Atomic Theory Development Authors of unit: Rebecca Anderson, Elaine Baker, Jacob Davis, Jesse Durdel, Debra Monigold, Garilyn Wells Partner Projects: UIUC Chemistry Library, ICLCS Intended Audience: Grade Level: First year high school chemistry students Subject Areas: Atomic theory development Unit Keywords: Atomic theory, Democritus, John Dalton, J.J. Thomson, cathode ray tube, plum pudding model, gold foil experiment, GeigerMarsden experiment, Rutherford model, Robert Millikan, oil drop experiment, electromagnetic radiation, electromagnetic spectrum, Niels Bohr, line emission spectrum, Bohr model, quantum mechanical, waveparticle duality, photon, photoelectric effect, Werner Heisenberg, uncertainty principle, orbital, electron cloud, electron, proton, neutron, quark Summary of the Module Rationale 1. Student will outline the history of the development of the atomic theory and analyze the experiments and observations made by key scientists that lead to the present view of the atom. 2. Students will generate their own explanations about the development of the atomic theory, and the teacher will guide students to confront their existing misconceptions about the atom. 3. Teachers will have resources available such as applets, computational tools and web sites that will aid in illustrating the main historical concepts, scientists and experiments in the development of the atomic theory. ©2011 University of Illinois Board of Trustees • http://islcs.ncsa.illinois.edu/copyright 4. Teachers will provide an interactive classroom module incorporating applets, computational tools and interactive websites which will allow students to explore atomic structure and infer atomic properties based on manipulation of such virtual tools. 5. This is a resource for any high school chemistry teacher or science teacher to be able to use as a unit or to use sections as appropriate to supplement the curriculum in their classroom. Use(s) of the Unit Students will be able to: 1. Compare and contrast different atomic models. 2. Synthesize a timeline of the various atomic models, including historical concepts and the key people associated with the development of the atomic theory. 3. Analyze the scientists’ experiments and infer the various properties of the atom. 4. Investigate applications of current atomic theory to explain natural phenomena and the use of scientific tools. 5. Utilize various applets and computational tools as related to the development of the current atomic theory. Illinois Learning Standards Science Goals 11, 12 and 13 This module addresses a variety of standards. Complete notation of standards is included in the final footnotes. Software needed and other hardware/software needs Required hardware: LCD projector for lecture, computer lab (with internet connection) outfitted with enough computers for each student to work independently Required software: Microsoft Word, Microsoft Excel, Microsoft PowerPoint, Windows Media Player, Java, Adobe Flash Media Player ©2011 University of Illinois Board of Trustees • http://islcs.ncsa.illinois.edu/copyright Content of the Unit This module is composed of three main parts: Part 1: Lecture/Applet Demonstrations In this section, you will guide the student through an Atomic Theory PowerPoint presentation, which shows the student the progression of the atomic theory. It also includes links to various applets and visualizations to enhance student understanding of the concepts. Part 2: Student Activities/Lab Activity First, the student will research the history of the atomic theory and prepare a timeline, highlighting the various scientists who contributed to our current understanding of the atom and its behavior. Then, the student will be self-guided through several applets which will illustrate the various key scientists’ contributions. Each applet has a companion worksheet. Part 3: Student Assessment and Feedback Each student will complete a quiz which will serve to assess what he has learned throughout the module. In addition, each student will be asked to complete an online survey which will provide valuable feedback to the instructor regarding the overall perception of the module and the instruction effectiveness. Background Information: Atomic theories have been discussed for centuries. Each theorist has had a different idea, some based on facts as they were known at the time and some based on erroneous beliefs about how matter is constructed and used. ©2011 University of Illinois Board of Trustees • http://islcs.ncsa.illinois.edu/copyright As early as 400 B.C., Greek philosophers such as Democritus were discussing questions about what matter was, how it interacted and what it became after a change. He was the first person who speculated that an atom was the smallest particle. The Greek definition of the word atom was “indivisible”. A generation later, Aristotle presented a different view of matter, describing it as a continuous substance called originally “hyle”, and later “phlogiston”. As with all things, popularity matters and since Aristotle was a respected philosopher, his theory became the accepted definition. However, neither man had any supporting experimental evidence. Until the eighteen century, Aristotle’s theory was accepted. Two thousand years of commonly held belief was difficult to overcome. It took cold hard facts, painstaking experimentation, great leaps forward in technology and the willingness to look beyond the obvious to develop a new theory based on facts. Prior to the late 1700’s, most of our beliefs about matter were based on simple observations. Matter was composed of earth, fire, water and air. Without the tools to conduct painstaking experiments, we had an