Sample Test Questions Chapter 1, Chemistry: Methods and Measurement 1. Name the branch of science that involves the study of matter and the changes it undergoes. Ans. chemistry 2. What do we call anything that has mass and occupies space? Ans. matter 3. What is meant by the term "scientific law"? Ans. a summary of a large amount of scientific information 4. What word means the application of scientific principles to meeting human needs? Ans. technology 5. What is a hypothesis? Ans. an attempt to explain an observation in a common-sense way 6. When does a hypothesis attain the status of a theory? Ans. when sufficient experiments have been performed to confirm that the hypothesis is correct 7. What does the prefix "centi-" mean? Ans. 10-2 or 0.01 8. 1 microgram is equivalent to how many grams? Ans. 1 x10-6 g 9. How many centimeters correspond to 15.68 kilometers? Ans. 1.568 x 106 cm 10. How many pounds are represented by 764.6 mg? [Use: 1 pound = 454 g] Ans. 1.684 x 10-3 pounds 11. A typical aspirin tablet contains 5.00 grains of pure aspirin analgesic compound. The rest of the tablet is starch. How many aspirin tablets can be made from 100.0 g of pure aspirin? [Use: 1.00 g = 15.4 grains] Ans. 308 12. A patient weighs 146 pounds and is to receive a drug at a dosage of 45.0 mg per kg of body weight. The drug is supplied as a solution that contains 25.0 mg of drug per mL of solution. How many mL of the drug should the patient receive? [Use: 1 pound = 454 g] Ans. 119 mL 13. If a person smokes 10.0 packs of cigarettes a week and each cigarette contains 5.00 mg of tar, how many weeks will she have to smoke to inhale 0.250 pounds of tar? [Use: 20 cigarettes = 1 pack and 1 pound = 454 g] Ans. 114 weeks 14. The cost of a drug is 125 francs per gram. What is the cost in dollars per ounce? [Use: $1 = 6.25 francs and 1 ounce = 28.4 g] Ans. $568/ounce 15. If one atom of carbon-14 weighs 14.0 atomic mass units and one atomic mass unit is equal to 1.66 x10-24 grams, what is the mass of 250.0 atoms of carbon-14 in grams? Ans. 5.81 x10-21 g 16. A patient needs 0.300 g of a solid drug preparation per day. How many 10.0 mg tablets must be given to the patient per day? Ans. 30.0 tablets 17. When the value of an experimental quantity or measurement (e.g. the mass of a tablet) is reported, it should consist of two parts. What are they? Ans. number and units 18. What do we call a basic quantity of mass, volume, time, etc.? Ans. unit 19. What is defined as the difference between the true value and our measurement of that value? Ans. error 20. In one sentence, define the word "accuracy" Ans. the agreement between the true value and the measured value of a quantity 21. What do we call the degree of agreement between replicate measurements of the same quantity? Ans. precision 22. What do we call the degree of doubt in a single measurement? Ans. uncertainty 23. Express the number 0.000327730 to three significant figures using scientific notation. Ans. 3.28 x10-4 24. How many significant figures are in the number 5.0630 x 104? Ans. 5 25. Write the number 3,000 using scientific notation and the proper number of significant digits. Ans. 3 x 103 26. Write the number 0.00946 using scientific notation and the proper number of significant digits. Ans. 9.46 x10-3 27. Provide the answer to the following problem using scientific notation and the proper number of significant digits: (6.00 x10-2)(3.00 x10-4) = ? Ans. 1.80 x 10-5 28. Provide the answer to the following problem using scientific notation and the proper number of significant digits: (4.3169 x104)/(2.02 x103) = ? Ans. 2.14 x101 29. Provide the answer to the following problem using the proper number of significant digits: 0.004 + 26.59 + 3.2 = ? Ans. 29.8 30. What is meant by the word "mass"? Ans. the quantity of matter in a sample measured comparing to a standard wieght 31. What instrument is used to measure the mass of an object? Ans. a balance 32. What commonly used mass unit is approximately the same as the mass of one hydrogen atom? Ans. atomic mass unit 33. What experimental quantity gives the force resulting from the pull of gravity upon an object? Ans. weight 34. What is the basic unit of volume in the metric system? Ans. liter 35. List four different forms of energy, other than kinetic energy or potential energy Ans. any four of heat, light, electrical, mechanical, chemical 36. What Fahrenheit