A. SCIENTIST NOTES – Discovering the atom-15-16 skip this page NAME CONTRIBUTION/EXPERIMENT http://www.youtube.com/watch?v=Rb6MguN0Uj4 JOHN DALTON The above video includes Thomson J. J. THOMSON http://www.youtube.com/watch?v=dNp-vP17asI ERNEST RUTHERFORD NIELS BOHR https://www.youtube.com/watch?v=GhAn8xZQ-d8 1 MODEL http://www.pbslearningmedia.org/resource/lsps07.sci.phys.matter.theatom/the-atom/ Amu = atomic mass unit ATOMIC STRUCTURE - http://youtu.be/-0xxEWd9utc just watch 2 min PARTICLE LOCATION CHARGE 1 amu = 1/12 mass of _____ atom RELATIVE MASS proton ________amu neutron ________amu electron ________amu http://youtu.be/o-3I1JGW-Ck atom – the smallest part of an element that_________________________________________________________ http://youtu.be/dRfrvpVdKGM An atom is __________________________(no net charge,) which means that the # of protons (p+) = # of electrons (e-) Periodic Table “Box” Isotopic Notation http://youtu.be/BYiu0kIWd30 11 Na 22.9897 atomic number –___________________________________________________________________________ mass number ___________________________________________________________________________ 2 Look up the atomic number on the periodic table and add it to the bottom of the isotopic notation. For Sodium 23 For Oxygen 16 For fluorine For Sodium Na ______p+ _______#e- O ______p+ _______#e- _________n0 19 F ______p+ _______#e- _________n0 22 Na ______p+ _______#e- _________n0 _________n0 http://youtu.be/EboWeWmh5Pg example #1 The average atomic mass for C is ____________ Isotopes - ________________________________________________________________________________ They have the same #________ but different number of _______________. example #2 The average atomic mass for Li is (use periodic table) ____________ example #3 The average atomic mass for Cl is ____________ 3 http://youtu.be/m15DWkkGe_0 Do you see mass numbers or Average Atomic Mass (Average Atomic Weight) on the periodic table?_________________ ____________________________________ http://youtu.be/n4WZ0-fItt8 100 PRACTICE: ISOTOPES AND AVERAGE ATOMIC MASS Determine the average atomic mass of the following isotopes: 1. 80.0% 127I, 2. 50.0% 197Au, 3. 15.0% 55Fe, 17.0% 126I, 3.00% 128I 50.0% 198Au 85.0% 56Fe 4 4. 99.0% 1H, 0.800% 2H, 0.200% 3H 5. 95.0% 14N, 3.00% 15N, 2.00% 16N 6. 98.0% 12C, 2.00% 14C Magnesium has 3 isotopes: 23Mg Use: Detailed (if given) (Mg-23)……….23.020amu Relative abundance 0.500 % 24Mg (Mg-24)………..24.012amu 79.5 % 25Mg (Mg-25)………..24.997amu 20.0 % 5. CHALLENGE a. Chlorine exists in nature as Cl-35 (atomic mass of 34.969 amu) and Cl-37 (atomic mass of 36.966 amu). Since the atomic mass of chlorine is 35.453 amu, find the percent abundances of these 2 isotopes found in nature. 5 b. Copper is made up of 2 isotopes, Cu-63 and Cu-65. Given that the atomic mass of copper from the periodic table is 63.546, find the percent abundance of these 2 isotopes. http://youtu.be/WWc3k2723IM http://youtu.be/a9WrrF8esuY Symbol Atomic Number Mass Number # of Protons # of Neutrons Mg 13 65 30 Be Hg # of electrons 5 80 4 200 16 8 10 What do we call that? _________ Class Warm-up 1. Find the element with an atomic number of 19._________ 2. How many protons does that element have?_________ 3. How many electrons does that element have?