, when a suitable organic compound is present. The white Nitratesmo test paper reacts 1. when dipped into 5 mol/l hydrochloric acid in the presence of nitrite: colour change to lemon-yellow 2. when dipped into sulphuric acid 96 % a) from white to red in the presence of nitrate alone or large amounts of nitrate with small amounts of nitrite, b) from white to orange-red in the presence of small amounts of nitrate with large amounts of nitrite. To detect very small amounts of nitrate in the presence of nitrite the latter has to be destroyed with amidosulphuric acid. Chlorate, bromate, iodate, hypochlorite, vanadate and iodide interfere with the Nitratesmo reaction; acetate, arsenate, hydrogen carbonate, borate, bromide, carbonate, and sulphite do not interfere. Limit of sensitivity: 10 mg/l nitrate (NO3–), 5 mg/l nitrite (NO2–) Oil test paper Cat. No. 907 60 This light blue paper turns dark blue in the presence of hydrocarbons, particularly gasoline, fuel oil, lubricating oil, etc. It is recommended for the rapid determination of oil contaminations in water and/or soil. Mastitis see Udder test paper Mercury bromide paper see Arsenic test paper 16 MN www.mn-net.com Testpapiere Seite 17 Mittwoch, 29. März 2006 1:56 13 Test papers for qualitative determinations Description of qualitative test papers in alphabetical order Substance Petroleum ether (b. p. 40 – 80 °C) Gasoline (high octane) Fuel oil Lubricating oil Colour reaction lower limit clearly [mg/l of detectable water] [mg/l of water] 250 400 10 5 1 25 10 5 When testing volatile substances, the colour reaction must be evaluated immediately, because it fades rapidly. Peroxtesmo KM Peroxtesmo KO Cat. No. 906 05 Cat. No. 906 06 Test papers for the detection of peroxidase or blood traces Peroxtesmo KM for the detection of blood traces in criminal investigation and forensic practice A sample of the suspicious material is soaked in water or physiological sodium chloride solution. Then the Peroxtesmo paper is opened by seizing both ends of the plastic envelope and tearing them apart. The wet sample, soaked for about 1 minute, is placed on the test paper. If traces of blood are present, a distinct discoloration appears after a few seconds. Peroxtesmo KO for the detection of peroxidase in foodprocessing industries A drop of the liquid to be tested, e.g. vegetable juice, is applied to the test paper, or a section of a plant part is firmly pressed against the test paper. Each blue or bluish-green discoloration within 2 minutes proves the presence of peroxidase. www.mn-net.com Colour reaction: Peroxtesmo KO and Peroxtesmo KM react with peroxidase or blood traces, forming blue spots on a white background. Specificity: Peroxtesmo is specific for peroxidase, but not for blood. For the latter, the use of Peroxtesmo can only be considered as a preliminary test. Peroxtesmo MI Test papers To determine oil in water, move the paper back and forth a few times in the test solution. For detection of oil in soil, press the paper firmly against the soil to be tested and rinse it with clear water. With volatile hydrocarbons, the colour reaction of the test paper has to be evaluated immediately. Limit of sensitivity: The sensitivity of the test paper is largely dependent on the solubility of the hydrocarbons. By moving the paper back and forth a few times at the surface of the water, the following amounts can be detected: Cat. No. 906 27 Test paper for the detection of peroxidase in milk The white paper turns dark blue in the presence of the enzyme lactoperoxidase. A drop of milk is applied to the test paper. Any blue coloration within 2 minutes indicates lactoperoxidase in the sample. This test serves to distinguish between raw milk and highly heated milk. It can replace the frequently used test based on guaiacol, which is toxic and has a bad smell. Limit of sensitivity: 3% raw milk in heated milk Presentation: box with 100 test papers 15 x 15 mm Phosphatesmo KM Cat. No. 906 07 Test paper for the detection of acid phosphatase Application: detection of sperm spots in criminal investigations and forensic practice The material to be tested is macroscopically checked for suspicious spots. Fabrics show a board-like appearance, and a bluish, white or yellowish fluorescence under a quartz lamp. The advantage of Phosphatesmo KM is that it permits – on the scene of crime – rapid indicative tests whether the suspicious traces contain sperms or not. Colour reaction: the test paper reacts with acid phosphatase (sperm spots) yielding violet spots on a white background. Specificity: Phosphatesmo is specific for acid phosphatase. The reaction is not a suitable substitute for the microscopic determination of live spermatozoa. MN 17 Testpapiere Seite 18 Mittwoch, 29. März 2006 1:56 13 Test papers for qualitative determinations Description of qualitative test papers in alphabetical order Phosphatesmo MI Cat. No. 906 12 Test papers Test sticks for the determination of alkaline phosphatase in milk. Suitable as a rapid test for successful pasteurization of raw milk Potassium test paper This test paper shows potassium as orange-red spots on a light yellow background. Rubidium, cesium and thallium(I) also produce orange-red colour reactions. Excess of sodium and heavy metal ions reduce sensitivity. Larger amounts of ammonium ions cause interfering discolourations. In the instructions for use, which are supplied with the paper, a special method is provided to circumvent any of these interferences. Limit of sensitivity: 250 mg/l K+ Potassium iodate starch paper Dip the test stick into the milk and incubate at 36 °C. A colour change from white to yellow indicates the presence of raw milk or non-pasteurized milk. No colour change indicates a successful pasteurization. Limit of sensitivity: 0.5% raw milk in pasteurized milk can be detected. Presentation: box with 50 test sticks 10 x 95 mm Store the test sticks dry and cool (+2 to +8 °C). Plumbtesmo® Cat. No. 907 27 Cat. No. 907 53 Potassium iodate starch paper is a filter paper impregnated with potassium iodate (KIO3) and starch, which is used for the detection of sulphurous acid (H2SO3) and alkali sulphites. The stoichiometry of the reaction is as follows: 2 IO3– + 5 SO32– + 2 H+ → 5 SO42– + I2 + H2O The sulphurous acid reduces potassium iodate to form elemental iodine which reacts with the starch to a blue-violet complex. Thus the white potassium iodate starch paper turns blue-violet in the presence of H2SO3. Limit of sensitivity: 5 mg/l SO2 Recommended application: detection of sulphur dioxide (SO2) in the chemical laboratory, testing of meat products suspected of containing added sulphite. Note: For the detection of sulphite in meat products, also refer to our Sulphite test paper. Cat. No. 906 02 Plumbtesmo® provides a convenient and simple way to detect lead and lead salts in solutions or on any surface including painted surfaces, metal surfaces, dishes, ceramics, toys and other items. It can also be used for