MATERIAL SAFETY DATA SHEET Ethofumesate 96%TC 1. IDENTIFICATION OF CHEMICAL PRODUCT AND COMPANY PRODUCT NAME: Ethofumesate 96%TC CHEMICAL NAME: (2-Ethoxy-3,3-dimethyl-2H-1-benzofuran-5-yl) methanesulfonate CHEMICAL FORMULA: C13H18O5S MOLECULAR WEIGHT: 286.3 USAGE: Herbicide MANUFACTURER & ADDRESS: Jadesheen Chemical Co., Ltd No. 123, Rd Qigang shizhuang, Lingang new city, Jiangyin (214446), P.R.China EMERGENCY PHONE NUMBER: 0086 2134096507 2. COMPOSITION/INFORMATION ON INGREDIENT Components Ethofumesate Inerts 3. CAS No. % 26225-79-6 96 - 4 HAZARD IDENTIFICATION N: Dangerous for the environment R51/53: Toxic to aquatic organism, may cause long-term adverse effects to the aquatic environment 4. FIRST AID MEASURES INHALATION: Move to fresh air. Obtain medical advice if at all worried SKIN CONTACT: Carefully remove contaminated clothing. Wash affected areas with soap and water. EYE CONTACT: Rinse thoroughly with plenty of water, also under the eyelids. Keep eye wide open while rinsing. Consult a physician SWALLOWED: Immediately offer water to drink. Do not induce vomiting without medical advice. If symptoms occur, get medical attention. 5. FIRE FIGHTING MEASURES FLASH POINT: 201°C EXTINGUISHING MEDIA: Carbon dioxide, foam, dry chemical powder or water spray 1/4 FIRE FIGHTING: If significant quantity of this product is involved in a fire, cal the fire brigade. There is little danger of a violent reaction or explosion if significant quantities of this product are involved in a fire. Recommended personal protective equipment is full fire kit and breathing apparatus.. 6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: Wear personal protective equipment ENVIRONMENTAL PRECAUTIONS: Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. METHODS FOR CLEANING UP: Clean up promptly by scoop or vacuum. Use approved industrial vacuum cleaner for removal. Shovel into suitable container for disposal. If spill area is on ground near valuable plants or trees, remove 5 cm of top soil after initial cleanup. 7. HANDLING AND STORAGE HANDLING: Provide appropriate exhaust ventilation at places where dust is formed. Wear personal protective equipment. STORAGE: Keep containers tightly closed in a dry, cool and well-ventilated place. Store in a place accessible by authorized persons only. Keep away from food, drink and animal feeding stuffs. Keep out of reach of children. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION EYE PROTECTION: Safety glasses with side-shields RESPIRATORY PROTECTION: Half mask with a particle filter P2. HYGINE MEASURES: Wash hands before breaks and immediately after handling the product. When using, do not eat, drink or smoke. For environmental protection remove and wash all contaminated protective equipment before re-use. Dispose of rinse water in accordance with local and national regulations. PROTECTIVE MEASURE: All chemical protective clothing should be visually inspected prior to use. Clothing and gloves should be replaced in case of chemical or physical damage or if contaminated. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: White crystalline powder Solubility in water: Insoluble Melting point: 69°C Boiling point: 409°C 10. STABILITY AND REACTIVITY 2/4 STABILITY: Stable at normal temperatures and pressures FIRE DECOMPOSITION: Carbon dioxide, Carbon monoxide, Sulfur oxides. 11. TOXICOLOGICAL INFORMATION ACUTE TOXICITY Oral: LD50=6400mg/kg (rat) DERMAL: LD50>1440mg/kg (Rat) 12. ECOLOGICAL INFORMATION Toxic to Birds: Slightly toxic Toxic to aquatic organisms: LC50=12-22ppm (Slightly toxic) Toxic to bees: Honey bee: LD50>50µg/bee 13. DISPOSAL CONSIDERATIONS PRODUCT: Recycle if appropriate facilities/equipment available. Burn in special, controlled high temperature incinerator. Dispose of as hazardous industrial waste. Keep out of drains, sewers, ditches and water ways. Follow all local/regional/national regulations. CONTAINER: Triple rinse empty containers. Pour rinse water into spray tank. Store for collection by approved waste disposal service. Dispose of as non hazardous industrial waste. Do not re-use containers. Follow all local/regional/national regulation. 14. TRANSPORT INFORMATION UN No: 3077 Class: 9 Package group: III 15. REGULATORY INFORMATION S61: Avoid release to the environment. Refer to special instructions safety data sheet 16. OTHER INFORMATION All information and instructions provided in this Material Safety Data Sheet (MSDS) are based on the current state of scientific and technical knowledge at the date indicated on the present MSDS and are presented in good faith and believed to be correct. This information applies to the product as such. In case of new formulations or mixes, it is necessary to ascertain that a new danger will not appear. It is the 3/4 responsibility of persons on receipt of this MSDS to ensure that the information contained herein is properly read and understood by all people who may use, handle, dispose or in any way come in contact with the product. If the recipient subsequently produce formulations containing this product, it is the recipients sole responsibility to ensure the transfer of all relevant information from this MSDS to their own MSDS. 4/4