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List of publications by C Eaborn et. al on compounds containing the trisyl and related
ligands attached to silicon, germanium or tin
1 C. Eaborn, D. A. R. Happer, S. P. Hopper, and S. D. Safa. Novel rearrangements in reactions
of tris(trimethylsilyl)methylsilicon iodides and hydrides with electrophilic reagents, and the
possibility of cationic intermediates. J. Organomet. Chem., 1979, 170, C9-C12.
2
C. Eaborn and S. P. Hopper. Anchimeric assistance in solvolysis of an organosilicon
chloride and acetate. J. Organomet. Chem., 1979, 170, C51-C52.
3 S. S. Dua, C. Eaborn, D. A. R. Happer, S. P. Hopper, K. D. Safa, and D. R. M. Walton.
Preparation of tris(trimethylsilyl)methyl ("trisyl") derivatives of silicon. J. Organomet.
Chem., 1979, 178, 75-82.
4 C. Eaborn, D. A. R. Happer, P. B. Hitchcock, S. P. Hopper, K. D. Safa, S. S. Washburne, and
D. R. M. Walton. Thermolysis of [tris(trimethylsilyl)methyl](diphenyl)fluorosilane.
Isomerization of a sila-olefin intermediate. J. Organomet. Chem., 1980, 186, 309-323.
5 C. Eaborn, D. A. R. Happer, S. P. Hopper, and K .D. Safa. The reactions of
[tris(trimethylsilyl)methyl]silicon halides and hydrides with electrophilic reagents. J.
Organomet. Chem., 1980, 188, 179-192.
6 C. Eaborn, D. A. R. Happer, and K. D. Safa. Reaction of tris(trimethylsilyl)methylsilicon
halides with methanolic sodium methoxide. Probability of sila-olefin intermediates. J.
Organomet. Chem., 1980, 191, 355-362.
7 C. Eaborn and S. P. Hopper. The reactions of tris(trimethylsilyl)silicon iodides and hydrides
with iodine monochloride. J. Organomet. Chem., 1980, 192, 27-32.
8 S. S. Dua, C. Eaborn, and F. M. S. Mahmoud. A unimolecular solvolysis of an organosilicon
perchlorate. J. Organomet. Chem., 1980, 192, 293-295.
9 C. Eaborn and N. P. Y. Siew. Tris(trimethylsilyl)methyl germanium halides. J. Organomet.
Chem., 1980, 202, 157-162.
10 S. S. Dua and C. Eaborn. Sterically-hindered organosilicon perchlorates. J. Organomet.
Chem., 1981, 204, 21-26.
11 C. Eaborn and K. D. Safa. Pyrolysis of the "trisyl" compounds (Me3Si)3CSiPh2I and
(Me3Si)3CsiPhMeI. J. Organomet. Chem., 1981, 204, 169-179.
12 C. Eaborn and F. M. S. Mahmoud. Rate-determining ionization in methanolysis of an
organosilicon halide. J. Chem. Soc., Chem. Commun., 1981, 63-64.
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13 C. Eaborn, K. D. Safa, A. Ritter, and W. Binder. Photo-induced reactions of an organosilicon
iodide. J. Chem. Soc., Chem. Commun., 1981, 175-176.
14 C. Eaborn and F. M. S. Mahmoud. Unimolecular solvolysis of some organosilicon
perchlorates and iodides. J. Chem. Soc., Perkin Trans.2, 1981, 1309-1315.
15 C. Eaborn and F. M. S. Mahmoud. Some properties of the sterically-hindered aminosilane
(Me3Si)3CSiMe2NH2. J. Organomet. Chem., 1981, 220, 139-143.
16 C. Eaborn, P. B. Hitchcock and P. D. Lickiss. The molecular structure of
[dimethyl(phenyl)silyl]tris(trimethylsilyl)methane. J. Organomet. Chem., 1981, 221, 13-17.
17 C. Eaborn, P. B. Hitchcock and K. D. Safa. An unusual bicyclic tetrasiloxane. J. Organomet.
Chem., 1981, 222, 187-194.
18 S. A. I. Al-Shali, C. Eaborn, and F. M. S. Mahmoud. The SN1 methanolysis of a tertiary
organosilicon iodide, (Me3Si)3CSiMe2I. J. Organomet. Chem., 1982, 232, 215-218.
19 C. Eaborn and K. D. Safa. Some highly sterically hindered organo-silanols and -siloxanes. J.
Organomet. Chem., 1982, 234, 7-14.
