CHEMFAX PRODUCTS Ltd. 1106-46 Avenue S.E. Calgary, Alberta T2G 2A6 (403)287-2055 Fax(403)287-6545 In Case of Emergency Only: Phone CANUTEC: (613)996-6666 ‘SOLVENT’ WHMIS CODES: B3 D2B SECTION 1: MATERIAL IDENTIFICATION Product Identifier: Solvent Chemical Name: Solvent Chemical Family: Petroleum Distillates Chemical Formula: Not applicable Molecular Weight: Not applicable Trade Name-Synonym: Solvent Material Use: Industrial Solvent Flammability: 2 Reactivity: 0 Health: 1 Personal Protection: 2 SECTION 2: HAZARDOUS INGREDIENTS OF MATERIAL Hazardous Ingredients: Solvent Approximate Concentrations %: 100 % Exposure Limits: 100 ppm Stoddards Solvent 25ppm Trimethylbenzene LD:50 LC:50/Species/Route: LD:50 5g/kg(oral rat), LC:50 5g/m3 (rat) CAS#: 8052-41-3 SECTION 3: PHYSICAL DATA FOR MATERIAL Physical State: Liquid Odour and Appearance: Light coloured liquid with aromatic odour. Odour Threshold (PPM): 1 - 30 ppm Specific Gravity: 079 @ 15.5 oC Vapour Pressure (mm Hg): <0.133 KPA @ 20oC Vapour Density (air = 1): 4.8 Boiling Point (°oC): 156 to 197°oC Solubility in Water: Insoluble % Volatile: 100 % pH: Not available Density: Not available Coefficient of Water/Oil: Not available Freezing Point: Not available SECTION 4: FIRE AND EXPLOSION HAZARD Flammability: Flammable Flash Point (°oC): 43 oC TCC Upper Flammable Limit (% by volume): 13.3 % Lower Flammable Limit (% by volume): 1 % Autoignition Temperature (°oC): 229 oC Hazardous Combustion Products: Toxic gases will form upon combustion Explosive Power: Sensitivity to Static Discharge: Means of Extinction: Special Procedures: Will form explosive mixtures with air Yes Foam, water fog, dry chemicals Fire fighters should wear self contained breathing apparatus and full protective clothing. Use water spray to disperse vapours and to cool containers and nearby structures exposed to fire. Vapours may settle in low areas, or travel along the ground to ignition sources. Storage and pumping equipment should be grounded. SECTION 5: REACTIVITY Chemical Stability: Under Fire Conditions: Incompatibility to Products: Reactivity, and under what Conditions: Hazardous Decomposition Products: Hazardous Polymerization: Conditions to Avoid: Materials to Avoid: SECTION 6: TOXICOLOGICAL AND HEALTH Route of Entry Skin Contact: Route of Entry Skin Absorption: Route of Entry Eye Contact: Route of Entry Inhalation Acute: Route of Entry Inhalation Chronic: Route of Entry Ingestion: Reproductive Effects: Mutagenicity: Teratogenicity: Carcinogenicity: Synergenistic Materials: Sensitization to Product: Exposure Limits: Irritancy of Product: LD:50 LC:50/Species/Route: Effects of Chronic Exposure: Effects of Acute Exposure: SECTION 7: PREVENTATIVE MEASURES Stable Flammable, will produce irritant fumes, smoke, CO and CO2 Strong oxidizing agents Strong oxidizing agents No data Will not occur High temperatures, sparks, open flames and sources of ignition. Strong oxidizing agents DATA Yes Yes Yes Yes Yes Yes No data No data No data No data No data No data 100 ppm Stoddards Solvent 25ppm Trimethylbenzene Irritant to eyes, nose, mouth, throat, skin and respiratory tract. LD:50 5g/kg(oral rat), LC:50 5g/m3 (rat) May cause abdominal pain, CNS depression, coma, possible death due to respiratory failure. Intentional misuse of solvent e.g. glue sniffing over prolonged periods of time have caused neurological effects as well as liver and kidney injury. May cause dermatitis, burning of the mouth and throat. May cause severe irritation of eyes, nose, throat, respiratory tract, corneal damage, headache, dizziness, drowsiness, nausea, vomiting, abdominal pain, lack of coordination and defatting of the skin. Personal Protective Equipment: Gloves (Specify): Respirator (Specify): Eyes (Specify): Footwear (Specify): Clothing (Specify): Other (Specify): Engineering Controls: Leak and Spill Procedure: Waste Disposal: Handling Procedures and Equipment: Storage Requirements: Special Shipping Information: If engineering controls are effective no special requirements should be needed. Wear full protective equipment with self contained breathing apparatus if large spills occur or exposure limits will be exceeded Rubber, neoprene. SCBA or SAR with organic vapour cartridge if exposure limits will be exceeded. Safety goggles. Rubber boots. Rubber apron, rubber pants and jacket if conditions require such - ie spill or accidental release. Eye wash fountain, safety shower. Mechanical ventilation / exhaust systems should be in place. Use explosion proof equipment. Restrict access to the area until completion of clean up. Eliminate all ignition sources. Ventilate area. Contain spill with earth or sand. Collect material into a suitable container for disposal. Dispose of according to Federal, Local and Provincial Regulations. Use material with plenty of ventilation. Keep container closed at all times. Do not smoke in area. Empty container may contain flammable residue. Store in cool, dry, well ventilated area. Keep away from fire, sparks, open flames and other sources of ignition. Naptha Solvent Class 3.3 U.N. 1256 P.G. III SECTION 8: FIRST AID MEASURES Skin: Eyes: Ingestion: Inhalation: General Advice: Flush with plenty of water for at least 15 minutes. Remove and discard contaminated clothing immediately. Flush affected area with plenty of water and call a physician at once. Flush with plenty of water for at least 15 minutes. Keep eye lids open when flushing with water and get medical attention at once. Never give anything by mouth to a convulsing or unconscious person. Do not induce vomiting. Drink plenty of water. If vomiting occurs, have person lean forward to reduce aspiration. Get medical attention immediately. General Supportive Measures: comfort, warmth, rest. Move victim to fresh air. If breathing stops, give CPR. Avoid mouth to mouth contact. Give oxygen by trained personnel only. Keep out of reach of children. SECTION 9: PREPARATION DATE OF M.S.D.S. Prepared by: Technical Service Dept., Chemfax Products Ltd. (403)287-2055 August 1, 2002 Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of it’s subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Chemfax Products Ltd. expressly disclaims all expressed or implied warranties of merchantability and fitness for a particular purpose with respect to the product provided.