Reflection and Transmission of Plane Waves from a Fluid-Porous Piezoelectric Solid Interface Anil K. Vashishth* and Vishakha Gupta Department of Mathematics Kurukshetra University Kurukshetra -136 119 INDIA Email: anil_vashishth@yahoo.co.in 1 ABSTRACT The reflection and transmission of plane waves from a fluid-porous piezoelectric solid interface is studied. The porous piezoelectric solid, having 6mm symmetry, is supposed to be filled with viscous fluid. The expressions for amplitude ratios and energy ratios corresponding to reflected wave and transmitted waves are derived analytically. The Christoffel equation of leaky wave propagating along the surface of porous piezoelectric solid is derived. The effects of angle of incidence, frequency, porosity, piezoelectric interaction and anisotropy on the reflected and transmitted energy ratios are studied numerically for a particular model BaTiO3 . The porous piezoelectric solid half space is assumed to be loaded with water. The effects of porosity and frequency on the leaky wave velocity are also studied. PACS numbers: 43.20.Gp, 43.38.Fx 2 I. INTRODUCTION The theory of electro-acoustic waves in piezoelectric solids poses numerous challenging problems that attract wide attention. Much of the interest in the subject of electro-acoustic waves is directed at the applications in the areas of signal processing, transduction and frequency control, where transmission and reflection of acoustic energy at boundary surfaces play an important role. A number of problems, which are related to phenomena of reflection and refraction of plane waves in piezoelectric materials, can be found in the texts1-3. In the analysis of the reflection of plane electro-acoustic waves at the boundary of a piezoelectric half space, four partial waves are required in the reflection field so that the mechanical and electrical boundary conditions can be satisfied4. Recently, reflection studies5-7 at the boundaries of piezoelectric media have also been carried out. Knowledge and control of the reflection and transmission of ultrasonic waves at the boundary between piezoelectric materials and water are important problems in designing acoustic transducers, which in most of the cases are piezoelectric ceramics, for use in under water imaging8. Noorbehesht and Wade9 studied the reflection and transmission of plane elastic waves at the boundary between piezoelectric material and water. Nayfeh and Chien10-11 derived the analytical expressions for the reflected and transmitted amplitude ratios for the fluid-loaded piezoelectric plate and fluid-loaded piezoelectric half-space in order to study influence of piezoelectricity on such waves. 3 Wave propagation and reflection-transmission phenomena in viscous fluid in the presence of electric field have been dealt separately by many authors12-14. The electrohydrodynamic instability of a plane layer of dielectric fluid which is in hydrostatic equilibrium between two semi-infinite conducting fluids with surface charges in porous media was studied and dispersion relation was derived by Sayed15. Piezoelectric crystals find many applications in ultrasonic devices, such as resonators in electromechanical filters, sensors and ultrasonic delay lines in surface acoustic wave (SAW) devices. One of the most important problems in designing SAW devices is the observation and investigation of the properties of surface waves such as Rayleigh waves, leaky waves etc. The relative efficiency of excitation of piezoelectric surface waves can be judged from the piezoelectric surface velocities under different electrical boundary conditions16. Different laminated structures17-19 were analyzed for dispersion characteristics of leaky surface acoustic waves. Porous piezoelectric materials offer lower acoustic impedance, higher hydrostatic coefficients, higher piezoelectric sensitivity, lower density and stiffness than monolithic piezo-ceramics. The interest in porous piezo-ceramics has grown rapidly in the recent years with the demands from new fields of applications. Porous piezoelectric ceramics have shown their advantages on dense ceramics in many possible applications20-22. Use of piezoelectric effect in porous piezoelectric ceramic offers an original method for studying the coupling between the electric, mechanical, permeability and piezoelectric properties of porous systems. The effects of dynamic fluid compressibility and permeability on oil 4 filled porous piezoelectric ceramics23 were studied with PZT hydrophones. The bone tissue