20 C. Eaborn, K. D. Safa, A. Ritter, and W. Binder. Photoinduced ionic and free-radical
reactions of some organosilicon iodides. J. Chem. Soc., Perkin Trans. 2, 1982, 1397-1401.
21 C. Eaborn. Novel properties of some highly sterically hindered organosilicon compounds. J.
Organomet. Chem., 1982, 239, 93-103.
22 C. Eaborn, P. D. Lickiss, G. Marquina-Chidsey, and E. Y. Thorli.
(Dimethyl)[tris(trimethylsilyl)methyl]silyl cyanate and related species: the first silicon
cyanate. J. Chem. Soc.,, Chem. Commun., 1982, 1326.
23 R. Damrauer, C. Eaborn, D. A. R. Happer and A. I. Mansour. A novel 1,3-migration of a silyl
group from carbon to oxygen in a silanolate ion. J. Chem. Soc., Chem. Commun., 1983, 348.
24 S. A. I. Al-Shali and C. Eaborn. Bimolecular displacements of iodine in reactions of
dimethyl[tris(trimethylsilyl)methyl]silyl iodide with salts. J. Organomet. Chem., 1983, 246,
C34-36.
26 Z. Aiube, J. Chojnowski, C. Eaborn, and W. A. Stanczyk. Internal nucleophilic
displacements within silanolate ions. A new mechanism of substitution at silicon. J. Chem.
Soc., Chem. Commun., 1983, 493-495.
27 C. Eaborn and D. E. Reed. Anchimeric assistance in methanolysis of some organosilicon
halides, perchlorates, and trifluoromethanesulphates. J. Chem. Soc., Chem. Commun., 1983,
495-496.
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28 C. Eaborn, P. B. Hitchcock, and P. D. Lickiss. Some derivatives of
tris(dimethylsilyl)methane. A novel bicyclic tris(disiloxane) with a manxane structure. J.
Organomet. Chem., 1983, 252, 281-288.
29 A. I. Al-Wassil, C. Eaborn, and A. K. Saxena. Oxidatively assisted nucleophilic substitution
of organosilicon iodides. J. Chem. Soc., Chem. Commun., 1983, 974-975.
30 C. Eaborn and A. I. Mansour. Reactions of some sterically-hindered organosilicon hydrides
and iodides with halogens. J. Organomet. Chem., 1983, 254, 273-282.
31 C. Eaborn, Y. Y. El-Kaddar, and P. D. Lickiss. [Tris(trimethylsilyl)methyl](dimethyl)silyl
cyanate. The cyanate to isocyanate isomerization, and the high activity of cyanate as a
leaving group in solvolysis. J. Chem. Soc, Chem. Commun., 1983, 1450-1451.
32 C. Eaborn, P. D. Lickiss, and N. A. Ramadan. Cleavages of silicon-carbon bonds in
tris(trimethylsilyl)methylsilicon compounds by trifluoroacetic acid. Rearrangements and
anchimeric assistance. J. Chem. Soc., Perkin 2, 1984, 267-270.
33 A. I. Al-Wassil, C. Eaborn, A. Hudson, and R. A. Jackson. An electron spin resonance study
of some silicon-centred free radicals with a tris(trimethylsilyl)methyl substituent. J.
Organomet. Chem., 1983, 258, 271-275.
34 S. A. I. Al-Shali, C. Eaborn, F. A. Fattah, and S. T. Najim. An SN2 (intermediate) mechanism
for solvolysis of organosilicon iodides. J. Chem. Soc., Chem. Commun., 1984, 318-319.
35 C. Eaborn, P. B. Hitchcock, and P. D. Lickiss. Tetrakis(hydroxymethylsilyl)methane and its
dehydration with rearrangement. Crystal structure of 2,2,4,4,6,6-hexamethyl-5hydroxydimethylsilyl)1,3-dioxa-2,4,6-trisilacyclohexane. J. Organomet. Chem. 1984, 264,
119-126.
36 C. Eaborn and A. K. Saxena. Comparisons of the reactivities of the tri-t-butyl- and
tris(trimethylsilyl)methyl-silicon compounds. J. Organomet. Chem. 1984, 271, 33-46.
