Igneous Petrol. EPSC-423; Francis, 2013 Igneous Petrology LAB 9: Sifton Range Volcanic Complex Today’s lab is the first of a two parts examining the relationship between continental calc-alkaline volcanism and granitoid plutonism. We will use the Eocene Magmatic Province of the northern Canadian Cordillera as a case study. Today’s lab will focus on the volcanic rocks of the Sifton Volcanic Complex, while next week’s lab will examine granitoids along two transects of the associated Eocene plutons of the Coast Plutonic Belt. The Eocene magmatism of the northern Cordillera is particularly well suited to such an integrated study because uplift has exposed the deep core of the Coast Plutonic Belt (CPB), but shallow plutons and thick volcanic sequences are preserved along its eastern margin, and the SNORCLE Lithoprobe transect provides 3-D geophysical constraints. The final phase of extensive plutonism in the Coast Plutonic Belt occurred during the Early Tertiary, between 48 and 62 Ma, followed by uplift and erosion that has exposed the plutons to increasing depths from east to west across the belt. Volcanic activity was pervasive during the Eocene and remnant volcanic successions outcrop along the length of the western Intermontane Belt. In the southern Yukon, major Eocene volcanic centres occur at the Sifton Range, Mount Skukum, and Bennett Lake, and are all assigned to the Skukum Group; while in northern British Columbia coeval more effusive Eocene volcanics occur south of Atlin Lake and are referred to as the Sloko Group. The intensity of activity during the Eocene was probably linked to a change in the relative motion of the North American plate with respect to the Kula-Farallon plate, from dominantly orthogonal to oblique. The oblique northward motion of the Kula plate relative to North America imposed a clockwise torque on western North America, producing extension within the Coast and Omineca belts. The magmatism of the CPB is characterized by the effusion of basalt to andesite lavas, followed by the development of central volcanic complexes characterized by the explosive eruption of fragmental rocks from dacite to rhyolite in composition, along with minor felsic flows. These volcanic complexes are then intruded by coeval intrusive rocks ranging from granodiorites to granites, which are compositionally complimentary to the basalts and andesites. Crystal fraction models indicate that this relationship can be understood in terms of the interplay between increasing viscosity of a crystal-charged magma and the build up of water, which leads to stagnation and water saturation at the transition from andesite to dacite (Miskovic et al, 2003). 1 Igneous Petrol. EPSC-423; Francis, 2013 Sifton Range Geology: The rocks below come from a section through the Sifton Range Volcanic Complex, an erosion remnant of an Eocene central volcanic complex that occurs as a series of sub-horizontal sheets, underlain by a younger Eocene granitoid batholith. Six stratigraphc units can be defined on the basis of field occurrence and characteristics. The specimens within each stratigraphic unit are not identical, but are from different cooling units sampled stratigraphically across the stratigraphic unit. The total stratigraphic thickness is ~ 1600 meters. TASKS: 1. Plot the compositions of the Sifton volcanic rocks that you will study in thin section (PetLab9Sifton.xls) along with the more extensive Eocene volcanic databases (PetLab9Solo.xls and PetLab9VolcBSS.xls)) in a total alkalis versus SiO2 diagram. Examine both the hand specimen and thin sections, making note of volcanic textures that will enable you to characterize the type of cooling units found in each map sheet. Give the rocks of each map unit a 2 part name, the first based on the rock’s composition (fields in alkalis versus SiO2 diagram) and the second based on the probable type of cooling unit (eg. basalt flow, rhyolite tuff, etc.). Make note of the phenocryst phases and the range of SiO2 contents found in each map unit. 2 Igneous Petrol. EPSC-423; Francis, 2013 3 Igneous Petrol. EPSC-423; Francis, 2013 2. Plot both the compositions of the Sifton Volcanic Rocks in the Lab and those of the Eocene volcanic databases in a plot of K2O versus SiO2 to characterize the potassium content of the Eocene lavas. How does the variation of K2O with SiO2 in the Eocene suite compared to the dividing lines of the diagram? 3. Briefly describe the evolution of the Sifton Range Volcanic complex in terms of the variations in both composition and eruption style with stratigraphic position. 4 Igneous Petrol. EPSC-423; Francis, 2013 4. Plot the CIPW Norms in oxygen units for the Sifton volcanic rocks in this lab (assume XFe3+ = 0.20) and those of the Eocene databases (EoceneVolcNORM.xls) in a Quartz - Orthoclase - Plagioclase liquidus projection (Petrogeny’s Residua). Where do they fall with respect to the granite cotectic curve at 1 atm, and/or the granite eutectic and cotectic curves at 5 Kbs H2O, and comment on possible implications for the depth of fractionation of these felsic lavas. Calculate the diagram end-members as follows: Quartz = normative Quartz Orthoclase = 1.25 × normative Orthoclase Plag = normative An + (normative Ab – 0.25 × Or) 5 Igneous Petrol. EPSC-423; Francis, 2013 6 Igneous Petrol. EPSC-423; Francis, 2013 5. PA-3 is the most primitive lava in the Eocene Volcanic suite (PetLab10Sifton.xls). Assume that it is the parental magma to all the Eocene lavas. Model the closed system, liquid line of descent of PA-3 by crystal fractionation using AlphaMelts. Begin with dry conditions at 1 atm buffered on FMQ, and compare the liquid line of descent to the spectrum of Eocene volcanic compositions in a plot of Al versus Si. Adjust the pressure and water content in successive models in order to best reproduce the observed behaviour of Al with Si. How good is the best fit, and what does it tell us about the conditions of crystal fractionation for this volcanic suite (water content, pressure)? Compare the rise in K, Zr, Ba, and Rb with increasing SiO2 in the best AlphaMelts model to that observed in the Eocene lavas by plotting each element versus Si and superimposing the calculated liquid line of descent. Comment of the ability of closed-system crystal fractionation to reproduce the observed variations. Reference: Miskovic, A., and Francis, D.; 2006: Interaction between mantlederived and crustal calc-alkaline magmas in the petrogenesis of the Paleocene Sifton Range Volcanic Complex, Yukon, Canada. Lithos 87, 104-134. 7 Igneous Petrol. EPSC-423; Francis, 2013 Field Classification of Volcanic Rocks 8 Igneous Petrol. EPSC-423; Francis, 2013 9