can accurately be characterized by a porous saturated piezoelectric model in which piezoelectric effect, porosity and the relative pore fluid motion are found as interrelated phenomena24. Different theoretical models25-26 were developed to study the porous piezoelectric ceramics and 0-3/3-3 connectivity piezoelectric composites. Gomez et al.27 made an experimental study on wave propagation in porous piezoelectric materials. Different experimental studies28-31, related to the manufacturing, synthesis and characterization of porous piezoelectric materials, have been presented. Gupta and Venkatesh32 developed a finite element model to study the effects of porosity on the electromechanical responses of porous piezoelectric materials. A micromechanics based method was developed to evaluate the performance of 1-3 piezoelectric composites with a porous non-piezoelectric matrix33. A survey of literature reveals that although a lot of experimental work has been done in the field of porous piezoelectric materials but theoretical work is much less, in comparison. Recently, Vashishth and Gupta34 derived the constitutive equations for porous piezoelectric materials using Biot theory and electric enthalpy density function. Wave propagation in porous piezoelectric materials, having 6mm symmetry, has been studied analytically by Vashishth and Gupta35. The effects of porosity, frequency and direction of propagation on the phase velocity, attenuation and polarization were studied therein. In this paper, the Christoffel equation for plane harmonic waves propagating in porous piezoelectric materials in a plane is derived in Section II. Porous piezoelectric solid is considered of the type 6mm and is supposed to be filled with a viscous fluid. Next, the 5 reflection and transmission of waves from fluid- porous piezoelectric solid interface is studied in Section III. The characteristic equation of leaky waves is obtained in Section IV. Finally, the effects of angle of incidence, frequency, porosity, anisotropy and piezoelectric interaction on the reflected and transmitted energy ratios are observed numerically for a particular model BaTiO3 in Section V. The variation of leaky wave velocity with the frequency is also studied. II. CHRISTOFFEL EQUATION Based on Biot theory for porous materials, the details of the constitutive equations for porous piezoelectric materials are given in the paper34 and these equations are given as ij cijkl kl mij * ekij Ek kij Ek* , * mij ij R * i Ei ei* Ei* , Di eikl kl i * ij E j Aij E *j , Di* ikl kl ei* * Aij E j ij* E*j . (1) where σ( ij ) / σ* ( *ij ) are the stress tensors acting on the solid/ fluid phase of porous aggregate. D( Di ), E( Ei ) / D* ( Di* ), E* ( Ei* ) are the electric displacement and electric field vectors for the solid/ fluid phase of porous bulk material respectively. ε( ij ) / ε* ( *ij ) are the strain tensors for the solid/fluid phase respectively. eijk , ij / ek* , ij* are the piezoelectric and dielectric constants for the solid/ fluid phase respectively. mij ; ijk , k ; Aij are the material parameters which take into account the elastic; piezoelectric; dielectric coupling 6 between the two phases of porous aggregate. cijkl are the elastic coefficients for the solid phase of porous aggregate. The elastic constant R measures the pressure to be exerted on fluid to push its unit volume into the porous matrix. For an infinitesimal deformation, the elastic strain components ij and * are related to the components of mechanical displacements u (ui ) and U (Ui ) respectively as 1 2 ij (ui , j u j , i ), * U i , i . The electric field vectors (2) E and E* are related to the electric potentials and * respectively as E , E* * . (3) The equations of motion in x1 x3 plane, in the absence of body forces and free charge density, are34 .σ = ρ11 u + ρ12 U + b ( u - U* ) , .σ* = ρ12 u + ρ 22 U b ( u - U* ) , .D = 0 , .D* = 0 , (i, j 1,3) . (4) Here ρ11 ( ij11 ), ρ12 ( ij12 ) and ρ22 ( ij22 ) are dynamical coefficients which depend upon the porosity ( f ), density of porous aggregate ( ), pore fluid density ( * ) and the inertial coupling parameters. The dissipation tensor b(bij ) steers the effect of wave frequency ( ), fluid viscosity ( ), solid-matrix permeability ij ) and the porosity. The dissipation tensor b 36 is 7 b f 2 χ -1 , for low frequency waves where 0 fc 0.15 . (5) For high frequency waves, is replaced by F ( ) , where F ( ) is a complex function of frequency and is given by F ( ) 1 tanh( ) , 3 (1 tanh( ) ) (6) and 6 0 * / f . where 0 is the norm of the permeability matrix. Following Biot theory37, the complex function F ( ) , in term of non-dimensional parameter 8 8 tanh fc fc 1 F ( ) 3 8 8 1 tanh fc fc , can be written as fc , where f c is the Biot characteristic frequency. Consider a harmonic plane wave propagating in x1 x3 plane at a given angular frequency ( ), the associated physical quantities can be expressed as 1 (uk , U k , , * ) ( Bk , Fk , G, H ) exp ( ( x1 q x3 t )) , c ( k =1, 3), (7) where q is unknown slowness parameter. c is the apparent phase velocity given by c v sin , (8) where v is the phase velocity of wave propagating in x1 x3 plane, along a direction making an angle with x3 axis. ( B1 , B3 , F1 , F3 , G, H ) are the amplitudes associated with the harmonic waves. 8 The equation (4), along with the equations (1) and (7), reduces to a system ΓS 0, (9) where S [ B1 , B3 , F1 , F3 , G, H ] T and Γ is a symmetric matrix whose elements are listed in the Appendix A. This system is consistent if det(Γ) 0 . (10) This leads to T1q10 T2 q8 T3q 6 T4 q 4 T5 q 2 T6 0 . (11) The coefficients T j ( j 1, 2,.., 6) are given in the Appendix B. q1 , q3 , q5 , q7 and q9 correspond to the roots whose imaginary part are positive and q2 , q4 , q6 , q8 and q10 to those whose imaginary part are negative. Here, q1 , q3 correspond to the electric potential component wave modes and q5 , q7 and q9 correspond to the propagating quasi P1 mode, quasi S1 mode and quasi P2 mode. For each qi (i 1, 2,..,10) , the corresponding amplitude ratios are defined as Wi B3i F F G H , U i 1i , Wi * 3i , i i , *i i . B1i B1i B1i B1i B1i (12) These can be written in terms of eigen solutions as Wi c(62 )qi c(61 )qi , Ui c(63 )qi c(61 ) qi , Wi* c(64 ) qi c(61 ) qi , i c(65 ) qi c(61 ) qi , *i c(66 ) qi c(61 ) qi , (13) where c(ij ) qi denotes the cofactor of ij corresponding to the eigen value qi . 9 The amplitudes ( B1 , B3 , F1 , F3 , G, H ) of the plane harmonic waves decrease as these waves progress in porous piezoelectric medium. The amplitudes of the plane waves propagating in porous piezoelectric solid also depend on the frequency. The formal solution for the mechanical displacement and electrical potential becomes (u1 , u3 , U1 , U 3 , , * ) 10 (1,W ,U i 1 i * i , Wi* , i , *i ) B1i exp (i ( x1 qi x3 t )) . c (14) III. REFLECTION AND TRANSMISSION COEFFICIENTS A. AMPLITUDE RATIOS Let us consider a porous piezoelectric half-space, having 6mm symmetry, loaded with elastic fluid half space (FHS). The porous piezoelectric half-space (PPHS) occupies a region x3 0 and the fluid half-space occupies a region x3 0 . A plane wave, making an angle with x3 axis, becomes incident at the interface. This wave results in one reflected wave in FHS and five transmitted modes in PPHS. The transmitted wave modes are represented by quasi P1 , quasi S1 and quasi P2 and the other two modes, represented by PE1 and PE2 , corresponding to electric potential wave modes. The formal solution for the mechanical displacements, electrical potentials, stress components and electric displacements, in porous piezoelectric half space, are (u1 , u3 ,U1 ,U 3 , , * ) (1, Wi , U i* , Wi* , i , *i ) B1i exp (i ( i x1 qi x3 t )) , c and 10 ( 31 , 33 , * , D3 , D3* ) i ( D1i , D3i , D4i , D5i , D6i ) B1i exp ( i ( i x1 qi x3 t )), (i 1,3,5, 7,9) c (15) where D1i , D3i , D4i , D5i and D6i are given in the Appendix C. The displacements and normal stress in the FHS can be written as (u1f , u3f ) 33f i (1,W p 1,2 p 1,2 f p ) U pf exp (i ( f cU pf exp (i ( x1 ( 1) p 1 q f x3 t )) , c x1 (1) p 1 q f x3 t )) , c (16) where W1 f q f c, W2f q f c, q f 1 c2 1 . c c 2f Here c f is the longitudinal incident wave velocity in fluid medium. p 1 for the incident wave and p 2 for the reflected wave. The boundary conditions at the interface x3 0 are (a) Mechanical Boundary Conditions (i) 33 * 33f , (ii) * f 33f , (iii) 13 0, (iv) (1 f ) u3 f U 3 u3f . (17) Here, dot represents the differentiation with respect to time. (b) Electrical (Free case) Boundary Conditions (v) D3 0 , 11 (vi) D3* 0 . (18) The equations (15)-(18), result into a non-homogeneous system AX B , (19) where X [ B11 , B13 , B15 , B17 , B19 ,U 2f ]T , B [0,0,0, f c , f f c, q f c]T U1f and elements of matrix A are given in the Appendix C. On solving system (19), the transmitted and reflected amplitude ratios are obtained as B1i 2 f c( dtr f dtr 1 ) , U1f A' Y Y1 and U 2f A' Y Y1 . U1f A' Y Y1 (20) where expressions for A' , Y , Y1 and dtr (r 1, 2,..,10) are given in the Appendix C. B. ENERGY RATIOS Distribution of energy between different reflected and transmitted waves is considered across a surface element of unit area at the interface x3 0 . Following Ikeda38 and Vashishth and Gupta34, the normal acoustic flux P in a porous piezoelectric solid is P ( 31 u1 33 u3 U 3 D3 D3* * ) . (21) The average energy flux of incident and reflected waves are 12 2 1 P I 2 q f f c 2 U1f , 2 and 2 1 P R 2 q f f c 2 U 2f . 