criminalistic search for traces of projectiles. For detection of metallic lead and lead salts on surfaces, moisten the test paper with distilled water and press it against the surface to be tested for about 1 to 2 minutes. Plumbtesmo is white when dry and turns yellow when wet. Lead is indicated when the paper turns pink to dark purple. Large quantities are indicated immediately, smaller quantities after a few minutes. The evaluation should be made within 15 minutes. Plumbtesmo® can also be used as an indicator for lead in automobile exhaust pipes, when leaded gasoline has been burnt. For this test Plumbtesmo® offers the following advantages: the test can be performed directly on the vehicle it is rapid and reliable and does not require any chemical skills no additional laboratory equipment is necessary; some distilled water, a spray bottle with acetone (to remove the soot, if necessary), disposable gloves and the test paper Plumbtesmo® for the detection of lead is all you need Potassium iodide starch paper This is a filter paper impregnated with potassium iodide (KI) and starch for the detection of nitrite and free chlorine. Interferences by tellurium, silver, cadmium, barium and strontium are readily circumvented. Limit of sensitivity: 0.05 µg lead on surfaces or as solid Pb salt, 5 mg/l Pb2+ in solutions 18 MN www.mn-net.com Testpapiere Seite 19 Mittwoch, 29. März 2006 1:56 13 Test papers for qualitative determinations Description of qualitative test papers in alphabetical order Silver test paper Turmeric paper Cat. No. 907 47 Turmeric paper is a filter paper impregnated with curcumin, the yellow dye extracted from the roots of Curcuma tinctoria (yellow ginger). It is used to detect boric acid and borates. Colour reaction: yellow → greenish black Oxidising agents and iodide interfere. Application: A drop of the acidified test solution (pH 1 – 2 with HCl) has to be applied to the yellow test paper. The paper has to be dried at 100 °C for about 3 minutes. After that a drop of 1 N NaOH is applied on the same spot. After 4 – 5 minutes the spot turns to greenish-black in the presence of boron. Brown-red colours are of no significance. Limit of sensitivity: 20 mg/l boron (100 mg/l H3BO3) Test papers Nitrite or free chlorine oxidise potassium iodide to form elemental iodine which reacts with the starch to a blue-violet complex. Colour reaction: white → blue-violet Potassium iodide starch paper may be used by dipping it into the solution to be tested. More often, however, it is used in the manner of a spot test by applying drops of the solution to the paper. MN 816 N standard grade Cat. No. 907 54 MN 616 T recommended for spot tests Cat. No. 907 58 Limit of sensitivity: 1 mg/l NO2– / 1 mg/l free Cl2 Recommended application: end point detection during diazotations (for this reason, potassium iodide starch paper is sometimes called "Diazonium paper"); determination of acetic acid anhydride; general test for organic substances which release iodine; detection of residues of peracetic acid in dialysates. Cat. No. 907 32 This test paper shows silver ions (Ag+) as red-violet spots on a salmon-red background. Interferences caused by mercury and copper ions (Hg2+, Cu2+) are readily circumvented. Gold, platinum and palladium produce colour reaction similar to that of silver, but can be masked. Limit of sensitivity: 20 mg/l Ag+ Sulphide test paper Cat. No. 907 61 In the presence of H2S or sulphide ions this paper turns from white to brownish-black. This test does not contain any harmful substances which must be declared as hazardous. In contrast, lead acetate paper, which is comparable in application, contains toxic reagents. Limit of sensitivity: 1 drop of a solution containing 5 mg/l sulphide (S2–) gives a brown ring which is just visible. Sulphite test paper Cat. No. 907 63 This test paper is recommended for the rapid detection of sulphites and gaseous sulphur dioxide. The white paper turns pink to brick-red in the presence of sulphite or free sulphur dioxide. The paper does not react with sulphites in acidic solutions. These have to be neutralised with solid sodium acetate. Thiosulphates only interfere with the determination of gaseous sulphur dioxide. Limit of sensitivity: 10 mg/l Na2SO3 Note: sulphite test paper can also be used for medical-diagnostic purposes as a rapid test for sulphite oxidase deficiency. www.mn-net.com Udder test paper Cat. No. 907 48 The udder test paper is a specially adapted indicator paper for the rapid determination of streptococcal mastitis. Milk of cows infected with this disease cannot be sold, if it is obviously changed. Most cases of mastitis cause the pH value of the milk to depart from the normal value, and the udder test paper detects such changes. Occasionally, only one teat of an udder shows symptoms of the infection. Consequently, all four teats require testing. The udder test paper contains four indicator areas, one for a sample from each teat. Colour reaction: The milk of healthy cows changes the indicator colour to yellowish-green (pH 6.4 – 6.6). Milk from moderately afflicted animals causes the colour to turn green (pH about 7) while milk from severe cases of mastitis gives rise to different shades of blue (pH 7 – 8 or higher). If the indicator remains yellow, the milk shows a pronounced acidic pH value (pH 6.3 or less) indicating other types of diseases. Presentation: 20 udder test papers 90 x 140 mm in PE bags, with four indicator spots and imprinted cow and udder symbol. Additionally the papers provide space for individual remarks. MN 19 Testpapiere Seite 20 Mittwoch, 29. März 2006 1:56 13 Test papers for qualitative determinations Description of qualitative test papers in alphabetical order Test papers Vat dye conversion Wator see Indanthrene yellow paper Indicator paper for the determination of water in butter according to DIN 10 311 The storage life of butter is closely linked to the size of the water and buttermilk particles it contains. For this reason it is important to check the water distribution during the manufacturing process and before storing larger quantities. The WATOR indicator paper allows an exact means for controlling the water distribution. Evaluation charts according to the 5-point evaluation system are available on request. On contact with water WATOR develops dark-blue spots, the size and number of which is correlated to the distribution of the water in the butter. Watesmo Cat. No. 906 09 WATESMO is a test paper for the detection of water in the liquid as well as the vapour phase a) in the liquid phase in aliphatic and aromatic hydrocarbons (gasoline, oil), in isopropanol and higher alcohols, in waxes, for determination of absorptive moisture in salts, in solid fats as well as aqueous emulsions of ointment bases Depending on the type of sample, a water content of more than 10 – 15% can be indicated with WATESMO paper. b) in the vapour phase (indirect determination) the test strip is dipped into absolutely anhydrous