Fluid Fertilization in Corn/Coybean Rotation in the United States. Larry Murphy Fluid Fertilizer Foundation Introduction The Fluid Fertilizer Foundation (FFF) sponsors research with fluid fertilizers at state and federal research locations in the United States, Canada, Australia and Mexico as part of the Foundation’s responsibilities in education and research. Fertilization practices for corn/soybean rotations are an important part of the research program simply based on the importance of that rotation in the Cornbelt states. Some recent findings have important implications for overall production levels in that rotation, especially for corn (maize). This paper will outline some of those developments. Fluid Starter Fertilizers for Corn: N-P Interactions Many corn producers in either a corn-soybean rotation or continuous corn systems in the central Cornbelt do not use starter fertilizers for several reasons. One of the most often quoted reasons is that don’t want to take the time to fill their fluid starter tanks when they are planting thus simplifying the logistics of the operation. Another stated reason is that planters are not equipped for starters or are so large that producers do not want to add more weight to the equipment though the addition of openers for fluid placement. Others cite possible corrosion to equipment and other reasons but all lead basically to the same result….lost production potential in high yield capacity corn hybrids. In the past, university research has frequently not shown a yield response to starters. Unfortunately, much of that research was conducted 25-30 years ago on essentially clean till corn. Movement to higher residue systems and the higher yield capabilities of new hybrids has substantially modified the equation in favor of starters. Research sponsored by the FFF in recent years has shown that composition of fluid starters has a major impact on yield of corn, particularly in high residue systems. Further, fluid starter composition manipulation has produced additional options for starter application that allow easy adaptation to large planters without the addition of openers for starter placement. Dr. Barney Gordon, Kansas State University, has demonstrated repeatedly that responses to N-P-K-S-Zn fluid starters can be increased substantially by increasing the amount of nitrogen (N) in the starter. That is effected by the blending of urea-ammonium nitrate solution (UAN) with ammonium polyphosphate (10-34-0) and a potassium (K) source such as potassium thiosulfate. Nitrogen to P2O5 ratios of at least 1:1 and possibly higher have produced much more frequent and higher yield responses even on high soil test P soils. Dr. Gordon’s work with irrigated no-till corn on near neutral pH, silt loam soils in Kansas has shown that ammonium polyphosphate alone or even N-P-K-S-Zn formulations whose N content is dictated by the compositon of the ammonium polyphosphate (10-34-0) do not produce the same effects with a constant amount of P (Table 1). Plant analyses indicate clearly that even with a high P soil test, plant uptake of P is substantially increased with the higher N amounts in the starter formulation. Table 1. Starter composition and placement effects on irrigated no-till corn yield (bu/A). 3 year average. Gordon, Kansas State Univ. Starter In-furrow 5-15-5 172 15-15-5 2x2 Dribble Row Band 194 190 179 177 197 198 180 30-15-5 174 216 212 192 45-15-5 171 215 213 195 60-15-5 163 214 213 201 Average 171 207 205 189 One tonne corn/ha = 16 bu corn/acre The higher amounts of ammonium N with the P are theorized to result in improved P uptake due to (a) effects of ammonium on P movement into the roots and (b) possibly slowed P fixation. pH of this soil, however, was approximately 6.8. Soil test P was high, approximately 40 ppm Bray P-1. Another important aspect of this work is the flexibility in starter placement. Note that the two center columns in Table 1 show values that are essentially equal. The designation 2 x 2 is placement of the fluid band 5 cm to the side of the row and 5 cm below the soil surface. This is considered the optimum starter placement in corn production. However, note that the column labeled “dribble” involves placement of the fluid band on the soil surface 5 cm to the side of the seed row. The implication of this information is that corn planters can be equipped for fluid starter application without the addition of openers to place the starter below the soil surface. This seems to fly in the face of common belief that P does not move appreciably in the soil. Yield results