Livre P. Braunstein, P. R. Raithby et L. A. Oro “Metal Clusters in Chemistry”, Wiley-VCH, 1999, 3 volumes, 1798 pages REVUES RECENTES P. BRAUNSTEIN Metal-metal and metal-ligand interactions in heterometallic complexes. New J. Chem. 1994, 18, 51-60. P. BRAUNSTEIN, J. ROSE Catalysis and Related Reactions with Compounds Containing Heteronuclear Metal-Metal Bonds in Comprehensive Organometallic Chemistry, Second Edition, E. W. Abel, F. G. A. Stone, G. Wilkinson (Eds.), Pergamon Press: Oxford 1995, Vol. 10, Chapter 7, p 351-385. P. BRAUNSTEIN Les clusters en chimie. L'Actualité Chimique 1996, 7, 75-85. P. BRAUNSTEIN, J. ROSÉ Heterometallic Clusters for Heterogeneous Catalysis in Catalysis by Di- and Polynuclear Metal Clusters, R. D. Adams, F. A. Cotton (Eds.), John Wiley, NewYork 1998, p 443-508. P. BRAUNSTEIN, J. ROSÉ Heterometallic Clusters in Catalysis in Metal Clusters in Chemistry, P. Braunstein, L. A. Oro and P. R. Raithby (Eds.); Wiley-VCH, Weinheim (Germany), 1999, Vol. 2, pp. 616-677. PUBLICATIONS RECENTES P. BRAUNSTEIN, J. R. GALSWORTHY, B. J. HENDAN, H. C. MARSMANN Reactions of thiol-functionalized silsesquioxanes with metal carbonyl clusters: syntheses and characterization of [Si8O12(Prn)7{(µ2-SC3H6)M3(µ-H)(CO)10}] (M = Ru, Os; Prn = C3H7), [Si8O12(Prn)6{(µ2-SC3H6)M3(µ-H)(CO)10}2] and [Si8O12(C3H6SH)x){(µ2-SC3H6)Ru3(µ-H)(CO)10}8-x] (x = 6, 0) J. Organomet. Chem. 1998, 551, 125-131. P. BRAUNSTEIN, G. E. HERBERICH, M. NEUSCHÜTZ, M. U. SCHMIDT, U. ENGLERT, P. LECANTE, A. MOSSET Heterometallic Borole Complexes of Iron and Gold. Organometallics 1998, 17, 2177-2182. I. BACHERT, P. BRAUNSTEIN, M. K. McCART, F. FABRIZI DE BIANI, F. LASCHI, P. ZANELLO, G. KICKELBICK, U. SCHUBERT Synthesis, Structure and Electrochemical Studies of the First Mixed-Metal Clusters with the P-N-P Assembling Ligands (Ph2P)2NH (dppa), (Ph2P)2N(CH3) (dppam) and (Ph2P)2N(CH2)3Si(OEt)3 (dppaSi). J. Organomet. Chem. 1999, 573, 47-59. R. BENDER, S.-E. BOUAOUD, P. BRAUNSTEIN, Y. DUSAUSOY, N. MERABET, J. RAYA, D. ROUAG Thermal C-P and C-H Cleavage in Coordinated Phosphines leading to Dinuclear Platinum Complexes and Contrasting Reactions with M(PPh3)+ (M = Cu, Ag, Au) and HgCl2. J. Chem. Soc., Dalton Trans. 1999, 735-741. P. BRAUNSTEIN, G.E. HERBERICH, M. NEUSCHÜTZ, M. U. SCHMIDT Cyano-Bridged Fe-CN-Pt-NC-Fe Chain Complexes. Structural and Spectroscopic Characterization of Four Isomers of [{5-(1-phenylborole)Fe(CO)2(µ-CN)}2Pt(PEt3)2]. J. Organomet. Chem. 1999, 580, 66-71. I. BACHERT, I. BARTUSSECK, P. BRAUNSTEIN, E. GUILLON, J. ROSÉ, G. KICKELBICK Synthesis of Co2Pd and MoPd2 mixed-metal clusters with the P-N-P assembling ligands (Ph2P)2NH (dppa) and (Ph2P)2NMe (dppaMe). Crystal structure of [Co2Pt(µ3-CO)(CO)6(µ-dppa)]. J. Organomet. Chem. 1999, 580, 257-264. Corrigendum du fait d’erreurs de l’imprimeur: J. Organomet. Chem. 1999, 588, 144-151. P. BRAUNSTEIN, U. ENGLERT, G. E. HERBERICH, M. NEUSCHÜTZ, M. U. SCHMIDT Heterometallic Complexes with Borole Ligands. J. Chem. Soc., Dalton Trans. 1999, 2807-2812. R. BENDER, P. BRAUNSTEIN, S.