CH 9 Homework 1. iron + sulfur iron (II) sulfide 1-1-1; synthesis 2. silver nitrate + sodium bromide sodium nitrate + silver bromide 1-1-1-1; double replacement 3. potassium chlorate potassium chloride + oxygen 2-2-3; decomposition 4. butane (C4H10) + oxygen carbon dioxide + water 2-13-8-10; combustion 5. potassium iodide + lead (II) nitrate lead (II) iodide + potassium nitrate 2-1-1-2; double replacement 6. aluminum + oxygen aluminum oxide 4-3-2; synthesis 7. magnesium chloride + ammonium nitrate magnesium nitrate + ammonium 1-2-1-2; double replacement chloride 8. sodium peroxide + water sodium hydroxide + oxygen 2-2-4-1; none 9. iron (III) chloride + potassium hydroxide potassium chloride + iron (III) 1-3-3-1; double replacement hydroxide 10. aluminum + sulfuric acid aluminum sulfate + hydrogen 2-3-1-3; single replacement 11. sodium carbonate + calcium hydroxide sodium hydroxide + calcium carbonate 1-1-2-1; double replacement 12. carbon dioxide + water carbonic acid 1-1-1; synthesis 13. sodium + water sodium hydroxide + hydrogen 2-2-2-1; single replacemnt 14. zinc + sulfuric acid zinc sulfate + hydrogen 1-1-1-1; single replacement 15. aluminum sulfate + calcium hydroxide calcium sulfate + aluminum hydroxide 1-3-3-2; double replacement 16. calcium oxide + water calcium hydroxide 1-1-1; synthesis 1 17. iron + copper (I) nitrate iron (II) nitrate + copper 1-2-1-2; sr 18. iron (II) sulfide + hydrochloric acid hydrogen sulfide + iron (II) chloride 1-2-1-1; dr 19. potassium oxide + water potassium hydroxide 1-1-2; syn 20. octane (C8H18) + oxygen carbon dioxide + water 2-25-16-18; comb 21. potassium hydroxide + phosphoric acid potassium phosphate + water 3-1-1-3; neutralization; neutralization 22. calcium chloride + nitric acid calcium nitrate + hydrochloric acid 1-2-1-2; dr 23. magnesium hydroxide + sulfuric acid magnesium sulfate + water 1-1-1-2; neutralization; neutralization 24. phosphorous + oxygen phosphorous pentoxide 2-5-2; syn 25. sodium carbonate + hydrochloric acid sodium chloride + water + carbon 1-2-2-1-1; none dioxide 26. magnesium + nitric acid magnesium nitrate + hydrogen 1-2-1-1; sr 27. calcium carbonate calcium oxide + carbon dioxide 1-1-1; decomp 28. ammonia (NH3) + sulfuric acid ammonium sulfate 2-1-1; syn 29. magnesium chloride + fluorine magnesium fluoride + chlorine 1-1-1-1; sr 30. fluorine + sodium hydroxide sodium fluoride + oxygen + water 2-4-4-1-2; none 2 Oxidation/Reduction: Identify the species in each reaction that have been oxidized and reduced and write the half reaction. 1. FeCl3 + SnCl2 FeCl2 + SnCl4 Fe+3 + e- Fe+2 (reduced); Sn+2 Sn+4 + 2 e- (oxidized) 2. SbCl5 + KI SbCl3 + KCl + I2 Sb+5 + 2 e- Sb+3 (reduced); I-1 I20 + e- (oxidized) 3. CdS + I2 + HCl CdCl2 + HI + S I20 + e- I-1 (reduced); S-2 S0 + 2 e- (oxidized) 4. H2SO3 + I2 + H2O H2SO4 + HI I20 + e- I-1 (reduced); S+4 S+6 + 2 e- (oxidized) 5. NaClO + H2S NaCl + H2SO4 Cl+1 + 2 e- Cl-1 (reduced); S-2 S+6 + 8 e- (oxidized) CH 8 Review: (Why is it here?) 1. What things can you do to initiate or increase the rate of a reaction? Add energy, stir, add a catalyst, change ratio of reactants, increase surface area 2. What is a catalyst? Initiates or speeds up a reaction and is not involved in the reaction 3. Draw Lewis structures to illustrate the reaction on page 1 #12. O=C=O + O – H H – O –C – O –H | || H O 4. Why does alpha decay result in the loss in mass of 4 units and change in the identity of the element? You lose 2 p+ and 2 no 5. How are electrons produced during beta decay? no is converted to a p+ and an e-; the electron is ejected from the nucleus. 