UNIT 8: SOLIDS, LIQUIDS, AND GASES THE FOREST: Gas particles move independently of each other and are far apart. The behavior of gas particles can be modeled by the kinetic molecular theory. In liquids and solids, unlike gases, particles are close to each other. THE TREES: 6.1 Using the kinetic molecular theory, explain the behavior of gases and the relationship between pressure and volume (Boyle’s law), volume and temperature (Charles’s law), pressure and temperature (Gay-Lussac’s law), and the number of particles in a gas sample (Avogadro’s hypothesis). Use the combined gas law to determine changes in pressure, volume, and temperature. List and explain the basic assumptions of the kinetic molecular theory. Relate pressure to molecular motion. Relate temperature and energy transfer to molecular motion. Determine the relative velocities of gas molecules at the same temperature. Relate the laws of Boyle, Dalton, and Charles and perform calculations using these laws. Solve problems involving the change of more than one condition for gases. Explain Graham’s law and solve problems using it. State Avogadro’s principle. 6.2 Perform calculations using the ideal gas law. Understand the molar volume at 273 K and 1 atmosphere (STP). Explain the concept of an ideal gas. Differentiate between an ideal gas and a real gas. Describe the conditions of STP. Define molar volume. Explain and use the ideal gas equation. Compute the molar mass of a gas from its mass, temperature, pressure, and volume. Solve gas volume-mass, mass-gas volume and volume-volume problems. Identify the limiting reactant and be able to solve problems based upon it. 6.3 Using the kinetic molecular theory, describe and contrast the properties of gases, liquids, and solids. Describe characteristics of substances in each of the three common states of matter in terms of the kinetic molecular theory and intermolecular forces within the substances. Describe characteristics of all solid substances. Explain the relationship of melting point to bonding type and crystal type. Explain the properties of liquids in terms of the kinetic molecular theory. Explain the unique properties of water in terms of its molecular structure. Explain surface tension and capillary rise on the basis of unbalanced surface forces. IMPORTANT VOCABULARY Absolute zero adiabatic system amorphous anhydrous Avogadro’s principle barometer Body-centered cubic Face-centered cubic Graham’s law Hexagonal closest packing Hydrated ion Hydrogen bond hygroscopic Ideal gas pascal Phase diagram plasma Point mass polymorphous pressure Real gas Boyle’s law Capillary rise Charles’s law Crystal Cubic closest packing Dalton’s law Deliquescent Diffusion Dislocation Doped Dynamic equilibrium Enthalpy of fusion Enthalpy of vaporization Equilibrium Excess reactant Ideal gas equation isomorphous Kelvin scale Kinetic theory Limiting reactant Liquefaction Liquid crystal Macromolecule Manometer Mean free path Melting point Metastable Molar volume Network crystal Normal boiling point Reversible change saturated Simple cubic Space lattice Standard atmospheric press. Standard temperature STP sublimation Surface tension Triple point Unit cell Vapor viscosity volatile STUDY GUIDE CONTENT: Assumptions of kinetic molecular theory Define pressure in terms of particle motion Define temperature in terms of particle motion Define kinetic energy in terms of particle motion and temperature STP Avogadro’s principle Direct v. inverse for Boyle, Charles, and Gay-Lussac Ideal v. real gases Molar volume Properties unique to solids, liquids, and gases Compare and contrast solids, liquids, and gases Four major types of solids MATH SKILLS: Convert pressures and temperatures to standard units Boyle’s law, Charles’s law and Gay-Lussac’s law Dalton’s law of partial pressures Combined Gas law Graham’s law of diffusion and effusion Ideal gas law Gas stoichiometry at STP and at non-STP