H CH 9 Homework 1. iron + sulfur iron (II) sulfide 2. silver nitrate + sodium bromide sodium nitrate + silver bromide 3. potassium chlorate potassium chloride + oxygen 4. butane (C4H10) + oxygen carbon dioxide + water 5. potassium iodide + lead (II) nitrate lead (II) iodide + potassium nitrate 6. aluminum + oxygen aluminum oxide 7. magnesium chloride + ammonium nitrate magnesium nitrate + ammonium chloride 8. sodium peroxide + water sodium hydroxide + oxygen 9. ferric chloride + potassium hydroxide potassium chloride + ferric hydroxide 10. aluminum + sulfuric acid aluminum sulfate + hydrogen 11. sodium carbonate + calcium hydroxide sodium hydroxide + calcium carbonate 12. carbon dioxide + water carbonic acid 13. sodium + water sodium hydroxide + hydrogen 14. zinc + sulfuric acid zinc sulfate + hydrogen 15. aluminum sulfate + calcium hydroxide calcium sulfate + aluminum hydroxide 16. calcium oxide + water calcium hydroxide 17. iron + cuprous nitrate ferrous nitrate + copper 18. iron (II) sulfide + hydrochloric acid hydrogen sulfide + iron (II) chloride 19. potassium oxide + water potassium hydroxide 20. octane (C8H18) + oxygen carbon dioxide + water 21. potassium hydroxide + phosphoric acid potassium phosphate + water 22. calcium chloride + nitric acid calcium nitrate + hydrochloric acid 23. magnesium hydroxide + sulfuric acid magnesium sulfate + water 24. phosphorous + oxygen phosphorous pentoxide 25. sodium carbonate + hydrochloric acid sodium chloride + water + carbon dioxide 26. magnesium + nitric acid magnesium nitrate + hydrogen 27. calcium carbonate calcium oxide + carbon dioxide 28. ammonia (NH3) + sulfuric acid ammonium sulfate 29. magnesium chloride + fluorine magnesium fluoride + chlorine 30. fluorine + sodium hydroxide sodium fluoride + oxygen + water Now, try these!!! 1. ZnSO4 + KI + KIO3 + H2O Zn5(OH)8SO4 + K2SO4 + I2 2. K2SeO3 + KI + HCl KCl + Se + I2 + H2O 3. KIO3 + KI + HCl KCl + I2 + H2O 4. FeCl2 + K2Cr2O7 + HCl FeCl3 + KCl + CrCl3 + H2O 5. Cr2(SO4)3 + KMnO4 + H2O H2CrO4 + MnSO4 + K2SO4 + H2SO4 6. HBO2 + KIO3 + KI KBO2 + H2O + I2 Now try the MOTHER of ALL balancing problems: [Cr(N2H4CO)6]4[Cr(CN)6]3 + KMnO4 + H2SO4 K2Cr2O7 + MnSO4 + CO2 + KNO3 + K2SO4 + H2O Oxidation/Reduction: Identify the species in each reaction that have been oxidized and reduced and write the half reaction. 1. FeCl3 + SnCl2 FeCl2 + SnCl4 2. SbCl5 + KI SbCl3 + KCl + I2 3. CdS + I2 + HCl CdCl2 + HI + S 4. H2SO3 + I2 + H2O H2SO4 + HI 5. NaClO + H2S NaCl + H2SO4 Reaction Prediction: Identify the type of reaction, predict the products, balance the equation, and tell if the reaction will take place or not. 1. aluminum + hydrochloric acid 2. calcium hydroxide + nitric acid 3. methane (CH4) + oxygen 4. aluminum + oxygen 5. zinc chloride + hydrogen sulfide 6. dinitrogen pentoxide + water 7. silver chloride + bromine 8. sodium chlorate 9. barium nitrate + sodium chromate 10. zinc carbonate 11. calcium phosphate + aluminum sulfate 12. potassium + fluorine 13. copper + sulfuric acid 14. lithium oxide + water 15. strontium chloride (electrolyzed) 16. magnesium carbonate + phosphoric acid 17. propane (C3H8) + oxygen 18. lead + potassium chlorate 19. calcium carbonate + lithium chloride 20. potassium nitrate 21. calcium + oxygen 22. potassium hydroxide + sulfuric acid 23. calcium + aluminum chloride 24. potassium sulfide + iron (II) nitrate 25. sulfur dioxide + water 26. lithium sulfide (dissociated) 27. calcium + water 28. sodium + nitric acid 29. barium oxide 30. stannous sulfate + copper Alpha/Beta Decay: U92238 Undergoes decay and becomes Th90234 Undergoes decay and becomes Undergoes decay and becomes Undergoes decay and becomes Undergoes decay and becomes Undergoes decay and becomes Rn86222 Undergoes decay and becomes Undergoes decay and becomes Undergoes decay and becomes Undergoes decay and becomes Undergoes decay and becomes Undergoes decay and becomes Bi83210 Undergoes decay and becomes Undergoes decay and becomes Which is stable. Half-Life Calculations: 1. 64 g of a substance decays for 4 half-lives. How much of the original substance is left? 2. Plutonium-236 has a half-life of roughly 2 years. 32 g of it decay over a period of 8 years. How much of the original sample is left? 3. How long will it take 60 g of a substance to decay to 3.8 g if the half-life is 4.3 x 106 years? 4. Molybdenum-91 has a half-life of 15.49 minutes. After 40 minutes 1 g of it remains. What was the mass of the original sample? 5. 64 g of a substance decays to 1 g in 18 minutes. What is the half-life of the substance. CH 8 Review: 1. What things can you do to initiate or increase the rate of a reaction? 2. What is a catalyst? 3. Draw Lewis structures to illustrate the reaction on page 1 #12. 4. Why does alpha decay result in the loss in mass of 4 units and change in the identity of the element? 5. How are electrons produced during beta decay? 6. Why do you write water as HOH on the reactant side?