2 (22) The average energy flux of transmitted waves are derived as 1 2 Ps 2 Re( D1s D3 sWs D4 sWs* D5 s i D6 s *s ) B1s , ( s 1, 2,..,5) . 2 (23) The energy ratios of the reflected and transmitted waves are defined as ER PR , PI Es Ps , PI ( s 1, 2,..,5). (24) Following Vashisth and Gogna39, the interaction energy ratios, which account for interaction between stress/electric potential field and mechanical/ electric displacement field of different transmitted waves, are described as Est Pst Pts , PI (25) where 1 Pst 2 Re[ D1s B1s B1t D3s B1s B1tWt D4 s B1s B1tWt * D5 s B1s B1t t D6 s B1s B1t *t ], 2 ( s, t 1, 2,..,5and s t ). (26) The energy is conserved if 5 E s 1 s Eint ER 1 , (27) 13 where Eint 5 E s , t 1 s t s t st is the resultant interaction energy between the transmitted waves. IV LEAKY WAVE EQUATION The expressions for reflection and transmission amplitude ratio coefficients contain, as a by product, the characteristic equation for leaky wave propagating along the surface of porous piezoelectric half space. The characteristic equation of leaky wave, obtained by equating denominator of reflection coefficient to zero, is given by A Y Y1 0 . (28) The equation (28) leads to T1' c3 T2' c 2 T3' c T4' 0 . (29) The coefficients Tl ' (l 1, 2,3, 4) are listed in the Appendix D. Out of three roots of Equation (29), the root having positive real part and negative imaginary part corresponds to the leaky wave velocity. The leaky wave velocity is denoted by vL . The equation (28) reduces to the characteristic equation A 0 when f 0 i.e. the characteristic equation of Rayleigh waves in porous piezoelectric solid half space. V NUMERICAL DISCUSSION The energy ratios for reflected and transmitted waves are calculated for a particular model BaTiO3 . The porous piezoelectric half space is loaded with water. The elastic, 14 dielectric, piezoelectric and dynamical coefficients, followed from Gupta and Vankatesh33 and Stoll and Kan40, are listed in the Table I and Table II. The energy ratios of reflected wave, transmitted waves and interaction energy coefficients are computed using the equations (24) - (27). The Fig. 1 shows the variation of energy ratios with the angle of incidence ( ) of compressional wave propagating in the fluid medium at frequency=1MHz. The energy ratios corresponding to reflected and transmitted waves are represented by ER and Es ( s 1, 2,..,5) respectively. The total interaction energy ratio between the transmitted waves is denoted by Eint . It is observed that before 13 , all the transmitted wave modes, namely PE1 , PE2 ,quasi P1 ,quasi S1 and quasi P2 , propagate in the PPHS and after 13 the transmitted quasi P1 wave mode is no longer excited. Between 13 and 31 , two modes i.e. quasi S1 and quasi P2 propagate in PPHS and after 31 , only quasi P2 mode is excited. The energy carried out by the quasi S1 and quasi P2 modes increase after the critical angle of transmitted quasi P1 mode. The energy carried out by the electric potential components PE1 and PE2 is very small. The contribution of interaction energy ratio between the transmitted waves is almost negligible except at 33 and 45 . In Fig. 1, we observe a dip in the amplitude of the reflection coefficient at a polar angle corresponding to a single quasi P2 wave mode excitation in PPHS medium. At this angle of incidence there is almost mode conversion from the low impedance fluid medium to high impedance solid medium. For a compressional wave, incident from the fluid medium, there are three critical angles 1 13 , 2 31 and 3 41 corresponding to 15 transmitted P1 wave, S1 wave and P2 wave respectively in porous piezoelectric half space. Beyond the third critical angle i.e. 41 , the incident wave is totally reflected and energy reflection coefficient equals unity. In the case of perfect elastic medium i.e. for a lossless medium, transmitted wave decays with distance from the interface for supercritical incidence ( Krebes41 ). However, for a medium with loss, it is possible to have transmitted waves whose amplitude grows with distance from the interface for some angles of incidence beyond critical