Title: Emerging chemicals and analytical methods Author(s): Morley MC, Snow DD, Fox A, Youngblood D Source: WATER ENVIRONMENT RESEARCH 76 (6): 481-530 2004 Document Type: Review Language: English Cited References: 111 Times Cited: 0 KeyWords Plus: PERSONAL CARE PRODUCTS; CHROMATOGRAPHY-MASS SPECTROMETRY; SOLID-PHASE EXTRACTION; NONSTEROIDAL ANTIINFLAMMATORY DRUGS; POLYBROMINATED DIPHENYL ETHERS; N-NITROSODIMETHYLAMINE NDMA; DISINFECTION BY-PRODUCTS; SEWAGE-TREATMENT PLANTS; WASTE-WATER; DRINKING-WATER Addresses: Morley MC (reprint author), Univ Nebraska, Dept Civil Engn, W348 Nebraska Hall, Lincoln, NE 68588 USA Univ Nebraska, Water Sci Lab, Lincoln, NE 68588 USA Univ Nebraska, Dept Biol Syst Engn, Lincoln, NE 68588 USA Univ Nebraska, Environm Engn Grad Program, Lincoln, NE 68588 USA E-mail Addresses: mmorley2@unl.edu Publisher: WATER ENVIRONMENT FEDERATION, 601 WYTHE ST, ALEXANDRIA, VA 22314-1994 USA Subject Category: ENGINEERING, ENVIRONMENTAL; ENVIRONMENTAL SCIENCES; LIMNOLOGY; WATER RESOURCES Title: Fate of environmental pollutants Author(s): Darnault C Source: WATER ENVIRONMENT RESEARCH 76 (6): 2297-2344 2004 Document Type: Article Language: English Cited References: 94 Times Cited: 0 Abstract: This section covers studies published during the calendar year 2003 on the fate of environmental pollutants in soil, groundwater and surface water resources. Studies related to water quality and sources of pollution by environmental pollutants as well as reaction kinetics and modeling are reviewed in detail. Also included in the coverage of the present review is research on pollutants such as nutrients, xenobiotics, pathogens, metals, and radionuclides. KeyWords Plus: HEAVY-METAL CONCENTRATIONS; ORGANIC-COMPOUNDS VOCS; UNITED-STATES; OVERLAND-FLOW; ARTIFICIAL RADIONUCLIDES; CRYPTOSPORIDIUMPARVUM; NITRATE CONTAMINATION; CONSTRUCTED WETLAND; POTENTIAL POLLUTION; NUTRIENT MANAGEMENT Addresses: Darnault C (reprint author), Environm Engn & Technol Inc, Water Resources Grp, 712 Gum Rock Court, Newport News, VA 23606 USA Environm Engn & Technol Inc, Water Resources Grp, Newport News, VA 23606 USA E-mail Addresses: cdarnault@eetinc.com Publisher: WATER ENVIRONMENT FEDERATION, 601 WYTHE ST, ALEXANDRIA, VA 22314-1994 USA Subject Category: ENGINEERING, ENVIRONMENTAL; ENVIRONMENTAL SCIENCES; LIMNOLOGY; WATER RESOURCES IDS Number: 905DM ISSN: 1061-4303 Title: Physico-chemical processes Author(s): Ahmad R, Begum S, Hoek EMV, Karanfil T, Genceli EA, Yadav A, Trivedi P, Zhang CL Source: WATER ENVIRONMENT RESEARCH 76 (6): 823-1002 2004 Document Type: Review Language: English Cited References: 491 Times Cited: 0 KeyWords Plus: WASTE-WATER TREATMENT; ZERO-VALENT IRON; ACTIVATED CARBON ADSORPTION; WET AIR OXIDATION; AGRICULTURAL DRAINAGE WATER; HYDROXYL RADICAL GENERATION; PARTICLE-SIZE DISTRIBUTION; HYDROPHOBIC COTTON FIBERS; REVERSE-OSMOSIS MEMBRANES; OZONE-ENHANCED OXIDATION Addresses: Ahmad R (reprint author), KHAFRA Engn Consultants Inc, 230 Peachtree St 200, Atlanta, GA 30303 USA KHAFRA Engn Consultants Inc, Atlanta, GA 30303 USA Georgia Inst Technol, Atlanta, GA 30332 USA Univ Calif Riverside, Dept Chem & Environm Engn, Riverside, CA 92521 USA Clemson Univ, Dept Environm Engn, Clemson, SC 29631 USA Univ Alaska Fairbanks, Dept Civil & Environm Engn, Fairbanks, AK 99775 USA Univ Houston Clear Lake City, Dept Environm Sci, Houston, TX 77058 USA Publisher: WATER ENVIRONMENT FEDERATION, 601 WYTHE ST, ALEXANDRIA, VA 22314-1994 USA Subject Category: ENGINEERING, ENVIRONMENTAL; ENVIRONMENTAL SCIENCES; LIMNOLOGY; WATER RESOURCES Title: A perspective of riverbank filtration Author(s): Ray C, Grischek T, Schubert J, Wang JZ, Speth TF Source: JOURNAL AMERICAN WATER WORKS ASSOCIATION 94 (4): 149-+ APR 2002 Document Type: Article Language: English Cited References: 35 Times Cited: 6 Abstract: Riverbank filtration (RBF) is a process In hili pumping wells located along riverbanks induce