37 C. Eaborn, P. B. Hitchcock, P. D. Lickiss, A. Pidcock, and K. D. Safa. Crystal stucture and
variable-temperature hydrogen-1 nuclear magnetic resonance spectrum of
(dimethylnitratosilyl)[methyldiphenylsilyl]bis(trimethylsilyl)methane,
C(SiMe3)2(SiMePh2)(SiMe2ONO2). J. Chem. Soc., Dalton Trans., 1984, 2015-2017.
38 C. Eaborn and A. K. Saxena. .1,3-methyl migration from germanium to silicon in reactions of
(Me3Si)2(Me3Ge)C(SiMe2Br) with silver salts. J. Chem. Soc., Chem. Commun., 1984, 14821483.
39 C. Eaborn and M. N. Romanelli. The first silicon thiocyanate. J. Chem. Soc., Chem.
Commun., 1984, 1616-1617.
40 R. I. Damja, C. Eaborn, and A. K. Saxena. Acyl-oxygen fission in reactions of organosilicon
carboxylates with sodium methoxide in methanol. J. Chem. Soc., Perkin 2, 1985, 597-598.
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41 C. Eaborn and A. I. Mansour. Reactions of silicon centres bearing the bulky
tris(phenyldimethylsilyl)methyl ligand. J. Chem. Soc., Perkin 2, 1985, 729-735,
42 C. Eaborn. .Highly sterically hindered organosilicon compounds, in Organosilicon and
Bioorganosilicon Chemistry. (ed. H. Sakurai). Ellis Horwood. Chichester. 1985, 123-130.
43 R. I. Damja and C. Eaborn. Preparation and reactions of some sterically hindered silanols,
including [tris(trimethylsilyl)methyl]silanetriol. J. Organomet. Chem. 1985, 290, 267-275.
44 R. I. Damja, C. Eaborn, and W.-C. Sham. .Reactions of (Me3Si)3CSiMe2R compounds (R =
CH=CH2, CH2CH=CH2, CCPh, Ph, and CH2Ph) with electrophiles. J. Organomet. Chem.
1985, 291, 25-33.
45 Z. H. Aiube, N. H. Buttrus, C. Eaborn, P. B. Hitchcock, and J. A. Zora. .The preparation and
crystal structures of [(Me3Si)3C]PhSi(OH)2 and [(Me3Si)3PhSi(OMe)OH. J. Organomet.
Chem. 1985, 292, 177-188.
46 C. Eaborn and D. E. Reed. Preparation and reactions of difunctional sterically hindered
organosilicon compounds of the type (Me3Si)2C(SiMe2X)(SiMe2Y). J. Chem. Soc., Perkin
Trans. 2, 1985, 1687-1693.
47 C. Eaborn and D. E. Reed. Absence of rearrangement in reactions of the compounds
(Me3Si)3CSiMe(OMe)I, (Me3Si)3CSi(OMe)2I with electrophilic reagents. J. Chem. Soc.,
Perkin Trans. 2, 1985, 1695-1697.
48 J. L. Atwood, S. G. Bott, C. Eaborn, M. N. A. El-Kheli, and J. D. Smith. The crystal and
molecular structure of fluoro(hydroxy){tris-(dimethylphenylsilyl)methyl}borane. J.
Organomet. Chem. 1985, 294, 23-30.
49 C. Eaborn and P. D. Lickiss. Some tetrasilylmethane derivatives. J. Organomet. Chem. 1985,
294, 305-313.
50 N. H. Buttrus, R. I. Damja, C. Eaborn, P. B. Hitchcock, and P. D. Lickiss. The crystal
structure of [tris(trimethylsilyl)methyl]silanetriol. A novel and remarkably stable hydrogenbonded cage structure. J. Chem. Soc., Chem. Commun., 1985, 1385-1386.
51 C. Eaborn, P. D. Lickiss, S. T. Najim, and M. N. Romanelli. Unimolecular alcoholysis of
organosilicon halides of the type (Me3Si)2C(SiMe2OMe)(SiR'2X). Anchimeric assistance by
and migration of the OMe group. J. Chem. Soc., Chem. Commun., 1985, 1754-1755.
52 G. A. Ayoko and C. Eaborn. Neighbouring group participation by the vinyl group in
reactions of sterically-hindered organosilicon compounds. J. Chem. Soc., Chem. Commun.,
1986, 630-631.
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53 N. H. Buttrus, C. Eaborn, P. B. Hitchcock, P. D. Lickiss, and A. D. Taylor. Hydrogen
bonding in organosilicon hydroxides: crystal structures of dichlorohexylsilanediol and
bis(hydroxydimethylsilyl)bis(trimethylsilyl)methane. J. Organomet. Chem. 1986, 309, 25-33.
