Chapter 15 Chemical Equilibrium Introduction [Note Fig 15.2 is commonly used as examples of equilibrium] Copy the chemical equation in 15.1 and note color of reactants and products 15.1 The Concept of Equilibrium Copy and summarize Fig 15.3a Define dynamic equilibrium in terms of rates (see also 11.5) 15.2 The Equilibrium Constant Copy and summarize Fig 15.6 Copy equations [15.7], [15.8], and [15.9] [Note the Haber Process is commonly used as examples of equilibrium] equation [15.6] The Magnitude of Equilibrium Constants Summarize Fig 15.8 The Direction of the Chemical Equation and Keq What is the relationship between the direction of a reaction and the equilibrium-constant expression? Other Ways to Manipulate Chemical Equations and Keq Values Summarize: 1. 2. 3. Units of Equilibrium Constants Chapter 15 Chemical Equilibrium 15.3 Heterogeneous Equilibria Summarize what is included and what is not included in the equilibriumconstant expression. 1. 2. 3. 15.4 Calculating Equilibrium Constants Summarize procedure: 1. 2. 3. 4. Copy sample exercise 15.8 15.5 Applications of Equilibrium Constants Predicting the Direction of Reaction Summarize Fig 15.10 in terms of the reaction quotient Calculating Equilibrium Concentrations Copy sample exercise 15.10 Copy sample exercise 15.11 Chapter 15 Chemical Equilibrium 15.6 Le Châtelier’s Principle His principle states: If a system at equilibrium … Change in Reactant or Product Concentrations If a chemical system is at equilibrium and we add a substance (either a reactant or a product), … Effects of Volume and Pressure Changes Reducing the volume of a gaseous equilibrium mixture causes … Effect of Temperature Changes When the temperature is increased, it is as if we have added a reactant to the system at equilibrium. The equilibrium shifts … Summarize endo vs. exothermic reactions: The Effect of Catalysts A catalyst …