ESPM 121: Homework Set 1: Due Feb. 21 @ 5pm (return to my mailbox in 145 Hilgard or slide under my door in 317 Hilgard). Soil processes on the western slope of the Sierra Nevada, Fresno County, CA References and resources for calculations: Dahlgren, R.A., J.L Boettiner, G.L. Huntington, and R.G. Amundson. 1997. Soil development along an elevational transect in the western Sierra Nevada, California. Geoderma 78:207-236. For all calculations, you are encouraged to use Excel to perform the calculations, and: • Please provide the approach to the problem on this sheet. • Attach the Excel sheet of results for all questions. • Attach plots where for all problems where they are required. Residence time vs. elevation/climate 1. In lecture 2, we covered the concept of residence time as a guide to soil age on sloping landscapes. a. For the 7 soils examined by Dahlgren et al., calculate their residence time. Assume all sites have an average erosion rate of 4 cm/1000 yrs (a value both probably too high and not applicable to all sites, but one calculated from reservoir sedimentation by Janada, 1967). See the plot below. Problem 1 5 10 4 residence time 4.5 10 4 Residence Time (yr) 4 10 4 3.5 10 4 3 10 4 2.5 10 4 2 10 4 1.5 10 4 1 10 4 0 500 1000 1500 Elevation (m) 2000 2500 3000 b. Discuss why the trends occur as they do with MAP/MAT. In this discussion, remember that soil thickness (which essentially drives the residence time calculations) is the balance of erosion rates and soil production (rock conversion to soil) rates. See plot below of residence time vs. the ratio of MAP/MAT. This ratio increases with elevation due to declining temps and increasing precip. It seems that there is a critical ratio which promotes the establishment of thick soils and long residence times. So, the thickest soils are found at mid elevation with a favorable combination of both temperature and moisture which leads to high rates of chemical weathering and conversion of rock to soil. Given our assumption of constant erosion rates regardless of elevation, the longest residence times are found with the thickest soils. Problem 1 5 10 4 residence time 4.5 10 4 Residence Time (yr) 4 10 4 3.5 10 4 3 10 4 2.5 10 4 2 10 4 1.5 10 4 1 10 4 0 5 10 15 20 25 30 35 MAP/MAT Clay production vs. elevation 2. a. Calculate the rate of clay formation (kg clay/cm2x1000 yrs) for all seven soils. You can assume all soils have a bulk density of 1.4 g cm-3. Use clay data from Table 3 in paper, and data from #1 above. See plot below. I apologize for making you convert to cm2 scale! It was a typo on my part – my data are on a m2 scale, 10,000x the values I accidentally asked for. Problem 2 8 clay prod rate Clay Prod Rate (kg/m2 1000 yrs) 7 6 5 4 3 2 1 0 500 1000 1500 2000 2500 3000 Elevation (m) b. Discuss why the weathering rates (i.e. clay production rates) vary as they do with MAT and MAP. As mentioned above to some degree, the combination of water vs. temperature is critical for weathering rates. Water is needed as the solvent in which silicate weathering occurs, and temperature (heat) drives the reactions. The mid elevations in the Sierra Nevada appear to be the most ideal combination in that region. Use of CEC to evaluate soil clay mineralogy 3. a. Calculate the CEC of the clay fraction (meq/100g of clay) as a function of both soil depth and elevation for the 7 soils. Obtain CEC and clay from Table 3. Please see the Excel sheet for the numerical results. b. Given the clay mineralogical data in Figs. 7 and 9, do the CEC values seem consistent with these data. If not, what might be contributing to the CEC of the soils beyond the clay minerals? In general, the results (CEC/100 g clay) are not consistent with the mineralogical measurements, which show increasing kaolinite/gibbsite with elevation (and loss of mica/vermiculite). The former are low in CEC, the later higher. The relatively high apparent clay CEC is most likely due to OM contributions. To support this, CEC decreases with depth (as does OM). If I had the numerical values for OM vs depth for all soils, we could have easily corrected the CEC values and gotten a better handle on the actual clay mineral contributions (but I didn’t have that information). Soil color and soil mineralogy 4. In the lecture, we discussed that soil Munsell values are related to soil organic C contents. We hypothesized that Munsell chroma should be related to degree of weathering and the amount of secondary Fe oxides the soil contains. To test this hypothesis, plot the soil chroma (for moist soils) vs. the Fe(d) of the B horizons only (neglect any A horizons or any Cr horizons) (citratedithionite extractable Fe)(Fe(d) is a chemical extractant that removes most important secondary Fe oxides, including hematite, goethite, and ferrihydrite). a. Discuss the results of the analysis. Does it conform to the hypothesis? The results of this analysis very nicely supported our hypothesis that soil color reflects degree of weathering and the amount of secondary Fe oxides present. See plot below. western Sierra Nevada: Dahlgren et al., 1997 Citrate-dithionite extractable Fe (g/kg) 2 4 6 8 10 12 14 16 1 2 3 4 5 6 7 8 9 Moist Chroma Soil morphology and climate 5. a. Plot O and Bt horizon thicknesses vs. elevation. Discuss reasons why these trends occur as they do. For the O horizons, considered the vegetation (Table 1) and the effect of climate. See plot below. As we would expect from the clay analysis above, the thickest Bt horizons are at the middle elevation zones. The O horizons loosely follow this pattern as well. In a few days we will go into the soil C cycle in more detail, but at this stage, the O horizon thickness corresponds to forest/plant density. The mid elevation is the premier commercial forest of California. Sites above and below it (in elevation) have lower productivity due to climatic limitations (water or temp). Also, the persistence of organic matter once added to the soil surface is related to temperature: high temps promote rapid decomposition. We will go into this more in the future. western slope of Sierra Nevada 150 Horizon Thickness (cm) O horizon A horizon Bt horizon 100 50 0 0 500 1000 1500 Elevation (m) 2000 2500 3000