1 FACIES ANALYSIS AND PETROLEUM SYSTEM OF 2 SAN SAI OIL FIELD, FANG BASIN 3 4 Running head: FACIES ANALYSIS AND PETROLEUM SYSTEM OF SAN 5 SAI OIL FIELD, FANG BASIN 6 Peerawat Kongurai1 and Chongphan Chonglakmani2* 7 8 9 1,2 School of Geotechnology, Institute of Engineering, Suranaree University of 10 Technology, 111 University Avenue, Muang District, Nakhon Ratchasima 30000, 11 Thailand. 12 Email: p.kongurai@gmail.com 13 * Corresponding Author 14 Abstract 15 The San Sai oil field is an important oil field in the Fang Basin. 16 sedimentary facies and basin evolution have been interpreted using well data 17 incorporated with 2D seismic profiles. The study indicates that the Fang 18 Basin was subsided as a half-graben in the Late Eocene by regional plate 19 tectonism. The deposit is thicker westward toward the major fault. The 20 sedimentary sequence of the Fang Basin can be subdivided into two 21 formations which comprise five associated depositional environments. The 22 results of total organic carbon content (TOC), vitrinnite reflectance (%Ro), The 23 Rock-Eval pyrolysis and headspace gas analyses and the study of basin 24 modeling using PetroMod1D software are compiled and interpreted. They 25 indicate that source rocks of kerogen type II and III with 1.78 – 3.13%wt. 26 TOC were mature and generated mainly oil at 5,600 – 6,700 feet deep 27 (Middle Mae Sod Formation). Source rocks of kerogen type II and III with 28 2.07 – 39.07%wt. TOC locating deeper than 6,700 feet (Lower Mae Sod 29 Formation) were mature to late mature and generated mainly gas at this 30 level. 31 hydrocarbon generation took place in the Middle Miocene and the generated 32 oil and gas migrated through fractures and faults to accumulate in traps at 33 2,900-4,000 feet deep (Upper Mae Sod Formation). According to TTI modeling using PetroMod11.1D software, 34 35 Keywords: 36 Depositional environment Rift basin, Basin modeling, Petroleum geochemistry, 37 38 Introduction 39 Fang oil field was the first discovered field in Thailand and has been operated till 40 today by the Defense Energy Department, Ministry of Defense. It is located in 41 Fang district, Chiang Mai province of northern Thailand near Thai-Myanmar 42 border. In Thailand, hydrocarbons are found in pre-Tertiary and Tertiary basins. 43 Pre-Tertiary basins include the Khorat Plateau and its vicinity. Tertiary basins 44 can be found both onshore and offshore which include northern intermontane, the 45 central plain, the Gulf of Thailand and the Andaman Sea basins. The Tertiary 46 basins began to accumulate sediments in the Oligocene. Most of deposits are 47 accumulated in non-marine environment except the Andaman Sea sediments are 48 mainly marine. 49 50 Geological setting of the Fang Basin 51 The Fang Basin is one of the Cenozoic intermontane basins of northern Thailand 52 (Figure 1). It represents the flood plain of approximately 1 to 3 kilometers wide. 53 However, in the central part of the basin the flood plain increases in width to 6 54 kilometers. 55 longitudinal trunk stream. On the western and the southern sides of the basin the 56 inner hilly belt ends abruptly against a high rugged mountain range whose 57 summits rise about 1,400 meters above the basin floor. The eastern margin is 58 lower elevated area. Presumably, the eastern margin is geomorphological more 59 mature than that of the western one (Kaewsang, 1987). The geology of the Fang 60 Basin and the adjacent areas (Figure 2a and 2b) were previously studied by 61 numerous workers, namely, Dutescu et al (1980), Bunopas and Vella (1983), 62 Braun and Hahn (1976), Settakul (1985) and etc. The basin is located on the 63 western side of the Sukhothai Fold Belt, which comprises Paleozoic to Triassic 64 strata and volcanic rocks that were accumulated on the eastern margin of the 65 Shan-Thai Craton prior to the Indosinian orogeny. This fold belt is complex and 66 trends north and northeast-southwest. These rocks were uplifted, deformed and 67 intruded by granite during the collision of the Indochina and the Shan-Thai 68 Cratons (Bunopas and Vella, 1983). This flood plain is bisected by the Mae Fang River which is a The Fang Basin was formed in early 69 Paleogene by reactivation of these structures as the result of the Himalayan 70 Orogeny. 