Atomization Characteristics of High-Flow Variable-Orifice Flooding Nozzles Alvin R. Womac Abstract Droplet spectra factors for variable-orifice flooding nozzles in quasi-static air were investigated to possibly aid the reduction of spray drift, and to provide a basis for future atomizer design. A laser-diffraction instrument measured the droplet size spectra of water sprays through orifices with diameters ranging from 1.14 to 6.35 mm. Spray discharge flow rates up to 40 L min-1 were measured with a Coriolis-type sensor. Nozzles produced an array of droplet size spectra with volume median diameters (D v0.5) ranging from 296 to 1062 µm. For single-orifice flooding nozzles, orifice diameter was the most important factor positively correlated with droplet size spectra factors, except the Dv0.9 . For flooding nozzles utilizing two orifices in series, the magnitude of difference between the two orifice diameters was the most important factor positively correlated with droplet size spectra factors. Also, two-orifice flooding nozzles had strong negative correlations between pressure and droplet size factors. Whereas, single-orifice flooding nozzles had strong positive correlations between flow rate and droplet size factors. A unique flow–pressure phenomenon, in which flow decreased or remained steady with increasing pressure, was observed for some orifices and pressures - possibly due to orifice inlet limiting conditions. The use of regression coefficients predicted most droplet size spectra factors with coefficients of determination (r2) ranging from 0.72 to 0.91, except for low r2 values (0.11 to 0.50) associated with the Dv0.9 of single orifice nozzles. Keywords. Applicators, Atomizers, Drift, Droplets, Quality control, Spray, Sprayers << Footnotes are on page 15 >> 2 Introduction Spray drift reduction is very important since pesticides have been detected in the atmosphere across the nation (Majewski and Capel, 1995) and in Canadian arctic snow (Gregor, 1990). The use of increased droplet size spectra on boom-type sprayers may reduce drift under various conditions due to increased spray plume porosity to airflow (Murphy et al., 2000) and increased droplet sedimentation (Zhu, 1994). Flooding nozzles typically produce very coarse and extremely coarse (ASAE S572, 2000) droplets. As a result, sprayers may be reasonably engineered for reduced spray drift using flooding nozzles. The nozzle design is simple, since a round liquid jet is directed onto a curved surface to form a fan spray (Lefebvre, 1989). Also, the use of a secondary orifice in series downstream from the primary metering orifice may reduce the production of small drift-prone droplets (Pearson et al., 1993). Flooding nozzles with nominal flow ratings of 1.5 L min-1 and less for boom sprayers were droplet-size tested (Womac et al., 1997). New variable-orifice flooding nozzles have become commercially available in nominal flow ratings up to 23 L min -1. Variable orifice selections may affect the droplet spectra, though there is little data published for these nozzles for ground boom applications in quasi-static air. Also, the availability of regression coefficients for droplet spectra factors from variable-orifice flooding nozzles in quasi-static air would aid future design. 3 The objectives of the study were: to determine the influence of variable-orifice flooding nozzle type, orifice size, operating pressure, and nozzle flow rate on emitted droplet spectra; to determine regression coefficients to predict droplet spectra from variableorifice flooding nozzles. Materials and Methods Nozzles and Pressures A manufacturer (CP Products Co., Inc.) supplied representative samples of four types of variable-orifice flooding nozzles. Nominal flow ratings ranged up to 23 L min -1. The nozzles produced flat sprays with long-axis discharge angles ranging up to 150˚. All tested nozzles had variable orifices selected by indexing a round, flat orifice plate so that the selected orifice was in alignment with a pressurized supply chamber. Orifice centers, as measured radially from the center of the orifice plate, increased with increasing orifice size to maintain a tangent of the orifice circumference in alignment with the radial-innermost dimension of a deflector. Single orifice nozzles (Figure 1) were distinguished from nozzles that used two orifices in series (Figure 2). Each type of nozzle had a different type of deflector, or had selectable flood-type tips that served as a secondary orifice and a deflector. The CP Floater Turbo nozzle and CP Sprayer Turbo nozzle utilized the flood-type tips. A common aspect of all