Lab: Plop Plop Fizz Fizz Reaction Rate Name Period Date Team Names Background: Alka Seltzer and other effervescent antacid pain reliever tablets are made using solid forms of aspirin, citric acid, and sodium bicarbonate. When sodium bicarbonate dissolves in water, it dissociates (splits apart) into sodium (Na+) and bicarbonate (HCO3−) ions. The bicarbonate then reacts with hydrogen ions (H+) from the citric acid to form carbon dioxide and water. It will be your task to predict conditions that will change the rate at which this reaction happens and then create lab conditions to test your hypotheses. Materials: Small beaker (250 – 400 ml) Timer (clock or watch with second hand) Effervescent tablets Graduated cylinder (100 ml) Mortar and pestle Hot or cold tap water Thermometer Baseline Reaction: 1. 2. 3. 4. 5. Using the graduated cylinder, measure out 50 ml of tap water and transfer it to the beaker. Measure the temperature of the water in the beaker and record it here: Prepare to measure how long it takes the tablet to completely react. (Reaction starts when tablet is dropped and continues until tablet is gone and the fizzing noise has stopped.) Drop a tablet into the beaker and measure the reaction time to the nearest second. Record the seconds for the reaction here: BASELINE REACTION TIME (seconds) Factors: We studied 5 factors that typically effect reaction rate. Record them here: 2) 3) 4) 1) 5) Experimental Design: 1. Utilizing the materials provided, design individual experiments for as many of these factors as you can to see what impact each of them has on the reaction rate. 2. Remember to keep in mind that a Controlled Experiment needs to have most things held constant while one variable is manipulated at a time. Be sure to think about which variables (things that could change) need to be held constant in order to do this in a controlled fashion. 3. You are limited to one tablet per experiment, and no more than 100 ml of water for any given experiment. 4. Your team will be allowed to run up to 4 individual experiments (in addition to baseline reaction). 5. Design for each experiment will be approved by instructor before you get a tablet to run the experiment. (Be sure to record the temperature as part of conditions for each experiment.) Exp Reaction Detailed Description of Conditions Prediction* Reaction Time % of Baseline (Exp secs/Base secs) (faster or slower) (# seconds) (exactly record all reaction factors each time) Factor #1 #2 #3 #4 #5 * Prediction is faster or slower compared to Baseline experiment reaction time WRITE UP CONCLUSIONS ON BACK OF PAGE Conclusions: 1. Create a bar chart for your data. Include results for the baseline and all the experiments. Be sure to include a title for the chart and to clearly label all data and to label both axis. Reflections: 2. If any of your predictions were incorrect, try to you think of a reason(s) why and describe it below. Also, how you could improve your data with another experiment(s)? Lab: Plop Plop Fizz Fizz Reaction Rate – Write Up RUBRIC Author Name Evaluator Name Title Page Possible: 2 Introduction: Discussion of reaction rate factors Possible: 10 Materials List Possible: 3 Experimental Design: Procedures for each experiment Possible: 25 ______ Baseline reaction: Water temp & reaction time – 1 pt each Possible: 2 Reaction rate factors – 1 pt each Possible: 5 Experimental data (up to sets) – Conditions 3 pts/1 each for rest Possible: 28 Bar Chart: Title, Axis labels, and accurate scale – 5 pts Possible: 5 Data: each factor correctly plotted, clearly labeled – 5 pts Possible: 25 Conclusion/Reflections: 20 pts Possible: 20 (Possible: 125) Comments: Total ______ ______ Lab: Plop Plop Fizz Fizz Reaction Rate – Write Up RUBRIC Introduction: Should discuss the 5 factors which affect reaction rates - providing background on how each factor specifically relate to reaction rate. Also discuss the background for the baseline experiment and present the purpose of this lab. (hint – observe how reaction rate is affected) Materials: List all materials used in the experiments Procedures: Outline step by step the procedures followed for each individual experiment including the baseline experiment. Provide a sub-heading for each individual experiment within the section heading. Example – Procedures: Baseline Experiment: 1. ……… Data: Present all data collected in a chart like the one listed on the data sheet. This chart should be inserted into the write-up in