71 Cenozoic rocks and sediments consist of shale, sandstone, conglomerate, sand, 72 and gravel (Braun and Hahn, 1976). Settakul (1985) classified sediments and 73 rocks in the Fang Basin into two units. These units are the younger Mae Fang 74 Formation and the older Mae Sod Formation. The depositional environment in 75 the Tertiary time was fluvial-lacustrine and changed to fluvial and alluvial in 76 Quaternary time. 77 sandstone, claystone and shale. The Quaternary deposits are silt, clay, sand and 78 gravel and they occur as stream channel, terrace and alluvial fan deposits. These 79 sediments are covered by recent soil and lateritic sand. The pre-Tertiary basement 80 rocks consist of sedimentary, metamorphic and igneous rocks. On the western 81 side of the basin, the rocks are consisted of Cambrian-Permian sediments and the 82 Carboniferous granite. While on the eastern side, the rocks are Silurian-Devonian 83 and Jurassic sediments together with the Triassic granite. It was filled with rocks of Tertiary and Quaternary age. These The Tertiary rocks of the Fang Basin are conglomerate, 84 85 Structure of the Fang Basin 86 Zollner and Moller (1996) summarized the structural setting of Fang Basin and 87 adjacent basins in northern Thailand as a series of intramontane basin generally 88 trending NNE-SSW. These basins were formed in Early-Mid Tertiary time as 89 pull-apart basins in a transtensional regime followed by Pliocene to Pleistocene 90 compressional tectonics. Fang Basin is subdivided into three sub-basins separated 91 by basement ridges. It is composed of the Huai Pa Sang, the Huai Ngu and the Pa 92 Ngew sub-basins. The basin has an elongated rhombohedra outer shape. The 93 southern part is trending N-S and the northern part is deflected to a NE-SW 94 direction. The 3D seismic survey data indicates that the Fang Basin is bordered to 95 the west by a steep dipping NNE-SSW trending basin margin fault. Petersen 96 (2006) described the Fang Basin as an onshore Cenozoic rift-basin and is 2-4 km 97 deep. Approximately 800 bbls/day of crude oil is produced from the Fang field, 98 which in reality consists of a number of minor structures including the Ban Thi, 99 the Pong Nok, the San Sai, the Nong Yao and the Mae Soon. 100 101 Lithological Sequence 102 The sedimentary facies of the San Sai oil field can be divided into two formations. 103 The upper part is Mae Fang Formation and the lower part is Mae Sod Formation. 104 These two formations comprise five associated environment of deposition. The 105 typical lithological sequence of San Sai area which is compiled from the 106 subsurface data of seven drilled wells is shown in Figure 3 and the overall 107 lithological sequence is shown in Figure 4. 108 Mae Fang Formation 109 The Mae Fang Formation (Pleistocene to Recent in age), 2,500 feet thick, 110 is composed mainly of clay, coarse- to very coarse-grained sandstones, gravel and 111 carbonized woods which were deposited in fluvial environment. It overlies 112 unconformably on the Mae Sod Formation. The uppermost portion of the Mae 113 Fang Formation is represented by approximately 500 feet thick of mainly sand 114 with some thin layers of gravel, clay and trace of coal and thin top-soil. The sand 115 is generally light gray to dark gray, coarse- to very coarse-grained with some 116 granule and moderately sorted. The gravel is light gray to gray, with some coarse- 117 to very coarse-grained and poorly sorted sand. The clay is generally gray. The 118 lithological succession is composed of texturally and mineralogically immature 119 sand and gravel. Sand is poorly to moderately sorted with high angular grains. 120 The overall geometry is tabular or wedge shape which was deposited in a high 121 energy environment of braided stream system. 122 approximately 2,000 feet thick sequence of sand interbedded with shale. The sand 123 is light gray to dark gray, medium- to very coarse-grained and mostly well sorted. 124 The shale layers are 7 to 25 feet thick and are generally dark gray color. The 125 sequence of sand and clay is fining upward. 