Supported by: Activities for Probeware Temperature Probe By Jim Dyer and Dustan Smith Indiana Science Indicators Addressed: 6.1.2 Give examples of different ways scientists investigate natural phenomena and identify processes all scientists use, such as collection of relevant evidence, the use of logical reasoning, and the application of imagination in devising hypotheses and explanations, in order to make sense of evidence. 6.1.6 Explain that computers have become invaluable in science because they speed up and extend people’s ability to collect, store, compile, and analyze data; prepare research reports; and share data and ideas with investigators all over the world. 6.1.7 Explain that technology is essential to science for such purposes as access to outer space and other remote locations, sample collection and treatment, measurement, data collection and storage, computation, and communication of information. 6.2.2 Use technology, such as calculators or computer spreadsheets, in analysis of data. 6.2.3 Select tools, such as cameras and tape recorders, for capturing information. 6.2.6 Read simple tables and graphs produced by others and describe in words what they show. 6.2.8 Analyze and interpret a given set of findings, demonstrating that there may be more than one good way to do so. 6.3.18 Investigate and describe that when a new material, such as concrete, is made by combining two or more materials, it has properties that are different from the original materials. 6.5.4 Demonstrate how graphs may help to show patterns—such as trends, varying rates of change, gaps or clusters—which can be used to make predictions. -1- Objectives: Students will be able to… Use logical reasoning to predict what will be observed. Read a graph and identify trends in the data. Explain that computers play an important role in the collection and analysis of scientific data. Describe that new materials have different properties then what it comes from. Quick Background/Overview: The main purpose of these activities is to acquaint the user with the Probeware software with a specific focus on using a temperature probe. The first activity is a comparison of the insulating abilities of a normal plastic drinking cup and a Styrofoam drinking cup. The first half of the activity involves observing how fast hot water cools in each of the cups, while the second half involves observing how fast cold water heats up in each of the cups. The second activity is designed to observe the temperature changes associated with exothermic and endothermic reactions. Exothermic reactions are those that give off heat during the reaction and thus the temperature increases. Endothermic reactions absorb heat during the reaction and thus the temperature decreases. Note: If using Probeware is new to you, it is highly recommended that you visit the Appendix section at the end of this activity to get yourself acquainted with the program. -2- Setup Temperature Sensor Connect USB Link to Computer Connect Temperature Probe to USB (or to Xplorer GLX) Setup the Probeware Software Open PASPortal: Here are three (3) ways to open PASPortal: 1) Select the quick-launch button for PASPortal ( ) on the Taskbar, or 2) the desktop “Shortcut” link for PASPortal/DataStudio ( ), or 3) if the “shortcut” is not visible on the desktop then try the long version: Select the [Start] button on the Taskbar Select [All Programs] Place cursor over [DataStudio] folder Launch [DataStudio] Program. Open DataStudio Select “Create an Experiment” -3- Your screen should look like this now (below). The Probeware system is ready to collect data. Note: For Macintosh users, the program my skip past the “Create Experiment” step and go directly to a screen like the one below. Which Insulates Better - Plastic Cup or Styrofoam Cup? Materials Hot water source, e.g. coffee maker, hot plate (between 45 - 55 °C) Cold water source, e.g. ice water (around 0 °C) Ice (It may be convenient to store the ice in a Styrofoam container before it is needed for the experiment.) 8 oz (240 mL) plastic cups (widebottom) Solo 8 oz (240 mL) Styrofoam cups (approximately the same size and shape as the plastic cups) plastic teaspoon (for gentle stirring) -4- Set up experiment 1. If the temperature probe is not already set up, please do so as shown above. 2. Add 4 oz (120 mL) hot water to the cup (plastic cup for the first trial and Styrofoam cup for the second trial). 4 oz (or 120 mL) is about half of the cup’s volume. The key is to have a consistent volume of water for each of the trials. 3. Place the temperature sensor in the hot water and click the Start button ( ) in DataStudio or ( ) on the Xplorer to begin collecting data. Collect data for ten (10) minutes. (To see a more significant cooling “curve” then you may elect to collect data for a significantly longer time. This may be done during a different day so it can be run in the background during other class lessons.) 4. After the data collection time period (ten minutes) is up, click the Stop button ( ) in DataStudio or ( ) on the Xplorer to end data collection. *** If you have collected data remotely using Xplorer, your data can be downloaded to the computer automatically. Connect the Xplorer to the USB port on your computer using the cable provided, and follow the on-screen prompts. Now would be a good time to save the data. Select [File], [Save As]. Select an appropriate name for your file. This is just for safety reasons, so you do not happen to lose the data. You will be able to analyze and manipulate the data and resave the data later. *** Adjust the scaling of your graph to fit nicely by selecting the “Scale to Fit” button for scaling. My graph before “Scale to Fit” After “Scale to Fit” -5- There is a lot you can do with DataStudio. If you are unfamiliar with navigating around DataStudio, it is recommended that you visit the Appendix at the end of this set of activities to learn a few of the more useful functions for this set. Other Helpful DataStudio Tools: Use the Smart Tool ( ) to pinpoint starting and ending temperatures. Use DataStudio’s Note Tool ( ) to add annotations to your graphs. 