the appropriate order – Do not simply reference of attach the data sheet! Do not forget to list the data from the baseline experiment – either add in a section to the data chart, create a separate chart, or simply list and label the baseline data (before the data chart). The Bar Graph/Chart should also be presented within the paper. Either create the chart using the computer or insert the graph paper model into the flow of the paper and then manually create the graph. Conclusion: Write a conclusion passed on your reflections. The conclusion should address the results of each experiment, and discuss them in relation to the facts presented in the introduction. The conclusion should bring the report full circle – tying everything up – bringing it all together back to the introduction discussion. Other Important Notes: Use headings for each section – just like they are listed on this sheet – keep in order. You will not be turning in the lab data sheet – all data and information will be presented in the write – up. DO NOT use first or second person – NO: I’s, WE’s, YOU’s, etc. – everything should be addressed in third person. Use good writing – transitions & conclusion sentences. o Be concise and specific – this is not about quantity but about quality! However cover everything in detail! o Use the lab instructions and data sheet to help you! It lays out a lot of information and order for you. If you have any questions please ask! Do not wait for the last minute to complete this – Worth a test grade! Lab: Plop Plop Fizz Fizz Reaction Rate Name KEY Period Date Team Names Background: Alka Seltzer and other effervescent antacid pain reliever tablets are made using solid forms of aspirin, citric acid, and sodium bicarbonate. When sodium bicarbonate dissolves in water, it dissociates (splits apart) into sodium (Na+) and bicarbonate (HCO3−) ions. The bicarbonate then reacts with hydrogen ions (H+) from the citric acid to form carbon dioxide and water. It will be your task to predict conditions that will change the rate at which this reaction happens and then create lab conditions to test your hypotheses. Materials: Graduated cylinder (100 ml) Mortar and pestle Hot or cold tap water Thermometer Small beaker (250 – 400 ml) Timer (clock or watch with second hand) Effervescent tablets Baseline Reaction: 1. 2. 3. 4. 5. Using the graduated cylinder, measure out 50 ml of tap water and transfer it to the beaker. Measure the temperature of the water in the beaker and record it here: XX F or XX C Prepare to measure how long it takes the tablet to completely react. (Reaction starts when tablet is dropped and continues until tablet is gone and the fizzing noise has stopped.) Drop a tablet into the beaker and measure the reaction time to the nearest second. Record the seconds for the reaction here: BASELINE REACTION TIME XX (seconds) Factors: We studied 5 factors that typically effect reaction rate. Record them here: 2)Surface Area 3)Mixing 4)Concentration 1)Temperature 5)Catalyst Experimental Design: 1. Utilizing the materials provided, design individual experiments for as many of these factors as you can to see what impact each of them has on the reaction rate. 2. Remember to keep in mind that a Controlled Experiment needs to have most things held constant while one variable is manipulated at a time. Be sure to think about which variables (things that could change) need to be held constant in order to do this in a controlled fashion. 3. You are limited to one tablet per experiment, and no more than 100 ml of water for any given experiment. 4. Your team will be allowed to run up to 4 individual experiments (in addition to baseline reaction). 5. Design for each experiment will be approved by instructor before you get a tablet to run the experiment. (Be sure to record the temperature as part of conditions for each experiment.) Exp Reaction Detailed Description of Conditions Prediction* Reaction Time % of Baseline (Exp secs/Base secs) (faster or slower) (# seconds) (exactly record all reaction factors each time) Factor #1 factor XX mls XX temp other faster XX sec XXX % #2 #3 #4 #5 * Prediction is faster or slower compared to Baseline experiment reaction time WRITE UP CONCLUSIONS ON BACK OF PAGE Conclusions: 1. Create a bar chart for your data. Include results for the baseline and all the experiments. Be sure to include a title for the chart and to clearly label all data and to label both axis. Reflections: 2. If any of your