spray deflectors was that they terminated with a trailing edge at 90˚ from the discharge orifice. Descriptions of nozzles and orifice size ranges are as follows: 4 The CP 360˚ nozzle (Figure 3) had stainless steel variable orifices ranging in diameter from 1.32 to 6.35 mm, and the orifice selection resulted in a single-orifice operation (Figure 1). A stainless steel 360˚ deflector encircled the orifices. Discharge distance, defined as the width of the opening between the orifice plate and trailing edge of the deflector measured normal to the orifice plate, was approximately 12 mm. The CP 360˚ nozzles were droplet size tested at pressures of 138, 207, 276, and 345 kPa. The CP 3-way nozzle (Figure 4) had stainless steel variable orifices ranging in diameter from 1.32 to 6.35 mm, and the orifice selection resulted in a single-orifice operation (Figure 1). Three stainless steel deflector settings were available. Discharge distances, as defined above, for small (S), medium (M), and large (L) deflectors were about 6, 10, and 14 mm. Manufacturer-recommended combinations of orifice size and deflector selection were tested – such that increasing orifice sizes used increasing deflector sizes. The CP 3-way nozzles were droplet size tested at pressures of 138, 207, 276, and 345 kPa. The CP Floater Turbo nozzle (Figure 5) had plastic orifices ranging in diameter from 1.32 to 6.35 mm, and stainless steel flood tips (secondary orifices) ranging in diameter from 1.85 to 6.35 mm. Selection of orifice and flood tip resulted in two orifices in series (Figure 2). The CP Floater Turbo nozzles were droplet size tested at pressures of 138, 207, 276, 345, and 414 kPa. The CP Sprayer Turbo nozzle (Figure 6) had plastic orifices ranging in diameter from 1.14 to 4.39 mm, and stainless steel flood tips (secondary orifices) ranging in diameter from 1.85 to 4.39 mm. Selection of orifice and flood tip resulted in two orifices 5 in series (Figure 2). The CP Sprayer Turbo nozzles were droplet size tested at pressures of 69, 138, 207, and 276 kPa. Droplet Sizing Laser Instrument A Malvern 2605 Lc droplet/particle size analyzer (Malvern Instruments, Malvern, England) monitored the number density weighted droplet spectra. Spray droplets were discharged down through a collimated laser beam to diffract light onto a multi-element detector. The instrument uses the detected energy signature for mathematical inversion and determines the droplet spectra. According to the manufacturer, the instrument has an overall accuracy of ±4%. A variable-orientation test stand supported the laser instrument so that the spray plume from a nozzle was traversed across the laser beam approximately 20 times per measurement run, with the long axis of spray at a right angle to the laser beam. The nozzle output was approximately 250 mm above the laser. This height was determined based on avoidance of the sheet action of spray at the nozzle, spatial density of droplets, and minimization of the traverse distance. Instrument lens selection was generally 800 mm, although a few runs with a 1000 mm lens were conducted. Lens selection had little effect on the measurements for the tested nozzles. Fiberglass filter media on the instrument bed reduced droplet rebound thereby minimizing measurement bias. A minimum of three replicate measurement runs was conducted. Tap water was the test liquid. Droplet size measures were conducted as described by Womac et al. (1999) and Womac (2000). Pressures were measured using a 0.25%-accuracy precision test gage mounted close to the nozzle via a tee plumbed in the supply line. Flow rates through nozzles 6 were monitored with a Coriolis-type mass flow meter (Model CMF050, Micro Motion, Inc., Boulder, CO). The manufacturer designed and certified (N.I.S.T. traceable) the flow meter for flows ranging from 0.19 to 76 L min-1 with accuracies from ±1.54 to ±0.10 %, respectively. Data Analyses Dv0.1, Dv0.5, and Dv0.9 are droplet size spectra factors corresponding with 10, 50, and 90%, respectively, of the cumulative spray liquid volume contained in droplets up to the indicated diameter (ASAE S327.2, 1997). These factors were calculated by the laser instrument software and were used exclusively throughout this study to indicate the droplet spectra. An analysis of variance (SAS, Cary, NC) of pooled data was conducted. Droplet size spectra factors were dependant variables. Independent variables included nozzle type, orifice size, secondary orifice size (used on CP Floater Turbo and CP Sprayer Turbo nozzles), difference in orifice and secondary orifice sizes (delta orifice), and pressure. For