Isopropanol and, while still moist, is placed into the medium to be tested, such as a current of air. The isopropanol acts as a solvent aid between the water vapour and WATESMO. After evaporation of the alcohol in the driest possible atmosphere, a blue colour will appear, the intensity of which depends on the amount of water vapour present. WATESMO changes colour from light blue to deep blue. Do not touch the test paper, except with absolutely dry fingers or forceps. When dry, the paper does not react with atmospheric moisture. WATESMO indicates the absence of water, if the test strip remains colourless after evaporation of the solvent. Therefore it can be used to indicate water seeping into waterproof containers, through impermeable clothing or other watertight products. Exceptions and sources of error: WATESMO cannot be used where methanol, dimethylformamide, dimethylsulphoxide or mixtures containing these solvents are present. When dipped onto a solvent containing substantial amounts of water, the test strips turns deep blue immediately, i. e. even prior to evaporation of the solvent. Allowing the test paper to dry in a moist atmosphere may also produce a blue colour. Drying in a desiccator may therefore be indicated (see above under b). 20 MN Zirconium test paper Cat. No. 906 10 Cat. No. 907 21 This test paper shows zirconium as purple-red spots on a yellow background. Note: Zirconium test paper is identical with the aluminium test paper. For this reason it is important to follow the instructions for the respective test. Only hafnium interferes. Limit of sensitivity: 20 mg/l Zr4+ www.mn-net.com Testpapiere Seite 21 Mittwoch, 29. März 2006 1:56 13 Test sticks and test papers for semi-quantitative determinations QUANTOFIX® test sticks for semi-quantitative determinations Test papers QUANTOFIX® test sticks meet the most important requirements for a modern quick-test: rapid dip and read convenientthe analysis can be carried out without any further equipment, only a single test stick of QUANTOFIX® is needed specific QUANTOFIX® test sticks are highly specific – possible interferences are eliminated by precipitation or masking stable shelf life 2 1/2 years after production (below +30 °C) Type QUANTOFIX® Aluminium1) QUANTOFIX® Ammonium1) QUANTOFIX® Arsenic 10 1) QUANTOFIX® Arsenic 501) QUANTOFIX® Ascorbic acid Gradation Colour change Cat. No. 0–5–20–50–200–500 mg/l Al3+ pink to red 913 07 0–10–25–50–100–200–400 mg/l NH4+ yellow to orange 913 15 0 – 0.01 – 0.025 – 0.05 – 0.1 – 0.5 mg/l As3+/5+ white to yellowish-brown 913 34 0 – 0.05 – 0.1 – 0.5 – 1.0 – 1.7 – 3.0 mg/l As3+/5+ white to yellowish-brown 913 32 0–50–100–200–300–500–1000–2000 mg/l yellow to green-blue 913 14 vitamin C QUANTOFIX® Calcium1) 0–10–25–50–100 mg/l Ca2+ yellow to red 913 242) ® QUANTOFIX Carbonate hardness 0–3–6–10–15–20 °d light green to blue 913 23 QUANTOFIX® Chloride 0–500–1000–1500–2000– ≥ 3000 mg/l Cl– brown to yellow 913 21 QUANTOFIX® Chlorine1) 0–1–3–10–30–100 mg/l Cl2 white to red-violet 913 17 QUANTOFIX® Chromate1) 0–3–10–30–100 mg/l CrO42– white to violet 913 01 QUANTOFIX® Cobalt 0–10–25–50–100–250–500–1000 mg/l Co2+ white to green-blue 913 03 QUANTOFIX® Copper 0–10–30–100–300 mg/l Cu+/2+ white to red-violet 913 04 QUANTOFIX® Cyanide1) 0–1–3–10–30 mg/l CN– white to red-violet 913 18 QUANTOFIX® EDTA 0–100–200–300–400 mg/l EDTA red to yellow 913 35 QUANTOFIX® Formaldehyde1) 0–10–20–40–60–100–200 mg/l HCHO beige to blue-violet 913 28 QUANTOFIX® Iron 10001) 0–5–20–50–100–250–500–1000 mg/l Fe2+/3+ white to dark red 913 02 QUANTOFIX® Iron 1001) 0–2–5–10–25–50–100 mg/l Fe2+/3+ white to blue-violet 913 08 QUANTOFIX® LubriCheck NEW! 0 – 15 – 50 – 75 – 130 – 200 mmol/l KOH yellow to blue 913 36 QUANTOFIX® Molybdenum1) 0–5–20–50–100–250 mg/l Mo6+ white to green 913 25 QUANTOFIX® Nickel 0–10–25–50–100–250–500–1000 mg/l Ni2+ white to light red 913 05 QUANTOFIX® Nitrate/nitrite 0–10–25–50–100–250–500 mg/l NO3– white to red-violet 913 13 white to red-violet 0–1–5–10–20–40–80 mg/l NO2– QUANTOFIX® Nitrite 0–1–5–10–20–40–80 mg/l NO2– white to red-violet 913 11 ® QUANTOFIX Nitrite 3000 0–0.1–0.3–0.6–1–2–3 g/l NO2– yellow to red 913 22 Ozone see Ozone test sticks page 29 light yellow to brown – QUANTOFIX® Peroxide 1000 0–50–150–300–500–800–1000 mg/l H2O2 white to brown 913 33 QUANTOFIX® Peroxide 100 0–1–3–10–30–100 mg/l H2O2 white to blue 913 12 QUANTOFIX® Peroxide 25 0–0.5–2–5–10–25 mg/l H2O2 white to blue 913 19 QUANTOFIX® Phosphate1) 0–3–10–25–50–100 mg/l PO43white to blue-green 913 20 QUANTOFIX® Potassium1) 0–200–400–700–1000–1500 mg/l K+ yellow to orange 913 16 QUANTOFIX® QUAT NEW! 0 – 10 – 25 – 50 – 100 – 250 – 500 – 1000 mg/l yellow to blue-green 913 37 Benzalkonium-chloride Silver see Ag-Fix page 27 yellow to brown – QUANTOFIX® Sulphate <200 – >400 – >800 – >1200 – >1600 mg/l SO42– red to yellow 913 29 QUANTOFIX® Sulphite 0–10–25–50–100–250–500–1000 mg/l SO32– white to salmon 913 06 Swimming pool see Swimming pool test page 30 – – QUANTOFIX® Tin 0–10–25–50–100–250–500 mg/l Sn2+ white to dark blue 913 09 total Hardness see AQUADUR® test sticks page 28 green to red – ® QUANTOFIX for 0–5–10–15–20–25 °d total hardness green to red 913 26 aquarium owners 0–3–6–10–15–20 °d carbonate hardness light green to blue 913 273) yellow to red pH 6.4–6.8–7.2–7.6–8.0–8.4 1) These tests are supplied complete with all reagents required for Presentation: container with 100 test sticks 6 x 95 mm 2) Presentation: container with 60 test sticks 3) Presentation: container with 25 test sticks the determination : CE-marked according to the IvD-directive 98/79/EC www.mn-net.com MN 21 Testpapiere Seite 22 Mittwoch, 29. März 2006 1:56 13 Test sticks and test papers for semi-quantitative determinations Description of QUANTOFIX® test sticks in alphabetical order QUANTOFIX® Aluminium Cat. No. 913 07 Test papers Test sticks and reagents for the semi-quantitative determination of aluminium in solutions Range: 5 – 500 mg/l Al3+ After dipping the test stick into the strongly alkaline test solution (pH 13.5 – 14) immerse the test area in 10 % acetic acid for about 1 minute. Be2+ interferes. Cu2+ interferes > 10 mg/l (precipitation with KI or Cd powder). The following anions cause low results: > 100 mg/l MnO4–, PO43–, SO32–, S2– > 500 mg/l B4O72–, F–, [Fe(CN)63–], S2O42–, SiO44–, citrate and tartrate. QUANTOFIX® Ammonium Cat. No. 913 15 Test sticks and reagents for the semi-quantitative determination of ammonium in solutions Range: 10 – 400 mg/l NH4+ QUANTOFIX® QUANTOFIX® QUANTOFIX® Calcium Cat. No. 913 24 Test sticks and reagents for the semi-quantitative determination of calcium in solutions Range: 10 – 100 mg/l Ca2+ The following ions only interfere above the indicated concentrations: > 1000 mg/l Al3+, As3+, NH4+, Sb3+, K+, Na+, Bi3+, Br–, Cl–, CN–, CrO42–, [Fe(CN)6]3–, [Fe(CN)6]4–, I–, NO2–, NO3–, PO43–, SCN–, S2O52–, acetate, ascorbate, citrate, tartrate > 500 mg/l Ba2+, Mg2+ > 250 mg/l Sr2+ – > 100 mg/l MnO4 Heavy metals