_________ 4. Determine the # of protons and the # of electrons in one atom of calcium (Ca).___________________________ 6 5. List the number of protons, neutrons, and electrons in the following atoms: 14 37 C 18 Cl 6 O 17 8 p+ ______ _______ ______ n ______ _______ ______ e- ______ _______ ______ 6. Fill in the number of protons, neurons, and electrons in the following ions: 27 32 Al3+ S2- 13 16 p+ ______ _______ n ______ _______ e- ______ _______ 7. Fill in the following table: (a) Isotopic Notation ________ (b) ________ ATOMIC # __30____ ________ MASS # ________ ___80___ # PROTONS ________ ___35___ # NEUTRONS __36____ ________ # ELECTRONS __28____ ________ 7 8. C -12 is the most abundant isotope for carbon. C- 14 also exists. What does the number following the dash represent? _________ (how do we know that it cannot be the atomic number?____________________________________________________________ 9. (ex) Mg- 27 ______p+ _______#e- 10. (ex) H-- 1 ( _________n0 H-- 2 ) isotopic notation H--3 #p+ = ___ #p+ = ___ #p+ = #e- = ___ #e- = ___ #e- = ___ #n0 = ___ #n0 = ___ #n0 = ___ ___ Which choice below shows isotopes?________ Which choice is an atom and an ion?_________ Which choice is impossible?___________ Which choice is just 2 different elements?________ 4 w. 2 35 He H y. 1 17 16 16 17 O 8 z. O 8 Cl 17 14 C 6 7 -1 Cl 2 x. 35 C 6 Symbol Mass # Atomic # # e- #p+ #n Isotopic Notation (Don’t look up and round. Add up the ___ and ___) A-3 (look up symbol and put mass # and atomic # and charge) 83 B 126 78 C 184 D 53 74 25 D E+5 117 31 210 80 9 The Mole a. http://youtu.be/wHwGm9oL-GA http://youtu.be/NMdN1LtHuDA WATCH ALL 3 OF THESE VIDEOS!!!!! http://youtu.be/HMAOrGpkTsQ 1 mole = molar mass MASS (g) MOLE (look it up on the PT!) 1 mole = 6.02 x 1023 atoms PARTICLES (ATOM) B. MOLAR MASS AND MOLE CONVERSIONS 1 mole = 6.02 x 1023 particles and 1 mole = _____grams (molar mass found on periodic table) Avogadro’s number: 6.02 x 1023 particles= 1 mole 6.02 x 1023 atoms = 1 mole 6.02 x 1023 molecules = 1 mole (covalent) 6.02 x 1023 formula units = 1 mole (ionic) 11 Molar Mass: the mass of of 1 mole of an element (in grams) Molar mass of Na is 22.99 g/mol. (use Periodic table) Molar mass of C is 12.01 g/mol. (use Periodic table) Molar mass of He is 4.00 g/mol. (use Periodic table) Na 22.9897 10 1 CONVERSION FACTORS: mole = 6.02 x 1023 atoms 1 mole = atomic mass (g) 1. How many atoms are in 6.5 moles of zinc? 6.5 moles Zn 6.02 x 1023 atoms Zn = 3.91 x 1024 atoms Zn 1 mole Zn 2. How many moles of argon are in a sample containing 2.4 x 1024 atoms of argon? 2.4 x 1024 atoms of argon 1 mole 6.02 x 1023 atoms = 3.99 mol of argon 3. How many moles are in 2.5g of lithium? 4. Find the mass of 4.8moles of iron. CONVERSION FACTORS: 1 mole = 6.02 x 1023 atoms Two Step Problems: 1. What is the mass of 2.25 x 1025 atoms of lead? 2. How many atoms are in 10.0g of gold? 11 1 mole = atomic mass (g) PRACTICE PROBLEMS: a. Convert to moles: 1. 625g of copper 2. 4.25 x 1026 atoms of barium b. How many atoms are in: 1. 2.35 moles of carbon 2. 4.0g of potassium 3. 9500g of iron c. Determine the mass of: 1. 0.250 moles of aluminum 2. 3.48 x 1022 atoms of tin 12 3. 4.48 x 1021 atoms of magnesium - report your answer in regular and scientific notation Try: 4. How many moles is 2.50kg of lead? 5. Find the mass, in cg, of 3.25 x 1021 atoms of lithium 13