126 Mae Sod Formation Underlying the upper part is 127 The Mae Sod Formation, overlying unconformably on pre-Tertiary 128 basement, can be divided into three parts, i.e., A, B, and C which comprise four 129 depositional environments. 130 Sub-unit A (upper Mae Sod Formation). The unit can be divided into two 131 parts. The upper part consists of interbedded shale with sandstone. It is about 132 1,400 feet thick. Shale is characterized by gray to dark gray and brown color, 133 whereas the sandstone is generally light gray to gray color and is medium- to very 134 coarse-grained and mostly well sorted. Oil show is present in some sandstone 135 beds. The upper part is interpreted to be the marginal lacustrine facies (Late 136 Miocene to Pliocene in age). 137 The lower part is composed of thick shale with fine-grained sandstone 138 intercalations. The total thickness of this sequence is approximately 1,000 feet. 139 The shale is characterized by dark gray, black and dark brown color and with 140 some coal layers. It represents a shallow to deep lacustrine facies (Early Late 141 Miocene in age). 142 Sub-unit B (middle Mae Sod Formaion). The unit consists of extremely 143 thick dark gray shale, fine-grained sandstone and coal. 144 succession is interpreted to be deposited in low energy condition of fresh water 145 paleo-lake. The products accumulated in this environment are sedimentary rocks 146 of lacustrine facies (Oligocene in age). This lithological 147 Sub-unit C (lower Mae Sod Formation). The lower part of unit consists of 148 sandstone and coal bed interbedded with black shale. The upper part comprises 149 coal beds approximately 200 feet thick and some sandstone. 150 generally red and gray color, fine- to very coarse-grained with some layers of very 151 clean sand. It represents a marginal lacustrine facies (Late Eocene in age). Sandstone is 152 153 Structural Evolution 154 The Fang Basin can be divided into three stages of tectonic events based on 155 interpretation of 2D seismic profiles as shown in Figure 5. 156 The first stage or the initial stage (pre-rift) represents an early extensional 157 rifting phase formed by north-south normal faults in the Late Eocene (Figure 6A). 158 Sandstone is accumulated at the basin margin and predominantly claystone at the 159 basin center in the fluviatile environment. 160 The secondary stage (syn-rift) represents a rapid subsidence phase in the 161 Oligocene to Pliocene (Figure 6B). The basin accumulated mainly the lacustrine 162 shale facies. 163 The third stage (post-rift) represents a slow subsidence stage in the 164 Pleistocene (Figure 6C). The basin accumulated mainly the semi-consolidated 165 gravel, sand, silt and clay of the alluvial facies. 166 167 Petroleum system 168 Characteristics of sedimentary organic matter 169 In order to characterize source rock potential its maturity level, the cutting and 170 core samples of Well no. FA-SS-35-04 were analysed geochemically by the Core 171 Laboratories Malaysia SDN BHL (Ablins, 1992). 172 The whole section of Mae Sod Formation below the depth of 2,500 feet 173 was analyzed for the total organic carbon content (TOC). The values of TOC of 174 upper Mae Sod Formation, at depth of 2,500 to 5,900 feet, are in the range of 2.05 175 – 4.27%. The values of middle Mae Sod Formation, at depth 5,900 to 6,700 feet, 176 are in range of 1.78 – 3.13% . The values of lower Mae Sod Formation, at depth 177 of 6,700 to 9,100 feet, are in the range of 2.05 – 39.07% (Figure 7). According to 178 the headspace gas analysis as shown in Figures 8a and 8b, the result is consistent 179 with the TOC values which are fair to excellent. It indicates that the potential of 180 the whole section of Mae Sod Formation is a good source rock. 181 The modified Van Krevelen diagram comparing hydrogen index (mg HC/g TOC) 182 and oxygen index (mg HC/g TOC) data obtained from rock-eval pyrolysis 183 analysis is used for indicating the kerogen types of the source rock. The result of 184 Mae Sod Formation indicates that the organic matter of the upper Mae Sod 185 Formation is type I/II oil prone (Figure 9) and the middle and lower Mae Sod 186 Formation are type II/III of mixed oil and gas prone kerogen (Figure 10-11). 