Page 1 of 4
MATERIAL SAFETY DATA SHEET
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
SUPPLIER:
METPREP LTD.
CURRIERS CLOSE
CHARTER AVENUE
COVENTRY CV4 8AW
TELEPHONE:
PRODUCT INFORMATION: 024 7642 1222
FAX:
024 7642 1192
CHEMICAL NAME:
PRODUCT:
MetPrep ‘ COOL ‘ Cutting Agent
PRODUCT NUMBERS:
10 90 01, 10 90 05
2. COMPOSITION / INFORMATION ON INGREDIENTS
Substance / Preparation :
Components :
Composition :
Preparation.
This product is not hazardous but contains hazardous components.
Mineral oil , anionic and nonionic emulsifiers , organic and inorganic corrosion
inhibitors , biocides , borates , water .
Substances to be mentioned
Weight %
<0.25
2-Pyridinethiol, 1-oxide , sodium salt
CAS No
3811-73-2
EC No
223-296-5
-----
3,3’-Methylene-bis (5-methylozaxolidine)
1–4
66204-44-2
266-235-8
-----
Alcoholethoxylates, polymer
<2
157627-86-6
500-337-8
-----
64742-52-5
265-155-0
-----
Mineral oil, note H, L : <3% DMSO:
extract (IP346)
20 - 40
Classification
Xn; R20/21/22
Xi:;R36/38
N: R50
Xn: R21/22
C: R34
R52
Xi; R41
N; R50
3. HAZARDS IDENTIFICATION
Hazard classification :
Symbol (s):
R Phrase (s):
S Phrase (s):
Specific hazards :
This product is not hazardous (Directive 1999/45/EC).
None
None
None
Spilled product may result in slippery floors.
Do not allow material to contaminate ground water system
4. FIRST AID MEASURES
General information :
Inhalation :
Skin contact :
Eye contact :
Ingestion :
Ref. C:\MSDS\COOL.DOC
Seek medical attention if ill effect develops.
Not expected to require first aid measures.
Repeated or prolonged skin contact may cause irritation. Remove
Contaminated clothing and shoes. Wash skin with mild soap and water.
Diluted product is not irritating to the skin when used as recommended
and good personal hygiene is practised.
May cause eye irritation. In case of eye contact, immediately rinse with
clean water for 10-15 minutes. Seek medical advice.
Ingestion may cause nausea, vomiting and diarrhea.
Do not induce vomiting.
Drink promptly large quantities of milk, egg whites, gelatin solutions, or
if these are not available, drink large quantities of water. Obtain medical attention.
Prepared April 2011
Page 2 of 4
MATERIAL SAFETY DATA SHEET
5. FIRE FIGHTING MEASURES
Flammable class :
Hazardous combustion products :
Suitable extinguishing media :
The product is not flammable.
If involved in a fire the following toxic and/or corrosive fumes
may be produced by thermal decomposition : carbon oxides ,
smoke , nitrogen oxides (NOx) .
Not applicable.
6. ACCIDENTAL RELEASE MEASURES
General precautions :
Personal precautions :
Environmental precautions :
Clean up methods :
Spill area may be slippery.
Avoid contact with skin and eyes.
Prevent entry to sewers and public waters.
Dispose in a safe manner in accordance with local/national regulations.
Soak up spills with inert solids, such as clay or diatomaceous earth as
soon as possible. Flush/dilute residue with water.
7. HANDLING AND STORAGE
General :
Handling :
Storage :
Specific use(s) :
Technical protective measures :
Handle in accordance with good industrial hygiene and safety practice.
Avoid contact with skin and eyes. Wash hands and other exposed areas
with mild soap and water before eating, drinking or smoking and when
leaving work. Wash clothing before re-using.
Keep at temperatures between 5°C and 35°C in original container.
Use only as recommended on the product application sheet.
More information can be found on:
www.hse.gov.uk/metalworking,
www.ukla.org.uk,
Use only in well-ventilated areas.
8. EXPOSURE CONTROL / PERSONAL PROTECTION
Personal protection
- Respiratory protection :
- Hand protection :
- Skin protection :
- Eye protection :
- Industrial hygiene :
- Occupational Exposure Limits :
Ref. C:\MSDS\COOL.DOC
No special respiratory protection equipment is recommended under
normal conditions of use with adequate ventilation.
Follow MetPrep Skin Protection Plan (SPP01). Impervious gloves are
required when handling product concentrate.
Type of glove (DIN/EN 374): nitril, 0,11mm; minimum breakthrough time:
480 min. The same gloves can be used for the diluted product, if considered
necessary. Consider the particular working conditions under which the
gloves are being used.
Effective metalworking plant protective clothing as appropriate.
Safety shield or goggles required when handling concentrated product
(EN 166). Consider the particular working conditions under which the
goggles are being used.
When using, do not eat, drink or smoke.