interfere above the following concentrations: > 50 mg/l Ni2+ > 100 mg/l Mn2+ 2+ 3+ 2+ > 25 mg/l Fe , Fe , Pb > 10 mg/l Cr3+, Co2+, Cu2+, Hg2+, Zn2+ QUANTOFIX® Carbonate hardness Cat. No. 913 23 Arsenic 50 Arsenic 10 Cat. No. 913 32 Cat. No. 913 34 Test sticks and reagents for semi-quantitative determination of arsenic Ranges: QUANTOFIX® Arsenic 50 0.05 – 3 mg/l As3+/5+ QUANTOFIX® Arsenic 10 0.01 – 0.5 mg/l As3+/5+ Addition of zinc and a solid acid results in the formation of arsine from any arsenic compounds in the sample solution. Arsine reacts in the gaseous phase with mercury bromide of the reaction zone of the test stick to form mixed arsenic/mercury halides, which depending on concentration are coloured yellow to brown. QUANTOFIX® Ascorbic acid Test sticks for the semi-quantitative determination of the carbonate hardness This test measures the concentration of carbonate and bicarbonate ions (CO32– and HCO3–) in water. The carbonate hardness is a measure for the buffer capacity of the water. It is also that part of the total hardness (determination see AQUADUR), which can cause the formation of boiler scale. Range: 3° – 20 °d (corresponds to 50 – 350 mg/l CaCO3) Strong bases or other acid-consuming substances cause false results. Cat. No. 913 14 Test sticks for the semi-quantitative determination of vitamin C in solutions. Range: 50 – 2000 mg/l ascorbic acid Store test sticks for ascorbic acid in a cool and dry place, protected from sunlight and moisture. . 22 MN www.mn-net.com Testpapiere Seite 23 Mittwoch, 29. März 2006 1:56 13 Test sticks and test papers for semi-quantitative determinations Description of QUANTOFIX® test sticks in alphabetical order QUANTOFIX® Chloride Cat. No. 913 21 CO32– CrO42–, NO2–, NO3–, PO43–, SO32–, Cat. No. 913 04 Test sticks for the semi-quantitative determination of copper (Cu+/Cu2+) in solutions Range: 10 – 300 mg/l Cu+/Cu2+ Strongly acid solutions (pH < 2) have to be buffered to pH 2 to 6 using crystalline sodium acetate. QUANTOFIX® Cyanide Test papers Test sticks for the semi-quantitative determination of chloride (Cl–) in solutions Range: 500 – 3000 mg/l Cl– QUANTOFIX® Chloride uses the same general principle as the AQUADUR® test sticks (see page 28). In the pH range 2 to 12 the reaction is independent of the pH value of the solution to be analysed. Strongly acidic solutions have to be adjusted to pH 5 – 7 with sodium hydroxide solution, alkaline solutions are adjusted to the same pH range with nitric acid. Chloride concentrations greater 3000 mg/l can be determined after defined dilution of the test sample with distilled water. The following ions only interfere above the indicated concentrations: > 1000 mg/l Al3+, Ca2+, Cd2+, Ce4+, Cu2+, K+, Mg2+, Mn2+, Na+, NH4+, Ni2+, Pb2+, Sn2+, Zn2+, BO3–, QUANTOFIX® Copper Cat. No. 913 18 Test sticks and reagents for the semi-quantitative determination of cyanide in solutions Range: 1 – 30 mg/l CN– Only free cyanides or cyanide complexes which can be decomposed with chlorine are detected. Strongly alkaline solutions (pH > 10) must be adjusted to a pH of 6 – 7 using dilute sulphuric acid. Thiocyanates in excess of 1 mg/l produce a similar coloration. Iodide and bromide above 5 mg/l cause the colour to fade as does sulphide above 20 mg/l. SO42–, acetate, citrate, oxalate, tartrate, EDTA > 500 mg/l Fe2+, Fe3+ > 200 mg/l I–, > 100 mg/l Ag+, Br–, SCN– > 75 mg/l Hg2+ > 20 mg/l CN–, S2O32– QUANTOFIX® EDTA > 10 mg/l S2–, ascorbate Chloride test sticks have to be stored cool and dry, protected from sunlight and moisture! Store unopened packages in the refrigerator! QUANTOFIX® Chlorine Cat. No. 913 17 Test sticks and reagents for the semi-quantitative determination of free chlorine in solutions Range: 1 – 100 mg/l Cl2 Bromide and iodide above 5 mg/l cause fading of the colour. Higher concentrations bleach out the colour. Nitrite can also cause low readings. Strongly alkaline solutions (pH > 10) have to be adjusted to a pH value of 6 – 7 using dilute sulphuric acid. QUANTOFIX® Chromate Cat. No. 913 01 Test sticks and reagents for the semi-quantitative determination of chromate in solutions Range: 3 – 100 mg/l CrO42– Interferences caused by molybdates are eliminated by addition of oxalic acid in crystalline form to the strongly acidic solution. Iron(III) ions are precipitated with sodium hydroxide solution 32 %. QUANTOFIX® Cat. No. 913 03 Test sticks for the semi-quantitative determination of cobalt in solutions Range: 10 – 1000 mg/l Co2+ If the reaction colour does not appear on the colour scale, larger quantities of interfering ions (Cu2+, Hg+) are present. To eliminate these interferences, follow the procedure given in the instructions for use provided with the test sticks. www.mn-net.com Test sticks for the semi-quantitative determination of ethylenediaminetetraacetic acid (EDTA) in solutions Range: 100 – 400 mg/l EDTA Complexing agents such as ethylenediaminetetraacetic acid (EDTA) are frequently used as additives in washing and cleansing agents, cosmetics, in the photographic industry or paper industry. Since the biological degradation of such compounds is very difficult, their dosing should be thorougly monitored. The proper dosage concentration can be checked with QUANTOFIX® EDTA. The test sticks can also be used to detect the absence of complexing agents. The following complexing agents can also be determined with this method: nitrilotriacetic acid (NTA), cyclohexanedinitrilo(1,2)-tetraacetic acid, diethyltrinitrilopentaacetic acid, bis(aminoethyl)glycol ether N,N,N’,N’-tetraacetic acid. Conversion factor: 1 mg/l EDTA = 0.7 mg/l NTA QUANTOFIX® Formaldehyde Cat. No. 913 28 Test sticks and reagents for the semi-quantitative determination of formaldehyde in solutions Range: 10 – 200 mg/l HCHO Other aldehydes such as acetaldehyde or glutardialdehyde only react at higher concentrations, resulting in a discoloration which deviates from the colour scale. Acetone does not react. Strong oxidising and reducing agents cause low results. QUANTOFIX® Iron 1000 Cobalt Cat. No. 913 35 Cat. No. 913 02 Test sticks and reagents for the semi-quantitative determination of iron (Fe2+/Fe3+) in solutions Range: 5 – 1000 mg/l Fe2+/Fe3+ Some heavy metals, when present in larger concentrations, can cause slight discolorations. These can be eliminated by addition of a small quantity of cadmium powder. MN 23 Testpapiere Seite 24 Mittwoch, 29. März 2006 1:56 13 Test sticks and test papers for semi-quantitative determinations Description of QUANTOFIX® test sticks in alphabetical order QUANTOFIX® Iron 100 Cat. No. 913 08 Test papers Test sticks and reagents for the semi-quantitative determination of iron (Fe2+/Fe3+) in solutions Range: 2 – 100 mg/l Fe2+/Fe3+ Cobalt > 50 mg/l Co2+ produces a yellow-brown colour, which can be eliminated by boiling with sodium dithionite. Iron in hexacyanoferrates is not determined unless it is first decomposed with conc. sulphuric acid. QUANTOFIX® LubriCheck Cat. No. 913 36 Test sticks for the