54 G. A. Ayoko and C. Eaborn. The effects of the vinyl groups in reactions of the highly
sterically hindered compound [tris(trimethylsilyl)methyl]divinylsilyl chloride. J. Chem. Soc.,
Perkin Trans. 2, 1986, 1289-1293.
55 G. A. Ayoko and C. Eaborn. Silicon-oxygen and acyl-oxygen bond cleavage in reactions of
sterically hindered organosilicon carboxylates. J. Chem. Soc., Perkin Trans. 2, 1986, 13571361.
56 A.I. Al-Wasssil, C. Eaborn, and M.N. Romanelli. Peparation and some reactions of
compounds of the type (Me3Si)2C(SiMe2OMe)(SiMe2X). Anchimeric assistance by the
methoxy group. J. Chem. Soc., Perkin Trans. 2, 1986, 1363-1365
57 C. Eaborn, P.D. Lickiss, S.T. Najim, and M.N. Romanelli. 1,3-Migration of chloride and
azide substituents within organosilicon cations, and anchimeric assistance by the azido
group. J. Organomet. Chem. 1986, 315, C5-C8.
58 G.A. Ayoko and C. Eaborn. Reactions of bis[dimethyl(vinyl)silyl]bis(trimethylsilyl)methane, (Me3Si)2(SiMe2CH=CH2)2. J. Chem. Soc., Perkin Trans. 2, 1987, 657-662.
59 C. Eaborn and M.N. Romanelli. Anchimeric assistance by the methoxy group in solvolysis of
the compounds (Me3Si)2C(SiMe2OMe)-(SiMe2X). J. Chem. Soc., Perkin Trans. 2, 1987, 657662.
60 S.A. Al-Juaid, S.M. Dhaher, C. Eaborn, P.B. Hitchcock, and J.D. Smith. Preparation and
crystal structures of the crowded organotin fluorides (PhMe2Si)3CSnMe2F,
(Me3Si)3CSiMe2F, and (Me3Si)3CSnPh2F. J. Organomet. Chem. 1987, 325, 117-127.
61 C. Eaborn and A.K. Saxena. 1,3-Migration of a methyl group from germanium to silicon in
reactions of (Me3Si)2C(GeMe3)(SiMe2Br) with silver salts. J. Chem. Soc., Perkin Trans. 2,
1987, 779-782.
62 C. Eaborn and A.K. Saxena. The effect of the _-OMe group on the reactivity of the
germanium chloride (Me3Si)2C(SiMe2OMe)(GeMe2Cl). J. Chem. Soc., Perkin Trans. 2,
1987, 775-778.
63 N.H. Buttrus, C. Eaborn, P.B. Hitchcock, P.D. Lickiss, and S.T. Najim. Migration of the
methoxy group in an organosilicon cation. Reactions of (bromodiphenylsilyl)(methoxydimethylsilyl)bis(trimethylsilyl)methane with silver borofluoride and silver
chloride. Crystal structure of (chlorodiphenylsilyl)(methoxydimethylsilyl)-bis(trimethylsilylmethane). J. Chem. Soc., Perkin Trans. 2, 1987, 891-894.
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64 G.A. Ayoko and C. Eaborn. Assistance by and migration of the vinyl group in reactions of
the sterically hindered compounds of the type (Me3Si)2C(SiMe2 CH=CH2)(SiR2X). J. Chem.
Soc., Perkin Trans. 2, 1987, 1047-1058.
65 D. B. Azarian, C. Eaborn, and P.D. Lickiss. Effects of the substituents Y in reactions of
compounds of the type (Me3Si)3CSiH(C6H4Y-p)I. Evidence against the SN2(intermediate)
mechanism for methanolysis of (328, Me3Si)3CSiMe2I and (Me3Si)3CSiHPhI. J. Organomet.
Chem. 1987, 328, 256-262.
66 D.B. Azarian, C. Eaborn, and P.D. Lickiss. Reactions of tris(trimethylsilyl)methylsilicon
compounds with organolithium reagents. J. Organomet . Chem., 1987, 330, 1-7.
67 S.M. Dhaher, C. Eaborn, and J.D. Smith. 1,3-Migration of a methyl group from tin to silicon
via a cationic intermediate. J. Chem. Soc., Chem. Commun., 1987, 1337-1388.