5. Repeat steps 1-4 for the Styrofoam cup. Note: It is critical that the starting temperatures be about the same (within 1 degree Celsius)!!! The following is a sample result. When you select the [Start] button for the second set of data, it should begin charting the data on the same graph as the first set of data. Analysis for hot water in Styrofoam cup These downward sloping curves on the graph are called “cooling curves”. How does the cooling curve for the hot water in the Styrofoam cup compare to the cooling curve for the hot water in the plastic cup? Determine temperature change over the 10 minute period for each of the curves. [Hint: Subtract the temperature at 10 minutes from the beginning temperature.] What is the rate of heating/cooling (i.e. degrees/minute) for each of the curves? Perform the same experiment, except this time with ice-water. (Directions below.) Set up experiment (for ice-water) Add 4 oz (120 mL) ice-water to an empty plastic cup (Remember: The key to good results is to have a consistent starting volume of water and a -6- consistent starting temperature between the two trials.) (Use a plastic cup for the first trial and Styrofoam cup for the second trial.) *** Careful Make sure that no "ice" from the ice-water mixture gets into the experimental cup!!! The reason is that any remaining ice in the cup will keep the water from heating up, and it is the rate of heating we are trying to observe. *** Place probe in water Start data collection ( / ). You can collect data on the same chart as for the hot water experiments if you’d like. Collect data for ten (10) minutes (to see a more significant "curve" then you make elect to collect data for a significantly longer time. This may be suggested to do during a different lab day and have it run in the background while other class lessons are going on. Stop data collection ( / ) Save the activity: [File], [Save Activity As…], select a useful filename. Check Graph to see if it looks smooth. Use the “Scale to Fit” button to optimize chart viewing. Use the Smart Tool ( ) to pinpoint starting and ending temperatures. Use DataStudio’s Note Tool ( ) to add annotations to your graphs. Resave the activity: [File], [Save Activity]. Repeat ice-water experiment using a Styrofoam cup Ice water (heating up) in plastic cup Plastic cup vs. Styrofoam cup Analysis for ice water in plastic cup Did the temperature change between the beginning of the experiment and the end? Did it get warmer or colder? Determine temperature change over the 10 minute period for the plastic cup. Subtract the initial temperature from the final temperature (at 10 minutes). -7- What is the rate of heating/cooling (i.e. degrees/minute) for of the water in the plastic cup? Why do you think the temperature changed this way? Analysis for ice water in Styrofoam cup How does the curve for the ice water in the Styrofoam cup compare to the curve for the ice water in the plastic cup? Determine temperature change over the 10 minute period for the Styrofoam cup. Subtract the initial temperature from the final temperature (at 10 minutes). What is the rate of heating/cooling (i.e. degrees/minute) for of the water in the Styrofoam cup? How do the rates of heating/cooling compare for each of the curves? Discussion Items Based on your results, what can you say about the ability of the Styrofoam cup to help keep hot water hot and cold water cold when compared to a plastic cup? (The following graph summarizes the cooling and heating curves.) If there is a difference, why do you think there is a difference? Which material is more effective at reducing the amount of temperature change? Offer suggestions to further reduce the temperature change in future experiments. [Examples: Use “nested” Styrofoam cups. Use a cardboard lid to prevent heat loss out of the top of the cup.] -8- What are some other places where we use substances to keep something hot or cold? Exothermic Reaction - CaCl2 dissolving in water Materials CaCl2 - from Driveway "Heat" by Prestone? Water (room temperature – prepare enough for your class ahead of time so that the water temperature equals the temperature of the room) 8 oz (240 mL) Styrofoam coffee cup Plastic teaspoon Set up experiment Materials for Exothermic Reaction Collecting data Add 4 oz (120 mL) water (room temperature) to the Styrofoam cup (~half full). [Hint: Fill the cup consistently for each experiment.] Place probe in water Allow system to equilibrate (a fancy way of saying, “Let the temperature stabilize.”). This should not be a problem if the water is already at room temperature. Measure out 4 teaspoons (tsp) of CaCl2 in a separate (and dry) cup Collect data (i.e. Hit the [Start] button) for about 10 seconds to establish a baseline. (Obtaining a baseline means, “Let the temperature stabilize so you have a clear starting temperature.”) Add CaCl2 (from the dry cup) to the water and stir smoothly and continuously with the spoon. [Note: do not allow the CaCl2 to “stick” to the -9- probe. This will create “hot spots” on the probe and cause temperature “spikes” in the data.] Collect data for 90-120 seconds (with continuous stirring) Stop data collection. Save the activity. Check Graph to see if it is nice and smooth and that it is easy to determine the temperatures at the bottom and top