temperature corresponds to -168.7◦C? Ans. -271.7◦F 37. What form of energy is usually absorbed or liberated during chemical reactions? Ans. heat 38. In the swinging of a pendulum, what two forms of energy are constantly being interconverted? Ans. kinetic energy and potential energy 39. What kind of energy is stored or the result of position or composition? Ans. potential energy 40. What do we call the experimental quantity which gives the number of particles of a substance (or their mass) contained per unit volume? Ans. concentration 41. The density of an object is the ratio of its _______ to its _______. Ans. mass; volume 42. If we assume the density of blood is 1.060 g/mL, what is the mass of 6.56 pints of blood in grams? [Use: 1 L = 2.113 pints] Ans. 3.29 x 103 g 43. A solid that had a mass of 189.6 g was found to have the following measurements: length = 9.80 cm; width = 46.6 mm; height = 0.111 m. What is its density in g/mL? Ans. 0.374 g/mL 44. When a large object fell into a "full" swimming pool, it displaced 32.0 gallons of water. The density of the object is 1.65 g/mL. What is the object's weight in pounds? Remember that any fully immersed object displaces its own volume. [Use: 454 g = 1 pound; 1 L = 1.06 quarts] Ans. 439 pounds 45. What is the branch of chemistry that is being applied in measuring the concentration of an air pollutant? A. analytical chemistry B. biochemistry C. inorganic chemistry D. organic chemistry E. physical chemistry Ans. A 46. What do we call a statement of observed behavior for which no exceptions have been found? A. hypothesis B. theory C. law D. model E. result Ans. C 47. The speed of light is 186,000 miles per second. What is its speed in centimeters per second? [Use: 5280 feet = 1 mile; 12 inches = 1 foot; 2.54 cm = 1 inch] A. 3.01 x1011 cm/s B. 3.01 x1010 cm/s C. 6.06 x1012 cm/s D. 3 x1011 cm/s E. 2.99 x1010 cm/s Ans. E 48. 1 kilometer equals how many millimeters? A. 10-6 B. 10-3 C. 103 D. 104 E. 106 Ans. E 49. Round off 0.052018 to three significant figures. A. 0.05 B. 0.052 C. 0.0520 D. 0.05201 E. 0.05202 Ans. C 50. Select the answer which best expresses the result of the following calculation: 1.86 + 246.4 – 79.9208 = ? A. 168 B. 168.3 C. 168.34 D. 168.339 E. 168.3392 Ans. B 51. The appropriate number of significant figures to be used in expressing the result of 51.6 / 3.1416 is A. 1 B. 2 C. 3 D. 4 E. 5 Ans. C 52. What Celsius temperature corresponds to -4.6◦F? A. –20◦C B. –20.3◦C C. –23.0◦C D. –10.9◦C E. –68.4◦C Ans. B 53. What Fahrenheit temperature corresponds to -40.0◦C? A. –8◦F B. 16.8◦F C. –36.9◦F D. –40.0◦F E. –1.94◦F Ans. D 54. What Kelvin temperature corresponds to 98.6◦F? A. 310K B. 310.0K C. 31.00K D. 132.0K E. 199K Ans. B 55. Which temperature scale does not use a degree sign? A. Celsius B. Kelvin C. Centigrade D. Fahrenheit E. Absolute zero Ans. B 56. If the density of carbon tetrachloride is 1.59 g/mL, what is the volume, in L, of 4.21 kg of carbon tetrachloride? A. 0.149 L B. 0.378 L C. 2.65 L D. 6.69 L E. 6690 L Ans. C 57. What is the specific gravity of an object that weighs 13.35 g and has a volume of 25.00 mL? The density of water under the same conditions is 0.980 g/mL. A. 1.335 B. 0.545 g/mL C. 1.335 mL D. 0.545 E. 0.980 Ans. D 58. T F Organic chemistry is the study of those chemical processes that are found in living systems. Ans. F 59. T F Hypotheses are not acceptable in the scientific method. Ans. F 60. T F In the scientific method, a hypothesis carries more weight than a theory. Ans. F 61. T F Each piece of data is the individual result of a single measurement. Ans. T 62. T F The presence of some error is a natural consequence of any measurement. Ans. T 63. T F Errors which are scattered equally above and below the correct value are called systematic errors. Ans. F 64. T F It is possible for a set of measurements to be precise yet inaccurate. Ans. T 65. T F The number 0.068 has 3 significant figures. Ans. F 66. T F The terms mass and weight are identical. Ans. F 67. T F Mass is the force resulting from the pull of gravity upon an object. Ans. F 68. T F Equal masses of glass and steel at the same temperature will generally have different heat energies. Ans. T 69. T F Energy may be defined as the heat content of an object. Ans. F 70. T F One Calorie is the amount of energy needed to raise the temperature of one gram of water one degree Celsius. Ans. T 