clarification, % delta orifice, a variant of delta orifice, is the percentage increase in the secondary orifice diameter over the orifice diameter. All variables were highly significant in the analysis of variance. The analysis of variance aided the selection of factors for the regression analyses. Data were sorted by nozzle type for additional analyses. A correlation analysis provided Pearson correlation coefficients (Ray, 1982a) that may be useful for future nozzle design by determining the relative importance of flood nozzle type, orifice size, and pressure on droplet spectra. Droplet spectra factors were correlated with orifice size, secondary orifice size, delta orifice, pressure, and flow rate. In addition, multivariate, polynomial regression analyses (Ray, 1982b) were conducted for each 7 nozzle type. Droplet size spectra factors were predicted based on intercept, orifice size, (orifice size)2, secondary orifice size, (secondary orifice size)2, pressure, and (pressure)2. Coefficients for the model variables are presented. This model was selected based on trial and error to maximize the coefficient of determination (r 2). Results Droplet size The complexity of atomization trends between droplet size factors and nozzle factors warranted the tabulation of droplet size factors for each nozzle (Tables 1, 2, 3, and 4). Also, an unexpected complexity in flow rate decreasing, or only slightly increasing, with pressure increases to 345 kPa for 6.35 mm orifices of the CP 360º and CP 3-way nozzles also merited specific data. The Dv0.5 ranged from 296 (Table 3) to 1062 µm (Table 4) when all nozzles and nozzle factors were considered. Table 1 shows the mean droplet size spectra factors for the CP 360º nozzle. Dv0.1, Dv0.5, and Dv0.9 generally increased at each tested pressure as the orifice diameter increased from 1.32 to 2.64 mm. Up to an orifice diameter of 2.64 mm, most factors decreased as pressure increased. The Dv0.9 for the 2.64 mm orifice tended to increase with increased pressure and were the maximum Dv0.9 values considering all orifices of this nozzle. Orifice diameters of 3.28 mm and up exhibited a trend in mean droplet spectra factors that differed from smaller orifices. Dv0.1 and Dv0.5 values tended to peak for this nozzle with the 3.28 mm orifice. Nozzle pressure had less of an effect on the droplet size spectra for orifice sizes ranging from 3.76 to 6.35 mm. For example, the CP 360º nozzle with orifice diameters of 4.57 and 6.04 mm had similar Dv0.5 values of about 8 500 µm as pressure increased from 138 to 345 kPa. However, the 4.09 and 5.31 mm orifices demonstrated slight decreases in Dv0.5 as pressure increased. Table 2 lists the mean droplet size spectra factors for the CP 3-way nozzle. The overall trend was for Dv0.1 to increase with increasing nozzle size, though the increase was irregular. Dv0.5 and Dv0.9 also tended to irregularly increase with increasing nozzle size. Specific exceptions to these increases were noted. The Dv0.5 decreased 93 µm as orifice size increased from 2.64 to 3.28 mm at 345 kPa. Similarly, Dv0.5 decreased 42 µm as orifice size increased from 4.09 to 4.57 mm at 345 kPa. Droplet size factors generally decreased as pressure increased. However, lowest values in Dv0.5 often occurred at neither the highest nor lowest pressures, such as 207 and 276 kPa as in the case of 2.31 and 2.64 mm orifices. Dv0.5 was often nearly constant or only slightly decreased with pressure for orifice sizes from 3.28 to 4.57 mm. Increasing the orifice size from 3.28 to 4.57 mm had little effect or slightly increased the Dv0.5 when averaged across pressure. Also, increasing the size of the deflector tended to slightly increase the droplet size spectra factors for the 2.64, 3.76, and 4.57 mm orifices, though the 3.76 mm orifice at 207 and 276 kPa was an exception. Perhaps the reduced sharpness of the curved path length of larger deflectors did not breakup, or shear, the jet of liquid as much as small deflectors. Table 3 presents the mean droplet size spectra factors for the CP Floater Turbo nozzle. The delta orifice effect was noted with small orifices. The 1.32 mm orifice and 2.31 mm secondary orifice (delta orifice = 0.99 mm, or 75 % delta orifice) produced a Dv0.5 of 1019 µm at 138 kPa while the 1.85 mm orifice and 1.85 mm secondary orifice (delta orifice = 0 mm, or 0 % delta orifice) had a Dv0.5 of 462 µm at 138 kPa (Table 3). 