187 Thermal maturation 188 There are many criteria to indicate the thermal maturity level of source 189 rocks, such as, vitrinite reflectance (%Ro) (Figure 12a), Tmax (Figure 12b), result 190 of headspace gas analysis 191 Production Index (Figure 14a). (Figure 13a), iC4/nC4 ratio (Figure 13b) and 192 The upper Mae Sod Formation has Ro values in the range of 0.31 - 0.61%, 193 Tmax in the range of 428° – 447°C and PI in the range of 0.01 – 0.1. The middle 194 Mae Sod Formation has Ro values in the range of 0.67 – 0.76, Tmax in the range 195 of 447° – 458°C and PI in the range of 0.09 – 0.25. The lower Mae Sod has Ro 196 values in range of 0.81 – 1.31%, Tmax 448° - 491°C and PI 0.04 - 0.17. In 197 conclusion, the result of Ro indicates the source rock is early mature at a depth of 198 5,600 to 8,300 feet and is mature below 8,300 feet. The result of Tmax indicates 199 that the source rock is early mature at a depth of 4,000 to 4,700 feet, mature at 200 4,700 to 7,900 feet and late mature below 7,900 feet. The result of PI indicates 201 that most of source rock is immature and some samples below 6,400 to 7,600 feet 202 are mature. PI (Production Index) values which are in a range of 0.15 – 0.40 203 indicate that the source rock is mature for hydrocarbon generation (Peters and 204 Cassa, 1994). The result of gas wetness indicates that the source rock is early 205 mature between a depth of 4,160 to 4,600 feet, mature at 4,600 to 6,800 feet deep 206 and late mature at 6,800 feet to total depth. Finally, the result of iC4/nC4 ratio 207 indicates that the source rock is mature below a depth of 4,180 feet to total depth. 208 The result of burial history modeling from Well FA-SS-35-04 including TTI and 209 Ro data indicates that the source rock is mature in middle Mae Sod Formation 210 (Oligocene) below 5,900 feet and is over mature at lower Mae Sod formation 211 below 6,800 feet as shown in Figure 15-16. In conclusion the source rock were 212 mature and generate mainly oil at 5,600 – 6,700 feet. The source rock deeper than 213 6,700 feet were late mature and generate mainly gas. 214 Petroleum migration 215 The buoyancy force is the main driving force for petroleum migration 216 from the kitchen areas (approximately 7.7 km2.). The generated and expelled 217 hydrocarbon migrated through fractures and fault zone to the reservoir rock in the 218 combination of fault and structural traps. (Figure 17) 219 220 Conclusion 221 1. The correlation of seven seismic profiles and lithological data of seven 222 drilled wells indicates that the Fang Basin was subsided as a half-graben in the 223 Late Eocene. The sedimentary fills of the basin can be subdivided into two 224 formations which comprise five associated depositional environments. 225 2. The source rocks of middle Mae Sod Formation at 5,600 – 6,700 feet 226 deep are composed of 1.78 – 3.13%wt. TOC of type I/II oil prone kerogen and 227 were mature. The source rocks of kerogen Type II and III with 2.07 – 39.0%wt. 228 TOC are located deeper than 6,700 feet (lower Mae Sod Formation). They were 229 mature to late mature and generated mainly gas. 230 3. The migration of generated hydrocarbon took place in the Middle 231 Miocene through fractures or faults and was accumulated in traps at 2,900-4,000 232 feet deep. 233 234 Acknowledgement 235 The authors would like to express our sincere appreciation to the School of 236 Geotechnology, Suranaree University of Technology for all supports and also to 237 Department of Geology, Northern Petroleum Development Center, Defence 238 Energy Department for providing the geophysical and drilling data for use in this 239 study. In addition I am grateful to Schlumberger Oversea S.A. for supporting the 240 software “Petral and PetroMod”. 241 242 Reference 243 Ablins, P. (1992). A geochemical evaluation of well FA-WR-35-04 Fang Basin, 244 245 246 247 248 249 250 Thailand. Defence energy department. (Unpublished manuscript) Braun, E.V., and Hahn, L. (1976). Geological Map of Northern Thailand 1:250,000. Geological Mission in Thailand. Hannover. Bunopas, S., and Vella, P. (1983). Tectonic and Geological Evolution of Thailand. Workshop on Stratigraphic Correlation of Thailand and Malysia. Defence Energy Department, Exploration and Production Division. (1990). Seismic profile. Defence Energy Department. (Unpublished manuscript) 251 Defence Energy Department, Exploration and Production Division. (2004). 