68 C. Eaborn, P.D. Lickiss, S.T. Najim, and W.A. Stanczyk. 1,3-Migrations of a phenyl group
via a silicocation. J. Chem. Soc., Chem. Commun., 1987, 1183-1184.
69 N.H. Butruss, C. Eaborn, P.B. Hitchcock, P.D. Lickiss, and S.T. Najim. 1,3 Silicon to silicon
migration of the methoxy group in solvolysis of
(bromodiphenyl)(methoxydimethylsilyl)bis(trimethylsilyl)-methane. Crystal structure of
(ethoxydimethylsilyl)(methoxydiphenyl-silyl)bis(trimethylsilyl)methane and
(methoxydimethylsilyl)(methoxy-diphenylsilyl)bis(trimethylsilyl)methane. J. Chem. Soc.,
Perkin Trans. 2, 1987, 1753-1757.
70 C. Eaborn, P.D. Lickiss, and A.D. Taylor. Reactions of the sterically hindered organosilicon
diol (Me3Si)2C(SiMe2OH)2 and some of its derivatives. J. Organomet. Chem. 1988, 340,
283-292.
71 C. Eaborn, P.D.Lickiss, and A.D. Taylor. The nature of the anchimeric assistance by the
acetoxy group in solvolysis of (Me3Si)2C(SiMe2OCOMe)(SiMe2Cl). J. Organomet. Chem.
1988, 338, C27-C29.
72 A. Alvanipour, N.H. Buttrus, C. Eaborn, P.B. Hitchcock, A. I. Mansour, and A.K. Saxena.
Formation of a tetraazole from (PhMe2Si)3CSiMe2I. Crystal structure of
(PhMe2Si)3CSiMe2N-N=C(Me)-N=N. J. Organomet. Chem. 1988, 349, 29-36.
73 S.S. Al-Juaid, C. Eaborn, P.B. Hitchcock, and P.D. Lickiss, The crystal structure of
tetrakis(hydroxydimethylsilyl)methane. A remarkable three-dimensional network. J.
Organomet. Chem.; 1988, 353, 297-305.
74 S.M. Dhaher, C.Eaborn, and J.D. Smith. Synthesis and properties of some crowded organotin
compounds. J. Organomet. Chem. 1988, 355, 33-44.
75 S.S. Al-Juaid, N.H. Buttrus, R.I. Damja, Y. Derouiche, C. Eaborn, P.B. Hitchcock, and P.D.
Lickiss. Hydrogen bonding in organosilanetriols. The crystal structures of
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tris(trimethylsilyl)silyl- and tris(trimethylsilyl)methylsilanetriol. J. Organomet. Chem. 1989,
371, 287-295.
76 C. Eaborn, K.L. Jones, and P.D. Lickiss. Anchimeric assistance by -aryl groups in solvolysis
of organosilicon iodides. Some remarkably large remote substituent effects. J. Chem. Soc.,
Chem. Commun.,1989, 595-596.
77 A.I Al-Mansour, M.A.M.R. Al-Guarashi, C. E.Eaborn, F.A. Fatttah, and P.D. Lickiss. 1,3Migration of triorganosilyl groups from carbon to oxygen in highly crowded organosilanols.
J. Organomet. Chem. 1989, 393, 27-32.
78 C. Eaborn and F.A. Fattah. Miscellaneous reactions of tris(trimethylsilyl)methylsilicon
compounds. J. Organomet. Chem. 1990, 396, 1-8.
79 C. Eaborn, P.D. Hitchcock, P.D. Lickiss, and A.D. Taylor. The synthesis and crystal structure
of the crowded disiloxane [(Me3Si)3Cl2Si]2O. J. Organomet. Chem. 1990, 398, 59-64
80 C. Eaborn. A contribution to the silicenium ion debate. J. Organomet. Chem., 1991, 405, 141148.
81 F.I. Aigbirhio, S.S. Al-Juaid, C. Eaborn, P.B. Hitchcock, and P.D.Lickiss. Comparison of the
Reactivities of the Compounds (Me3Si)2C(SiMe2OMe)(SiMe2Cl) and
(MeOMe2Si)3C(SiMe2Cl). Crystal Structure of (MeOMe2Si)3CSiPh2H. J. Chem. Soc., Perkin
Trans. 2, 1991, 1407-1410.