Provide local exhaust or general room ventilation.
Metalworking fluid : United Kingdom (UK), guidance value : 1 (mg/m³)
Mineral oil : oilmist, TWA 8 hours ACGIH : 5 (mg/m³)
Prepared April 2011
Page 3 of 4
MATERIAL SAFETY DATA SHEET
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance :
Colour :
Odour :
Density (20°C, kg/m3) :
pH (concentrate, 20°C) :
pH (operating, 5%, 20°C) :
Viscosity (20°C, mm2/s) :
Melting point (°C) :
Flash point (°C) :
Water solubility (20°) :
liquid
yellow
mild
1005 [DIN 51757/7 (1/1984)]
not applicable
9.1 [DIN 51369 (7/1981)]
150 [DIN 51562/1 (1/1983)]
<0
not flammable [ASTM D93-80]
emulsifiable
The above data are typical values and do not constitute a specification.
10. STABILITY AND REACTIVITY
Conditions to avoid :
Materials to avoid :
Hazardous decomposition products :
Hazardous properties :
Extremely high or low temperatures.
Incompatible with strong acids and oxidizing agents.
Formaldehyde may be released below pH of 7.
If involved in a fire the following toxic and/or corrosive fumes
may be produced by thermal decomposition : See Heading 5.
Stable under normal conditions.
11. TOXICOLOGICAL INFORMATION
Description of possible hazardous to health effects is based on experience and/or toxicological characteristics of several
components.
Acute toxicity
- Inhalation :
- Dermal :
- Ocular :
- Ingestion :
No significant signs or symptoms indicative of any adverse health hazard are
expected to occur as a result of inhalation exposure.
Slight skin irritant. Mild skin irritation (redness and dryness of hands) may be
experienced when the diluted product has been contaminated by certain oils, by
dissolved metals or when mix ratio is too strong.
Slight eye irritant.
No significant signs or symptoms indicative of any adverse health hazard are
expected to occur as a result of ingestion. Ingestion may cause nausea, vomiting
and diarrhea.
Chronic toxicity
No chronic health hazards are likely for this material..
12. ECOLOGICAL INFORMATION
Environmental precautions :
On product :
On ingredients
3,3'-Methylene-bis-[5- :
methyloxazolidine]
Alcoholethoxylates, polymer :
2-Pyridinethiol, 1-oxide, sodium salt:
Ref. C:\MSDS\COOL.DOC
Avoid release to the environment.
Chemical oxygen demand (COD), 1% mix (g O2/l) = 14.
Freshwater Invertebrates Toxicity, acute EC50 : 10 - 100 (mg/l)
Freshwater Fish Toxicity, acute LC50 : 10 - 100 (mg/l)
Biodegradation : Product is biodegradable.
Biodegradation : OESO 301B (28d) > 60 %
Freshwater Invertebrates Toxicity, EC50/48h : .1 - 1 (mg/l)
49 H-LC50-Daphnia magna (mf/l): 0.15
96 H-LC50-Oncorhynchus mykiss (ug/l): 1300
Prepared April 2011
Page 4 of 4
MATERIAL SAFETY DATA SHEET
13. DISPOSAL CONSIDERATIONS
General :
Disposal method :
Comply with local regulations for disposal.
If pretreatment is needed, chemical emulsion breaking or ultrafiltration may be
used. The procedures are available on request.
Empty containers should be transported/delivered using a registered waste carrier
for local recycling or waste disposal.
Industrial waste number:120109*. This code is applicable for the product as supplied only. The conditions of
use may affect the waste classification after use; see Directive 2001/118/EC.
14. TRANSPORTATION INFORMATION
Not classified as dangerous in the meaning of transport regulations.
15. REGULATORY INFORMATION
The labelling of the product is indicated in Section 2.
National regulations/information:
16. OTHER INFORMATION
Product information :
List of relevant R phrases (heading 3) :
Note :
Product does not contain chlorine , diethanolamine .
R20/21/22 – Harmful by inhalation, in contact with skin
and if swallowed.
R21/22 - Harmful in contact with skin and if swallowed.
R34 - Causes burns.
R38 - Irritating to skin.
R41 - Risk of serious damage to eyes.
R50 - Very toxic to aquatic organisms.
R52 - Harmful to aquatic organisms.
This Safety Data Sheet has been established in accordance with the
applicable European Directives and applies to all countries that have
translated the Directives in their national laws.
Directive 67/548/EEC;
Directive 88/379/EEC (1999/45/EC, 2001/60/EC, 2006/8/EC);
Regulation (EC) No.1907/2006;
Regulation (EC) No.1272/2008 (790/2009/EC);
Regulation (EC) No. 453/2010
Revision:
Ref. C:\MSDS\COOL.DOC
20/04/2011 Revision –See *
20/01/Revision 1.
Prepared April 2011