angle as in viscoelasticity, critical angles for transmitted wave are isolated (Stoll and Kan40, Krebes41). For anelastic reflection-refraction problems, contrasts in anelastic absorption at a boundary give rise to inhomogeneous waves for all angles of incidence as opposed to the elastic reflection-refraction problems where inhomogeneous wave exist only beyond critical angles (Borcherdt et al.42). In the present paper, the dissipation due to the viscous coupling between the fluid phase and the solid phase motions is considered which is small, in general, in comparison to the viscoelastic dissipation of the skeleton frame (Rasolofosaon43, Vashishth and Sharma44). The major portion of incident energy is reflected back which signifies the fact that the transmitting medium is much denser. The results are in agreement with the law of conservation of energy. There is no null in the reflection coefficient which reveals the effect of anisotropy (Ankan et al.45 ). 16 Figure 1 Variation of Reflected and Transmitted energy ratios with the angle of incidence ( ); (i) Reflected wave, (ii) Transmitted PE1, (iii) Transmitted PE2, (iv) Transmitted (vi) Transmitted P1 , (v) Transmitted S1 , P2 , (vii) Interaction energy; 1MHz , f 0.2 . 17 Figure 2 Variation of Reflected and Transmitted energy ratios with the angle of incidence ( ); (i) Reflected wave, (ii) Transmitted PE1, (iii) Transmitted PE2, (iv) Transmitted (vi) Transmitted P1 , (v) Transmitted S1 , P2 , (vii) Interaction energy; 10MHz , f 0.2 . 18 Figure 3 Variation of Reflected and Transmitted energy ratios with the angle of incidence ( ); (i) Reflected wave, (ii) Transmitted PE1, (iii) Transmitted PE2, (iv) Transmitted (vi) Transmitted P1 , (v) Transmitted S1 , P2 , (vii) Interaction energy; 100MHz , f 0.2 . Figs. 2 and 3 depict the variation of energy ratios with the angle of incidence at frequency =10MHz and 100MHz respectively. Comparison of Figs. 1-3 shows that the kinks in the energy ratios corresponding to P1 and S1 waves beyond their corresponding critical angle disappear as the frequency increases. It is observed that at frequency =100 MHz, the P1 and S1 waves become evanescent beyond their respective critical angles. The energy ratio corresponding to PE1 and PE2 modes decreases with the increase in frequency. 19 The effects of porosity on the variation of reflected and transmitted energy ratios with the angle of incidence are depicted in Figs. 4 and 5. Fig. 4 shows that the energy carried out by the reflected wave decreases as the porosity increases. The porosity does not affect the value of critical angles. It is observed that the energy ratio corresponding to P2 wave increases with increase in porosity while that corresponding to other transmitted modes in porous piezoelectric solid half space decreases (Fig. 5). The resultant interaction energy ratio also increases with porosity (Fig. 5). It is also observed that the energy flux once again appears to occur in quasi P1 , S1 and P2 wave modes transmitted into PPHS after the critical angle as the porosity increases. Figure 4 Variation of Reflected energy ratios with the angle of incidence ( ) for different porosity; 1MHz . 20 Figure 5 Variation of Transmitted energy ratios with the angle of incidence ( ) for different porosity; (i) Transmitted energy P1 , (ii) Transmitted energy S1 , (iii) Transmitted energy P2 , (iv) Transmitted energy PE1, (v) Transmitted energy PE2, (vi) Interaction energy; 1MHz . Next we will observe the effects of piezoelectricity and anisotropy on the variation of reflected energy ratio with the angle of incidence. The elastic and other coefficients for transversely isotropic and isotropic non-piezoelectric porous material are listed in the Table III and IV respectively. The results are computed for three data sets: Set1 = The values of the elastic, piezoelectric, dielectric and dynamic coefficients as given in the Table I and Table II for porous piezoelectric materials; represented by solid curves. 