Date-Issued:
16-Feb-16
MSDS Ref. No:
PE-015
Date-Revised:
23/07/12
Revision No:
2
MATERIAL SAFETY DATA SHEET
KRISTOL M14
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
REACH Reg. No.
01-2119458049-33-0000
232-455-8
EC No.
CAS-No.
SYNONYMS, TRADE NAMES
8042-47-5
White Mineral Oil (Petroleum)
APPLICATION
The following uses are addressed through the Chemical Safety Report (CSR) and Generic
Exposure Scenario (GES) library:
Manufacture of substance
Distribution of substance
Formulation & (re)packing of substances and mixtures
Uses in coatings
Use in cleaning agents
Lubricants
Use in metal working fluids / Rolling oils
Agrochemical uses
Use as a fuel
Use as a functional fluid
Road and construction applications
Laboratories
Supplier:
Rocara Limited
Unit 4
Elmbank
Channel Commercial Park
Queens Road
Belfast
BT3 9DT
Contact
Telephone
administrator@rocara.com
+44 28 90 461742
2. HAZARDS IDENTIFICATION
CLASSIFICATION (67/548)
CLASSIFICATION (EC 1272/2008)
Physical
Health
Environmental
Kristol M14
Not classified.
Asp. Tox. 1 - H304
Not classified
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LABEL IN ACCORDANCE WITH (EC) NO. 1272/2008
SIGNAL WORD
Danger
HAZARD STATEMENTS
H304 May be fatal if swallowed and enters airways.
PRECAUTIONARY STATEMENTS
P301/310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P331
Do NOT induce vomiting.
P501a Dispose of contents/container to a registered waste disposal company
SUPPLEMENTARY PRECAUTIONARY STATEMENTS
P405
Store locked up.
ENVIRONMENT
The product is not expected to be hazardous to the environment.
3. COMPOSITION/INFORMATION ON INGREDIENTS
EC No.
CAS-No.
232-455-8
8042-47-5
COMPOSITION COMMENTS
This material is listed under CAS No: 8042-47-5 in the following inventories: TSCA, DSL, AICS,
ENCS / MITI ((9) 1692), ECL (KE35412), PICCS, Chinese
4. FIRST AID MEASURES
INHALATION
In case of inhalation of spray mist: Move person into fresh air and keep at rest.
Get medical attention if any discomfort continues.
INGESTION
Rinse mouth thoroughly.
Obtain medical advice if large amounts are swallowed - do not induce vomiting
SKIN CONTACT
Remove contaminated clothing immediately and wash skin with soap and water.
Get medical attention if any discomfort continues.
EYE CONTACT
Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes.
Get medical attention if any discomfort continues.
Kristol M14
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5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
This product is not flammable.
Extinguish with foam, carbon dioxide, dry powder or water fog.
Do not use water jet as an extinguisher, as this will spread the fire.
SPECIAL FIRE FIGHTING PROCEDURES
Use water to keep fire exposed containers cool and disperse vapours
SPECIFIC HAZARDS
In case of fire, toxic gases may be formed
PROTECTIVE MEASURES IN FIRE
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Wear protective clothing as described in Section 8 of this safety data sheet.
Do not smoke, use open fire or other sources of ignition.
ENVIRONMENTAL PRECAUTIONS
Do not discharge into drains, water courses or onto the ground.
Protect drains by covering to avoid any spillage entering the drainage system.
Large spillages must be notified to the appropriate authorities.
SPILL CLEAN UP METHODS
Absorb with sand or other inert absorbent.
Recover the product and place in a suitable container for reuse.
7. HANDLING AND STORAGE
USAGE PRECAUTIONS
Avoid forming spray/aerosol mists.
Avoid contact with skin and eyes..
STORAGE PRECAUTIONS
Store in tightly closed original container in a dry, cool and well-ventilated place.
8. EXPOSURE CONTROLS/ PERSONAL PROTECTION
Name
Kristol M14
Std
WEL
TWA - 8 hrs
No std.
5 mg/m3 (Oil
mist)
STEL - 15 min
No std.
No std.
Notes
-
WEL = Workplace Exposure Limit.
PROTECTIVE EQUIPMENT
Kristol M14
3
PROCESS CONDITIONS
Use engineering controls to reduce air contamination to permissible exposure level.
ENGINEERING MEASURES
Provide sufficient ventilation during operations which cause oil mists to be formed.
RESPIRATORY EQUIPMENT
No specific recommendation made, but respiratory protection may still be required under
exceptional circumstances when excessive air contamination exists.
HAND PROTECTION
The most suitable glove must be chosen in consultation with the gloves supplier, who can inform
about the breakthrough time of the glove material.
If repeated skin exposure to the substance is likely, then wear suitable gloves tested to EN374 and
provide employee skin care programmes.
EYE PROTECTION
Wear approved safety goggles.
OTHER PROTECTION
Wear suitable protective clothing as protection against splashing or contamination.