9 The delta orifice effect was also noted as orifice diameter increased. The 3.28 mm orifice produced mean Dv0.5 values of 642, 653, 874, and 882 µm when in combination with secondary orifices with diameters of 3.28, 3.58, 4.57, and 4.98 mm, respectively, at a pressure of 138 kPa (Table 3). Delta orifice values (and % delta orifice) were 0 (0%), 0.3 mm (9 %), 1.29 mm (39 %), and 1.7 mm (52 %) for these 3.28, 3.58, 4.57, and 4.98 mm secondary orifices. A large increase in Dv0.5 was observed as the % delta orifice increased from 9 to 39 %. Also, other droplet size factors increased as % delta orifice increased. The Dv0.1 for the previous example increased from 247 to 421 µm as the % delta orifice increased from 9 to 39 %. Table 4 lists the mean droplet size spectra factors for the CP Sprayer Turbo nozzle. This nozzle produced some of the largest droplet sizes measured in this study, and may be attributed to the lowest test pressure of 69 kPa. The largest droplet size factors of the study were produced by the 1.14 mm orifice and 1.85 mm secondary orifice at 69 kPa. This combination produced mean Dv0.1, Dv0.5, and Dv0.9 values of 518, 1062, and 1408 µm, respectively (Table 4). Delta orifice (% delta orifice) was 0.71 mm (62 %) for this combination of orifice diameters. The delta orifice effect was similar to that of the previous nozzle. For example, the 1.85 mm diameter orifice and secondary orifice (0 % delta orifice) produced much smaller droplets (Dv0.1=228 µm, Dv0.5=652 µm, Dv0.9=1239 µm) at 69 kPa than the previously discussed combination with a 1.85 mm secondary orifice. 10 Flow rates Overall, flow rates increased as orifice diameter increased and as pressure increased. However, the 6.35-mm orifice of the CP 360 nozzle had a decrease in flow rate from 39.15 to 38.23 L min-1 as pressure increased from 276 to 345 kPa. Shock and turbulence in the discharge pattern noticeably increased with a pressure increase to 345 kPa, and the nozzle produced hissing sounds resembling air induction, though air leakin points were not identified. Since the orifice plate was approximately 6.35 mm thick, it was hypothesized that the orifice was behaving as pipe flow operating under inlet limiting conditions. This may be possible due to streamlines from the large supply port being transitioned into the small orifice such that a necking, or constriction, occurred inside the orifice. As a result, full pipe flow through the orifice may not have been realized. Negative pressures at a constriction may have pulled the fluid apart as a vapor that caused the characteristic hissing sounds upon flow discharge. Subsequent smoothing and machining of the inlet side of the orifice altered the flow characteristics and may bear out this hypothesis. All droplet size and flow data reported pertain to the original orifice. Correlation coefficients Pearson correlation coefficients for each nozzle (Tables 5, 6, 7 and 8) indicated various droplet size correlations with orifice and pressure. These coefficients may be useful for future nozzle design by determining the relative importance of nozzle style, orifice size, and pressure on droplet spectra. Generally, the CP 360º and CP 3-way nozzles exhibited a strong positive correlation (0.568 to 0.849) between droplet spectra 11 factor with orifice diameter (Tables 5, 6). An exception (-0.008) occurred for the Dv0.9 for the CP 360º nozzle. Weak droplet spectra factor correlations (0.057 to –0.215) occurred with orifice diameter for the CP Floater Turbo and CP Sprayer Turbo nozzles (Tables 7, 8). Droplet spectra factors for these nozzles were strongly correlated (0.573 to 0.712) with delta orifice. Droplet spectra factors for each nozzle were negatively correlated with pressure (Tables 5, 6, 7, 8). Correlations with pressure were generally weaker than correlations with orifice diameter (or delta orifice), except for the pressure correlations of the CP Sprayer Turbo nozzle (-0.533 to –0.594) (Table 8). Flow rate and orifice diameter were similarly correlated with droplet spectra factors. This trend was expected since flow rate is largely determined by orifice size. These correlations may be useful in identifying the most important parameters for future nozzle design. Regression coefficients Regression modeling of droplet size factors by nozzle type determined coefficients of determination (r2) ranging from 0.11 to 0.91 (Tables 9, 10, 11, 12). Nozzle types without secondary orifices (CP 360º and CP 3-way nozzles) tended to have decreasing r2 with increasing droplet size factor, whereas r2 values were somewhat uniform for the CP Floater Turbo and CP Sprayer Turbo nozzles. The least r 2 (0.11) was for the Dv0.9 of the CP 360º nozzle (Table 9), and coincides with a lack of correlation between Dv0.9 and orifice diameter (Table 5). Prediction of Dv0.9 for the other single orifice nozzle, the CP 3-way nozzle, resulted in an r2 of 0.50. All other r2 values were 0.72 and greater. 