incomplete knowledge of what all things were made of. In the late 1700’s, our ability to experiment and our knowledge of what the resulting data determined took a great leap forward. The hunger to explain the interactions of matter drove the giants of science to explore ever deeper into the inner workings of matter and the atom. Even today, we are unsure of exactly what the atom is composed of. This module attempts to take you from the earliest theories of Democritus to the possibilities of the String Theory. Descriptions: Atomic Structure PowerPoint In this Atomic Structure PowerPoint1,2 presentation, you will find a variety of slides, which include visuals and simulations, that cover the history atomic theory, major scientists contributing to the understanding of the atom and subatomic particles,3,4 key experiments5 performed leading to breakthroughs4,6 in atomic theory, and analysis of the conclusions7 made by the major atomic theorists. This PowerPoint seeks to give the instructor a sequential and historical perspective of the development of atomic theory. The PowerPoint begins by investigating Democritus, an ©2011 University of Illinois Board of Trustees • http://islcs.ncsa.illinois.edu/copyright early Greek philosopher, and transitions to John Dalton, who laid the foundation for the modern understanding of the atom. The PowerPoint then moves into the J.J. Thomson, the cathode ray tube, and the discovery of the electron. After the discovery of the electron, Ernest Rutherford, the gold foil experiment, and the discovery of the nucleus are addressed. Robert Millikan and the oil drop experiment are not addressed in the PowerPoint, but could easily be included if desired. Niels Bohr, the line emission spectrum of hydrogen, energy levels, and common misconceptions are next explored. The PowerPoint concludes by describing the quantum mechanical model of the atom with a highlight of Werner Heisenberg and his uncertainty principle. Schrödinger and Max Planck are not covered in the PowerPoint. Other topics that are included in the PowerPoint are characterizing atoms by counting protons, neutrons, and electrons, types of electrons, and describing the location of electrons with electron configurations and quantum numbers. A computer with Microsoft PowerPoint and Internet access along with a LCD projector are needed to deliver this presentation. This presentation can be given in totality before the students complete the enrichment activities or broken into segments allowing the activities highlighting each experiment to be completed before covering the next scientist, contribution, and conclusions. The length of the PowerPoint can be adjusted to fit the time restraints of each individual teacher. Cathode Ray Tube Investigation In this cathode ray tube applet,8 students will investigate J.J. Thomson’s cathode ray tube experiment and his conclusion that all of matter contains electrons. Teachers will need a computer lab with Internet access through Internet Explorer to complete this activity. If a computer lab is not available, this activity could be done as a virtual classroom demonstration.9,10 Students will need to adjust11 the separation, plate length, and screen size to create a cathode ray tube more like the one that J.J. Thomson used.12,13 Students will then change the deflection to both positive and negative voltages to create an electrical field and use a magnet with north and south poles to create a magnetic field. Students can manipulate the speed of the beam and the length of the plates to determine what affects the path of a beam of charged particles.4 This activity could be extended by asking students ©2011 University of Illinois Board of Trustees • http://islcs.ncsa.illinois.edu/copyright to explore3 how analog televisions function as opposed to today’s flat screens at the following link to howstuffworks. Rutherford Gold Foil Simulation In the Rutherford gold foil simulation,14 students will probe how atomic theories transitioned from the atom being viewed as a solid sphere to mostly empty space.15 Ernest Rutherford’s gold foil experiment was critical to this modification of atomic theory. Teachers will need a computer lab with Internet access through Internet Explorer and a Flash 5 movie player. Students will fire12 alpha particles at a gold atom and observe the path of the alpha particle. A detection screen will record 16 the path of the alpha particle. After shooting multiple alpha particles at the gold atom, students can derive9,17 the shape and charge of the nucleus from the path recorded by the alpha particles. Students will also observe how many particles travel unaffected when moved away from the nucleus. Thus, from this simulation students should reach the same conclusions10 that Rutherford did – the atom contains a dense, positively charged center while most of the volume of the atom is empty space.3 Students will also be able to apply the scientific method to identify 18 variables that can be changed. Millikan Oil Droplet Simulation In the Millikan oil droplet applet, students will look into how the charge of an electron was determined.3 Teachers will need a computer lab with Internet access through Internet Explorer. Charged oil droplets will cascade from the top of the screen.10 Students will manipulate12 the voltage9 applied to the apparatus and analyze11 how the charge affects the movement of the particles. Bohr Model Simulation Using the Bohr Model Simulation, students can visualize3, 4 Bohr’s theories and the way wavelengths of light are absorbed and emitted when electrons transition from ground state orbits to excited state orbits and back to lower orbits in the hydrogen atom. In order to