HYGIENE MEASURES
Wash at the end of each work shift and before eating, smoking and using the toilet.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
COLOUR
ODOUR
SOLUBILITY
MOL. WEIGHT
MELTING POINT (°C)
VAPOUR DENSITY
(air=1)
EVAPORATION RATE
VAPOUR PRESSURE
FLASH POINT (°C)
PARTITION COEFFICIENT
(N-Octanol/Water)
BOILING POINT (°C)
RELATIVE DENSITY
VISCOSITY
AUTO IGNITION
TEMPERATURE (°C)
Liquid
Colourless
No characteristic odour
Insoluble in water
ca. 147.0
<-9
>1
<0.1 BuAc=1
<0.1 mmHg 20
>160 Cd OC (Cleveland opencup).
<1
310-550
0.83-0.86 15
15 cSt 40
>160
10. STABILITY AND REACTIVITY
STABILITY
No particular stability concerns.
CONDITIONS TO AVOID
Avoid excessive heat for prolonged periods of time. Avoid heat, flames and other sources of ignition.
HAZARDOUS POLYMERISATION
Will not polymerise.
MATERIALS TO AVOID
Strong oxidising substances.
HAZARDOUS DECOMPOSITION PRODUCTS
In case of fire, toxic gases (CO, CO2, NOx) may be formed.
11. TOXICOLOGICAL INFORMATION
Kristol M14
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TOXIC DOSE 1 - LD 50
TOXIC DOSE 2 - LD 50
TOXIC CONC. - LC 50
>5000 mg/kg (oral rat)
>2000 mg/kg dermal rabbit
>5200 mg/m3/4hr (rat)
TOXICOLOGICAL INFORMATION
Negative to Modified Ames Test Does not contain any IARC Group 1, 2(a) or 2(b) Listed Chemicals.
Polycyclic Aromatic Hydrocarbons by IP 346 <1%
GENERAL INFORMATION
No specific health warnings noted.
INHALATION
May cause irritation to the respiratory system.
INGESTION
Harmful: may cause lung damage if swallowed. Pneumonia may be the result if vomited material
containing solvents reaches the lungs.
SKIN CONTACT
Not a skin sensitiser. Prolonged contact may cause dryness of the skin.
EYE CONTACT
Repeated or prolonged contact with spray, mist or vapours may cause eye irritiation but no
permanent damage.
OTHER HEALTH EFFECTS
This substance has no evidence of carcinogenic properties.
12. ECOLOGICAL INFORMATION
LC 50, 96 Hrs, FISH mg/l
>400, 000ppm (Rainbow Trout 0% mortality)
MOBILITY
The product is insoluble in water and will spread on the water surface.
BIOACCUMULATION
Bioaccumulation is unlikely to be significant because of the low water solubility of this product.
DEGRADABILITY
This substance is inherently biodegradable
13. DISPOSAL
GENERAL INFORMATION
When handling waste, consideration should be made to the safety precautions applying to handling
of the product.
DISPOSAL METHODS
Dispose of waste and residues in accordance with local authority requirements.
WASTE CLASS
EWC Code 13 08 99 :oil wastes not otherwise specified
14. TRANSPORT INFORMATION
GENERAL
PROPER
SHIPPING
NAME
Kristol M14
The product is not covered by international regulation on the transport of dangerous goods (IMDG,
IATA,ADR/RID).
White Mineral Oil
5
MARINE
POLLUTANT
No.
15. REGULATORY INFORMATION
UK REGULATORY REFERENCES
Health and Safety at Work Act 1974.
EU DIRECTIVES
Dangerous Substance Directive 67/548/EEC.
Regulation (EC) No 1272/2008 CLP
Regulation (EC) No 1907/2006 REACH
STATUTORY INSTRUMENTS
Control of Substances Hazardous to Health.
16. OTHER INFORMATION
REVISION COMMENTS
Classification in accordance with REACH registration dossier and HSPA recommendations
Disclaimer
The information contained in this document is intended to describe the product only in terms of health, safety and
environmental requirements for the purposes of its safe handling, use and disposal and is to the best of ROCARA
Limited’s knowledge and belief correct. ROCARA Limited Technical Services will be pleased to give further advice and
assistance, but customers must satisfy themselves (by appropriate testing if necessary) that the product is suitable for their
purposes and conditions of use and that their facilities and arrangements are suitable for handling or using the product.
Accordingly ROCARA Limited disclaims any liability for loss, injury or damage which may result from the use of the
product, this information or from such advice and assistance save as may be expressly agreed under its terms of sale.
This information does not comprise a technical or performance specification for the product and customers are referred to
any relevant product technical information or specification issued by ROCARA Limited.
Customers are also reminded that there may be uses or application for the product which are protected by ROCARA
Limited or third parties' patent rights and nothing herein may be construed as an authority or encouragement to use or
apply the product in contravention of such rights.
Kristol M14
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