12 Regression coefficients, P levels, and standard error of estimates are tabulated in Tables 9, 10, 11, and 12. It should be noted that the prediction accuracy varies with the selection of parameter values. The CP Floater nozzle with 2.31 mm orifice and 3.58 mm orifice at 138 kPa had a Dv0.5 predicted at 881 µm versus a measured value of 882 µm (Table 3). On the other hand, this same combination at 414 kPa had a predicted Dv0.5 of 726 µm versus a measured value of 685 µm (Table 3). Finally, regression coefficients may be of interest for inclusion in atomization models used for spray drift prediction. Conclusions The following conclusions were determined for tests conducted on variableorifice flooding nozzles in quasi-static air: The rank order of the four tested nozzles, in terms of potential drift reduction based on Dv0.5 is as follows: CP 360 nozzle (463 µm), CP 3-way nozzle (467 µm), CP Floater Turbo nozzle (640 µm), and CP Sprayer Turbo nozzle (715 µm). The rank order of the four tested nozzles, in terms of potential drift reduction based on Dv0.1 is as follows: CP 3-way nozzle (147 µm), CP 360 nozzle (151 µm), CP Floater Turbo nozzle (247 µm), and CP Sprayer Turbo nozzle (276 µm). Generally, orifice size is the single most important factor positively correlated with droplet size factors – for single orifice flooding nozzles. However, exceptions for correlations with Dv0.9 can occur. For flooding nozzles utilizing two orifices in series, the difference in orifice diameters (delta orifice) is the single most important factor positively correlated with droplet size factors. 13 Pressure is negatively correlated with droplet size factors on flooding nozzles. Two-orifice flooding nozzles have stronger correlations between pressure and droplet size factors than single orifice flooding nozzles. Generally, flow rate has a strong positive correlation with droplet size factors for single orifice flooding nozzles. Exceptions for this correlation with Dv0.9 can occur. On the other hand, two-orifice flooding nozzles produce slight negative correlations between flow rate and droplet size factors. Unique flow – pressure phenomena can occur with single-orifice flooding nozzles. Increasing pressure can result in decreased or steady flow rates. Generally, regression coefficients involving orifice diameter, secondary orifice diameter, and pressure may provide an acceptable prediction of droplet spectra factors for variable-orifice flooding nozzles in quasi-static air. However, accurate prediction of Dv0.9 for single orifice nozzles can be poor. 14 References ASAE S327.2 1997. Terminology and definitions for agricultural chemical application. ASAE S327.2 Dec95, ASAE Standards-44th Edition, ASAE. ASAE S572. 2000. Spray nozzle classification by droplet spectra. ASAE S572 Aug99, ASAE Standards – 47th Edition, ASAE. Gregor, D.J. 1990. Deposition and accumulation of selected agricultural pesticides in Canadian artic snow. in Kurtz, D.A., ed., Long Range Transport of Pesticides, Lewis Publishers, Inc., Chelsea, Michigan. Lefebvre, A.H. 1989. Atomization and Sprays. Hemisphere Publishing Corp., New York. Majewski, M.S. and P.D. Capel. 1995. Pesticides in the Atmosphere – Distribution, Trends, and Governing Factors. Ann Arbor Press, Inc., Chelsea, Michigan. Murphy, S.D., P.C.H. Miller, and C.S. Parkin. 2000. The effect of boom section and nozzle configuration on the risk of spray drift. Journal of Agricultural Engineering Research 75(2): 127-137. Pearson, S.L., T. Reed, and B. Göbel. 1993. New developments in spray tips to reduce drift. Paper No. 93-1081. ASAE. 15 Ray, A.A. 1982a. SAS User’s Guide: Basics, 1982 Edition. Ed. A.A. Ray, SAS Institute, Inc., Cary, North Carolina. Ray, A.A. 1982b. SAS User’s Guide: Statistics, 1982 Edition. Ed. A.A. Ray, SAS Institute, Inc., Cary, North Carolina. Womac, A.R., J.C. Goodwin, and W.E. Hart. 1997. Tip selection for precision application of herbicides. Bulletin 695, The University of Tennessee Agricultural Experiment Station, Knoxville, Tennessee. Womac, A.R., R.A. Maynard, II, and I.W. Kirk. 1999. Measurement variations in reference sprays for nozzle classification. Transactions of the ASAE 42(3):609-616. Womac, A.R. 2000. Quality control of standardized reference spray nozzles. Transactions of the ASAE 43(1):47-56. Zhu, H., D.L. Reichard, R.D. Fox, R.D. Brazee, H.E. Ozkan. 1994. Simulation of drift of discrete sizes of water droplets from field sprayers. Transactions of the ASAE 37(5):1401-1407. 