predictions were incorrect, try to you think of a reason(s) why and describe it below. Also, how you could improve your data with another experiment(s)? Lab was developed by Scott Grigg in Feb, 2010. Background for this lab: The main ingredients of Alka-Seltzer tablets are aspirin, citric acid, and sodium bicarbonate (NaHCO3). When sodium bicarbonate dissolves in water, it dissociates (splits apart) into sodium (Na+) and bicarbonate (HCO3−) ions. The bicarbonate reacts with hydrogen ions (H+) from the citric acid to form carbon dioxide and water. The reaction is described by the following chemical equation: Sodium Bicarbonate NaHCO3 ( Na+ + HCO3− Citric acid (C6H8O7) is a weak organic acid with 3 carboxyl groups: HYPERLINK "http://upload.wikimedia.org/wikipedia/commons/c/c5/Zitronens%C3%A4ure__Citric_acid.svg" INCLUDEPICTURE "http://upload.wikimedia.org/wikipedia/commons/thumb/c/c5/Zitronens%C3%A4ure__Citric_acid.svg/256px-Zitronens%C3%A4ure_-_Citric_acid.svg.png" \* MERGEFORMATINET H+ + HCO3− ( H2O + CO2 Citric acid From Wikipedia, the free encyclopedia Not to be confused with C" Vitamin C . HYPERLINK "http://en.wikipedia.org/wiki/Vitamin_C" \o "Vitamin Citric acid is a weak HYPERLINK "http://en.wikipedia.org/wiki/Organic_chemistry" \o "Organic chemistry" organic HYPERLINK "http://en.wikipedia.org/wiki/Acid" \o "Acid" acid , and it is a natural HYPERLINK "http://en.wikipedia.org/wiki/Preservative" \o "Preservative" preservative and is also used to add an acidic, or HYPERLINK "http://en.wikipedia.org/wiki/Taste" \l "Sourness" \o "Taste" sour , taste to foods and HYPERLINK "http://en.wikipedia.org/wiki/Soft_drink" \o "Soft drink" soft drinks . In HYPERLINK "http://en.wikipedia.org/wiki/Biochemistry" \o "Biochemistry" biochemistry , it is important as an intermediate in the HYPERLINK "http://en.wikipedia.org/wiki/Citric_acid_cycle" \o "Citric acid cycle" citric acid cycle and therefore occurs in the HYPERLINK "http://en.wikipedia.org/wiki/Metabolism" \o "Metabolism" metabolism of virtually all HYPERLINK "http://en.wikipedia.org/wiki/Life" \o "Life" living things . It can also be used as an environmentally benign cleaning agent. Citric acid exists in greater than trace amounts in a variety of HYPERLINK "http://en.wikipedia.org/wiki/Fruit" \o "Fruit" fruits and vegetables, most notably HYPERLINK "http://en.wikipedia.org/wiki/Citrus_fruit" \o "Citrus fruit" citrus fruits . HYPERLINK "http://en.wikipedia.org/wiki/Lemon" \o "Lemon" Lemons and HYPERLINK "http://en.wikipedia.org/wiki/Lime_(fruit)" \o "Lime (fruit)" limes have particularly high concentrations of the acid; it can constitute as much as 8% of the dry weight of these fruits (about 47 HYPERLINK "http://en.wikipedia.org/wiki/Gram_per_litre" \o "Gram per litre" g/L in the juices HYPERLINK "http://en.wikipedia.org/wiki/Citric_acid" \l "cite_note-2#cite_note-2" [3] ). The concentrations of citric acid in citrus fruits range from 0.005 HYPERLINK "http://en.wikipedia.org/wiki/Molarity" \o "Molarity" mol/L for oranges and grapefruits to 0.30 mol/L in lemons and limes. Within species these values vary depending on the HYPERLINK "http://en.wikipedia.org/wiki/Cultivar" \o "Cultivar" cultivar and the circumstances in which the fruit was grown. At room temperature, citric acid is a white crystalline powder. It can exist either in an HYPERLINK "http://en.wikipedia.org/wiki/Anhydrous" \o "Anhydrous" anhydrous (water-free) form or as a HYPERLINK "http://en.wikipedia.org/wiki/Hydrate" \o "Hydrate" monohydrate . The anhydrous form crystallizes from hot water, where as the monohydrate forms when citric acid is crystallized from cold water. The monohydrate can be converted to the anhydrous form by heating above 78 °C. Citric acid also dissolves in absolute (anhydrous) ethanol (76 parts of citric acid per 100 parts of ethanol) at 15 degrees Celsius. In chemical structure, citric acid shares the properties of other HYPERLINK "http://en.wikipedia.org/wiki/Carboxylic_acid" \o "Carboxylic acid" carboxylic acids . When heated above 175°C, it decomposes through the loss of HYPERLINK "http://en.wikipedia.org/wiki/Carbon_dioxide" \o "Carbon dioxide" carbon dioxide and HYPERLINK "http://en.wikipedia.org/wiki/Water_(molecule)" \o "Water (molecule)" Citric acid leaves a white crystalline precipitate. water . Citric acid is a slightly stronger acid than typical carboxylic acids because the anion can be stabilized by intramolecular hydrogen-bonding from other protic groups on citric acid