Supplementary Material (ESI) for Journal of Materials Chemistry
This journal is © The Royal Society of Chemistry 2002
Supporting Information Available: 1. XRD pattern of the PbS CNWs, 2. FTIR
spectrum of the polymer, 3. TEM images of more PbS CNWs
10
20
30
40
50
60
331
400
222
311
220
Intensity (a.u.)
111
200
Manuscript No. B111187F
70
2/degree
1. XRD pattern of the PbS CNWs.
1
Supplementary Material (ESI) for Journal of Materials Chemistry
This journal is © The Royal Society of Chemistry 2002
(a)
(b)
1.0
(b)
1480
1566
1648
3261
0.2
1314
0.4
819
1160
0.6
3366
Transmittance (%)
0.8
0.0
4000
3500
3000
2500
2000
Wavenumber cm
1500
1000
500
-1
2. FTIR spectra: (a) the standard spectrum of polyacrylamide obtained from The
Aldrich Library of Infrared Spectra, Edition Ⅲ, No. 18127-2, (b) the spectrum of
poly[N-(2-Aminoethyl)acrylamide], its sample was obtained from the solvent after the
synthetic process was carried out by fully separating the PbS CNWs and evaporating
the small molecules (ethylenediamine, H2O). Compared to (a), a characteristic peak of
-CO-NH-R at 1566 cm-1 appeared in (b) resulting from the combination of the bending
vibration of NH and the stretching vibration of C-N,* which was apparently different
from that of –CO-NH2 [at ~1620 cm-1, δ(NH2)].** The wide peak at 3366-3261 cm-1
resulted from the stretching vibration of NH existing in the structure
–CO-NH-CH2-CH2-NH2. The deformation vibration of the NH2 in -CH2-CH2-NH2
was located at 1615 cm-1, which could not separated from that of the stretching
vibration of C=O (1641.8 cm-1).
*L.C. Afremow, K. E. Isakson, D. A. Netzel, D. J. Tessari, J. T. Vandeberg, Infrared Spectroscopy Its Use in the
Coating Inductry, Federation of Societies for Paint Technology, Philadelphia, 1969.
**N. B. Colthup, L. H. Daly, S. E. Wiberley, Introduction to Infrared and Raman Spectroscopy, Academic Press,
New York, 1975.
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Supplementary Material (ESI) for Journal of Materials Chemistry
This journal is © The Royal Society of Chemistry 2002
3. TEM images of more PbS CNWs.
Notes The first number (X) in the photos ×103 shows the amplifications of the samples
in this paper.
3