16 Footnotes: Article was submitted for publication in _______; reviewed and approved for publication by the Power and Machinery Division of ASAE in ________. Presented as ASAE Paper No. 001131, Milwaukee, Wisconsin, July 8-12, 2000. Mention of a trademark, vendor, or proprietary product does not constitute an endorsement, guarantee, or warranty of the product by The University of Tennessee, and does not imply its approval to the exclusion of other products that also may be suitable. The author expresses appreciation to the CP Products Co., Inc. for providing a grant to assist in conducting this research. Chris Christopher and Carolyn Baecker, both of CP Products Co., Inc., provided extremely helpful consultation on nozzles. Also, Dr. Daniel Yoder provided valuable insight regarding the phenomenon of decreasing flow rate with increasing pressure. The author is Alvin R. Womac, ASAE Member Engineer, Associate Professor, The University of Tennessee, Agricultural and Biosystems Engineering Department, P.O. Box 1071, Knoxville, TN 37901, phone : 865.974.7266, fax: 865.974.4514, e-mail: <awomac@utk.edu>. 17 Figure 1. Cross-section depiction of single orifice flooding nozzle used in the CP 360º nozzle and CP 3-way nozzle Figure 2. Cross-section depiction of two orifices in series used in CP Floater Turbo nozzle and CP Sprayer Turbo nozzle 18 Figure 3. Photograph of CP 360º nozzle showing orifice plate, 360º deflector, and positioning of orifice outlets relative to deflector Figure 4. Photograph of CP 3-Way nozzle showing orifice plate, 3-way deflector, and position of orifice outlet near the deflector 19 Figure 5. Photograph of CP Floater Turbo nozzle with selectable flood-type tips that served as secondary orifice and deflector Figure 6. Photograph of CP Sprayer Turbo nozzle with selectable flood-type tips that served as secondary orifice and deflector 20 Table 1. Mean droplet size spectra factors for CP 360 nozzle Orifice Diameter (mm) 1.32 1.85 2.31 2.64 3.28 3.76 4.09 4.57 5.31 6.04 6.35 Pressure (kPa) Flow rate (L min-1) 138 207 276 345 138 207 276 345 138 207 276 345 138 207 276 345 138 207 276 345 138 207 276 345 138 207 276 345 138 207 276 345 138 207 276 345 138 207 276 345 138 207 276 345 1.19 1.48 1.68 1.89 2.35 2.88 3.31 3.69 3.86 4.76 5.38 6.03 4.86 5.95 6.86 7.59 8.09 9.92 11.41 12.64 10.06 12.30 14.12 15.70 11.85 14.40 16.44 18.21 16.08 19.69 22.48 24.97 20.32 24.78 28.52 31.67 25.32 30.96 35.84 39.78 28.08 34.04 39.15 38.23 Mean Droplet Size Spectra Factor Dv0.1 Dv0.5 Dv0.9 (μm) (μm) (μm) 111 97 91 86 127 119 115 111 153 147 134 131 159 153 146 135 190 163 150 151 172 163 161 155 181 166 166 152 178 170 174 168 194 189 171 162 179 173 163 161 148 146 157 144 412 358 329 302 454 402 381 376 490 464 432 420 503 477 462 453 557 486 467 450 500 474 459 424 495 456 440 421 512 513 511 492 540 524 487 466 520 515 498 502 480 475 497 496 980 804 734 680 922 866 846 809 1029 1000 989 936 1066 1204 1144 1302 1236 875 831 813 884 869 823 831 875 835 898 817 862 887 903 894 993 916 904 881 1044 1044 945 891 881 877 865 866 21 Table 2. Mean droplet size spectra factors for CP 3-way nozzle Mean Orifice Droplet Size Spectra Factor Diameter Deflector Pressure Flow rate Dv0.1 Dv0.5 Dv0.9 -1 (mm) (kPa) (L min ) (μm) (μm) (μm) 1.32 S 1.85 S 2.31 M 2.64 S 2.64 M 3.28 M 3.76 M 3.76 L 4.09 L 4.57 M 4.57 L 5.31 L 6.04 L 138 207 276 345 138 207 276 345 138 207 276 345 138 207 276 345 138 207 276 345 138 207 276 345 138 207 276 345 138 207 276 345 138 207 276 345 138 207 276 345 138 207 276 345 138 207 276 345 138 1.22 1.51 1.74 1.96 2.40 2.97 3.43 3.81 3.40 4.92 5.66 6.27 5.00 6.12 7.04 7.87 5.03 6.14 7.08 7.91 8.22 10.07 11.56 12.81 10.50 12.84 14.76 16.36 10.50 12.86 14.78 16.40 11.94 14.59 16.72 18.33 14.50 17.70 20.40 22.71 14.56 17.79 20.45 22.75 20.81 25.46 29.25 29.08 25.71 124 109 100 94 123 112 106 107 126 119 120 125 136 129 126 136 126 121 118 136 147 160 146 122 161 164 153 124 158 160 159 157 159 166 155 150 158 176 157 131 173 175 175 159 178 174 175 155 190 434 363 327 314 420 374 354 365 464 440 445 485 442 412 413 457 464 445 447 486 503 515 503 393 498 534 516 406 503 504 504 504 505 511 501 474 491 520 498 432 530 518 501 482 517 491 488 462 515 913 752 694 655 800 747 719 702 823 832 830 859 805 770 770 868 823 821 851 875 847 913 941 785 828 1027 1057 786 868 891 860 913 924 885 882 877 876 907 933 854 988 894 856 878 939 901 928 869 928 22 6.35 L 207 276 345 138 207 276 345 31.53 36.37 40.37 28.07 34.22 33.74 33.81 185 176 169 178 183 151 146 506 511 479 501 507 465 462 883 901 861 874 893 876 894 Table 3. Mean droplet size spectra factors for CP Floater Turbo nozzle Secondary Mean