3 Reaction Prediction: Identify the type of reaction, predict the products, balance the equation, and tell if the reaction will take place or not. 1. aluminum + hydrochloric acid 2 Al + 6 HCl 2 AlCl3 + 3 H2 ; single replacement; yes 2. calcium hydroxide + nitric acid Ca(OH)2 + 2 HNO3 Ca(NO3)2 + 2 HOH ; neutralization; yes 3. methane (CH4) + oxygen CH4 + 2O2 CO2 + 2 H2O ; combustion 4. aluminum + oxygen 4Al + 3O2 2Al2O3 ; synthesis 5. zinc chloride + hydrogen sulfide ZnCl2 + H2S ZnS + 2 HCl ; double replacement; yes 6. dinitrogen pentoxide + water N2O5 + H2O 2 HNO3 ; synthesis 7. silver chloride + bromine 2 AgCl + Br2 2 AgBr + Cl2 ; single replacement; NR 8. sodium chlorate 2 NaClO3 2 NaCl + 3 O2 ; decomposition 9. barium nitrate + sodium chromate Ba(NO3)2 + Na2CrO4 BaCrO4 + 2 NaNO3 ; double replacement; yes 10. zinc carbonate ZnCO3 ZnO + CO2; decomposition 11. calcium phosphate + aluminum sulfate Ca3(PO4)2 + Al2(SO4)3 3 CaSO4 + 2 AlPO4; double replacement; yes 12. potassium + fluorine 2 K + F2 2 KF; synthesis 13. copper + sulfuric acid Cu + H2SO4 CuSO4 + H2; single replacement; no 14. lithium oxide + water Li2O + H2O 2 LiOH; synthesis 15. strontium chloride (electrolyzed) SrCl2 Sr + Cl2; decompositon 4 16. magnesium carbonate + phosphoric acid 3 MgCO3 + 2 H3PO4 Mg3(PO4)2 + 3 H2CO3; double replacement ; yes 17. propane (C3H8) + oxygen C3H8 + 5 O2 3 CO2 + 4 H2O; combustion 18. lead + potassium chlorate Pb + 2 KClO3 Pb(ClO3)2 + 2 K; single replacement; NR 19. calcium carbonate + lithium chloride CaCO3 + 2 LiCl Li2CO3 + CaCl2; double replacement; NR(look up lithium) 20. potassium nitrate 4 KNO3 2 K2O + 2 N2 + 5 O2; decomposition 21. calcium + oxygen 2 Ca + O2 2 CaO; synthesis 22. potassium hydroxide + sulfuric acid 2 KOH + H2SO4 K2SO4 + 2 HOH; neutralization; 23. calcium + aluminum chloride 3 Ca + 2 AlCl3 3 CaCl2 + 2 Al; single replacement; yes 24. potassium sulfide + iron (II) nitrate K2S + Fe(NO3)2 FeS + 2KNO3; double replacement; yes 25. barium carbonate BaCO3 BaO + CO2; decomposition 26. lithium sulfide (dissociated) Li2S 2 Li+1 + S-2 27. calcium + water Ca + 2 HOH Ca(OH)2 + H2; SR; Yes 28. sodium + nitric acid 2 Na + 2 HNO3 2 NaNO3 + H2; SR; yes 29. barium oxide 2 BaO 2 Ba + O2; decomposition 30. carbon dioxide + water CO2 + H2O H2CO3; synthesis 5 Alpha/Beta Decay: U92238 Undergoes decay and becomes Th90234 Undergoes decay and becomes Pa91234 Undergoes decay and becomes U92234 Undergoes decay and becomes Th90230 Undergoes decay and becomes Ra88226 Undergoes decay and becomes Rn86222 Undergoes decay and becomes Po84218 Undergoes decay and becomes Pb82214 Undergoes decay and becomes Bi83214 Undergoes decay and becomes Po84214 Undergoes decay and becomes Pb82210 Undergoes decay and becomes Bi83210 Undergoes decay and becomes Po84210 Undergoes decay and becomes Pb82206 Which is stable. 6 Half-Life Calculations: 1. 64 g of a substance decays for 4 half-lives. How much of the original substance is left? 4 g 2. Plutonium-236 has a half-life of roughly 2 years. 32 g of it decay over a period of 8 years. How much of the original sample is left? 2g 3. Molybdenum-91 has a half-life of 15.49 minutes. After 40 minutes 1 g of it remains. What was the mass of the original sample? 6g 7