Water Pollution Any change in water quality that has a harmful effect on living organisms Any change that makes the water unsuitable for the use intended Chemical Biological Physical Thermal Safe Drinking Water 95% in developed countries have safe drinking water 74% in developing countries 1.4 billion lack safe water 9,300 die/day: contaminated water or lack of adequate hygiene Water Quality Tests and analyses of water samples Fecal coliform test Coliforms inhabit intestines of human and other animals Presence indicates water has been exposed to wastes that may carry pathogens Fecal Coliforms Not all coliforms cause disease Pass water through filter Place filter on culture medium Grow out bacteria for 24 hours Safe for drinking—no colonies in sample size of 100 ml Fecal Coliforms Safe for swimming ≤ 200 colonies/ 100 ml Raw sewage—several million colonies/100 ml High readings—determine source Look at different strains Identify source—humans, pets, livestock Dissolved Oxygen Related to amount of oxygen-demanding wastes Organic materials that are usually biodegradable by aerobic bacteria if there is enough dissolved oxygen in the water Biological Oxygen Demand Amount of dissolved oxygen consumed by aquatic decomposers Given volume of water at a certain temperature over a specific time period Chemical Analyses Presence and concentration of organic and inorganic chemicals that pollute water Various methods, various machines Sediment content—measure weight of sediment Suspended sediment—measure turbidity of sample Living organisms Indicator species: cattail, mussels, rockfish Plants and bottom dwellers or filter feeders Biosensors: bioengineered bacteria or fungi glow in presence of specific pollutant Sources Single source—point source Release at specific locations Drain pipes, sewage lines Easier to identify, monitor, regulate sources Sources Nonpoint sources—scattered and diffuse Not traced to single discharge site Acid deposition (rain), runoff of agricultural chemicals, urban runoff, lawns, golf courses Difficult to identify and control source Activities Producing Pollution Food production Sediment from cropland and rangelands Fertilizers Pesticides Bacteria from livestock Food processing wastes Excess salts Activities Producing Pollution Making things—industrial facilities and mining Industrial wastewater Acid deposition Sediments toxic chemical runoff Acid drainage Infectious Agents Typhoid, cholera, bacterial and amoebic dysentery, polio, hepatitis A, schistosomiasis—contaminated water Malaria, yellow fever, dengue fever, filariaisis—insects with aquatic larvae Infectious Waste Sewage treatment facilities—treat human waste Water treatment—chlorination and filtration Keep two streams separate Rehydration cocktail—clean water, sugar, salt Oxygen-Demanding Waste Oxygen content above 6 ppm supports game fish < 2ppm—worms, bacteria, fungi Add O2—turbulence and diffusion Deplete O2—respiration and chemical processes Oxygen-demanding Waste BOD COD DO—more related to organism survival, measures pollutants, but is also function of temperature and aeration Fresh Water Streams & OD Waste Effects on streams depends on volume, flow and temperature Combination of dilution and biodegradation—natural processes help Moderate pollution loads Fresh Water Streams & OD waste Oxygen sag curve—oxygen depleted as bacteria breaks pollutants down Hits populations with high O demands Recover downstream Factors include—waste volume, stream volume, flow rate, turbulence, temperature, pH Lakes and OD Wastes OD wastes more problematic Layers of lake allow little mixing Little flow Little discharge Agricultural chemicals, oils, lead, mercury, selenium Biomagnification Water Quality Oligotrophic—clear water, low biological activity Eutrophic—rich in organisms and organic materials Eutrophication Natural nutrient enrichment of lakes, nitrates and phosphates Increase phytoplankton -> increase fish Cultural eutrophication—increase from human activities Blooms of plant and bacterial growth May reduce productivity Cultural Eutrophication Decaying organisms depletes O If continuous, aerobic organisms die Anerobics take over Produce methane and hydrogen sulfide Eutrophication and Marine Systems Nearshore waters, bays, estuaries Dead zones—Mississippi River and Gulf of Mexico, Nile River and Meditteranian Sea Toxic tides—red tides, dinoflagellates, Pfiesteria piscisida Water-soluble Inorganic Chemicals Acids, toxic metals (lead, arsenic, selenium), salts (sodium chloride) and flourides Inorganic Chemicals Make fresh water unusable Skin cancers, spine and neck damage Nervous system damage Harm fish and aquatic life Lower crop yields Accelerate metal corrosion Inorganic Pollutants Weathering of rocks Industrial activities Metals—lead, mercury Non-metallic salts—selenium, arsenic Acids and bases—acid deposition Alkaline soils (with limestone)—help to neutralize Organic Chemicals Chemical, pharmaceuticals and plastics Oil, gasoline, cleaning solvents, detergents Nervous system damage Cancers Harm fish and wildlife Thermal Pollution Temperature change (+ or - ) alters water quality and ability to support life Water temperature changes alter ability to hold O Warmer temperature, less O Industrial and power plants use water to cool Thermal Pollution Restrictions on how much temperature change is allowed Animals attracted to warmth and food source Alter plant life Sediment Erosion rates increase as result of human activities Sediments fill lakes, alter shipping channels Cover eggs and bottom dwelling animals Blocked sunlight Sediment Rebuild wetlands Deposit nutrient laden silt Build land Groundwater Pollution So far, “easy” Groundwater—invisible but valuable Major source of drinking water Once contaminated, pollutants hard to remove Groundwater Pollution moves from site of introduction Forms plume Contaminated water may be used for drinking or agricultural water Groundwater Degradable waste not degraded Slow flow—no dilution or dispersion Lower dissolved O Lower numbers of aerobic decomposing bacteria Lower temperature Nondegradable waste not degraded Groundwater Pollution Identification, monitoring, remediation—expensive Municipal groundwater supplies contaminated—45% in U. S. Industrial waste ponds and lagoons leak Acids, wood preservatives, fuels Groundwater Pollution Leaking Underground Storage Tanks Historically 85% leakage Silicon Valley Leaking gasoline storage Cleanup costs--$10,000 to $250,000 per tank Groundwater Pollution Military facilities Wash facilities Fuel dumps Explosive washouts Etc. Groundwater Pollution Leaking landfills No liner or cracked liner Deep well injection Should not have migrated into groundwater Ocean Pollution Materials on land end up in ocean Oils, metals, solvents, sediments Solid waste—ends up in ocean After storm—mountains of waste end up in LA and San Gabriel Rivers, transported to ocean and beaches Ocean Pollution Federal law requires clean up before solid waste hits ocean Temporary dams, barricades Stay out of water for three days minimum before swimming Ocean Pollution—Oil Oil tanker spills—dramatic, ship impaled on rocks Intensive clean-up efforts and costs Greater impact overall—land-based activities, waste oil, washing and loading oil tankers & ships Ocean Pollution—Oil Effects depend on Type of oil: crude or refined Type of system: open ocean, bay, estuary Amount released Distance from shore Time of year Weather conditions Average water temperature Ocean currents Oil Pollution VOCs—immediately kill several types of organisms Tar-like globs float and cover ocean and shore birds Heavy oil sinks to bottom—smothers bottom-dwelling organisms Oil Pollution Rule of thumb for recovery time from exposure to large exposures— Crude oil—3 years Refined oil—10-15 years Water Pollution Control Source Reduction Don’t produce Don’t release Alter agriculture practice Nonpoint Source Agriculture—erosion, agriculture chemicals, animal waste Urban runoff—salts, oil rubber metals, fertilizer Construction sites—sediment, barriers and filters on catch basins Land disposal—leaking liners