Orifice Orifice Droplet Size Spectra Factor Diameter Diameter Pressure Flow rate Dv0.1 Dv0.5 Dv0.9 (mm) (mm) (kPa) (L min-1) (μm) (μm) (μm) 1.32 1.85 1.32 2.31 1.85 1.85 1.85 2.31 1.85 2.64 1.85 3.28 2.31 2.95 2.31 3.28 138 207 276 345 414 138 207 276 345 414 138 207 276 345 414 138 207 276 345 414 138 207 276 345 414 138 207 276 345 414 138 207 276 345 414 138 207 276 1.04 1.28 1.47 1.65 1.80 1.08 1.33 1.54 1.71 1.88 1.75 2.16 2.50 2.79 3.05 2.02 2.51 2.88 3.22 3.53 2.33 2.89 3.34 3.74 4.09 2.48 3.06 3.55 3.97 4.33 2.57 3.17 3.68 4.11 4.50 3.36 4.15 4.78 320 211 167 159 155 425 385 338 279 251 149 131 122 111 105 197 164 152 142 129 263 233 218 212 191 427 360 326 289 275 266 231 216 193 171 300 263 244 844 624 534 502 482 1019 922 814 749 708 462 381 343 310 296 586 522 489 459 396 728 658 610 590 562 915 849 815 765 717 704 625 592 571 554 759 708 652 1349 1122 1095 1020 1016 1398 1373 1337 1312 1292 967 735 665 621 607 1154 1029 960 882 795 1299 1241 1146 1095 1041 1369 1349 1337 1317 1285 1276 1167 1085 1036 1025 1311 1281 1212 23 2.31 3.58 2.64 2.64 2.64 2.95 2.64 3.28 2.64 3.58 3.28 3.28 3.28 3.58 3.28 4.57 3.28 4.98 3.76 4.57 3.76 4.98 345 414 138 207 276 345 414 138 207 276 345 414 138 207 276 345 414 138 207 276 345 414 138 207 276 345 414 138 207 276 345 414 138 207 276 345 414 138 207 276 345 414 138 207 276 345 414 138 207 276 345 414 138 207 276 5.34 5.84 3.44 4.23 4.88 5.45 5.91 3.67 4.53 5.23 5.84 6.40 3.99 4.92 5.70 6.38 6.99 4.38 5.43 6.25 6.97 7.63 4.55 5.60 6.45 7.21 7.87 5.29 6.50 7.49 8.37 9.17 5.50 6.74 7.78 8.69 9.48 6.37 7.84 9.02 10.03 10.95 7.38 9.06 10.41 11.36 12.21 9.21 11.32 13.02 14.52 15.84 9.50 11.68 13.49 229 220 396 354 285 278 260 205 163 147 144 139 228 209 181 172 162 259 240 224 208 197 321 271 254 244 239 239 211 197 184 178 247 241 225 212 198 421 415 385 329 310 434 404 379 352 316 336 274 267 255 248 346 295 271 609 596 882 810 746 726 685 572 515 480 458 444 616 583 548 537 524 697 634 602 588 576 796 717 668 646 634 642 603 584 569 556 653 625 603 594 581 874 857 812 774 753 882 860 809 787 772 797 719 694 652 615 807 727 689 1113 1090 1360 1334 1301 1287 1249 1033 1045 909 855 801 1149 1062 1007 1008 1018 1264 1172 1110 1112 1090 1328 1280 1232 1199 1178 1193 1148 1139 1125 1074 1209 1142 1121 1134 1122 1356 1350 1332 1313 1299 1358 1352 1333 1323 1315 1329 1282 1258 1194 1088 1331 1267 1230 24 4.09 4.57 4.09 4.98 4.57 4.57 4.57 4.98 5.31 6.35 6.04 6.35 6.35 6.35 345 414 138 207 276 345 414 138 207 276 345 414 138 207 276 345 414 138 207 276 345 414 138 207 276 345 414 138 207 276 345 414 138 207 276 345 414 15.09 16.47 10.52 12.92 14.88 16.62 18.18 10.90 13.45 15.46 17.27 18.83 11.73 14.46 16.70 18.64 20.37 12.68 15.59 17.95 20.04 21.88 20.80 25.45 29.41 32.88 36.19 22.90 27.94 32.29 36.07 39.60 23.09 28.01 31.94 33.97 38.62 257 246 272 256 250 238 231 276 249 238 230 220 259 243 234 222 211 255 237 229 219 208 305 270 252 238 229 283 260 244 223 209 291 258 235 189 183 664 625 703 654 623 642 619 701 645 615 602 584 685 649 615 588 576 653 614 599 574 563 717 625 595 553 537 685 598 575 531 494 716 631 569 483 474 1211 1149 1267 1204 1156 1208 1171 1263 1195 1121 1100 1042 1253 1208 1172 1140 1079 1191 1122 1095 1020 1016 1263 1104 1031 982 941 1229 992 973 989 900 1274 1145 1002 926 950 25 Table 4. Mean droplet size spectra factors for CP Sprayer Turbo nozzle Secondary Mean Orifice Orifice Droplet Size Spectra Factor Diameter Diameter Pressure Flow rate Dv0.1 Dv0.5 Dv0.9 -1 (mm) (mm) (kPa) (L min ) (μm) (μm) (μm) 1.14 1.85 1.42 1.85 1.85 1.85 1.85 2.95 2.64 2.95 3.58 2.95 3.58 4.39 4.39 4.39 69 138 207 276 69 138 207 276 69 138 207 276 69 138 207 276 69 138 207 276 69 138 207 276 69 138 207 276 69 138 207 276 0.57 0.82 1.00 1.15 0.63 0.89 1.09 1.27 1.16 1.67 2.05 2.35 1.56 2.24 2.72 3.14 2.82 4.08 4.92 5.68 3.51 4.89 5.87 6.75 5.92 8.25 9.96 11.38 6.88 9.58 11.68 13.37 518 420 355 255 436 250 193 164 228 161 151 141 445 375 287 259 289 231 218 205 242 203 184 152 425 348 285 271 373 270 257 247 1062 1006 836 703 1010 694 588 520 652 507 469 431 1029 892 803 741 802 650 617 602 690 586 551 487 905 807 731 697 792 700 680 629 1408 1395 1344 1286 1396 1287 1199 1075 1239 1069 932 835 1400 1363 1334 1309 1334 1235 1193 1183 1274 1160 1091 1033 1366 1332 1291 1268 1322 1267 1250 1180 26 Table 5. Pearson correlation coefficients for CP 360 nozzle Pearson Correlation Coefficient (P level) Nozzle Factor Dv0.1 Dv0.5 Orifice Dv0.9 0.677 (< 0.0001) 0.677 (< 0.0001) -0.008 (0.9240) Pressure -0.300 (0.0005) -0.407 (< 0.0001) -0.281 (0.0011) Flow rate 0.517 (< 0.0001) 0.541 (< 0.0001) -0.088 (0.314) Table 6. Pearson