of the curve. (See graph below as an example.) If it looks too erratic you may consider re-running the experiment. Use the “Scale to Fit” button to optimize chart viewing. Use the Smart Tool ( ) to pinpoint starting and ending temperatures. Use DataStudio’s Note Tool ( ) to add annotations to your graphs. Save the activity under an appropriate filename. Analysis Did the temperature change? Did it get warmer or colder? Determine the temperature change for this experiment. Predict what the temperature change would be if you only used 2 tsp of CaCl2. Discussion Why do you think the temperature changed? Do you think you could add enough CaCl2 that you could boil water? What are some specific uses you can think of for CaCl2? - 10 - Endothermic Reaction - Baking Soda (NaHCO3) in Vinegar (acetic acid CH3CH2COOH) Materials Baking soda Vinegar (Vinegar allows for more baking soda to react/dissolve, thus creating a greater temperature drop than if mixed with just water.) 8 oz (240 mL) Styrofoam coffee cups Plastic teaspoon Set up experiment Add 4 oz (120 mL) vinegar (room temp) to the Styrofoam cup. (Cup should be about half full.) Place probe in vinegar. Allow system to equilibrate Measure out 4 teaspoons (tsp) of baking soda in a separate “dry” cup Collect data (i.e. Hit the [Start] button) for about 10 seconds to establish a baseline. Add baking soda (from the dry cup) to the vinegar “slowly” and stir with the spoon. Add the baking soda slow enough that the bubbles do not overflow out of the cup. Keep adding and stirring until all of the baking soda has been added. Collect data for 90-120 seconds (with continuous stirring) Stop data collection Save the activity. Check Graph to see if it is nice and smooth and that it is easy to determine the temperatures at the bottom and top of the curve. (See graph below as an example.) If it looks too erratic you may consider re-running the experiment. Use the “Scale to Fit” button to optimize chart viewing. Use the Smart Tool ( Use DataStudio’s Note Tool ( ) to add annotations to your graphs. Save the activity under an appropriate filename. ) to pinpoint starting and ending temperatures. Analysis Did the temperature change? Did it get warmer or colder? Determine the temperature change for this experiment. Predict what the temperature change would be if you only used 2 tsp of baking soda. - 11 - Discussion Why do you think the temperature changed? Do you think if you added enough baking soda that you could freeze water? What are some specific uses you can think of for baking soda? Here are the two experiments, with the exothermic reaction on the left and the endothermic reaction on the right. If you collected both sets of data on the same graph, they might look like this. Discussion When the two graphs are compared directly, what do you notice that is different between the two? (Hint: Look at the time variable. Possible Answers: The CaCl2 reaction has a much greater change in temperature. The baking soda reaction takes a lot longer. This is because we had to add it slowly so that we did not lose the vinegar out of the cup due to bubbling.) - 12 - Appendix Here is a sample set of data of me picking up the Temperature Probe and holding it in my hand for 60 seconds. Things worth viewing: Digits, Graph, and Table The three most useful items in the Display menu (on the left side of screen) are the Digits, Graph, and Table selections. Digits: displays the numeric value of the probe selected when recording data Graph: displays the graph of the data Table: displays the numerical values for your data Sometimes it is helpful to see the temperature of - 13 - the probe before you collect your experimental data. To see the numerical value of the temperature probe while collecting data, select the Digits ( ) button. Note: Any box that is displayed on the screen can be moved around and resized at your convenience, To change the precision of the numerical value displayed in the Digits box, select the “Digits Settings” box ( ), followed by [Increase Precision]. Note: If you do not see an increase in decimal places, drag the right-hand edge of the box farther to the right. (See below). - 14 - Sometimes it is helpful to be able to see the raw data. This is simple enough. Just select the Table ( convenience. ) button, move and resize for your Many of the things can be done in DataStudio the same way they could be done in any other Windows program. Investigate for yourself and see. Try these tasks: 1) Determine the maximum temperature of the run. 2) Practice a few “drag and drop” maneuvers, e.g. drag the “Temperature” Data to the “Table” Display and observe what happens. 3) Try to display the Graph, Table of data, and the Digits windows on the screen in a user-friendly fashion. 4) Highlight some data (on the graph or the table) and observe what happens. 5) Collect a second set of data (hint: hit the start button again) 6) Change the rate of data collection (Hint: hit the [Setup] button) 7) Change the scaling of the axes. - 15 - 8) Use the cross-hairs ( ) (called the “Smart Tool”) to determine the exact coordinates on a data point on the graph. Note: You can also use the arrow keys to make fine adjustments to the position of the smart tool and the slope tool. This may be of particular convenience for large sets of data. 9) Determine the slope of the graph at a point, e.g. at 30 seconds. 10) Double click on the graph to change the graph settings. The main point is… if you want to do something reasonable with your data, then it probably can be done and it can probably be done in a relatively simple and logical way. Just poke around and try it. - 16 - Temperature Probe Student Worksheet Name: ___________ Which insulates better—Plastic of Styrofoam Follow the instruction below: 1. 