Material Safety Data Sheet
..
Commercial Product Name: metocid
Revision date: 21.06.2010
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND
OF THE COMPANY / UNDERTAKING
Commercial Product Name metocid
Company designation ÇATAK DİŞ DEPOSU
Fevzi Çakmak-2 sokak. No: 31/B Kızılay-ANKARA/TURKEY
Telephone: ++90/ (0) 312 2292718
Contact person Mr. ÇINAR ÇATAK
Use Manufacturing of dental prosthesis in a dental laboratory.
2. HAZARDS IDENTIFICATION
Classification and labelling according to Directive 67/548/EEC. Xn; R22 Xi; R36/38
ATP: 29
R-phrase(s)
R22: Harmful if swallowed.
R36/38: Irritating to eyes and skin.
Hazard symbols
Xn: Harmful
Particular information pertaining
specific risk for human / environment
Harmful if swallowed.
Irritating to eyes and skin.
Hazard precautions Process vapours can irritate airways, skin and eyes.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Danger of cutaneous absorption.
Wear suitable protective clothing, gloves and eye/face protection.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ingredients
Ingredient
ethanediol
sulphuric acid ...%
CAS No.
107-21-1
7664-93-9
EG-No.
203-473-3
231-639-5
Index-No.
603-027-00-1
016-020-00-8
Classification
Xn; R22
C; R35
Concentration
>= 30.0 %
6.0 - 11.0 %
Material Safety Data Sheet as per regulation (EC)
Commercial Product Name: metocid
Revision date: 21.06.2010
The classification was carried out for tested properties according to
the substance directive, annex VI, otherwise according
to the calculation procedure described in the preparation directive
4. FIRST AID MEASURES
General advice In case of accident or if you feel unwell, seek medical advice immediately
(show safety data sheet if possible).
Even in the case of a mere suspicion of poisoning a doctor must be consulted.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Move victim out of danger zone and lay down.
Put victim at rest, cover with a blanket and keep warm.
Take off immediately all contaminated clothing.
Symptoms of poisoning may develop several hours following exposure.
Victim should be under medical observation for at least 48 hours after exposure.
If inhaled When inhaling vapours, first symptoms of poisoning may develop hours later, so always consult a
doctor. In case of breathing difficulties administer oxygen. If victim is at risk of losing consciousness, position
and transport on their side. No mouth-to-mouth or mouth-to-nose resuscitation.Use respiratory bag or oxygen
resuscitation apparatus. In the case of lung irritation: Primary treatment using corticoide spray, eg. Auxiloson
spray, Pulmicort-dosage-spray. (Auxiloson and Pulmicort are registered trademarks). Move victim to fresh air.
Put victim at rest and keep warm.
In case of skin contact Remove/Take off immediately all contaminated clothing.
After contact with skin, wash immediately with plenty of water and soap.
In case of prolonged or frequently repeated skin contact: Immediately get medical attention.
Do not rinse with: Solvent / Thinner. Alcohol.
In case of eye contact Immediately get medical attention.
In case of contact with eyes, rinse immediately with plenty of flowing water for 10 to 15 minutes holding eyelids
apart.
Protect the eye that is not injured. If swallowed Immediately get medical attention.
Do not induce vomiting. Let water be swallowed in little sips.
Material Safety Data Sheet as per regulation (EC)
Commercial Product Name: metocid
Revision date: 21.06.2010
Rinse mouth thoroughly with water.
Milk or fat oils and are strongly contraindicated.
Notes to physician First Aid, decontamination, treatment of symptoms.
Hazards: Following decontamination of the skin, pain treatment and shock prophylaxis.
Process vapours can irritate airways, skin and eyes. Danger of poisoning when in contact with mucous
membrane. It can take hours before symptoms of poisoning show up following exposure.
Symptoms: unconsciousness. Impaired consciousness. Depression of the central nervous system. vomiting.
Coughing. Narcosis condition. Intoxication. Dizziness. Liver and kidney damage.
Treatment: In case of contact with eyes, rinse immediately with plenty of flowing
water for 10 to 15 minutes holding eyelids apart. In case of skin contact, wash immediately with large quantities
of water/polyethylene glycol 400 (Roticlean). Treat skin and mucous membrane with antihistermine and cortison
preparation.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media Carbon dioxide (CO2). Extinguishing powder. Water fog. alcohol resistant foam.
In case of major fire and large quantities: Water fog. alcohol resistant foam.
Extinguishing media which must not be used for safety reasons
High power water jet.
Special exposure hazards arising from the substance or preparation
itself, its combustion products, or released gases
The product is hardly ignitable. Vapours are heavier than air and will spread at floor level.
In case of fire and/or explosion do not breathe fumes.
Use water spray/stream to protect personnel and to cool endangered containers.
Can be released in case of fire: Sulfur oxides Sulphuric acid and sulphurous
acid. Possibly extensive generation of hydrogen on contact with amphoteric
metals (e.g. aluminium, lead, zinc) (explosive hazard!). Special protective equipment for
firefighting Protective respiration apparatus not using surrounding air (breathing apparatus)
Special protective equipment for fire-fighters: Full protective suit. Additional information on firefighting
Use water spray/stream to protect personnel and to cool endangered containers.
Use a water spray jet to knock down vapours/gases/mists.
Do not allow to enter into soil/subsoil. Do not empty into drains or the aquatic environment.
Material Safety Data Sheet as per regulation (EC)
Commercial Product Name: metocid
Revision date: 21.06.2010
6. HANDLING AND STORAGE
Advice on safe handling Keep container tightly closed.
Use only in well-ventilated areas. Avoid contact with skin and eyes.
Do not breathe gas/fumes/vapour/spray. Wear suitable protective clothing, gloves and eye/face protection.
Advice on protection against fire and explosion
The product is hardly ignitable. Keep away from sources of ignition - No smoking.
Storage space and container requirements
Store only in original container.
Keep container tightly closed in a cool, well-ventilated place.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
The floor should be leak tight, jointless and not absorbent.
Hints on storage assembly Keep away from food, drink and animal feedingstuffs.
Material Safety Data Sheet as per regulation (EC)
Commercial Product Name: metocid
Revision date: 21.06.2010
Do not store together with: Very toxic. Toxic. Oxidizing. Highly flammable.
(highly-)explosive materials radioactive materials self-igniting
materials Highly flammable. Storage specifications Keep away from heat/sparks/open flames/hot surfaces. - No
smoking. Keep cool. Protect from sunlight.
Specific use(s) Notice the directions for use on the label.
7. PHYSICAL AND CHEMICAL PROPERTIES
Form
Colour
Odour
Flash point / °C
Risk of explosion.
Vapour pressure
temperature:
Density
temperature:
Water solubility
temperature:
pH
pH:
Concentration:
liquid
yellowish
odourless
not applicable
In use, may form flammable/explosive vapour-air mixture.
0,13 g/cm³
(bei 20 °C)
1,2 g/ml
(bei 20 °C)
complete miscible
(bei 20 °C)
1
100 %