82 S. S Al-Juaid, A. K. A. Al-Nasr, C. Eaborn, and P. B. Hitchcock. Hydrogen bonding
interaction between a hydroxy group and the -electrons of an aryl group. Crystal structure
of [tris(dimethylphenylsilyl)methyl]methylsilanol. J. Chem. Soc., Chem. Commun, 1991,
1482-1484.
83 Z. H. Aiube and C. Eaborn, Reactions at highly sterically hindered centres. Chemistry of
(Me3Si)3CPhHI, (Me3Si)3CPh(OMe)I, and related species. J. Organomet. Chem. 1991, 421,
159-169.
84 S. S. Al-Juaid, C. Eaborn, and P.B. Hitchcock. The crystal structure of
(Me3Si)3CSi(OH)2(OCOCF3). J. Organomet. Chem. 1992, 423, 5-12.
85 C Eaborn, K.L. Jones, and P.D. Lickiss. Anchimeric assistance by -aryl groups in reactions
of organosilicon iodides. J. Chem. Soc., Perkin Trans. 2, 1992, 489-495.
86 C. Eaborn, Y.Y. El-Kaddar, and P.D. Lickiss. Preparation and reactions of some organosilicon
cyanates. Inorg. Chim. Acta., 1992, 200, 337-344.
87 S. S Al-Juaid, A. K. A. Al-Nasr, C. Eaborn, and P. B. Hitchcock. Crystallographic Evidence
for Intermolecular Interaction Between Aryl Groups and OH Groups in Silanols. J.
Organomet. Chem., 1992, 429, C9-C13.
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88 Y.Y. El-Kaddar, C. Eaborn, P.D. Lickiss, and D.E. Reed. The methanolysis of the highly
strerically hindered organosilicon compounds (Me3Si)3CSiMe2X with X = OSO2CF3, OCN,
or OClO3. A mechanistic enigma. J. Chem. Soc., Perkin Trans. 2, 1992, 1753-1759.
89 C. Eaborn, P.D. Lickiss, S.T. Najim, and W.A. Stanczyk. Reaction of
(Me3Si)2C(SiMe2Ph)(SiMe2I) with AgBF4. 1,3-Migration of the phenyl group. J. Chem.
Soc., Perkin Trans. 2, 1993, 59-62.
90 C. Eaborn, P. D. Lickiss, and S. T. Najim. 1,3-Migration of chloride and azide ligands in
reactions of highly sterically hindered organosilicon halides. J. Chem. Soc., Perkin Trans. 2,
1993, 391-394.
91 C. Eaborn, K. L. Jones, P. D. Lickiss and W. A. Stanczyk. Proportion of 1,3-phenyl migration
in the trifluoroethanolysis, methanolysis, and hydrolysis of (Me3Si)2C(SiMe2Ph)(SiEt2I), J.
Chem. Soc., Perkin Trans. 2, 1993, 395-397.
92 S.S. Al-Juaid, M. Al-Rawi, C. Eaborn, P.B. Hitchcock, and J.D. Smith. Preparation and
crystal structures of the crowded triorganotin isothiocyanate (PhMe2Si)3CSnMe2NCS and
nitrate (PhMe2Si)3CSnMe2ONO2. J. Organomet. Chem. 1993, 446, 161-166.
93 C. Eaborn and N M. Romanelli. Anchimeric assistance by the -N3 and -NCS groups in
solvolysis of (Me3Si)2C(SiMe2N3)(SiMe2Br) and (Me3Si)2C(SiMe2NCS)(SiMe2Br). J.
Organomet. Chem. 1993, 451, 45-52.
94 S.S. Al-Juaid, A.K. Al-Nasr, C. Eaborn and P.B. Hitchcock.The crystal structure of the
oganosilicon p-toluenesulfonate (Me3Si)3SiPh(H)(OSO2C6H4Me-p). J. Organomet. Chem.
1993, 455, 57-60.
95 Y. Y. El-Kaddar, C. Eaborn, and P. D. Lickiss. Reactions of the highly sterically hindered
compounds (Me3Si)3CSiMe2X (X = Cl, Br, I, or ONO2) with NaN3, CsF, KSCN, and KOCN
in MeOH. J. Organomet. Chem. 1993, 460, 7-13.
96 C. Eaborn, K. L. Jones, and P. D. Lickiss. Reactions of compounds of the type
(Me3Si)2C(SiMe2C6H4Y)(SiMe2X) with trifluoroacetic acid. J. Organomet. Chem. 1993, 461,
7-13.