71. T F Density and specific gravity can be expressed in the same units. Ans. F Chapter 2, The Composition and Structure of the Atom 1. In which state does matter have a definite shape and volume? Ans. solid 2. In which state of matter are forces between particles least dominant? Ans. gas 3. What kind of change does not alter the composition or identity of the substance undergoing the change? Ans. physical 4. Conversion of ice to liquid water or liquid water to steam is an example of what kind of change? Ans. physical 5. In one sentence, explain clearly what is meant by a "chemical change". Ans. A chemical change results in different substance(s) from those initially present. 6. What type of change is represented by the decay of a fallen tree? Ans. chemical 7. Give an example of a chemical property of iron metal. Ans. its tendency to form rust when exposed to the atmosphere 8. What do we call the starting and final materials in a chemical reaction? Ans. reactants and products 9. What type of property of matter is independent of the quantity of the substance? Ans. intensive 10. What word is used to describe properties of a substance that depend on the quantity of substance? Give two examples of such properties. Ans. extensive; mass, volume and others 11. What is meant in chemistry by the term "pure substance"? Ans. The substance consists of only one component; it has a fixed composition throughout. 12. What are two kinds of pure substance? Ans. elements and compounds 13. Explain what is meant in chemistry by the word "compound". Ans. a pure substance consisting of two or more elements chemically combined in a definite ratio 14. What are the two classes of mixtures? Ans. homogeneous and heterogeneous 15. Give an example of a heterogeneous mixture. Ans. concrete, salt and pepper, smoky air and others 16. What kind of mixture is a solution of alcohol and water? Ans. homogeneous 17. Which of the following terms are appropriate in describing an apple? pure substance; element; compound; mixture; homogeneous; heterogeneous Ans. mixture; heterogeneous 18. List the three primary particles found in an atom. Ans. proton, electron, and neutron 19. What quantity does the mass number minus the atomic number represent? Ans. number of neutrons 20. In a neutral atom, what number of particles is equal to the number of protons? Ans. number of electrons 21. Given that He helium has an isotope predict the number of electrons 42, in a helium atom. Ans. 2 22. How many neutrons are present in an atom of the isotope 3 7 Li? Ans. 4 23. What is the value of the mass number in the isotope 53 131I? Ans. 131 24. What is the term for atoms of the same element having different masses due to a different number of neutrons? Ans. isotopes 25. What is the process by which certain isotopes emit particles and release large amounts of energy? Ans. radioactive decay 26. What do we call electrically charged particles that result from the gain of one or more electrons by a parent atom? Ans. anions 27. Dalton proposed that all atoms of an element have identical properties. Briefly, explain why this proposal is invalid. Ans. Isotopes of an element have different properties, particularly their mass. 28. J. J. Thomson in 1897 announced that cathode rays consisted of a stream of _______. Ans. electrons 29. In one sentence, state Rutherford's important contribution to our knowledge of atomic structure. Ans. He concluded that atoms have a small, heavy, positively charged nucleus surrounded largely by empty space, occupied by electrons. General, Organic, and Biochemistry, 3/e Page 9 30. A more general term for "light" is _______ _______ (two words). Ans. electromagnetic radiation 31. What word means the study of wavelengths of light emitted and absorbed by atoms? Ans. spectroscopy 32. In Bohr's model of the hydrogen atom, what is an "orbit"? Ans. An orbit is a circular path followed by the electron. 33. In Bohr's theory of the atom, what is the number n (n = 1, 2, 3, 4) called? Ans. quantum number 34. In one sentence, explain the meaning/consequences of Heisenberg's Uncertainty Principle. Ans. It is impossible to know the exact position and momentum of a particle, such as an electron in an atom. 35. In modern atomic theory, Bohr's orbits are replaced by atomic orbitals. What is an atomic orbital? Ans. It is a region of space where an electron is likely to be found; or, an electron "cloud". 