Synthesis and Structural Characterization of
Palladium(II) Complex with (L)-3-Acetyl-5-benzyl-1-phenyl4,5-dihydro-1,2-4-triazin-6-one Oxime. Part II.
Accession number;00A0754663
Title;Synthesis and Structural Characterization of Palladium(II) Complex with (L)-3-Acetyl-5-benzyl-1-phenyl-4,5-dihydro-1,2-4-triazin-6one Oxime. Part II.
Author;ABUSHAMLEH A S(Hashemite Univ., Zarka, Jor) EL-ABADELAH M M(Univ. Jordan, Amman, Jor) MOESSMER C M(Univ.
Tuebingen, Tuebingen, Deu)
Journal Title;Heterocycles
Journal Code:S0966A
ISSN:0385-5414
VOL.53;NO.8;PAGE.1737-1744(2000)
Figure&Table&Reference;FIG.1, TBL.2, REF.8
Pub. Country;Japan
Language;English
Abstract;The synthesis and structural properties of the four-coordinate Pd(L)2(4), where L is chiral 3-acetyl-5-benzyl-1-phenyl-4,5dihydro-1,2,4-triazin-6-one oxime(2), are described. Deep-red needles of 4 crystallize in the hexagonal space group P61. The crystallographic
data reveal that the two oxime ligands are not symmetrically coordinated to Pd(II) ion, and the 4N-donor set comprises both oxime nitrogens,
an amidrazone nitrogen and a hydrazone nitrogen. 1H-, 13C-NMR and FD-MS spectral data of 4 are consistent with its X-Ray molecular
structure. (author abst.)