use this simulation, ©2011 University of Illinois Board of Trustees • http://islcs.ncsa.illinois.edu/copyright students need access to a computer with Internet Explorer. Students can manipulate11, 12, 13 the electrons of the atom and watch as different wavelengths of light are absorbed and emitted from the atom as the electrons jump between the orbits. We have included a worksheet with this simulation that has the students read a little about atomic line spectra and Bohr’s theory of distinct orbits before doing any changing of the atom. This part of the assignment can be skipped if the teacher has already covered this information. The worksheet then has students change the size of the orbits of the displayed model of the atom and visualize what color of light would be emitted because of the energy differences. The worksheet concludes by having the students adjust the orbits to try and get specific wavelengths of color. To complete the entire worksheet would take approximately 25-30 minutes. From this point students would be able to perform a flames test lab and a gas discharge tube activity and explain the atomic spectra they are observing. It must be cautioned that this is an activity to investigate a different model of the atom, not necessarily the correct model of the atom. The goal is to make sure that students understand that while Bohr was able to explain some phenomena he observed, he could not extend his explanation to all atoms and was not able to predict a correct model6, 22. This activity was included to emphasize that his ideas helped to shape our current model of the atom. Models of Hydrogen Simulation The Models of Hydrogen Simulation gives students an opportunity to review all the models of the atom that were discussed in class. On this site there are many things which the student can manipulate11,12 which allows the student to view the different variables that make the prediction of a model of an atom difficult. It also allows the student to see the limitations6 of earlier models and helps them to see the evolution of the atomic theory. In order to use this simulation the student must have access to a computer with Internet Explorer and JRE or later for Windows/Linux systems or JRE for Macintosh systems. When the student enters the site, the first thing that can be changed is the Experiment/Prediction button. Under the experiment part, the student observes what scientists have seen in the past, an unknown shape that when light is passed through, produces an atomic spectrum. Students can choose to view the spectrum that is produced when light passes through ©2011 University of Illinois Board of Trustees • http://islcs.ncsa.illinois.edu/copyright the unknown atom. If the button is changed to Prediction, then all the predicted models of the atom appear to the left of the screen. The student can choose one and view what happens when light passes through that certain model. The student can choose between the Billiard Ball Model, the Plum Pudding Model, the Classical Solar System Model, the Bohr Model, the DeBroglie Model, and the Schrödinger Model. The student can choose to send white or monochromatic light through the atom. There is an option to show the electron energy level diagram for the models that came later than the Plum Pudding. Students also have the option to make the light travel faster or slower. On the Schrödinger Model, quantum numbers are given in the lower right hand corner of the atom showing to which orbitals the electrons are being excited. This is a good review site and would also help solidify the concept of absorption/emission spectra they view from the gas discharge tubes and the flames test labs. The student should be allowed at least 30 minutes to really go through this site and see the different models and manipulate12, 17 all the different variables. Target Lab In the target lab, students will study12,19 the concept of electron clouds, probability, and orbitals. Teachers will need a copies of the lab procedure for each student and a felt tip marker and target for each lab group. A computer lab is needed to analyze24 the data with a computational tool such as Microsoft Excel or another spreadsheet and graphing program.10 This lab aims to confront the misconception perpetuated by the Bohr model that electrons are found on a fixed orbit circling the nucleus like plants circling the sun in the solar system. Students should gain an appreciation for the likelihood of finding electrons in a certain region. Students will need 45-50 minutes to complete the lab activity. Analyzing the data with Microsoft Excel and answering the laboratory questions would require an additional 45-50 minutes. Spectrum Virtual Lab When completing this virtual lab 3, 12, 20, students have the opportunity to view emissions spectra using a spectrometer. Previously, this lab may have been completed by students using spectrometers, tubes filled with various gases and diffraction grating. This process is frequently difficult for first year chemistry students. This lab allows them to see a clearer picture of the emission data for various gases, collect data about the ©2011 University of Illinois Board of Trustees • http://islcs.ncsa.illinois.edu/copyright emission lines, and calculate the frequency of the lines viewed. Using this information, students are asked to calculate the energy of the emitted photons. After completing the unit, a quiz is available asking the students to use their data on the emission spectra of the various elements to identify a spectrum of an unknown element. To complete the lab, students will need a computer with the following: Explorer and Sun Java 1.4.2_16 or later for Windows/Linux