semi-quantitative determination of the alkalinity of solutions. The test is suitable to determine the concentration of cooling lubricants. Range: 15 – 200 mmol/l KOH The principle of QUANTOFIX® LubriCheck is comparable to AQUADUR test strips, described on page 28. It is an easy dip-and-read test. When metal parts are being machined (drilling, cutting...) cooling lubricants or coolants are indispensable to guarantee the quality of the NEW! workpiece as well as the lifetime of the machines. Using QUANTOFIX® LubriCheck the concentration of the cooling lubricant can easily be checked on the spot. This ensures optimal cooling and lubrication and at the same time optimal quality of the workpiece. QUANTOFIX® Molybdenum QUANTOFIX® Nitrite Cat. No. 913 11 Test sticks for the semi-quantitative determination of nitrite (NO2–) in solutions Range: 1 – 80 mg/l NO2– Between pH 1 and 13 the reaction is independent of the pH value of the test solution. Strongly acidic solutions (pH < 1) should be buffered with sodium acetate, and strongly alkaline solutions (pH > 13) are adjusted to about pH 3 – 5 using citric acid. Store nitrite test sticks in a cool and dry place, protected from sunlight and moisture. QUANTOFIX® Nitrite 3000 Cat. No. 913 22 Test sticks for the semi-quantitative determination of high concentrations of nitrite (NO2–) in solutions Range: 0.1 – 3 g/l NO2– Between pH 2 and 12 the reaction is independent of the pH value of the test solution. Adjust strongly acidic solutions with dilute sodium hydroxide solution and strongly alkaline solutions with dilute sulphuric acid to a pH of about 4 – 6. Store nitrite test sticks in a cool and dry place, protected from sunlight and moisture. Cat. No. 913 25 Test sticks and reagents for the semi-quantitative determination of molybdenum Range: 5 – 250 mg/l Mo6+ Store molybdenum test sticks in a cool and dry place, protected from sunlight and moisture (storage temperature below + 30 °C). QUANTOFIX® Nickel Cat. No. 913 05 Test sticks for the semi-quantitative determination of nickel (Ni2+) in solutions Range: 10 – 1000 mg/l Ni2+ If the reaction colour does not appear on the colour scale, larger quantities of interfering ions (Co2+, Hg+) are present. To eliminate these interferences, follow the procedure given in the instructions for use provided with the test sticks. QUANTOFIX® Nitrate/Nitrite Cat. No. 913 13 Test sticks for the semi-quantitative determination of nitrate and nitrite in solutions Range: 10 – 500 mg/l NO3–, 1 – 80 mg/l NO2– Because nitrite interferes with the determination of nitrate, the test sticks contain an additional test field for nitrite. If this upper test field turns red indicating the presence of nitrite, the NO2– has to be destroyed with amidosulphuric acid (Cat. No. 918 973); then the nitrate test is repeated with another test stick. Following this procedure, 10 mg/l nitrate can be determined even when 1000 mg/l nitrite are present. Store nitrate test sticks in a cool and dry place, protected from sunlight and moisture. 24 MN QUANTOFIX® Peroxide 1000 QUANTOFIX® Peroxide 100 QUANTOFIX® Peroxide 25 Cat. No. 913 33 Cat. No. 913 12 Cat. No. 913 19 Test sticks for the semi-quantitative determination of hydrogen peroxide (H2O2) and peroxides in solutions Ranges: QUANTOFIX® Peroxide 1000: 50 – 1000 mg/l H2O2 QUANTOFIX® Peroxide 100: 1 – 100 mg/l H2O2 QUANTOFIX® Peroxide 25: 0.5 – 25 mg/l H2O2 QUANTOFIX® Peroxide is also suited for the determination of peracetic acid and other organic and inorganic hydroperoxides. For the determination of hydroperoxides in organic solvents the test field is moistened with a drop of water after evaporation of the solvent. www.mn-net.com Testpapiere Seite 25 Mittwoch, 29. März 2006 1:56 13 Test sticks and test papers for semi-quantitative determinations Description of QUANTOFIX® test sticks in alphabetical order The following ions do not interfere: < 1000 mg/l Al3+, Ba2+, Bi3+, Ca2+, Fe2+/Fe3+, Mg2+, Mn2+, Sr2+, Zn2+; < 200 mg/l NH4+, Hg+/Hg2+, Tl+; < 25 mg/l S2– Protect test sticks from sunlight and moisture. Store package in a cool and dry place (storage temperature below +30 °C). QUANTOFIX® QUAT Test papers Between pH 2 and 9 the reaction is independent of the pH value of the test solution. Strongly acidic solutions should be buffered with sodium acetate, alkaline solutions are adjusted to pH 5 – 7 using citric acid. Strong oxidising agents interfere. Store peroxide test sticks in a cool and dry place. Avoid exposing the sticks to sunlight and moisture. Store unopened packs in a refrigerator! Cat. No. 913 37 Test sticks for the semi-quantitative determination of quaternary ammonium compounds (QUATS) in solutions, i.e. disinfectants Range: 10 – 1000 mg/l Benzalkonium chloride QUANTOFIX® QUAT can be used for the NEW! general determination of quaternary ammonium compounds. The relation compound for the color scale is benzalkonium chloride. For the following other QUATs, concentrations can be determined using additional information provided in the instruction leaflet: N-Cetyl-N,N,N-trimethylammonium bromide (CTAB), N-Cetylpyridinium bromide, Dodecyltrimethylammonium bromide (LTAB), Octadecyltrimethylammonium bromide, Didecyldimethylammonium bromide, Hyamine® 1622 (Hyamine® is a registered trade-mark from Rohm und Haas Co.), Cetyldimethylbenzylammonium chloride, Benzyldimethyldodecylammonium bromide For special manufactures of test papers for quaternary ammonium compounds please see INDIQUAT page 28. QUANTOFIX® Sulphate QUANTOFIX® Phosphate Cat. No. 913 20 Test sticks and reagents for the semi-quantitative determination of ortho-phosphate (PO43–) in solutions Range: 3 – 100 mg/l PO43– Only ortho-phosphate is determined. Other phosphates, such as poly-, pyro-, and metaphosphates, have to be decomposed for the determination of total phosphates. Silica (SiO2) contents above 10 mg/l react in the same way giving a blue coloration. Larger amounts of sulphide ions (S2–) cause a brown colour of the test field, smaller concentrations cause low results. The following ions do not interfere: < 1000 mg/l Ag+, Al3+, Cd2+, Co2+, Cr3+, Mg2+, Mn2+, NH4+, Ni2+, Zn2+, Cl–, F–, NO3–, SO42–, citrate, oxalate, tartrate, < 500 mg/l Ca2+, < 250 mg/l Pb2+, < 50 mg/l Cu2+, < 25 mg/l Fe3+, 5 mg/l Fe2+, < 2 mg/l NO2– QUANTOFIX® Potassium Cat. No. 913 16 Test sticks and reagents for the semi-quantitative determination of potassium (K+) in solutions Range: 200 – 1500 mg/l K+ Sodium ions > 3000 mg/l cause low results. www.mn-net.com Cat. No. 913 29 Test sticks for the semi-quantitative determination of sulphate in solutions Range: 200 – 1600 mg/l SO42– QUANTOFIX® sulphate uses the same general principle as the AQUADUR® test sticks (see page 28). Between pH 4 and 8 the reaction is independent of the pH value of the test solution. Strongly acidic samples have to be adjusted with sodium acetate, alkaline solutions are adjusted using tartaric acid. The following ions only interfere above the indicated concentrations: > 