-E. BOUAOUD, N. MERABET, D. ROUAG, P. ZANELLO, M. FONTANI First Platinum Clusters Containing a Direct Pt-Si Bond; Molecular Structure of [Pt3{Si(OSiMe3}3}(µPPh2)3(PPh3)2 and Electrochemical Studies. New J. Chem. 1999, 23, 1045-1047. S. BOUHEROUR, P. BRAUNSTEIN, J. ROSÉ, L. TOUPET Metallosite Selectivity Studies in Reactions of Tetrahedral MCo 3 Carbonyl Clusters (M = Fe, Ru) with Cyclohexylphosphine. Skeletal Rearrangements Leading to Tri- and Pentanuclear Phosphinidene Clusters and Crystal Structures of RuCo4(µ4-PCy)(µ-CO)2(CO)11 and RuCo2(µ3-PCy)(CO)9. Organometallics 1999, 18, 4908-4915. P. KEMPGENS, J. RAYA, K. ELBAYED, P. GRANGER, J. ROSÉ, P. BRAUNSTEIN Theoretical Study of Two-Dimensional COSY Experiments for S = 7/2 Spins: Application to 59Co in the Tetrahedral Cluster HFeCo3(CO)11(PPh2H). J. Magn. Res. 2000, 142, 64-73. F. SCHWEYER, P. BRAUNSTEIN, C. ESTOURNÈS, J. GUILLE, H. KESSLER, J.-L. PAILLAUD, J. ROSÉ Metallic nanoparticles from heterometallic Co-Ru carbonyl clusters in mesoporous silica xerogels and MCM-41-type materials. Chem. Commun. 2000, 1271-1272. P. BRAUNSTEIN, B. OSWALD, A. TIRIPICCHIO, F. UGOZZOLI Carbonylcyanometalates as building blocks : heterometallic complexes containing Mn(µ-CN)M (M = Cu, Au, Ni, Pd or Pt), Mn(µ-CN)Pd(µ-dppm)2Mn and Mn(µ-CN)M(µ-dppm)2Pd((µ-NC)-Mn (M = Pt or Pd) chains of atoms and crystal structure of the mixed-metal cluster [Ru3{(µ3-NC)MnCp(CO)2}(µAuPPh3)(CO)10]. J. Chem. Soc., Dalton Trans. 2000, 2195-2203. P. BRAUNSTEIN, H.-P. KORMANN, W. MEYER-ZAIKA, R. PUGIN, G. SCHMID Strategies for the Anchoring of Metal Complexes, Clusters and Colloids Inside Nanoporous Alumina Membranes. Chem. Eur. J. 2000, 6, 4637-4646. C. ARCHAMBAULT, R. BENDER, P. BRAUNSTEIN, S.-E. BOUAOUD, D. ROUAG, S. GOLHEN, L. OUAHAB Unexpected bonding similarities between the bridging metalloligands [MoCp(CO) 3]- and [PtI(CO)2(PPh3)]- acting as 4-electron donors in metal clusters. Crystal structures of [Pt 2Mo(µ-CO)3(µPPh2)Cp(PPh3)2] and [Pt3(µ-CO)2(µ-PPh2)I(PPh3)3]. Chem. Commun. 2001, 849-850. P. BRAUNSTEIN, E. CURA, G. E. HERBERICH Heterometallic complexes and clusters with 2-boratanaphtalene ligands. J. Chem. Soc., Dalton Trans. 2001, 1754-1760. P. BRAUNSTEIN, J. DURAND, M. KNORR, C. STROHMANN Heterobimetallic Intermediates in Alkene Insertion Reactions into a Pd-acetyl Bond. Chem. Commun. 2001, 211-212. F. BALEGROUNE, P. BRAUNSTEIN, J. DURAND, T. FAURE, D. GRANDJEAN, M. KNORR, M. LANFRANCHI, C. MASSERA, X. MORISE, A. TIRIPICCHIO Iodo derivatives of Bimetallic Fe-Pd and Fe-Pt Complexes. Crystal Structures of [(OC)3Fe(µ-I)(µdppm)PdI], [(OC)3Fe{µ-Si(OMe)2(OMe)}(µ-dppa)PdI], and [(OC)3Fe{µ-Si(OMe)2(OMe})(µ-dppm)PdI]. Monatshefte für Chemie 2001, 132, 885-896. P. BRAUNSTEIN, M.J. CHETCUTI, R. WELTER Bimetallic-induced tail-to-tail dimerization and C-H activation for methyl acrylate. Chem. Commun. 