indicate otherwise. Dr. John Kovar of the USDA-ARS Soil Tilth Laboratory in Ames, Iowa researched the fate of P applied in this manner. His data, collected using a resin impregnated membrane to adsorb the fertilizer P, showed that on a silt loam soil by day 43 after application, P had moved about 10 cm into the soil directly below the point of application. That information helps explain why Dr. Gordon was able to effectively place starter P on the soil surface in bands with good effectiveness. Dr. Terry Tindall has reported at this meeting on research by Dr. Gordon and others using a high charge density co-polymer (Avail) in fluid starter which has further enhanced the availability and uptake of P by corn, soybean and a number of other crops. Action of the polymer chemistry delaying P fixation reactions by Fe and Al in acid soils and Ca and Mg in high pH soils in the microenvironment of the fluid band (or around a solid P particle) provides another tool to enhance fluid starter band effectiveness. The polymer chemistry is not over shadowed by high ammonium N concentrations in starters. Fluid Starter Fertilizers for Corn: Sulfur in Starters General thinking regarding the need for sulfur (S) on high organic matter soils (4-8% organic matter) of the northern Cornbelt of the U.S. and southern Canada has been, and still is, that mineralization of organic matter in these soils is sufficient for crop needs. However, with the decline of S in the atmosphere from various abatement programs, S deposition in rainfall has declined substantially in the past 20 years. That S was adding to S availability from organic matter mineralization. Further, with the increasing frequency of high residue cropping systems and early planting into cold, wet and frequently compacted soils, stresses on early plant growth have been magnified. Sulfur is one of the nutrients whose availability and uptake is compromised by these un-measured stresses. Potassium and zinc are also affected. What ever the reasons, lower S deposition, less S released by organic matter mineralization and less S in fertilizers, research supported by FFF is showing that indeed corn in a corn soybean rotation does respond to inclusion of S in the starter formulation. A recent report by Dr. Gyles Randall of the University of Minnesota has emphasized the importance of starters and S in starters for corn on pH 7.1, high P, high organic matter (6.8%) clay loam soils. Grain yield was consistently increased on this high P-testing soil over the no-starter control by the starter treatments (Table 2). The starter NPKS treatments that contained 10 lb/A of K2O and S consistently produced the greatest yields. When 20 lb/A of N and P were applied, the inclusion of S gave an average yield increase of 18 bu/A compared to where S was excluded. The presence of K in the starter did not appear to effect yield. Placement position (2x0 or 2x2, 5 cm x 5 cm or 5 cm x 0)) did not differ in their effect on yield similar to Dr. Gordon’s research, and there was no interaction between starter rate and placement position. Table 2. Grain yield, grain moisture, and plant population as influenced by rate, placement, and source of fluid starter fertilizer. 2006. Randall, Univ. of Minnesota. Starter Fertilizer Treatments Trt Rate Placement lb N+P2O5+K2O+S/A Sources 1 0+0+0+0 None None 4 20+20+6+4 2x0 APP + UAN + KTS 5 20+20+6+4 2x2 APP + UAN + KTS 6 20+20+0+4 2x0 APP + UAN + ATS 7 20+20+0+4 2x2 APP + UAN + ATS 8 20+20+6+0 2x0 UAN + 7-21-7 9 20+20+6+0 2x2 UAN + 7-21-7 10 20+20+10+10 2x0 APP + UAN + KTS + ATS 11 20+20+10+10 2x2 APP + UAN + KTS + ATS Stats for RCB Design (All Treatments) P > F: LSD (0.05): LSD (0.10): CV (%): Grain Grain Initial Plant Final Plant Yield bu/A H2O % Popl’n p*103/A Popl’n p*103/A 209.2 233.0 221.0 215.5 229.0 206.3 208.5 231.1 223.5 20.2 18.9 20.0 19.7 19.4 19.8 20.9 19.3 19.2 34.1 34.5 34.3 33.0 34.2 33.8 34.5 34.2 34.5 33.1 33.1 33.1 32.5 33.1 32.6 33.1 33.1 33.0 0.006 14.9 12.4 4.7 0.025 1.2 1.0 4.4 0.016 1.1 0.9 2.2 0.223 NS NS 1.2 One tonne corn/ha = 16 bu corn/acre Fluid Starters for Corn and Soybean: Seed-Safe Applications of Fluids at Seeding Corn. A recently summarized 3-year study supported by FFF at the University of Minnesota and supervised by Dr. George Rehm, compared three fluid starter formulations for their effects on plant population and yield of corn, soybean and sugar beets. The study found that for soils with a non-sandy texture, the three fluid fertilizers (10-34-0 and low salt index 3-18-18 and 4-10-10) can be applied in a band close to corn seed at reasonable rates (47 to 94 liters/ha) without having a serious effect on yield. The use of 10-34-0 at high rates had a negative effect on germination. Although there were fewer plants, the corn crop was able to compensate by producing larger ears on each plant. The data collected over three years provide a strong base for the positive impact for the use of seed placed fertilizer on yield if the soil texture is not sandy. Management suggestions change for corn production on sandy soils. Data collected for the three years show that there is a risk for reduction in emergence if banded fertilizer is placed too close to the seed. Although there was no objective to define an ideal distance between seed and fertilizer, there was some reduction in emergence when this distance was 2 cm. A distance of at least 2.5 cm between seed and fertilizer should reduce the risk of damage to emergence when soils are sandy. Soybean. In past trials conducted by Dr.Rehm, soybean emergence was negatively affected by placement of fertilizer near the seed. Results of emergence measurements taken in 2006 were consistent with results from previous studies. Emergence was significantly affected by the grade used as well as rate and placement. There was also a significant rate X placement interaction. The effect of these factors on emergence is summarized in Table 5. When averaged over placement and rate emergence was 91.0%, 95.2% and 97.3% of the control when 3-18-18, 10-34-0, and 4-10-10 respectively were applied. Considering placement, greatest emergence was achieved when all fertilizers at both rates were applied above the seed (97.8% of the control). In 2006, the reduction in emergence (Table 3) was not as large as in past years when reductions of approximately 35% were measured. This difference is attributed to the fact that there was approximately 13 mm of rain within 2 hours of planting in 2006. Table 3.. The effect of rate and placement of three fluid grades on emergence of soybeans in 2006. Rehm, Univ. of Minnesota. Placement and Rate with seed top of seed below seed Grade high low high low high low - - - - - - - - - % of control - - - - - - - - 10-34-0 89.2 99.4 99.0 101.7 89.5 92.6 4-10-10 97.2 96.3 99.7 96.0 95.5 98.9 3-18-18 81.1 95.8 93.8 96.9 85.8 92.9 control = 153,767 plants per acre; 380,000 plants/ha The main effects of fertilizer grade, placement, and rate had no significant effect on soybean yield in 2006 (Table 4). The interaction between fertilizer grade and placement, however, was significant. Even though there were differences in emergence, these differences were not reflected in yield. This is not unusual for soybeans. Frequently, there is compensation for fewer plants from more pods per plant. Table 4. The effect of rate and placement of three fluid grades on yield of soybeans. 2006. Rehm, Univ. of Minnesota. Placement and Rate with seed top of seed below seed Grade high low high low high low - - - - - - - - - bu./acre - - - - - - - - 10-34-0 68.4 65.3 69.2 69.2 68.3 69.0 4-10-10 70.6 69.6 66.4 66.9 66.7 66.0 3-18-18 65.0 67.1 71.1 74.3 67.0 control = 64.5 bu. per acre; 1 tonne/ha = 15 bu/A 67.8 The interaction between fertilizer grade and placement is explained by examining yields when the fertilizer was placed above the seed. With the use of 10-34-0 and 3-18-18, this placement produced the highest yield. However, placement with the seed produced the highest yield when the 4-10-10 was used. Soybean is more sensitive than corn to fertilizer placed close to the seed. All fluid materials, even though applied at lower rates, reduced emergence. This was most noticeable when 10-34-0 was used. Soybeans, however, compensated for the stand reduction and the yields were not affected. Previous guidelines suggest that the sum of N and K2O should be considered when rate of fertilizer placed close to the seed is in question. The results from this study indicate, however, that N is the component most responsible for reduced emergence. Selected References: Gordon, W.B. 2002. “Effects of Application Method and Composition of Starter Fertilizer on Irrigated Ridge-Tilled Corn”, Kansas State University Report of Progress 893, p. 73-76, Kansas State University, Manhattan, KS USA. Randall, Gyles and Jeff Vetsch. 2007. “Optimum Placement of NPKS Starter Fertilizers in High Testing Soils”, in 2007 Fluid Forum Proceedings, v. 24, p. 6774. Fluid Fertilizer Foundation, Manhattan, KS USA Rehm, George and John Lamb. 2007. “Seed Safe Applications of Fluids at Planting”, in 2007 Fluid Forum Proceedings, v. 24, p. 86-92. Fluid Fertilizer Foundation, Manhattan, KS, USA.