1000 mg/l BrO3–, ClO3–, CrO42–, SO32–, S2O52–, SeO32–, > 500 mg/l S2O42–, > 100 mg/l CN–, S2– QUANTOFIX® Sulphite Cat. No. 913 06 Test sticks for the semi-quantitative determination of sulphite in solutions Range: 10 – 1000 mg/l SO32– Strongly or weakly acidic solutions have to be buffered with solid sodium acetate prior to testing, since the test paper does not react with sulphites in acidic media. Sulphide ions interfere since they also produce a red reaction colour of the test paper in neutral solution. This interference can be eliminated by the addition of an excess of nickel(II) ions. The NiS formed can be removed by filtration. Larger amounts of reducing agents, such as hydroxylammonium chloride or ascorbic acid, interfere, causing low sulphite results. MN 25 Testpapiere Seite 26 Mittwoch, 29. März 2006 1:56 13 Test sticks and test papers for semi-quantitative determinations Description of QUANTOFIX® test sticks in alphabetical order QUANTOFIX® Tin Cat. No. 913 09 Test papers Test sticks for the semi-quantitative determination of tin(II)ions in solutions Range: 10 – 500 mg/l Sn2+ Tetravalent tin has to be reduced. To do this, add 0.5 ml hydrochloric acid 37 % and some magnesium turnings to 5 ml of the test solution and heat to boiling temperature. Hexacyanoferrates interfere > 10 mg/l (yellow-brown colour) and must be decomposed by evaporation with sulphuric acid 96 %. QUANTOFIX® Zinc Cat. No. 913 10 Test sticks and reagents for the semi-quantitative determination of zinc (Zn2+) in solutions Range: 2 – 100 mg/l Zn2+ The following ions only interfere in larger concentrations: > 1000 mg/l Ag+, Al3+, Bi3+, Ca2+, Cd2+, Co2+, Fe2+, Fe3+, Mn2+, NH4+, Pb2+, Sn2+, Sn4+, Cl–, CrO42–, NO2–, NO3–, PO43–, SCN–, SO32–, SO42–, acetate, ascorbate, citrate, oxalate, tartrate The following ions will cause low results: > 500 mg/l Cr3+, > 200 mg/l CN–, > 100 mg/l Mg2+, > 50 mg/l S2–, > 25 mg/l Ni2+. The presence of Cu2+, > 10 mg/l Hg+/Hg2+ (precipitation with iron or cadmium powder in weakly acidic solution) and > 50 mg/l MnO4– (destroy with hydroxylammonium chloride in acidic solution) cause a brown coloration of the test field. 26 MN QUANTOFIX® Multisticks for aquarium owners Cat. No. 913 26 / 913 27 Test sticks for the semi-quantitative determination of the total hardness (Ca2+, Mg2+), carbonate hardness (HCO3–, CO32–) and the pH value of aquarium water Ranges: total hardness 5° – 25 °d carbonate hardness 3° – 20 °d pH value 6,4 – 8,4 The total hardness of a water is caused by its content of calcium and magnesium salts (Ca2+, Mg2+). When measuring the total hardness, the sum of these salts is determined. The carbonate hardness is a part of the total hardness and is caused by that portion of alkaline earth metals which are equivalent to the carbonate and hydrogen carbonate ions (CO32–, HCO3–) present in the water. The carbonate hardness is thus a measure for the buffer properties of the water. Water with a low carbonate hardness is not sufficiently buffered, therefore the pH value can fluctuate easily. The pH value indicates whether the water is acidic, alkaline or neutral. Water with a pH of 7 is called neutral. Towards lower pH values the water becomes increasingly acidic, towards higher pH values it becomes more alkaline. The QUANTOFIX® multisticks are a convenient tool for orienting measurement of these three parameters, which are very important for aquarium waters. www.mn-net.com Testpapiere Seite 27 Mittwoch, 29. März 2006 1:56 13 Test sticks and test papers for semi-quantitative determinations Other test sticks and test papers for semi-quantitative determinations Test paper / test stick Aquadur® Aquadur® Chlorine test Fluoride test INDIQUAT Moisture indicator Ozone test sticks Saltesmo Swimming pool test water hardness water hardness chlorine fluoride ions QUATS relative humidity in air ozone content in air halide ions free chlorine alkalinity pH Gradation Presentation Cat. No. 0–1–2–3–5–7–10 g/l Ag+ 0–0.5–1–2–3–5–7–10 g/l Ag+ / pH 4–5–6–7–8 < 3, >5, >10, >15, >20, >25 °d < 3, > 4, > 7, > 14, > 21 °d 10 – 50 – 100 – 200 mg/l Cl2 0–2–5–10–20–50–100 mg/l F– customers request 20–30–40–50–60–70–80 % reel of 5 m length box of 100 test sticks 6 x 95 mm 907 40 907 41 box of 100 test sticks 6 x 95 mm box of 100 test sticks 6 x 95 mm reel of 5 m length box of 30 test disks + reagent reel of 5 m length different presentations 912 01 912 20 907 09 907 34 90900-2 908 01 < 90, 90–150, 150-210, > 210 µg/m3 O3 0–0.25–0.5–1–2–3–4–5 g/l NaCl 0–0.5–1–3–5–10 mg/l (ppm) Cl2 0–80–120–180–240 mg/l (ppm) CaCO3 6.4–6.8–7.2–7.6–8.4 box of 12 test sticks 10 x 95 mm 907 36 box of 30 test disks box of 50 test sticks 6 x 95 mm 906 08 907 52 Test papers Ag-Fix (test paper) Ag-Fix (test sticks) Determination of silver silver and pH Description of semi-quantitative test sticks / test papers in alphabetical order Ag-Fix test sticks Ag-Fix test paper Cat. No. 907 41 Cat. No. 907 40 During operation of a fixing bath it is necessary to check the silver content as well as the pH in regular intervals to insure proper operation. A decrease in fixing capacity is noted as an increase in silver concentration or an alteration of the pH value. The convenient Ag-Fix test sticks from MACHEREYNAGEL allow a simultaneous semi-quantitative determination of silver and the pH value in photographic solutions. With these sticks two paper zones are sealed onto the lower end of a plastic strip, one for the determination of the silver concentration and one for pH measurement. After dipping the test sticks in the test solution the colours of the test zones are compared with the colour scale on the container. Ag-Fix comes in packages of 100 test sticks. The length of the sticks has been chosen for safe and convenient handling. The plug of the container is filled with a desiccant resulting in a shelf life of 2 1/2 years for Ag-Fix sticks. The determination is very simple: remove only as many sticks as are required and close the container immediately. Do not touch the test paper zone. Dip the test stick briefly into the fixing bath and strip of excess liquid. After 30 seconds compare the test fields with the colour scale and read off results. AgFix test sticks and Ag-Fix paper are not suited for fixing baths with pH values below 4. Concentrations above 10 g per litre can be determined after dilution of the fixing bath. Iron and copper ions interfere and show a falsely positive reaction. These ions can be determined with the test sticks QUANTOFIX® Iron 100 (Cat. No. 913 08), QUANTOFIX® Iron 1000 (Cat. No. 913 02) or QUANTOFIX® Copper (Cat. No. 913 04). www.mn-net.com Gradation test sticks: Silver: 0 – 0.5 – 1 – 2 – 3 – 5 – 7 – 10 g/l Ag+ pH: 4–5–6–7–8 Gradation test paper: Silver: 0 – 1 – 2 – 3 – 5 – 7 – 10 g/l Ag+ 0 – 1/8 – 1/4 – 3/8 – 5/8 – 7/8 – 11/4 oz. per US gallon Colour reactions: Silver: ochreous → brown pH: yellow → blue MN 27 Testpapiere Seite 28 Mittwoch, 29. März 2006 1:56 13 Test sticks and test papers for