West Lothian Council Lorna C. Webster 1 Plastics Read We already know that oil can be separated into many useful substances (eg petrol, diesel, kerosine) using fractional distillation but oil is also used as the raw material for making other substances. Oil is the raw material that is used to make plastics. Plastics are relatively new materials. They are man-made in the chemical industry. This means that they are synthetic materials. Since the invention of plastic around 1940 there has been an explosion of the variety of uses for different plastics. Glass, paper and metal have been replace by plastics in many uses eg all milk and juice bottles 50 years ago were made of glass but now these are mainly made from plastic. The table below shows the names of some plastics and what they are used for. Name of plastic Polythene Polyvinyl chloride (PVC) Polystyrene Perspex Formica nylon silicone Kevlar Bakelite Lorna C. Webster uses plastic bags, bin liners, washing-up bowls, pen casings window frames, clothing, guttering coffee cups, packaging material, ceiling tiles spectacle lenses, safety screens plates, tumblers, kitchen work tops clothing, ropes, toothbrushes waterproofing, plastic surgery Bullet proof vests, bikers clothing electric plugs and switches 2 Write a heading and try the work below. 1. What is the raw material that is used to make plastics? 2. Why are plastics called synthetic materials? 3. Think of a room in your house and make a list of all of the things that are made of plastic. 4. Use the table to make a list of the names of all of the plastics. 5. Choose four plastics from your list and draw a picture for each to show what they are used for. Properties of plastics Read Plastics have many useful properties. They are electrical insulators, are light, waterproof and airtight. Some plastics are flexible, some are tough and some are elastic. Many plastics can be melted and moulded into a huge variety of shapes. Different plastics are chosen for different uses depending on their properties. Plastics are used to cover electrical wire because they are electrical insulators and help prevent electrocution. A waterproof plastic would be needed for a shampoo container to stop the shampoo leaking out. An airtight plastic would be needed for a food container to help stop air and bacteria getting in. Plastics are good for making containers like bottles because they can be melted and moulded into shape. In the past glass did the same job as plastics but it is an advantage to use plastic now as plastic bottles are lighter. This makes them cheaper to transport than glass bottles. Plastics are durable. This means that they will last a long time. Nylon clothing lasts longer than cotton clothing but sometimes natural materials are better eg wool is warmer than nylon or polyester. Lorna C. Webster 3 Write a heading and try the work below. 1. Make a list of some properties of plastics. 2. Why is plastic good for making a shampoo bottle? 3. Why can plastic containers have lots of different shapes? 4. Why is it cheaper to transport washing-up liquid in plastic bottles than in glass bottles? 5. What does durable mean? 6. Write down one advantage that plastics have over natural materials for making clothes. 7. Write down one disadvantage of using plastics instead of natural materials for clothes. Lorna C. Webster 4 Problems with plastics Read Although plastics have many useful properties, their use can cause problems. Plastics are durable (last a long time) and are often very light. If you ever look at the street after lunchtime or after a concert or a football match you will often notice a lot of the litter that is left lying around is made of plastic. Plastic litter can cause problems for two main reasons. 1. Many plastics are light and this means that litter from plastic can be spread over a very large area by the wind. This means that it is more difficult and expensive to clean it up. 2. Most plastics are non-biodegradable. This means that they will not be rotted away by bacteria and will still be causing litter hundreds of years later. A paper bag would be better as it is biodegradable and will rot away because it will be eaten by bacteria. Even once the bin men have collected the plastic, it is very difficult to get rid of because if we try to burn plastics, toxic gases are made. One toxic gas that is made is called carbon monoxide. This gas starves the blood of oxygen and can kill. Apart from incinerating plastics we also try to dispose of them by burying them but even this does not solve the problem for long. Another problem with plastics is what they are made from. You already know that crude oil is running out fast. To make the oil last longer we need to find ways to use less plastics or to recycle the ones we already have but recycling can be difficult due Lorna C. Webster 5 to the large number of different kinds of plastic that we have. There are many scientists employed in research companies to find out about making plastics without using oil. Write a heading and try the work below in your jotter. 