97 C. Eaborn, K. L. Jones, and P. D. Lickiss. Preparation of the iodides
(Me3Si)2C(SiMe2C6H4Y)(SiMe2I) and some related compounds. J. Organomet. Chem. 1994,
466, 35-42.
98 A. I. Al-Mansour, S. S. Al-Juaid, C. Eaborn and P. B. Hitchcock. Crystal structure.of the
crowded silanol (Me3Si)3SiPh2OH. J. Organomet. Chem., 1994, 480, 139-143.
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99 C. Eaborn, P. D. Lickiss and A. D. Taylor .Anchimeric assistance by the acetoxy group in
solvolysis of the compounds (Me3)2C(SiMe2OCOMe)(SiMe2X), X = Cl, NCS, or N3 .J. Chem.
Soc., Perkin Trans 2, 1994, 1089-1813.
100 S. S. Al-Juaid, A. A. K. Al-Nasr, G. A. Ayoko, C. Eaborn and P. B. Hitchcock. The
geometry of SiOCN and SiNCO linkages. The crystal structures of
(Me3Si)2(Ph2MeSi)CSiMe2OCN and (PhMe2Si)3CSiMe2NCO. J. Organomet. Chem., 1995,
488, 155-160.
101 A. I. Almansour and C. Eaborn. Preparation of (iPrMe2Si)3CH and its use as a source of the
bulky ligand (iPrMe2Si)3C. J. Organomet.Chem., 1995, 489, 181-183.
102 M. A. M. R. Al-Guarashi, G. A. Ayoko, C. Eaborn and P. D. Lickiss. Rates of solvolysis of
the compounds (Me3)2(Ph2MeSi)CSiMe2X, X = I, OSO2CF3 and OCN. Mechanistic
implications. J. Organomet. Chem., 1995, 499, 57-62.
103 A. I. Almansour, J. R. Black, C. Eaborn, P. M. Garrity and D. A. R. Happer.
Predominance of unrearranged products in the reactions of the iodide (Me3Si)3C(CD3)2I
with silver salts, and its mechanistic implications. J. Chem. Soc., Chem. Commun., 1995,
705-706.
104 M. A. M. R. Al-Gurashi, G, A. Ayoko, C. Eaborn and P. D. Lickiss, Anchimeric assistance
in the reactions of the crowded organosilicon iodide (Me3Si)2(Ph2MeSi)CSiMe2I with
electrophiles. Bull Soc. Chim. Fr., 1995, 132, 517-521.
105 G. A. Ayoko, C. Eaborn and P. B. Hitchcock, Geometry of the SiOCN Linkage. Crystal
Structure of (Me3Si)2(PhMe2Si)CSiMe2OCN, .Organometallics, 1995, 14, 4960-4961.
106 A.G. Davies, C. Eaborn, P.D. Lickiss and A.G. Neville, EPR spectra of
tris(trimethylsilyl)methyl(hydroxy)silyl radicals, (Me3Si)3SiROH., and
tris(trimethylsilyl)methylsilanone radical anions (Me3Si)3SiR=O.- (R = H, Me, Et, Bu, Ph, F). J.
Chem. Soc., Perkin Trans. 2, 1996, 163-169.
107 A.I. Almansour, G. A. Ayoko and C. Eaborn. The mechanism of the isomerization of
organosilicon cyanates to isocyanates. J. Organomet. Chem., 1996, 514, 277-280.
108 D. A. Antonov, C. Eaborn, J. D Smith, P. B. Hitchcock, E. Molla, V. I. Rozenberg, W. A.
Stancyk, and A. Kowaleska. A bulky tris(trisilylmethyl) ligand incorporating a donor sulfur
atom. Some (Me3Si)2(PhSMe2Si)CSnMe2X compounds. J. Organomet. Chem., 1996, 521,
109-112.
Supplementary Material (ESI) for Dalton Transactions
This journal is © The Royal Society of Chemistry 2001
109 A. I. Almansour, H. A. Abubishait, and C. Eaborn. 1,3-Si-toSi migration of a methyl group.
Ratio of rearranged and unrearranged products in the reactions of the iodide
(Me3Si)3C(Si(CD3)2I with ICl. J. Organomet. Chem., 1997, 531, 171-174.