2. 3. 4. 5. 6. 7. 8. Follow your teacher’s instructions about getting and starting the computer to be used as a temperature probe. In your Styrofoam cup put about 4 oz or 120 mL of warm water (about a half a cup), put the thermometer in the cup and then hit . Watch the graph of the temperature for eight minutes. What color line is being made? ___________ What is happening to the temperature as the time goes by? _________________________________________________ _________________________________________ At the end of the eight minutes hit . Now in the plastic cup put the same amount of warm water (has to be new water), add the thermometer and then hit . What color line is being made? ______________ Again watch the graph for eight minutes and then hit . What color line is being made? ______________ What is happening to the temperature as the time goes by? _________________________________________________ _________________________________________ It will be easier to see the graphs if we could zoom in so click on the button. Which of the two cups had the greatest change in temperature? _____________ Is this cup the better insulator? ______ What was the rate of change of the worst insulator? _____________ (hint: find the change in the temperatures and then divide it by the time it took) Now you will do the same experiments with ice water. Make a hypothesis: Which one will be the better insulator this time and - 17 - 9. 10. 11. 12. 13. 14. 15. why? _________________________________ _________________________________________________ _________________________________________ Get about the same amount of ice water in your Styrofoam cup but make sure there are no ice cubes in it. Put the thermometer in and hit . Watch the graph for eight minutes. What color line is being made? ________________ What is different about this graph then the graphs for the warm water? _________________________________________________ _________________________________________ When eight minutes are over hit . Now repeat the same process with your plastic cup. Make sure the amount of ice water is the same that you used before. What color line is being made for this run? ______________ Once you have done all four tests, answer the following questions: What is the better insulated cup for ice water? ________________ Was this cup also the better insulator for warm water? _________ What was the rate of change in temperature for the plastic cup when it held ice water? (remember the hint above) _________________ Make sure the thermometer is out of the water lay and hold it up in the air. Hit one more time. You are now measuring the temperature of what? _______________ When the temperature doesn’t change any more hit . To what did each of the cups temperatures try to go to? ______________________________ Which changed faster: the warm water getting colder or the cold water getting warmer? _________________________________ - 18 - Temperature Probe Student Worksheet Endothermic and Exothermic Reaction Name: ___________ Instructions: Follow the steps below and any addition instructions provided by your teacher. Exothermic Reaction: 1. Gather the supplies as directed by your teacher. 2. Turn your computer on, plug in the temperature probe and open the data program. 3. Once your computer is ready to collect data, put about a half cup of water (get from your teacher, not the faucet) in the Styrofoam cup. 4. Place the temperature probe in the cup, let it sit for 30 seconds and press start. What is the temperature of the water? __________ 5. In another cup, place two spoonfuls of Calcium Chloride (a type of driveway melting salt) in another cup. 6. Pour the salt into your cup of water and stir with a spoon. Watch the temperature graph. What is happening to the temperature of the solution? ______________________________________ 7. When the temperature stops decreasing or increasing stop collecting data. What was the final temperature? ___________ 8. How much did the temperature change in this experiment? _____________ 9. What do you think the temperature change would be if only one spoonful was used? ____________ 10. Repeat the experiment with one spoonful. What was the actual change in the temperature? _________ Was it close to what you expected? ______ Endothermic Reaction: 1. Gather the supplies as directed by your teacher. 2. Make sure your computer is still hooked up and working. - 19 - 3. Once your computer is ready to collect data, put about a half cup of vinegar in the Styrofoam cup. 4. Place the temperature probe in the cup, let it sit for 30 seconds and press start. What is the temperature of the vinegar? _________ 5. Put two spoonfuls of baking soda in your other cup. 6. While one person stirs the vinegar, another group member should slowly add the baking soda. It will bubble and spill if added to fast. What is the temperature of the solution doing? ______________ 7. Continue until there is no more baking soda in the cup. What is the final temperature? ________ 8. How much did the temperature change in this experiment? _________ 9. What do you think the temperature change would be if only one spoonful of baking soda was used? __________ 10. Based on what you did in these experiments, if your teacher told you that you would be doing an exothermic reaction, what would you expect to happen? ______________________ What would you expect for an endothermic reaction? __________________ 11. What did you use the computer to do in these experiments? What did the computer make or show you? ______________________ __________________________________________________ __________________________________________________ - 20 -