252 Geological 253 manuscript) Report. Defence Energy Department. (Unpublished 254 Dutescu, V., Enache, M., Pompilian, A.M. and Vasile, D. (1980). Consideration 255 on the present stage of the exploration and exploration activity for oil in 256 Fang Basin. Defence Energy Department. Thailand:38. 257 Khantaprab, C. and Kaewsang, K. (1987). Sedimentary Facies Analysis and 258 Petroleum Potential Assessment of the Cenozoic Intermontane Fang Basin, 259 Department of Geology, Chulalongkorn University, Bangkok. 260 Kaewsang, K. (1978). Sedimentary facies analysis of some upper tertiary deposits 261 of Fang Basin, Changwat Chiang Mai. M.S. thesis, Chulalongkorn 262 University, Thailand. 263 Miall, A.D. (1982). Alluvial Sedimentary Basin : Tectonic Setting and Basin 264 Architecture. Sedimentation and Tectonic in Alluvial Basin. The 265 Geological Association of Canada Special Paper No.23, p. 1-34. 266 Morley, C. K., Charusiri, P. and Watkinson, I. (2011). Structural geology of 267 Thailand during the Cenozoic. (Ridd, M. F., A.J. Barber, and M.J. Crow. 268 eds.) The Geology of Thailand. Geological society, London. p. 273-334. 269 Peters, K.E. and Cassa, M.R. (1994). Applied source rockgeochemistry, in 270 Magoon, L.B. and Dow, W.G., eds. The petroleum system—From source 271 to trap: Tulsa, Okla., American Association of Petroleum Geologists 272 Memoir 60. p. 93-117. 273 Petersen, H. I., Foopatthanakamol, A. and Ratanasthien, B. (2006). Petroleum 274 potential, thermal maturity and the oil window of oil shales and coals in 275 Cenozoic Rift Basin, Central and Northern Thailand. Journal of Petroleum 276 Geologgy, 29, p. 337-360. 277 278 Sethakul, B. (1985). Petroleum Geology of Fang Basin. Division of oil exploration and exploitation. Defence Energy Department. Chiang Mai. 279 Sweeney, J.J. and Burnham, A.K. (1990). Evaluation of a simple model of 280 vitrinite-reflectance based on chemical kinetics. AAPG BulL. Vol.74, p. 281 1559-1570. 282 283 Zollner, C. and Moller, N. (1996). 3D Seismics Interpretation Central Fang Basin, Thailand. Defence Energy Department.198. 284 285 Figure 1. Map showing the Tertiary basins of Thailand. The lines onshore are the 286 principal rivers draining Northern and Central Thailand and the Khorat Plateau 287 (Morley and Racey, 2011). 288 289 290 Figure 2(a). The geological map of Fang area (after Khantaprab and Keawsang, 1987). 291 292 293 Figure 2(b). The geological symbols of Fang area (after 294 Keawsang, 1987). Khantaprab and 295 296 297 Figure 3. Map showing study area with seismic lines and well locations. 298 299 300 Figure 4. Composite lithological sequence of the San Sai area. 301 302 303 Figure 5. Facies interpretation from 2D seismic profile line F2. 304 305 306 Figure 6. Basin evolution and sedimentary facies of the Fang Basin. 307 308 309 Figure 7. Total organic carbon content (TOC) in %wt. of the Mae Sod Formation. 310 311 312 Figure 8. Headspace gas analyses of the Mae Sod Formation (a) C1-C4 313 concentration and (b) C5+ concentration. 314 315 316 Figure 9. Plot of hydrogen index (HI) versus oxygen index (OI) of upper Mae Sod 317 Formation. 318 319 320 Figure 410. Plot of hydrogen index (HI) versus oxygen index (OI) of middle Mae Sod 321 Formation. 322 323 324 Figure 11. Plot of hydrogen index (HI) versus oxygen index (OI) of lower Mae Sod 325 Formation. 326 327 328 Figure 12. Maturity of source rock of Mae Sod Formation. (a) Ro (%) and (b) Tmax 329 (°C). 330 331 332 Figure 13. Headspace gas analysis for hydrocarbon maturation indicator (a) from 333 gas wetness. (b) from of iC4/nC4 ratio. 334 335 336 Figure 14. (a) Maturity of source rock of Mae Sod Formation from production 337 index. (b) hydrogen index. 338 339 Figure 15. Burial history at the San Sai oil field. The overlay shows organic matter 340 maturation calculated as time and temperature index model (TTI). 341 342 343 Figure 16. Burial history at the San Sai oil field. The overlay shows organic matter 344 maturation calculated as vitrinite reflectance (EASY%Ro, Sweeney and Burnham 345 1990). 346 347 348 Figure 17. Cross section of the San Sai oil field showing the migration pathway and oil accumulations.