36. Which state of matter has no definite shape or volume? A. liquid B. solid C. vapor D. steam E. gas Ans. E 37. Which of the following is NOT a physical property of matter? A. odor B. compressibility C. flash point D. melting point E. color Ans. C 38. What kind of change does NOT alter the composition or identity of the substance undergoing the change? A. molecular B. endothermic C. exothermic D. physical E. chemical Ans. D 39. What kind of change always results in the formation of new materials? A. molecular B. exothermic C. endothermic D. physical E. chemical Ans. E 40. Which of the following is a chemical property? A. flammability B. color C. hardness D. odor E. taste Ans. A 41. Which one of the following is an example of an extensive property? A. density B. specific gravity C. mass D. hardness E. boiling temperature Ans. C 42. Which one of the following is an example of a pure substance? A. ethyl alcohol B. sugar water C. salt and pepper D. milk E. sand Ans. A 43. Air is a/an A. element B. compound C. mixture D. molecule E. pure substance Ans. C 44. What type of mixture is represented by a collection of salt and pepper? A. atoms B. molecules C. solution D. heterogeneous E. homogeneous Ans. D 45. What kind(s) of particles can be found in the nucleus of an atom? A. protons B. neutrons C. electrons D. protons and electrons E. protons and neutrons Ans. E 46. The total mass of the protons in any neutral atom is about _______ times the total mass of electrons in the atom. A. 0.0005 B. 0.3 C. 1 D. 2 E. 2000 Ans. E 47. What is the quantity represented by the mass number (Z) minus the atomic number? A. number of atoms B. number of neutrons C. number of electrons D. number of protons E. number of particles in the nucleus Ans. B 48. Which isotope of hydrogen has two neutrons? A. hydrogen-1 B. hydrogen-2 C. hydrogen-3 D. deuterium E. H2 Ans. C 49. Which of the following accounts for the fact that chlorine has an atomic mass of 35.45 amu rather than a whole number? A. isotopes B. electrons C. protons D. radioactivity E. isomers Ans. A 50. Who discovered that cathode rays consist of a stream of negative particles, electrons? A. Crookes B. Thomson C. Geiger D. Rutherford E. Bohr 51. Who discovered the existence of the atomic nucleus? A. Crookes B. Thomson C. Geiger D. Rutherford E. Bohr Ans. D 52. In Rutherford &Geiger's experiment which led to the discovery of the atomic nucleus, what type of particle or ray was fired at the gold foil target? A. alpha B. beta C. gamma D. neutrons E. cathode rays Ans. A 53. Which of the following statements relating to Bohr's model of the hydrogen atom, is incorrect? A. The lowest energy orbit has quantum number n = 1 B. The highest energy orbits are furthest from the nucleus C. In a transition from the n = 3 to the n = 1 level, light is emitted D. Energy differences between energy levels can be calculated from the wavelengths of the light absorbed or emitted E. The greater the energy difference between two levels, the longer the wavelength of the light absorbed or emitted Ans. E 54. Who proposed that electrons could behave like waves, as well as like particles? A. Thomson B. Rutherford C. Bohr D. de Broglie E. Heisenberg Ans. D 55. T F The term "solution" refers only to homogeneous mixtures of liquids. Ans. F 56. T F In the cal Calcium atom represented by the symbol , 60Ca, calcium-60, there are 40 protons, 20 neutrons and 20 electrons. Ans. T 57. T F According to modern atomic theory, all atoms of a particular element have identical physical properties. Ans. F 58. T F According to modern atomic theory, an atom cannot be created, divided, destroyed or converted to any other type of atom. Ans. F 59. T F The atomic number of an ion tells us the number of protons that are present. Ans. T 60. T F If an atom gains one electron, it becomes a cation. Ans. F 61. T F The first experimentally based theory of atomic structure was proposed by John Dalton. Ans. T 62. T F J. J. Thomson was the first to state that an atom is mostly empty space. Ans. F 63. T F Short wavelengths of electromagnetic radiation have more energy than long wavelengths. Ans. T 64. T F Rutherford was the first to use the term "orbit" to explain the fixed energy levels of electrons. Ans. F 65. T F Niels Bohr developed a theory which accounted for the lines in the visible region of the hydrogen spectrum. Ans. T