systems or Apple Java 1.4.2_16 for Macintosh systems, copy of the lab and a pen. The quiz requires the use of Microsoft Power Point and a projector. Atomic Theorist / Model Timeline This project combines history of the major contributors of atomic theory with the chronology of the different types of atomic models in a timeline presentation.21 Students will research11 and gather data on the scientists and great thinkers who have shaped our perception of the atom in the form of their role in history and why 22 what they did was important to the development of the modern view of the atom. Students will search the internet and books for photos of the scientists and atomic models to use on their timelines. Students will also describe, compare and contrast3 the differences between the various models of the atom. As an extension of this project, students could also relate great scientists with breakthroughs that affect our everyday lives.23 Assessment Strategies: Any of the labs can be used as an assessment tool. Teachers can also collect oral feedback from students through questioning as students are completing the virtual applets, simulations, and laboratory experiments. Quiz – Five short answer questions asking students to compare and contrast different models of the atom along with scientists, their experiments and conclusions. This quiz will take 25-30 minutes to complete. Test – A summative evaluation can be given at the conclusion of the unit. This test includes multiple choice, short answer, and matching. An entire period is needed to administer this evaluation. ©2011 University of Illinois Board of Trustees • http://islcs.ncsa.illinois.edu/copyright Classroom Implementation The Atomic Theory PowerPoint was used in a lecture style in segments to outline the key scientists, their experiments, observations, conclusions, and contributions to our understanding of the atom. The PowerPoint was broken into different segments to allow the students to explore virtually in the computer lab or hands-on in the chemistry laboratory the concepts taught. For example, after the lecture on Rutherford conclusion that the atom contains a dense positive region surrounded by mostly empty space, students went to the computer lab to complete the Rutherford’s Gold Foil Simulation. Each class watched the applets or simulations that were hyperlinked in the PowerPoint including the “Constituents” video. Students remarked that the “Constituents” video was “cool” and “awesome.” Students also spent back-to-back days in the computer lab exploring the Cathode Ray Tube Investigation and the Rutherford Gold Foil Simulation. In one class, students demonstrated a better picture of the particles on a microscopic or atomic level than in previous years. Students were able to explain observations in terms of interactions between charged particles. This observation was based on the students’ performance on the quiz that was administered. Most students also completed the Target Lab. This lab helped students understand that the exact location of an electron cannot be known; rather the location can be described as a probability. However, not all classes used Microsoft Excel to analyze the data. Some items listed in the descriptions section, such as the Millikan Oil Droplet Simulation, Spectrum Virtual Lab, and Timeline were not implemented because of time constraints or lack of computer lab access. Overall students responded well to the variety in instruction, the use of technology, and the hands-on activities such as the Target Lab. The unit was concluded with a unit test. Recommendations for Future Work Future modification plans for this module fall under three categories; creating an alternate feedback system, including alternate activities for ©2011 University of Illinois Board of Trustees • http://islcs.ncsa.illinois.edu/copyright classrooms with limited computer access and expanding the module to include more information about current atomic theories. When our group began work on this module, we realized immediately that Quantum Mechanics/Atomic Theory was a huge topic. As a result of our discussions, we decided to focus the first on the history of Atomic Theories and the development of the Quantum Mechanical Model. As a result, we have not moved this module past briefest references to smaller particles of matter such as quarks or bosons, nor have we included other newer theories such as String Theory or M-theory. We hope to extend this module by researching information on some of these newer, less proven theories. One of our other goals with this project is to help students understand that all theories change, some theories are disproved and some are completely wrong. Therefore, knowledge, especially in science is never absolute. As the second half of this project, we would like to include a PowerPoint presentation on some of these theories, exercises to help students understand the theories and hands-on activities to illustrate some of the strengths and weakness of both newer and older theories. One of the difficulties we have struggled with as a group and we feel confident other teachers will also struggle with, is the limited access to computer resources. We plan to include activities that can be completed with access to only a few computers. Where ever possible, we have included instructions to allow the teacher to use this resource in a demonstration situation instead of student manipulated. One possible solution to this problem would be to create other activities the students could complete while waiting to use computers. Students could then be working on several parallel projects with some using computers and some doing other non-technology