semi-quantitative determinations Description of semi-quantitative test sticks / test papers in alphabetical order Aquadur® test sticks Cat. No. 912 01/ 912 20 Test papers Test sticks for determination of the water hardness The hardness of water depends on its content of calcium and magnesium salts. When measuring the total hardness, the sum of these salts is determined. It is expressed in mmol/l or in degrees of hardness, whereby it is important to differentiate between German, English and French values: in Germany: 1 °d = 10 mg/l CaO = 17,8 mg/l CaCO3 in England: 1 °e = 14.3 mg/l CaCO3 in France 1 °f = 10 mg/l CaCO3 Conversion factors: 1 °d = 1.25 °e = 1.78 °f = 0.178 mmol/l In the USA, the water hardness is simply expressed in terms of mg/l CaCO3. Apart from the above values, water is often simply classified as "soft water", or "hard water" etc. The following values generally apply to these terms: below 50 mg/l CaCO3 – very soft water 50 – 120 mg/l CaCO3 – soft water 120 – 240 mg/l CaCO3 – medium hard water 240 – 360 mg/l CaCO3 – hard water above 360 mg/l CaCO3 – very hard water The hardness of water is often of importance where no laboratory facilities for the analytical determination exist. In these cases Aquadur® provides a quick method for an indicative reading. Its sensitivity is adequate for textile establishments of moderate size, in dyeing, laundries, small water works, boiler rooms as well as in pisciculture, aquaria and also for household use. Sensitivity: Aquadur® allows the determination of the water hardness from 0 to over 21 °d, i.e. up to about 360 mg/l CaCO3. Standard gradations are: 0 – 5 – 10 – 15 – 20 – 25 °d or 0 – 4 – 7 – 14 – 21 °d Other sizes and other gradations are available (bulk package with 5000 sticks or single-sealed [pack of 1000]). < 3 °d 0-0.3 mol/m3 I > 4 °d 0.7-1.2 mol/m3 II > 7 °d 1.4-2.5 mol/m3 III > 14 °d 2.8-3.7 mol/m3 IV > 21 °d >4.0 mol/m3 ↑↑↑ ↑↑↑ ↑↑↑ ↑↑↑ ↑↑↑ 1 °d = 1.78 °f = 1.25 °e = 17.8 mg/l CaCO3 Chlorine test Test paper for the semi-quantitative determination of 50 – 200 ppm chlorine The white paper turns blue-violet in the presence of Cl2. The test is particularly suitable for high range applications in disinfectant solutions which are for example used in food and beverage industry and animal farms. Gradation 10 – 50 – 100 – 200 mg/l Cl2 Presentation: reel of 5 m length and 10 mm width Fluoride test 28 MN Cat. No. 907 34 Test disks and reagent for the semi-quantitative determination of fluoride ions Gradation 0 – 2 – 5 – 10 – 20 – 50 – 100 mg/l F– (each kit contains a colour comparison scale) The reaction is based on the bleaching action of fluoride ions on an aluminium colour complex. The fluoride test is especially suited for rapid control of fluoride concentrations. Its purpose is to define concentration ranges and to detect values which fall short of or exceed given limits. Chlorates and bromates cause white discolourations of the test paper. Addition of sodium dithionite (Na2S2O4) will circumvent this interference without affecting the fluoride test. Large concentrations of sulphate also cause discolorations. Addition of barium chloride (BaCl2) eliminates this interference. When testing intensely coloured solutions the colour of the sample must be taken into account for evaluation. INDIQUAT Colour reaction: green → red Method of application: Dip the stick briefly into the water and shake off excess liquid. After 1 minute compare with the colour scale. The stick should be held by the end and care should be taken not to touch the test papers. Cat. No. 907 09 Cat. No. 909 00 – 909 02 This paper is used for the semi-quantitative determination of the concentration of quaternary ammonium compounds (QUATS) in disinfectant solutions. Since concentration and composition of these solutions vary widely from one product to the next INDIQUAT papers are tailored to each individual disinfectant. This is why we supply INDIQUAT papers only to manufacturers. www.mn-net.com Testpapiere Seite 29 Mittwoch, 29. März 2006 1:56 13 Test sticks and test papers for semi-quantitative determinations Description of semi-quantitative test sticks / test papers in alphabetical order example Moisture indicator Cat. No. 908 01 This represents a simple method for the determination of the relative atmospheric humidity. It consists of a series of absorbent papers impregnated with various chemicals which change the colour or the paper from blue to pink or vice versa, according to the relative moisture of the air. The illustrated moisture indicator is supplied as pack of 12 adhesive labels 50 x 100 mm and permits readings for a range from 20 to 80 percent relative atmospheric humidity. It should be read at the point where the transition colour from pink to blue appears. Indicator for relative atmospheric humidity % 20 30 40 50 60 70 moisture indicators from MACHEREY-NAGEL are free of toxic and cancerogenic materials and thus eliminate any health and safety risk. The clear colour change from red to yellow ensures an even more precise reading than with established humidity indicators based on cobalt chloride. Moisture indicators without cobalt chloride are available on request. Ozone test sticks Test papers Consumers can purchase INDIQUAT papers from the producer of the respective disinfectant. Presentation: reels of 5 m length and 10 mm width in black plastic dispensers with colour scale. Special designs for labels or scales on request. Cat. No. 907 36 Ozone is a colourless toxic gas. It is irritating to eyes and mucous membranes and can cause respiratory complaints. An ozone content of 180 µg/m3 is considered as critical value above which sensitive persons should avoid stronger physical exertion. The ozone values published by public media like press, radio or TV represent the ozone concentrations in the vicinity of the measuring stations. However, actual ozone values in other locations can considerably deviate from these published values due to meteorological and chemical influences such as wind, solar radiation, exhaust gases from vehicles etc. For this reason a local measurement of ozone concentrations is recommended. Ozone test sticks are a convenient test for orienting determination of the ozone concentration in air. Similar to the QUANTOFIX® test sticks they consists of plastic strips 10 mm wide, onto which a test paper has been sealed at the lower end. This allows easy handling of the test. 80 % comparison colour Limit of sensitivity: about ±5 % relative moisture. Where temperatures are substantially above or below 20 °C, corrections have to be made as follows: add 2.5 % relative moisture per 5° temperature increase, or subtract 2.5 % relative moisture per 5° temperature decrease. Note: Special sizes and presentations can be produced to customer’s specification and design. Moisture indicator without cobalt chloride Established humidity indicators are based on cobalt chloride (CoCl2), which is rated as carcinognic and toxic. Contact to these types of