correlation coefficients for CP 3-way nozzle Pearson Correlation Coefficient (P level) Nozzle Factor Dv0.1 Dv0.5 Orifice Dv0.9 0.849 (< 0.0001) 0.646 (< 0.0001) 0.568 (< 0.0001) Pressure -0.258 (0.0007) -0.290 (0.0001) -0.178 (0.0207) Flow rate 0.742 (< 0.0001) 0.504 (< 0.0001) 0.468 (< 0.0001) 27 Table 7. Pearson correlation coefficients for CP Floater Turbo nozzle Pearson Correlation Coefficient (P level) Nozzle Factor Dv0.1 Dv0.5 Dv0.9 Orifice 0.057 (0.2332) -0.087 (0.0691) -0.115 (0.0164) Secondary Orifice 0.319 (< 0.0001) 0.166 (0.0005) 0.116 (0.0153) Delta Orifice (Secondary-Orifice) 0.712 (< 0.0001) 0.695 (< 0.0001) 0.637 (< 0.0001) Pressure -0.432 (< 0.0001) -0.446 (< 0.0001) -0.429 (< 0.0001) Flow rate -0.017 (0.7205) -0.172 (0.0003) -0.228 (< 0.0001) Table 8. Pearson correlation coefficients for CP Sprayer Turbo nozzle Pearson Correlation Coefficient (P level) Nozzle Factor Dv0.1 Dv0.5 Dv0.9 Orifice -0.142 (0.1691) -0.215 (0.0353) -0.074 (0.473) Secondary Orifice 0.141 (0.1716) 0.083 (0.4240) 0.226 (0.0267) Delta Orifice (Secondary-Orifice) 0.573 (< 0.0001) 0.619 (< 0.0001) 0.592 (< 0.0001) Pressure -0.594 (< 0.0001) -0.587 (< 0.0001) -0.533 (< 0.0001) -0.127 (0.2174) -0.194 (0.0588) -0.054 (0.5985) Flow rate 28 Table 9. Regression coefficients to predict droplet spectra factors for CP 360 nozzle Regression Coefficient (P level) [Standard Error of Estimate] Parameter† Dv0.1 Dv0.5 Dv0.9 Intercept (μm) 59.21 (< 0.0001) [8.90] 372.13 (< 0.0001) [29.07] 1030.46 (< 0.0001) [134.82] Orifice (mm) 63.41 (< 0.0001) [2.36] 93.02 (< 0.0001) [7.71] 68.63 (0.0571) [35.74] (Orifice)2 (mm2) -6.75 (< 0.0001) [0.30] -9.04 (< 0.0001) (0.97] -8.91 (0.0509) [4.52] Pressure (kPa) -0.186 (0.0092) [0.071] -0.649 (0.0056) [0.230] -1.454 (0.1759) [1.068] (Pressure)2 (kPa2) 0.00018 (0.224) [0.0001] 0.00076 (0.1120) [0.0005] 0.00207 (0.3477) [0.0022] 0.91 0.78 0.11 r2 † Ranges in Parameters: Orifice, Pressure, 1.32 – 6.35 mm 138 – 345 kPa Table 10. Regression coefficients to predict droplet spectra factors for CP 3-way nozzle 29 Dv0.1 Regression Coefficient (P level) [Standard Error of Estimate] Dv0.5 Dv0.9 Intercept (μm) 59.22 (< 0.0001) [9.86] 256.75 (< 0.0001) [28.64] 566.80 (< 0.0001) [55.03] Orifice (mm) 34.61 (< 0.0001) [2.68] 110.71 (< 0.0001) [7.80] 129.41 (< 0.0001) [14.98] (Orifice)2 (mm2) -2.63 (< 0.0001) [0.34] -11.27 (< 0.0001) [0.99] -12.91 (< 0.0001) [1.90] Pressure (kPa) 0.101 (0.1887) [0.077] -0.033 (0.8834) [0.223] 0.368 (0.3917) [0.429] (Pressure)2 (kPa2) -0.00038 (0.0171) [0.0002] -0.0005 (0.2957) [0.0005] -0.0011 (0.2032) [0.0009] 0.85 0.72 0.50 Parameter† r2 † Ranges in Parameters: Orifice, Pressure, 1.32 – 6.35 mm 138 – 345 kPa 30 Table 11. Regression coefficients to predict droplet spectra factors for CP Floater Turbo nozzle Regression Coefficient (P level) [Standard Error of Estimate] Parameter† Dv0.1 Dv0.5 Dv0.9 Intercept (μm) 147.69 (< 0.0001) [19.08] 411.40 (< 0.0001) [32.85] 704.70 (< 0.0001) [47.77] Orifice (mm) -195.57 (< 0.0001) [9.83} -403.87 (< 0.0001) [16.93] -502.40 (< 0.0001) [24.62] (Orifice)2 (mm2) 14.59 (< 0.0001) [1.33] 34.74 (< 0.0001) [2.29] 46.23 (< 0.0001) [3.32] Secondary Orifice (mm) 254.96 (< 0.0001) [12.46] 557.94 (< 0.0001) [21.46] 779.34 (< 0.0001) [31.20] (Secondary Orifice)2 (mm2) -18.54 (< 0.0001) [1.56] -48.28 (< 0.0001) [2.69] -73.59 (< 0.0001) [3.91] Pressure (kPa) -0.682 (< 0.0001) [0.099] -1.375 (< 0.0001) [0.171] -1.553 (< 0.0001) [0.249] 0.00069 (0.0001) [0.0002] 0.00148 (< 0.0001) [0.0003] 0.00156 (0.0005) [0.0004] 0.81 0.83 0.78 (Pressure)2 (kPa2) r2 † Ranges in Parameters: Orifice, Secondary Orifice, Pressure, 1.32 – 6.35 mm 1.85 – 6.35 mm 138 – 414 kPa 31 Table 12. Regression coefficients to predict droplet spectra factors for CP Sprayer Turbo nozzle Regression Coefficient (P level) [Standard Error of Estimate] Parameter† Dv0.1 Dv0.5 Dv0.9 Intercept (μm) 473.35 (< 0.0001) [53.76] 836.30 (< 0.0001) [83.02] 1118.17 (< 0.0001) [79.33] Orifice (mm) -361.87 (< 0.0001) [33.27] -656.91 (< 0.0001) [51.38] -550.82 (< 0.0001) [49.10] (Orifice)2 (mm2) 46.15 (< 0.0001) [5.81] 82.10 (< 0.0001) [8.97] 70.58 (< 0.0001) [8.57] Secondary Orifice (mm) 277.87 (< 0.0001) [45.54] 651.50 (< 0.0001) [70.33] 629.85 (< 0.0001) [67.21] -25.00 (0.0006) [7.00] -69.36 (< 0.0001) [10.81] -69.96 (< 0.0001) [10.33] -1.794 (< 0.0001) [0.302] -2.702 (< 0.0001) [0.466] -1.317 (0.0040) [0.445] 0.003 (0.0007) [0.0009] 0.0042 (0.0023) [0.0013] 0.0011 (0.3911) [0.0013] 0.84 0.87 0.82 (Secondary Orifice)2 (mm2) Pressure (kPa) (Pressure)2 (kPa2) r2 † Ranges in Parameters: Orifice, Secondary Orifice, Pressure, 1.14 – 4.39 mm 1.85 – 4.39 mm 69 – 276 kPa