MATERIAL SAFETY DATA SHEET 4 = EXTREME GAF MATERIALS CORPORATION FLAM M ABLE H EALTH 2 = MODERATE R E A C T IV E 1 0 1 = SLIGHT S P E C IA L HAZARDS TriPly® Granules 1 3 = HIGH 0 0 = INSIGNIFICANT ROOFING GRANULES Identity (Trade Name As Used On Label) Manufacturer GAF MATERIALS CORPORATION Address 1361 ALPS ROAD MSDS Number* 1029 A WAYNE, NEW JERSEY 07470-3689 CAS Number* Phone Number (For Information) Emergency Phone Number NONE Date Prepared 800-766-3411 7/26/00 Rev 05/03 Prepared By* P. ALLENSTEIN/P. J. HENNINGS 800-424-9300 NOTE: Blank spaces are not permitted. If any item is not applicable, or no information is available, the space must be marked to indicate that. SECTION 1 - MATERIAL IDENTIFICATION AND INFORMATION COMPONENTS - Chemical Name & Common OSHA ACGIH OTHER LIMITS %* PEL TLV RECOMMENDED Silica, Crystalline Quartz (Respirable Dust) 3.0 2.0 mg/m3 (Based on 3% SiO2) 0.05 mg/m3 Non-Hazardous Ingredients 97.0 Total 100 Names (Hazardous Components 1% or Greater; Carcinogens 0.1% or greater) SECTION 2 - PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point N/A Specific Gravity (H2O = 1) 2.60 – 3.00 Vapor Pressure (mm Hg and Temperature) N/A Melting Point N/A Vapor Density (Air = 1) N/A N/A Solubility in Water INSOLUBLE Evaporation Rate (Butyl Acetate = 1) Water Reactive N/A Appearance and Odor NATURAL/ARTIFICIALLY COLORED, SMALL ROCK PARTICLES. SECTION 3 - FIRE AND EXPLOSION HAZARD DATA Flash Point and Method Used Extinguisher Media: N/A Auto-Ignition N/A Temperature USE MEDIA PROPER FOR PRIMARY CAUSE OF FIRE Flammability Limits in N/A LEL N/A UEL N/A Air % by Volume Special Fire Fighting Procedures: NONE KNOWN Unusual Fire and Explosion Hazards; NONE KNOWN * Optional SECTION 4 - REACTIVITY HAZARD DATA OSHA 174 Page 1/2 MSDS GAF STABILITY Stable Unstable __X__ Conditions ____ NONE KNOWN To Avoid Incompatibility (Materials to Avoid) NONE KNOWN Hazardous Decomposition Products NONE KNOWN HAZARDOUS POLYMERIZATION ____ May Occur Conditions __X__ Will Not Occur NONE KNOWN To Avoid SECTION 5 - HEALTH HAZARD DATA PRIMARY ROUTES OF ENTRY: _X__ Inhalation ___ Skin Absorption Haz Acute HEALTH HAZARDS CARCINOGEN LISTED IN: ___ Ingestion ___ Not ___ NTP ___ IARC Monograph ___ OSHA ___ Not Listed Chronic Signs and Symptoms of Exposure: PROLONGED INHALATION – COULD RESULT IN THE DEVELOPMENT OF SILICOSIS, CHARACTERIZED BY SHORTNESS OF BREATH, DRY COUGH, FATIGUE AND DECREASED WORK CAPACITY Medical Conditions Generally Aggravated by Exposure: NO DATA FOUND EMERGENCY FIRST AID PROCEDURES Eye Contact FLUSH EYES WITH PLENTY OF WATER Skin Contact WASH AFTER EXPOSURE Inhalation IF DUST IS BREATHED IN LARGE AMOUNTS, REMOVE TO FRESH AIR AT ONCE. GET MEDICAL ATTENTION IF SHORTNESS OF BREATH CONTINUOUS Ingestion NO EFFECTS OF EXPOSURE EXPECTED SECTION 6 - CONTROL AND PROTECTIVE MEASURES Respiratory Protection (Specify Type) NIOSH/MSHA APPROVED RESPIRATOR, WHERE TLV OR PEL MAY BE EXCEEDED Protective Gloves AS REQUIRED VENTILATION ____ Local Exhaust TO BE USED ____ Special Eye Protection ____ Mechanical (General) __X__ Other (Specify) USE WITH ADEQUATE VENTILATION Other Protective Clothing and Equipment SAFETY GLASSES Hygienic Work Practices OBSERVE ORDINARY MEASURES OF PERSONAL HYGIENE SECTION 7 - PRECAUTIONS FOR SAFE HANDLING AND USE/LEAK PROCEDURES Steps to be Taken if Material is Spilled or Released: WET DOWN MATERIAL, PRIOR TO CLEAN-UP TO CONTROL DUSTING. Waste Disposal Methods: SCOOP UP AND DISPOSE OFF WITH SOLID WASTE ACCORDING TO FEDERAL, STATE AND LOCAL REGULATIONS. Precautions to be Taken in Handling and Storage: NONE Other Precautions and/or Special Hazards: NONE MSDS NO. 1029 - A PAGE 2/2