2001, 2508-2509. P. BRAUNSTEIN, G. CLERC, X. MORISE Synthesis and Reactivity of Heterodinuclear Fe-Ni Complexes with a Bridging Alkoxysilyl Ligand. Crystal Structure of [(OC)3Fe{µ-Si(OMe)2(OMe)}(µ-dppm)NiMe]. Organometallics 2001, 20, 5036-5043. P. BRAUNSTEIN, M. J. CHETCUTI, R. WELTER Improved syntheses of the electronically unsaturated heterobimetallic complexes [(C5Me5)NiM(CO)3(-C5H5)] (M = Mo, W), and their use as cluster building blocks: X-ray structure of the chiral trimetallic cluster [FeNiMo(µ3-CO)(µ2-CO)(CO)5(-C5H5)-C5Me5)]. C.R. Chimie 2002, 5, 67-72. P. BRAUNSTEIN, C. GRAIFF, C. MASSERA, G. PREDIERI, J. ROSE, A. TIRIPICCHIO Reactivity of the Heterometallic clusters [HMCo3(CO)12] and [Et4N][MCo3(CO)12] (M = Fe, Ru) towards phosphine selenides, including selenium transfer. Crystal structures of [HRuCo 3(CO)7(µ-CO)3(µ-dppy)], [MCo2(µ3-Se)(CO)7(µ-dppy)] and [RuCo2(µ3-Se)(CO)7(µ-dppm)] [dppy = Ph2(2-C5H4N)P, dppm = Ph2PCH2PPh2]. Inorg. Chem. 2002, 41, 1372-1382. R. BENDER, P. BRAUNSTEIN, S.-E. BOUAOUD, D. ROUAG, P. D. HARVEY, S. GOLHEN, L. OUAHAB Bonding Behavior of Co(CO)3L (L = CO, PPh3) Building Blocks in Platinum-Cobalt Carbonyl Clusters. Inorg. Chem. 2002, 41, 1739-1746. C. ARCHAMBAULT, R. BENDER, P. BRAUNSTEIN, Y. DUSAUSOY Reactivity of Phosphido-Bridged Diplatinum Complexes towards Electrophiles: Synthesis of New Hydrides and Related Pt2Cu and Pt2Ag Clusters. Crystal Structures of [Pt2{µ-Cu(PPh3)}(µ-PPh2)(µ-oC6H4PPh2) (PPh3)2]PF6 and [Pt2(µ-H)(µ-PPh2)(OPOF2)(PPh3)3](PF6)·0.5CH2Cl2 J. Chem. Soc., Dalton Trans. 2002, 4084-4090. P. BRAUNSTEIN, G. CLERC, X. MORISE Cyclopropanation and Diels-Alder reactions catalyzed by the first heterobimetallic complexes with bridging phosphinooxazoline ligands New J. Chem. 2003, 27, 68-72. N. AUVRAY, P. BRAUNSTEIN, S. MATHUR, M. VEITH, H. SHEN, S. HÜFNER Thin Films by Metal Organic Deposition of Fe-Mo-S Molecular Clusters: Synthesis and Crystal Structure of [Cp2MoFe2(µ3-S)2(CO)6] New J. Chem. 2003, 27, 155-160. F. SCHWEYER-TIHAY, P. BRAUNSTEIN, C. ESTOURNÈS, J. L. GUILLE, B. LEBEAU, J.-L. PAILLAUD, M. RICHARD-PLOUET, J. ROSÉ Synthesis and Characterization of Supported Co2P Nanoparticles by Grafting of Molecular Clusters into Mesoporous Silica Matrices. Chem. Mater. 2003, 15, 57-62. P. BRAUNSTEIN, X. MORISE, M. BÉNARD, M.-M. ROHMER, R. WELTER A quasi-covalent metal-metal bond in an early-late heterobimetallic Ti-Pt complex stabilized by bridging and chelating phosphinoenolate ligands. Chem. Commun. 2003, 610-611. W. SCHUH, P. BRAUNSTEIN, R. WELTER Heterometallic metal-metal chain complexes as metalloligands C. R. Chimie, 2003, 6, 59-65. W. SCHUH, P. BRAUNSTEIN, M. BÉNARD, M.-M. ROHMER, R. WELTER An Unusual Dynamic Fe-Hg-Pd Cluster with a Palladium(0) Fragment Stabilized by d10-d10 Heterometallic Bonding. Angew. Chem. Int. Ed. 2003, 42, 2161-2164. CHOUALEB, J. ROSÉ, P. BRAUNSTEIN, R. WELTER Routes to Ruthenium-Cobalt Clusters and Dicobalt Complexes with New Alkoxysilyl- or SulfurFunctionalized Alkynes. X-ray structures of [NEt4][RuCo3(CO)10{4-22 HC2(CH2)2OC(O)NH(CH2)3Si(OEt)3}] and [Co2(CO)6{2- -HC2CH2NHC(O)NH(CH2)3Si(OEt)3}] Organometallics, 2003, 22, 2688-2693. A. CHOUALEB, P. BRAUNSTEIN, J. ROSÉ, S.-E. BOUAOUD, R. WELTER Reactions of Diphosphine-Stabilized Tetracobalt Carbonyl Clusters with –Si(OR)3-Functionalized Alkynes. Organometallics, 2003, 22, 4405-4417.