Georgia Influence of land-based activities on riverine delivery of contaminants to estuaries Principal Investigators: Aaron T. Fisk,University of Georgia; James T. Peterson, University of Georgia; Gregg T. Tomy, Department of Fisheries and Oceans, Canada ABSTRACT There is still limited knowledge about the impact of the use and distribution of chemicals being applied in modern society and produced as by-products of chemical and manufacturing processes and energy production. These chemicals tend to accumulate in, and are a concern for, aquatic ecosystems. The range of contaminants that have been measured in US waters is extensive, and includes such diverse chemicals as fluorinated stain guards to pesticides to personal care products. Such chemicals are of particular concern in rivers, which drain urban, industrial, and agricultural regions, but also the estuaries for which they drain into. As well, changes in stream-flow in rivers in recent years due to low and high rainfall can influence in the input of freshwater and associated contaminants into estuaries. Thus the potential contaminants found and their levels in estuaries are thus likely to be highly influenced by the land-use within its watershed and changes in stream-flow. Unfortunately, very little is known about the types and concentrations of contaminants following into estuaries, particularly in the southeast. Even less is understood about the impact of land-use and stream-flow on the delivery of contaminants to estuaries. Estuaries, which are important and productive ecosystems, are under increasing pressure from things such as land development, climate change, and over-fishing. With increasing land development in the southeast and along coastal zones there is a need to understand the threat posed by anthropogenic chemicals. This project will collect water in two major river systems in Georgia (Atlamaha and Ogeechee Rivers) to identify and quantify organic contaminants. These rivers have very different land-use patterns, both between and within the river systems. By collecting samples in strategic locations on the rivers and use geographic information system (GIS) data and models, we will identify the types and levels of contaminants associated with land-use practices. Such information will be highly useful for the State of Georgia, and interested citizens, so that best management plans (BMPs) for reducing the risk of anthropogenic contaminants in estuarine systems can be developed. The methods used in this project and the models developed are applicable to all rivers and estuaries and will provide useful information and guidance for research and monitoring throughout the US. This project will utilize state-of-art extraction methods and analytical instrumentation to provide the most comprehensive examination of organic contaminants in Georgia estuaries and their watersheds undertaken to date. This project represents the first step in understanding the role that contaminants play in the health of estuaries