indicators represents a health and safety risk to staff involved in handling and packing. The new non-toxic www.mn-net.com Ranges and gradation: < 90, 90 – 150, 150 – 210, > 210 µg/m3 ozone Method of application: Place a test stick in the open air, protected from wind; if necessary, fix the test stick with a piece of adhesive tape. After 10 minutes compare the test field with the colour scale on the container. MN 29 Testpapiere Seite 30 Mittwoch, 29. März 2006 1:56 13 Test sticks and test papers for semi-quantitative determinations Description of semi-quantitative test sticks / test papers in alphabetical order Test papers Interferences: Other oxidising reagents (e. g. chlorine) cause a similar colour change and simulate higher ozone values. The measuring ranges are valid for a relative atmospheric humidity of 30 to 60 %. Humidity values below 30 % can cause low ozone results, humidity above 60 % can result in higher ozone values. Saltesmo Cat. No. 906 08 Test paper for the quantitative determination of halide ions This test is based on a reaction between the halide ions Cl–, Br–, I– and a coloured silver salt, which is decolourised by the reaction. Although the paper will react with all of the above halides, it is most frequently used for the determination of chloride and thus, indirectly, for the detection of NaCl. It is for this purpose that Saltesmo paper is specially recommended. Saltesmo is most commonly used in the analysis of foodstuffs1). It is an accepted practice to calculate the total halide content of a given sample, converted to the equivalent NaCl value, as the chloride content of the sample. The determination of the chloride content is important for the quality control and also permits comparison between different brands of the same product, e. g. tomato products1). The Saltesmo reaction is a "micro-titration on paper"2). As such, it is particularly suited for rapid checks on halogen ion or halide concentrations. Its purpose is to define concentration ranges and to detect values which fall short of or exceed labelled amounts. Cyanide and thiocyanate also bleach the brown colour. Fluoride ions do not interfere. Limit of sensitivity: Saltesmo permits the semi-quantitative determination of NaCl. Concentration gradations: 0 – 0,25 – 0,5 – 1 – 2 – 3 – 4 – 5 g NaCl/litre (each package is supplied with a comparison scale). 1) A Schaller, Fruchtsaftindustrie 9 (1964) 147 – 161 Swimming pool test Cat. No. 907 52 This swimming pool test consists of test sticks for the semiquantitative determination of free chlorine, alkalinity and the pH value of swimming pool water. Parameter: Ranges: Colour change Free chlorine 0.5 – 10 mg/l Cl2 yellow → violet Alkalinity 80 – 240 mg/l CaCO3 light green → dark green pH 6.4 – 8.4 yellow → red ^ 1 ppm) (1 mg/l = These test sticks are a convenient tool for orienting measurement of three parameters which are very important for swimming pool water. Now with easier application: Dip test stick with all test fields into the swimming pool water and make 5 back-and-forth movements. Shake off excess liquid. Read off the results for chlorine immediately and the results for pH and alkalinity after 30 seconds. The gradation and evaluation of the values for free chlorine, alkalinity and pH on the colour scale follow the rules and limiting values valid for the USA. 2)F.J. Förg und M. Staub, Chem. Rdsch. (Solothurn, Switzerland) 17 (1964) Nr. 19 30 MN www.mn-net.com Testpapiere Seite 31 Mittwoch, 29. März 2006 1:56 13 Test sticks for microbiological diagnostics BioFix® test sticks and test strips BioFix® is a family of test strips or test sticks belonging to the group of in-vitro diagnostics. They have been developed for Application BioFix® Oxidase rapid detection of the enzyme cytochromoxidase in microorganisms BioFix® Indole rapid detection of indole production by microorganisms BioFix® rapid detection of the enzyme L-alanineAminopeptidase aminopeptidase in microorganisms and evaluation of GRAM properties Shelf life: at least 2 years after production when stored between +2 ˚C and +8 ˚C Packing unit: Container with 50 test sticks or test strips and reagents, if required : CE-marked according to the IvD-directive 98/79/EC BioFix® test sticks and test strips meet the requirements for a modern rapid test: simplicity only few working steps and ready-to-use reagents reliability safe results with low effort clarity clear results by visual evaluation speed results in a few minutes convenience no additional accessories necessary Colour change for positive test result colourless to blue-violet colourless to bluish-green colourless to yellow Presentation Cat. No. test sticks 5.5 x 95 mm test strips 11 x 98 mm test sticks 5.5 x 95 mm 960 001 Test papers Designation the rapid detection of microbial properties or metabolic parameters. 960 002 960 003 BioFix® test strips are strips of absorbent paper 11 mm wide and 98 mm long, which are either completely impregnated with an indicator reagent or where several indicators have been applied as stripes. With BioFix® test sticks one or several indicator papers are sealed onto the end of a plastic strip which is 0.2 mm thick, 5.5 mm wide and 95 mm long. The length of the BioFix® test sticks and test strips allows a safe and hygienic handling even when testing microorganisms with potential hazard. The plug of the container is filled with a desiccant for increased shelf life of the sticks and strips. Depending on the test the BioFix® package may contain additional reagents. economy low price per test www.mn-net.com MN 31 Testpapiere Seite 32 Mittwoch, 29. März 2006 1:56 13 Test sticks for microbiological diagnostics BioFix® test sticks and test strips BioFix® Indole How is BioFix® used? BioFix® Test papers Handling of test sticks and strips is very easy: apply microorganisms wait several minutes visual evaluation of the colour change of the test field or test strip. Cat. No. 960 002 With an inoculating loop a well-grown, separate colony of the strain of microorganisms to be diagnosed is taken from the culture medium and applied to the end of the test strip. A bluish-green colour indicates indole-positive strains. Indol-negative Bacillus brevis BioFix® Aminopeptidase Indol-positive Escherichia coli Cat. No. 960 003 The colony to be diagnosed is suspended in a small volume of distilled water, and the test stick is dipped into this suspension. Yellow colouration indicates aminopeptidase-positive strains (= GRAM-negative microorganisms). BioFix® Oxidase Cat. No. 960 001 With an inoculating loop a well-grown, separate colony of the strain of microorganisms to be diagnosed is taken from the culture medium and applied to the test field of the stick. A blue-violet colour indicates oxidase-positive strains. Oxidase-negative Enterobacter aerogenes Aminopeptidase-positive GRAM-negative Escherichia coli 32 MN Aminopeptidase-negative GRAM-positive Enterococcus faecalis Oxidase-positive Pseudomonas aeruginosa www.mn-net.com