21 Set2 = The values of the elastic and dynamic coefficients as given in the Table III and Table II for non-piezoelectric porous materials; represented by dotted curves. Set3 = The values of the elastic and dynamic coefficients as given in the Table IV for isotropic porous materials; represented by dashed curves. It is observed that, in the absence of piezo-electric interaction and anisotropy, a sharp dip occurs at 28 which corresponds to the excitation of surface mode (see dashed curve, Fig. 6(i)). A minimum in the reflection coefficient at 28 also signifies the fact that for such an angle of incidence, a large amount of incident energy is transmitted into the porous piezoelectric solid. In the absence of piezoelectricity, there are four modes in the transmitting medium instead of six, as expected theoretically also. Comparison of solid and dotted curves reveals that the critical angle corresponding to S1 wave is shifted due to piezoelectric interaction while critical angle corresponding to P1 and P2 waves remains unaffected (Fig. 6 (ii-iv)). In the absence of piezoelectric effect, transmission coefficients of P1 and S1 phase change towards lower side. 22 Figure 6 Variation of Reflected and Transmitted energy ratios with the angle of incidence ( ); (i) Reflected wave, (ii) Transmitted P1 , (iii) Transmitted S1 , (iv) Transmitted P2 ; 1MHz , f 0.2 . The effect of porosity on the variation of leaky wave velocity ( vL ) with the frequency ( ) is depicted in the Fig. 7. The leaky wave velocity decreases with increase in frequency and increases with increase in porosity. Figure 7 Variation of Leaky wave velocity ( vL ) with frequency ( ) for different porosity; 50 . 23 VI CONCLUSION The reflection and transmission of waves from an interface separating the fluid half space and porous piezoelectric half space is studied in the present paper. The problem studied in present paper is of significant practical interest, since reflection and transmission of ultrasonic waves at the boundary between porous piezoelectric materials and water is an important problem in designing acoustic transducers for use in underwater imaging. The analytical expressions for reflected and transmitted amplitude and energy ratios are derived. The incident wave is totally reflected and energy reflection coefficient equals unity after 41 . The resultant interaction energy flux and energy flux corresponding to electric potential wave modes are less significant in comparison to those of propagating quasi P1 , quasi S1 and quasi P2 modes. The results are in agreement with the law of conservation of energy. It is also observed that the mode conversion occurs at a waterporous piezoelectric medium interface. There is no null in the reflection coefficient as expected in case of transversely isotropy. The change in porosity and frequency does not affect significantly the value of critical angle. The critical angle corresponding to quasi S1 wave is shifted when piezoelectric effect is neglected. The dispersion equation of leaky waves in transversely isotropic porous piezoelectric solid is also obtained from the expressions of amplitude ratios. The leaky wave velocity decreases with frequency while increases with porosity. Acknowledgement 24 The second author is grateful to University Grant Commission (Grant No. f.no.8(42)/2010 (MRP/NRCB)) for providing financial support for this work. Appendix A 11 c11 / c 2 c44 q 2 1111 ; 12 (c13 c44 )q / c ; 13 m11 / c 2 1112 ; 14 m11q / c ; 11 15 (e15 e31 ) q / c ; 16 ( 15 31 ) q / c ; 22 c44 / c 2 c33 q 2 33 ; 23 m33q / c ; 12 24 m33q 2 33 ; 25 e15 / c 2 e33q 2 ; 26 15 / c 2 33 q 2 ; 33 R / c 2 1122 ; 34 R q / c ; 35 3 q / c ; 36 e3* q / c ; 44 Rq 2 3322 ; 45 3 q 2 ; 46 e3* q 2 ; 55 11 / c 2 33 q 2 ; 56 A11 / c 2 A33 q 2 ; 66 11* / c 2 33* q 2 . where ρ11 ρ11 (i / ) b; ρ12 ρ11 (i / ) b; ρ22 ρ22 (i / ) b . Appendix B T1 1 y1 5 y10 9 y17 13 y26 , T2 2 y1 1 y2 6 y10 5 y11 10 y17 9 y18 14 y26 13 y27 , T3 3 y1 2 y2 1 y3 7 y10 6 y11 11 y17 10 y18 9 y19 15 y26 14 y27 13 y28 , T4 4 y1 3 y2 2 y3 8 y10 7 y11 12 y17 11 y18 10 y19 16 y26 15 y27 14 y28 , T5 4 y2 3 y3 12 y18 11 y19 8 y11 16 y27 15 y28 , T6 4 y3 12 y19 16 y28 . where 25 1 p1 y12 p4 y14 p7 y15 ; 2 p2 y12 p1 y13 p5 y14 p8 y15 p7 y16 ; 3 p3 y12 p2 y13 p6 y14 p9 y15 p8 y16 ; 4 p3 y13 p9 y16 ; 5 p1 y4 p4 y6 p7 y8 ; 6 p2 y4 p1 y5 p5 y6 p4 y7 p8 y8 p7 y9 ; 7 p3 y4 p2 y5 p6 y6 p5 y7 p9 y8 p8 y9 ; 8 p3 y5 p6 y7 p9 y9 ; 9 r1 y4 r4 y6 r7 y8 ; 10 r2 y4 r1 y5 r5 y6 r4 y7 r8 y8 r7 y9 ; 11 r3 y4 r2 y5 r6 y6 r5 y7 r9 y8 r8 y9 ; 12 r3 y5 r6 y7 r9 y9 ; 13 s1 y4 s4 y6 s7 y8 14 s2 y4 s1 y5 s5 y6 s4 y7 s8 y8 s7 y9 ; 15 s3 y4 s2 y5 s6 y6 s5 y7 s9 y8 s8 y9 16 s3 y5 s6 y7 s9 y9 . where p1 y22 y33 y24 y31 ; p2 y22 y34 y23 y33 y25 y31 y24 y32 ; p3 y23 y34 y25 y32 ; p4 y20 y33 y24 y29 ; p5 y20 y34 y21 y33 y24 y30 y25 y29 ; p6 y21 y34 y25 y30 ; p7 y20 y31 y22 y29 ; p8 y20 y32 y21 y31 y23 y29 y22 y30 ; p9 y21 y32 y23 y30 . r1 y14 y33 y15 y31 ; r2 y14 y34 y16 y31 y15 y32 ; r3 y16 y32 ; r4 y12 y33 y15 y29 ; r5 y12 y34 y13 y33 y16 y29 y15 y30 ; r6 y13 y34 y16 y30 ; r7 y12 y31 