13-14 IPS NAME Chapter 4 Review DATE PERIOD 1. Be sure the definitions the following terms are in your glossary and that you understand each. Solute Unsaturated Solvent Concentration Solution Solubility Precipitate Soluble Saturated Insoluble 2. When a substance such as an orange solid dissolves in water, what happens to it? Where can the solute be found? 3. As more orange solid is added, and the solution is stirred, what happens? For all problems-show your work, include units in work and answer, and follow sig dig rules. 4. A mass of 16 g of salt is mixed with 62 mL of water. What is the concentration of the solution? 5. How much water is needed to make a sugar solution with a concentration of 217 g/100 cm3, if 58 g of sugar is used? 6. A solution contains 112 g of sodium sulfate in 636 mL of water. If you want to make a solution with the same concentration, but must use 192 mL of water, how much sodium sulfate is needed? 7. Use the following data to calculate the solubility of unknown X. Show your work. Mass of evap. dish and watch glass 32.70g Mass of evap. dish, watch glass, and solution 46.53g Solubility = Mass of evap. dish, watch glass, and solid 39.17g 1 Mass of evap. dish and watch glass (g) 2 Mass of evap. dish, watch glass and solution (g) 3 (2-1) Mass of solution (g) 4 Mass of evap. dish, watch glass and solid (g) 5 (4-1) Mass of solid (g) 1 6 (3-5) Mass of solvent (g) 7 (7=6) Volume of solvent (cm3) 8 (5 ÷ 7) Concentration (g/cm3) 9 (8 x 100) Solubility (g/100cm3) 13-14 Refer to your solubility graph handout or page 74 in your text for questions 8-18. Show work. 8. What is the solubility of potassium nitrate ate 45 °C? 9. Which substance is most soluble at 65 °C? 10. Which substance is least soluble at 65 °C? 11. How much sodium nitrate would you need to have a perfectly saturated solution at 50 °C? 12. What is the lowest temperature 120 g of sodium nitrate will all dissolve? 13. A mass of 30 g of potassium nitrate is dissolved in 100 mL of water at 10ºC. The solution is heated to 80ºC. How much more solid needs to be added to keep the solution saturated? 14. A mass of 160 g of sodium nitrate is dissolved in 100 mL of water at 100ºC. The solution is cooled. At what temperature should a precipitate form? 15. How much sodium nitrate will precipitate out of solution if you cool a saturated solution from 80 °C to 20 °C? Are the following solutions saturated or unsaturated? 16. 50 g of potassium nitrate at 80 °C? 17. 100 g of sodium nitrate at 30 °C? ***18. If you dissolve 30 g of potassium nitrate in 25 mL of water and then heat it to 80 °C, how much solid should you add to keep the solution saturated? 19. Using the information in the table below: Are wood alcohol and grain alcohol the same substance? Explain. Alcohol Type Wood Alcohol Grain Alcohol Density (g/100 cm3) M.P. (ºC) .79 -98 .79 -117 20. What are the chemical names for wood alcohol? B.P. (ºC) 64.7 78.5 grain alcohol? 2 13-14 The following data was gathered at 30ºC to find the solubility of the two substances. The table below shows the maximum amount of each solute (washing soda and baking soda) that would dissolve in the volume of solvent given. Answer questions 21-23 using this information. Substance Solute (g) Solvent (mL) 220 1000 Washing Soda 24 350 Baking Soda 21. Which substance has a higher solubility (g/100mL)? Show work. 22. What is meant by ‘higher solubility”? 23. What is the largest mass of each substance that will dissolve in 60 mL of water? (show work) Washing sodaBaking soda- 24. If 6.7 g of a substance will dissolve in 57.3 mL of water at 40ºC, what is the solubility at that temperature?(show work) 25. The following table shows the solubility of carbon dioxide (CO2) at various temperatures. Graph the data. Temperature (ºC) Solubility (g/100 mL) 0 10 20 30 40 50 60 .34 .24 .18 .14 .12 .10 .08 3 13-14 Using the graph in problem #25 on the previous page, answer the following questions: a. How much CO2 will dissolve in 100 cm3 of water at 25ºC? b. Approximately how much CO2 will dissolve in 100 cm3 of water at 70ºC? c. How much CO2 will dissolve in 50 cm3 of water at 30ºC? (show work) 26. If you had to collect a gas by water displacement, would it be better to collect the gas at cooler or warmer temperatures? Explain. 27. Sketch a curve showing how increasing temperature would affect the solubility of solids? gases? 28. When a test tube of ammonia gas is inserted into a beaker of water already saturated with ammonia, would water go up into the test tube? Why or why not? 29. Can water displacement be used to collect a highly soluble gas like ammonia? Why or why not? 4