http://www.douglasproducts.com/agricultural/msds_mal.html DOUGLAS PRODUCTS & PACKAGING 1550 E. Old 210 Hwy., Liberty, Missouri (816) 781-4250 MATERIAL SAFETY DATA SHEET I. PRODUCT IDENTIFICATION MANUFACTURER'S NAME:Douglas Products & Packaging ADDRESS:1550 E. Old 210 Hwy., Liberty, Missouri 64068 EMERGENCY PHONE NUMBER:1-800-424-9300 REGULAR PHONE NUMBER:(816) 781-4250 FAX NUMBER:(816) 781-1043 MALATHION 57% DATE PREPARED:February 5, 1999 II. HAZARDOUS INGREDIENTS MATERIAL OR COMPONENT CAS# DATA *Malathion Technical (0,0121-75-5 dimethyl dithiophosphate of diethyl mercaptosuccinate) Inert Ingredients T-Mulz Light Aromatic 64742-95-6 M & P Xylene 1330-20-7 Cumene 98-82-8 Trimethyl Benzene 25551-13-7 % 57.00 OSHA PEL TLV HAZARD 15mg/m3 10mg/m3 43.00 100ppm 50ppm 150ppm 50ppm 25ppm *Equivalent to 5 lbs. of premium grade malathion per gal. Formulated with CYTHION Insecticide "The Premium Grade Malathion". HMIS:Health-2, Flammability-2, Reactivity-1, Personal Protection-H http://www.douglasproducts.com/agricultural/msds_mal.html III. PHYSICAL DATA BOILING POINT:240 Degrees F. MELTING POINT:30 SPECIFIC GRAVITY:1.1020 VAPOR PRESSURE:.00004mmHg VAPOR DENSITY:1.1 SOLUB. IN WATER:V.S. EVAPORATION RATE:.05 APPEARANCE AND COLOR:Mercaptan Odor, Clear Brown IV. FIRE AND EXPLOSION DATA FLASH POINT:140 Degrees F. FLAMMABLE LIMITS:Lower-N/A, Upper-N/A EXTINGUISHING MEDIA:CO2, Foam Dry Chemical or Carbon Dioxide for small fires. SPECIAL FIRE FIGHTING PROCEDURES:Firemen should wear self-contained breathing apparatus & rubber clothing, fight fire upwind, avoid heavy hose streams. UNUSUAL FIRE AND EXPLOSION HAZARDS:Vapors and fumes from fire are hazardous, evacuate people downwind from the fire. V. HEALTH HAZARD INFORMATION ROUTES OF ENTRY:Inhalation: Yes, Skin: Yes, Ingestion: Yes HEALTH HAZARDS:Acute may cause death due to Chlolinesterase Inhibition. EFFECTS OF EXPOSURE:Excessive sweating, headache, weakness, giddiness, nausea, vomiting, stomach pains, blurred vision, slurred speech, muscle twitching and diarrhea. EMERGENCY AND FIRST AID:EYES-Flush with water for at least 15 minutes, lifting eyelids frequently. SKIN-Wash with soap and water, remove and wash contaminated clothing before reuse. INHALATION-Move victim to fresh air, artificial respiration if necessary. INGESTION-DO NOT induce vomiting. NOTE TO PHYSICIAN: ADMINISTER ATROPINE SULFATE. DO NOT GIVE MORPHINE. CARCINOGINICITY:NTP-No, IARC-No, OSHA-No VI. REACTIVITY DATA http://www.douglasproducts.com/agricultural/msds_mal.html CONDITIONS CONTRIBUTING TO INSTABILITY:Storage at temperatures above 120 Degrees F. leads to non-hazardous decomposition. INCOMPATIBILITY:Aramite, Endrin, Carbaryl, Strong Alkalies and Strong Oxidizers. HAZARDOUS DECOMPOSITION PRODUCTS:Thermal Decomposition may produce carbon monoxide, carbon dioxide and sulfur dioxide. CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION:Temperatures above 120 Degrees F. VII. SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN MATERIAL IS RELEASED OR SPILLED:Absorb spill with sand, clay or soda ash, sweep up and place in a waste disposal container. Decontaminate area with Alkaline solution, contain and collect rinsate. WASTE DISPOSAL METHOD:Dispose of absorbent and rinsate in accordance with local disposal authorities. VIII. SPECIAL PROTECTION INFORMATION VENTILATION REQUIREMENTS:Local exhaust-General room ventilation. RESPIRATORY PROTECTION:Concentration exceeds, TLV, wear U.S. Bureau of Mines respirator approved for Organophosphate Insecticide. EYE:Splash Proof Goggles. GLOVES:Rubber. OTHER CLOTHING AND EQUIPMENT:Wear clothing designed to prevent eye and skin contact. IX. SPECIAL PRECAUTIONS PRECAUTIONARY STATEMENTS:Wash thoroughly after handling and before eating and smoking. OTHER HANDLING AND STORAGE REQUIREMENTS:Do not contaminate feed or foodstuffs, wash hands, arms and face with soap and water after handling. Change all contaminated clothing and wash it with soap and water before reuse.