y14 y29 ; r8 y12 y32 y14 y30 y13 y31 ; r9 y13 y32 . s1 y14 y24 y15 y22 ; s2 y14 y25 y16 y22 y15 y23 ; s3 y16 y23 ; s4 y12 y24 y15 y20 s5 y12 y25 y13 y24 y16 y20 y15 y21 ; s6 y13 y25 y16 y21 ; s7 y12 y22 y14 y20 ; s8 y12 y23 y14 y21 y13 y22 ; s9 y13 y23 . where y1 e33 x1 33 x6 ; y2 (e15 x1 15 x6 ) / c 2 (c44 c13 ) / c e33 x2 33 x7 ; 11 y3 (e15 x2 15 x7 ) / c 2 ; y4 e33 x3 33 x8 c33 ; y5 (e15 x3 15 x8 c44 ) / c 2 33 ; 26 y6 e33 x4 33 x9 m33 / c ; y7 (e15 x4 15 x9 ) / c 2 ; y8 e33 x5 33 x10 m33 ; 12 y9 (e15 x5 15 x10 ) / c 2 33 ; y10 3 x1 e3* x6 ; y11 m11 / c 3 x2 e3* x7 ; 12 y12 m33 3 x3 e3* x8 ; y13 33 ; y14 R / c 3 x4 e3* x9 ; y15 R 3 x5 e3* x10 ; y16 3322 ; y17 x133 x6 A33 ; y18 ( x111 x6 A11 ) / c 2 (e15 e31 ) / c 33 x2 A33 x7 ; y19 ( x211 x7 A11 ) / c 2 ; y20 e33 x333 x8 A33 ; y21 (e15 x311 x8 A11 ) / c 2 ; y22 3 / c A33 x9 33 x4 ; y23 ( x411 x9 A11 ) / c 2 ; y24 x10 A33 x533 3 ; y25 ( x511 x10 A11 ) / c 2 ; y26 x1 A33 x633* ; y27 ( x1 A11 x611* ) / c 2 ( 15 31 ) / c x2 A33 x733* ; y28 ( x2 A11 x711* ) / c 2 ; y29 33 x3 A33 x833* ; y30 ( 15 x3 A11 x811* ) / c 2 ; y31 e3* / c 33* x9 A33 x4 ; y32 ( x4 A11 x911* ) / c 2 ; y33 x1033* x5 A33 e3* ; y34 ( x5 A11 x1011* ) / c 2 . where x1 c44 d c ; x2 (c11 / c2 1111 ) d c (m11 / c2 1112 ) c / 3 (m11 / c 2 1112 )(e15 e31 ) d c / 3 ; x3 (m33 (e15 e31 )d m33 ) / 3 (c13 c44 ) d x4 (m11 / c2 1112 ) d c ( R / c2 1122 ) c / 3 ( R / c2 1122 )(e15 e31 ) d c / 3 ; x5 ( R(e15 e31 )d R) / 3 m11 d ; x6 c44 3 d c / e3* ; x7 (c11 / c2 1111 ) d c 3 / e3* (m11 / c2 1112 )(e15 e31 ) d c / e3* ; x8 (c13 c44 ) d 3 / e3* m33 (e15 e31 ) d / e3* ; x9 (m11 / c2 1112 ) d c 3 / e3* ( R / c2 1122 )(e15 e31 ) d c / e3* ; x10 m11 d 3 / e3* R (e15 e31 ) d / e3* . 27 d e3* /(e3* (e15 e31 ) 3 ( 15 31 )) . Appendix C D1i c55 qi (c55Wi e15 i 15*i ) / c , D3i (c33 Wi m33 Wi * e33 i 33*i ) qi (c31 m33 U i* ) / c ,, D4i (m33 Wi RWi* 3 i e3* *i ) qi (m11 RUi* ) / c , D5i (e33 Wi 3 Wi * 33 i a33 *i ) qi (e31 3 U i* ) / c , D6i ( 33 Wi e3* Wi * a33 i 33* *i ) qi ( 31 e3* U i* ) / c . D53 D51 D D63 61 D11 D13 A D31 D41 D33 D43 D41 D43 (1 f )W1 (1 f )W3 fW * fW3* 1 D55 D65 D15 D35 D45 D45 (1 f )W5 D57 D67 D17 D37 D47 D47 (1 f )W7 D59 D69 D19 D39 D49 D49 (1 f )W9 fW5* fW7* fW9* f c f f c qf c 0 0 0 A' ( D31 D41 ) dt1 ( D33 D43 ) dt3 ( D35 D45 ) dt5 ( D37 D47 ) dt7 ( D39 D49 ) dt9 Y [((1 f ) W1 f W1* ) dt1 ((1 f ) W3 f W3* ) dt3 ((1 f )W5 f W5* ) dt5 ((1 f ) W7 f W7* ) dt7 ((1 f ) W9 f W9* ) dt9 ] f / q f Y1 [((1 f ) W1 f W1* ) dt2 ((1 f ) W3 f W3* ) dt4 ((1 f ) W5 f W5* ) dt6 ((1 f ) W7 f W7* ) dt8 ((1 f ) W9 f W9* ) dt10 ] f f / q f dt1 det([ D53 D55 D57 D59 ; D63 D65 D67 D69 ; D13 D15 D17 D19 ; D43 D45 D47 D49 ]) ; 28 dt3 det([ D51 D55 D57 D59 ; D61 D65 D67 D69 ; D11 D15 D17 D19 ; D41 D45 D47 D49 ]) ; dt5 det([ D51 D53 D57 D59 ; D61 D63 D67 D69 ; D11 D13 D17 D19 ; D41 D43 D47 D49 ]) ; dt7 det([ D51 D53 D55 D59 ; D61 D63 D65 D69 ; D11 D13 D15 D19 ; D41 D43 D45 D49 ]) ; dt9 det([ D51 D53 D55 D57 ; D61 D63 D65 D67 ; D11 D13 D15 D17 ; D41 D43 D45 D47 ]) ; dt2 det([ D53 D55 D57 D59 ; D63 D65 D67 D69 ; D13 D15 D17 D19 ; D43 D33 D45 D35 D47 D37 D49 D39 ]) dt4 det([ D51 D55 D57 D59 ; D61 D65 D67 D69 ; D11 D15 D17 D19 ; D41 D31 D45 D35 D47 D37 D49 D39 ]) dt6 det([ D51 D53 D57 D59 ; D61 D63 D67 D69 ; D11 D13 D17 D19 ; D41 D31 D43 D33 D47 D37 D49 D39 ]) dt8 det([ D51 D53 D55 D59 ; D61 D63 D65 D69 ; D11 D13 D15 D19 ; D41 D31 D43 D33 D45 D35 D49 D39 ]) dt10 det([ D51 D53 D55 D57 ; D61 D63 D65 D67 ; D11 D13 D15 D17 ; D41 D31 D43 D33 D45 D35 D47 D37 ]) Appendix D T1' s1' ( s5' s9' s6' s8' ) s2' ( s4' s9' s6' s7' ) s3' ( s4' s8' s7' s5' ); T2' s1' ( s5' t9' s9' t5' s8' t6' s6' t8' ) s2' (s4' t9' s9' t 4' s7' t6' s6' t7' ) s3' (s4' t8' s8' t 4' s7' t5' s5' t 7' ) t1' ( s5' s9' s8' s6' ) t2' ( s4' s9' s7' s6' ) t3' ( s4' s8' s7' s5' ); T3' t1' ( s5' t9' s9' t5' s8' t6' s6' t8' ) t 2' (s4' t9' s9' t 4' s7' t6' s6' t 7' ) t3' (s4' t8' s8' t 4' s7' t 5' s5' t 7' ) s1' (t5' t9' t8' t6' ) s2' (t4' t9' t7' t6' ) s3' (t4' t8' t7' t5' ); T4' t1' (t5' t9' t6' t8' ) t2' (t4' t9' t6' t7' ) t3' (t4' t8' t7' t5' ); where s1' p1' p6' p2' p5' ; s2' p1' p7' p3' p5' ; s3' p1' p8' p4' p5' ; s4' p1' p10' p2' p9' ; s5' p1' p11' p3' p9' ; s6' p1' p12' p4' p9' ; s7' p1' p14' p2' p13' ; s8' p1' p15' p3' p13' ; s9' p1' p16' p4' p13' ; t1' p1' r2' p2' r1' ; t2' p1' r3' p3' r1' ; t3' p1' r4' p4' r1' ; t4' p1' r6' p2' r5' ; t5' p1' r7' p3' r5' ; t6' p1' r8' p4' r5' ; t7' p1' r10' p2' r9' ; t8' p1' r11' p3' r9' ; t9' p1' r12' p4' r9' . where 29 r1' D51 y2' D53 y1' ; r2' D51 y3' D55 y1' ; r3' D51 