oriented activities. This would allow each student to move through the projects at their own pace and order, but in the end all students would have access to the same activities. A timeline would need to be created to allow the teacher to give students due dates and completion points for collecting projects and grading their work. The final difficulty our group had encountered is feedback data collection. We created an online survey for students to complete about the module. When this survey was created, we set the collection format incorrectly and new data overwrote old data, without giving us group feedback. In addition to this problem, several of the members of this group found it impossible to schedule a time for an entire class to use a lab to collect the ©2011 University of Illinois Board of Trustees • http://islcs.ncsa.illinois.edu/copyright data at the same time. Some possible solutions to this problem are creating an alternate feedback form which could be printed off, filled out by students and then collected or creating an online survey that gives us better access to the data collection process, allowing us to assign students numbers to determine who has and has not filled out the survey. We would also be interested in a separate feedback system for teachers who use this module. We would like to obtain information from them on the success of this module in their classroom and suggestions for improvement. It is important that this module be completely user friendly to all levels of computer users. The only way to determine this is to have a wider audience of instructors use this module and offer us feedback. We may be able to link a feedback system to this module or to make a form instructors can fill out and then email or mail back to us. 1 Allan. ScienceGeek.net. http://www.sciencegeek.net/Chemistry/Powerpoint/Unit1/Unit1_files/frame.htm (Accessed: June 2007). 2 Cathode Ray Tube Video. http://www.its-about-time.com/htmls/ac/cathode-ray_large.wmv (Accessed: June 2007). Chasteen, Thomas. Sam Houston State University. http://www.shsu.edu/~chm_tgc/sounds/pushmovies/l2ruther.gif (Accessed: June 2007). Cristy, Jeff. Constituents. http://www.jeffreychristy.com/# (Accessed: June 2007). Davidson, Michael. Molecular Expressions. http://micro.magnet.fsu.edu/electromag/java/rutherford/ (Accessed: June 2007). Goldman, Martin. Bohr’s Atom. University of Colorado, Boulder. http://www.colorado.edu/physics/2000/quantumzone/bohr.html (Accessed: June 2007). Illkirch; Kiel; Strasbourg. Spectra of Gas Discharges: the Applet. http://astro.ustrasbg.fr/~koppen/discharge/discharge.html (Accessed: June 2007). Karlsson, Magnus. Millikan’s Oil Drop Experiment. http://physics.wku.edu/~womble/phys260/millikan.html (Accessed: June 2007). MrCristea. Quantum Mechanics – Indirect Observation. YouTube.com. http://www.youtube.com/watch?v=Y8IQbL_DnGk (Accessed: June 2007). 2110400. The Atom Song. YouTube.com. http://www.youtube.com/watch?v=vUzTQWn-wfE (Accessed: June 2007). 3 12.C.4b- Analyze and explain the atomic and nuclear structure of matter. 4 12.C.5b- Analyze the properties of materials in relation to their physical and/or chemical structures. 5 13.A.5b- Explain criteria that scientists use to evaluate the validity of scientific claims and theories. 13.A.5c- Explain the strengths, weaknesses and uses of research methodologies including observational studies, controlled laboratory experiments, computer modeling and statistical studies. 6 13.A.4c- Describe how scientific knowledge, explanations and technological designs may change with new information over time. 7 13.B.5e- Assess how scientific and technological progress has affected other fields of study, careers and job markets and aspects of everyday life. 8 McIntyre, Tim. Cathode Ray Tube. University of Queensland. http://www.physics.uq.edu.au/people/mcintyre/applets/cathoderaytube/crt.html (Accessed: June 2007). ©2011 University of Illinois Board of Trustees • http://islcs.ncsa.illinois.edu/copyright 9 11.A.4f- Using available technology, report, display and defend to an audience conclusions drawn from investigations. 10 11.B.4c- Develop working visualizations of the proposed solution designs. 11 11.A.4c- Collect, organize and analyze data accurately and precisely. 12 11.A.4b- Conduct controlled experiments or simulations to test hypotheses. 13 11.A.5c- Conduct systematic controlled experiments to test the selected hypotheses. 14 Rutherford Scattering Animation. http://www.waowen.screaming.net/revision/nuclear/rsanim.htm (Accessed: June 2007). 15 11.A.4a- Formulate hypotheses referencing prior research and knowledge. 11.A.5a- Formulate hypotheses referencing prior research and knowledge. 16 11.A.4c- Collect, organize and analyze data accurately and precisely. 17 11.A.4d- Apply statistical methods to the data to reach and support conclusions. 18 11.A.5d- Apply statistical methods to make predictions and to test the accuracy of results. 19 11.A.4a- Formulate hypotheses referencing prior research and knowledge. 20 11.A.5d- Apply statistical methods to make predictions and to test the accuracy of results. 21 11.A.5e- Report, display and defend the results of investigations to audiences that may include professionals and technical experts. 22 13.B.5b- Explain criteria that scientists use to evaluate the validity of scientific claims and theories. 13.B.5b- Analyze and describe the processes an effects of scientific and technological breakthroughs. 23 13.B.5e- Assess how scientific and technological progress has affected other fields of study, careers and job markets and aspects of everyday life. ©2011 University of Illinois Board of Trustees • http://islcs.ncsa.illinois.edu/copyright