1. Imagine you are walking home after a concert or football match one night. Make a list of all the litter you might see and what it is made of. 2. Why is the litter from plastics often spread over large areas? 3. What affect does this have on the cost of cleaning it up? 4. What does non-biodegradable mean? 5. Why is the fact that plastics are non-biodegradable a problem? 6. What is the problem with burning plastics? 7. Give an example of the name of a toxic gas that is made when a plastic is burned and say why it can kill. 8. Describe what we can do to help make oil last longer. 9. Why is recycling plastics sometimes difficult? Lorna C. Webster 6 Types of plastics Read Although there are many different plastics, they can be split up into two groups. One group of plastics is called thermoplastics and the other group is called thermosetting. To investigate the difference between these types of plastic collect experiment card 2.56 and try the experiment. Write a heading and try the work below. 1. What are the two groups of plastic called? 2. What did you notice happened to the thermoplastic in the experiment? 3. What happened to the thermosetting plastic when it was heated? 4. Copy and complete the sentences below by choosing the correct answers. Thermoplastics are plastics that will soften/harden when they are heated. This means that they can/cannot be reshaped over and over again. Thermosetting plastics do/do not soften when they are heated. This means that they can/cannot be reshaped because they do/do not melt. Use of thermoplastics and thermosetting plastics Read Thermoplastics are plastics that will soften when heated and so can be melted and moulded into lots of different shapes. Most plastics are thermoplastics eg polythene, polypropene, polystyrene, perspex and nylon. Washing -up bowls, pens, bottles and other containers are made of thermoplastics as they can be easily moulded into different shapes. If a thermosplastic is heated up too much it will melt so thermoplastics are no good for making kettles or pot handles. Lorna C. Webster 7 Thermosetting plastics are plastics that do not melt when heated. Bakelite and formica are the names of two thermosetting plastics. They are often used to make pot handles, cooker controls, oven controls and kettles because they will not melt when these things get hot.. Thermosetting plastics are used to make electrical plugs and sockets because they are electrical insulators but also if a short circuit happens the plastic will not melt and so this helps stop someone being electrocuted. The two most important properties of thermosetting plastics is that they don't melt and they are electrical insulators. Write a heading and try the work below. 1. Make a list of some things that a thermoplastic would be used to make. 2. Why is it easy to make these shapes with a thermoplastic? 3. Make a list of the things that a thermosetting plastic would be used to make. 4. Why would a thermoplastic be no good for making a kettle? 5. Why is it important to use a thermosetting plastic for making electrical plugs and wires? 6. What are the two most important properties of thermosetting plastics? Lorna C. Webster 8 The chemistry of making plastics Read Plastics are very large chemical molecules called polymers. The polymers are made by joining lots of smaller molecules together. The small molecules that join up are called monomers. When a plastics is made the monomers are forced to join up to make a polymer the reaction is called polymerisation. + + + + polymer (plastic) monomers polymerisation reaction Write a heading and try the work below. 1. Are plastics large of small molecules? 2. What is the special name for a large molecule like a plastic? 3. How is a polymer made? 4. What are the small molecules that join up called? 5. When a plastic is made what is the name of the type of reaction. 6. Copy the diagram showing how monomers can join up to make a polymer molecule. 7. a) Collect ten paper clips - these are your monomers. b) Do a polymerisation reaction with the clips (join them together). c) Make a drawing of the polymer you have made. Lorna C. Webster 9 Naming plastics Read It is very easy to work out the name of a plastic if we know the name of the monomer that was used to make it. eg 1. If we use a monomer called ethene the plastic we can make will be called poly(ethene). eg 2. If we use a monomer called styrene, the plastic we can make will be called poly(styrene). It is also easy to work out the name of a monomer if we know the name of a plastic eg. the plastic that is called poly(propene) is made from monomers called propene. Write a heading and try the work below. 1. What is the name of the plastic that would be made from a monomer called a) ethene? b) styrene? 2. What is the name of the monomer that would be used to make the plastic called poly(propene)? 3. Copy and complete the table below. name of monomer vinyl chloride tetrafluoroethene name of plastic poly(vinyl chloride) poly(chloroethene) poly(propylene) Check with your teacher if you have time to make your own polymer (experiment card 2.54) Lorna C. Webster 10