y4' D57 y1' ; r4' D51 y5' D59 y1' ; r5' D51 ( f y7' (1 f ) y12' ) D53 ( f y6' (1 f ) y11' ); r6' D51 ( f y8' (1 f ) y13' ) D55 ( f y6' (1 f ) y11' ); r7' D51 ( f y9' (1 f ) y14' ) D57 ( f y6' (1 f ) y1' 1 ); r8' D51 ( f y0' (1 f ) y15' ) D59 ( f y6' (1 f ) y11' ); r9' ( D51 y12' D53 y11' ) q f ; r10' ( D51 y13' D55 y11' ) q f ; r11' ( D51 y14' D57 y11' ) q f ; r12' ( D51 y15' D59 y11' )q f . p1' D51 D63 D53 D61 ; p2' D51 D65 D55 D61 ; p3' D51D67 D57 D61 ; p4' D51D69 D59 D61 ; p5' D51 x2' D53 x1' ; p6' D51 x3' D55 x1' ; p7' D51 x4' D57 x1' ; p8' D51 x5' D59 x1' ; p9' D51 ( f x7' (1 f ) x12' ) D53 ( f x6' (1 f ) x11' ); p10' D51 ( f x8' (1 f ) x13' ) D55 ( f x6' (1 f ) x11' ); p11' D51 ( f x9' (1 f ) x14' ) D57 ( f x6' (1 f ) x11' ); p12' D51 ( f x10' (1 f ) x15' ) D59 ( f x6' (1 f ) x11' ); p13' D51 ( f f x17' q f x12' ) D53 ( f f x16' q f x11' ); p14' D51 ( f f x18' q f x13' ) D55 ( f f x16' q f x11' ); p15' D51 ( f f x19' q f x14' ) D57 ( f f x16' q f x11' ); ' p16' D51 ( f f x20 q f x15' ) D59 ( f f x16' q f x11' ). where x1' c55 q1 ; x2' c55 q3 ; x3' c55 q5 ; x4' c55 q7 ; x5' c55 q9 , 30 x6' (c33 W1 m33 W1* e33 1 33 1* ) q1 ; x7' (c33 W3 m33 W3* e33 3 33 *3 ) q3 ; x8' (c33 W5 m33 W5* e33 5 33 *5 ) q5 ; x9' (c33 W7 m33 W7* e33 7 33 *7 ) q7 ; x10' (c33 W9 m33 W9* e33 9 33 *9 ) q9 ; x11' (m33 W1 RW1* 3 1 e3* 1* ) q1 ; x12' (m33 W3 RW3* 3 3 e3* *3 ) q3 ; x13' (m33 W5 RW5* 3 5 e3* *5 ) q5 ; x14' (m33 W7 RW7* 3 7 e3* *7 ) q7 ; x15' (m33 W9 RW9* 3 9 e3* *9 ) q9 ; x16' (1 f )W1 fW1* ; x17' (1 f )W3 fW3* ; x18' (1 f )W5 fW5* ; x19' (1 f )W7 fW7* ; ' x20 (1 f )W9 fW9* . y1' (c55 W1 e15 1 15 1* ); y2' (c55 W3 e15 3 15 *3 ); y3' (c55 W5 e15 5 15 *5 ); y4' (c55 W7 e15 7 15 *7 ); y5' (c55 W9 e15 9 15 *9 ); y6' (c31 m33 U1* ); y7' (c31 m33 U 3* ); y8' (c31 m33 U 5* ); y9' (c31 m33 U 7* ); y10' (c31 m33 U 9* ); y11' (m11 RU1* ); y12' (m11 RU 3* ); y13' (m11 RU 5* ); y14' (m11 RU 7* ); y15' (m11 RU 9* ). 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Elastic constants Piezoelectric ( GPa ) ( C m2 ) ( nC Vm ) c11 150.4 e15 11.4 c12 65.63 e31 4.32 11 10.8 33 13.1 c13 65.94 e33 17.4 c33 145.5 m11 8.8 15 4.56 31 1.728 33 6.96 11* 11.8 m33 5.2 e3* 3.6 c44 43.86 R 20 constants Dielectric constants 33* 13.9 A11 12.8 A33 15.1 3 7.5 38 TABLE II: Dynamical coefficients, Permeability tensor and other parameters: Dynamical Coefficients Permeability tensor Parameters ( Kg / m3 ) ( m2 ) 1111 = 3762 11 = 2.5 10 10 ( Kg / m3 ) = 5700 11 33 = 3876 33 = 4.5 10 10 * ( Kg / m3 ) =1000 1112 = -855 f ( Kg / m3 ) = 1000 12 33 = -741 ( Ns / m 2) = 1 10 3 1122 = 3648 3322 = 3762 ( MHz ) 1 f 0.2 39 c f (m / s ) =1500 TABLE III Elastic and other coefficients for non-piezoelectric porous material e15 e31 e33 15 31 33 e3* 3 11 33 11* 33* A11 A33 0 Rest of the values are same as in the TABLE I. 40 TABLE IV Elastic and dynamic coefficients for isotropic porous material c13 c12 , c33 c11 , c66 c44 , m33 m11; 11 11 12 12 33 11 , 33 11 , 3322 1122 ; 33 11 Rests of the values are same as given in the TABLE II and TABLE III. 41 Figures Captions Figure 1 Variation of Reflected and Transmitted energy ratios with the angle of incidence ( ); (i) Reflected wave, (ii) Transmitted PE1, (iii) Transmitted PE2, (iv) Transmitted (vi) Transmitted P1 , (v) Transmitted S1 , P2 , (vii) Interaction energy; 1MHz , f 0.2 . Figure 2 Variation of Reflected and Transmitted energy ratios with the angle of incidence ( ); (i) Reflected wave, (ii) Transmitted PE1, (iii) Transmitted PE2, (iv) Transmitted (vi) Transmitted P1 , (v) Transmitted S1 , P2 , (vii) Interaction energy; 10MHz , f 0.2 . 42 Figure 3 Variation of Reflected and Transmitted energy ratios with the angle of incidence ( ); (i) Reflected wave, (ii) Transmitted PE1, (iii) Transmitted PE2, (iv) Transmitted (vi) Transmitted P1 , (v) Transmitted S1 , P2 , (vii) Interaction energy; 100MHz , f 0.2 . Figure 4 Variation of Reflected energy ratios with the angle of incidence ( ) for different porosity; 1MHz . Figure 5 Variation of Transmitted energy ratios with the angle of incidence ( ) for different porosity; (i) Transmitted energy P1 , (ii) Transmitted energy S1 , (iii) Transmitted energy P2 , (iv) Transmitted energy PE1, (v) Transmitted energy PE2, (vi) Interaction energy; 1MHz . Figure 6 Variation of Reflected and Transmitted energy ratios with the angle of incidence ( ); (i) Reflected wave, (ii) Transmitted P1 , (iii) Transmitted S1 , (iv) Transmitted P2 ; 1MHz , f 0.2 . Figure 7 Variation of Leaky wave velocity ( vL ) with frequency ( ) for different porosity; 50 . 43