110 C. Eaborn, A. Kowalewska and W. A Stanczyk, 1,3-Migration of a phenyl group in the of
(Me3Si)2(PhMe2Si)CSiMePhX into (Me3Si)2(Ph2MeSi)CSiMe2X species, J. Organomet.
Chem., 1998, 560, 41-46.
111 C. Eaborn, A. Kowalewska, J. D. Smith and W. A. Stanczyk. Anchimeric assistance by substituents Z, Z = MeO, PhO, MeS or PhS, in reactions of the bromides
(Me3Si)2(ZMe2Si)CSiMe2Br with AgBF4. J. Organomet. Chem., in the press.
Additional List: Papers dealing with species containing the trisyl and related ligands not
attached to a metal or metalloid.
1 A. R. Bassindale, C. Eaborn, D. R. M. Walton, and D. J. Young .The electron-releasing effects
of mono-, bis-, and tris-(trimethylsilyl)methyl groups. The importance of hyperconjugation in
the electronic effects of -metalloalkyl groups. J. Organomet. Chem., 1969, 20, 49-56.
2 A. R. Bassindale, A. J. Bowles, M. A. Cook, C. Eaborn, A. Hudson, R. A. Jackson, and A. E.
Jukes .Tris(trimethylsilyl)methyl - a relatively stable saturated organic radical. J. Chem Soc.,
Chem., Chem. Commun., 1970, 559.
3 A. R. Bassindale, C. Eaborn, and D. R. M. Walton. Electronic effects of mono-, bis-, and tris(trimethylsilyl)methyl groups. The 19F nuclear magnetic resonance spectra of m- and p[(Me3Si)xCH(3-x)]C6H4F compounds (x = 0-3). J. Organomet. Chem., 1970, 21, 91-94.
4 M. A. Cook, C. Eaborn, and D. R. M. Walton .Organosilicon compounds. Part XLVII. The
substituent effects and leaving group abilities of mono-, bis-, and tris-(trimethylsilyl)silyl
groups in electrophilic aromatic substitution. J. Organomet. Chem., 1970, 23, 85-90.
5 M. A. Cook, C. Eaborn, and D. R. M. Walton. Substituent effects of mono-, bis-, and
tris(trimethylsilyl)methyl groups: determination of - and +-constants. J. Organomet.
Chem., 1970, 24, 293-299.
6 C. Eaborn, J. S. Johnson, and O. W. Steward. The preparation of bis- and tris(trimethylsilyl)acetic acid. J. Organomet. Chem., 1972, 46, 97-100.
7 B. Beagley, R. G. Pritchard, C. Eaborn, and S. S. Washburne. A gas-phase electron diffraction
study of tris(trimethylsilyl)methane. A C-H bond of high p-character. J. Chem. Soc.,, Chem.
Commun., 1981, 710-711.
8 C. Eaborn, P. B. Hitchcock, and P. D. Lickiss. The crystal structure of
tris(phenyldimethylsilyl)methane. J. Organomet. Chem. 1984, 269, 235-238.
Supplementary Material (ESI) for Dalton Transactions
This journal is © The Royal Society of Chemistry 2001
9 C. Eaborn and D.A.R Happer. A novel mode of reaction of a substituted alkyl halide. Reduction
of tris(trimethylsilyl)methyl iodide by methanol. J. Chem. Soc., Chem. Commun, 1991, 16081609.
10 P. T. Brain, M. Mehta, D. W. H. Rankin, H. E. Robertson, C. Eaborn, J. D. Smith and A. D.
Webb. Determination by electron diffraction of the molecular structures of chloro- and
bromo-tris(trimethylsilyl)methane in the gas phase. J. Chem. Soc., Dalton Trans., 1995, 349354
11 P.T. Brain, M. Mehta, D. W. H. Rankin, H. E. Robertson, C. Eaborn, J. D. Smith and A. D.
Webb. Determination by electron diffraction of the molecular structure of
bromotris(methoxydimethylsilyl)methane in the gas phase. J. Chem. Soc., Dalton Trans.,
1995, 975-978.
12 C A. Morrison, W. H. Rankin, H. E. Robertson, C. Eaborn, A Farook, P, B, Hitchcock and J.
D. Smith, Conformational control by halogen substitution and by crystallisation: a study of
the molecular structures of CH(SiMe2H)3 and CH(SiMe2Br)3 by gas-phase electron
diffraction and ab initio molecular orbital calculations, J. Chem. Soc., Dalton Trans., 2000,
4312-4322.