a portion of the river water to flow toward the wells. During RBF, which has many similarities to slow-sand filtration, river water contaminants are attenuated from a combination of processes such as filtration, microbial degradation, sorption to sediments and aquifer sand, and dilution with background groundwater. RBF systems have been operating in Europe since the 1870s. In the United States, there has been renewed interest among large- to medium-sized utilities to use It as a mechanism of water production to reduce treatment costs and to meet regulations on pathogens, disinfection by-products, and other contaminants under the Surface Water Treatment Rule. Although filtrate water quality from RBF systems can vary based on river conditions, it is possible that appropriately designed systems; can serve as pretreatment for drinking water, and at the same time, the utility can receive log-removal credits for pathogens and particle,. In addition, RBF can be used as a pretreatment for membrane filtration. In the United States, a knowledge gap exists oil the benefits and limitations of using RBF. This article addresses those gaps, outlining the benefits and limitations of the process. It also illustrates that RBF can be a viable alternative to surface water at suitable sites. KeyWords Plus: WATER; INFILTRATION; ELBE Addresses: Ray C (reprint author), Univ Hawaii Manoa, Dept Civil Engn, 2540 Dole St, Honolulu, HI 96822 USA Univ Hawaii Manoa, Dept Civil Engn, Honolulu, HI 96822 USA Tech Univ Dresden, Inst Water Chem, Dresden, Germany Stadtwerke Dusseldorf AG, Dusseldorf, Germany Louisville Water Co, Louisville, KY USA US EPA, Water Supply & Water Resources Div, Cincinnati, OH 45268 USA Title: Riverbank filtration - An overview Author(s): Kuehn W, Mueller U Source: JOURNAL AMERICAN WATER WORKS ASSOCIATION 92 (12): 60-+ DEC 2000 Document Type: Article Language: English Cited References: 12 Times Cited: 16 Abstract: Bank filtration is the process that occurs when river water passes through the river's banks and proceeds to the groundwater table. Natural riverbank filtration has long been recognized as a water treatment. Many substances present in surface water, such as natural organic matter or biodegradable micropollutants, are largely and in most cases completely removed by bank filtration. Furthermore, bank filtration is able to compensate for concentration or temperature peaks and provides protection against shock loads. Bank filtration is so effective in treating river water and offers so many additional benefits that it can replace or support treatment steps in a water plant. Although not widely used by utilities in the United States, bank filtration has been successfully practiced by German water providers for many years. Their experience indicates that bank filtration is a suitable technology for river water under certain conditions. Because it replaces or supports other treatment, bank filtration can help reduce costs for utilities using river water. Because it is a natural process, bank filtration wins support from consumers who want safe, but not highly treated, drinking water supplies. Addresses: Kuehn W (reprint author), DVGW Water Technol Ctr, Karlsruher Str 84, Karlsruhe, D-76139 Germany DVGW Water Technol Ctr, Karlsruhe, D-76139 Germany Publisher: AMER WATER WORKS ASSOC, 6666 W QUINCY AVE, DENVER, CO 80235 USA Title: The promise of bank filtration Author(s): Tufenkji N, Ryan JN, Elimelech M Source: ENVIRONMENTAL SCIENCE & TECHNOLOGY 36 (21): 422A-428A NOV 1 2002 Document Type: Article Language: English Cited References: 47 Times Cited: 13 KeyWords Plus: GROUND-WATER; RIVER WATER; ORGANIC-MATTER; INFILTRATION; AQUIFER; BEHAVIOR; QUALITY; SWITZERLAND; MIGRATION; TRANSPORT Addresses: Tufenkji N (reprint author), Yale Univ, New Haven, CT 06520 USA Yale Univ, New Haven, CT 06520 USA Univ Colorado, Boulder, CO 80309 USA Title: MULHEIM PROCESS Author(s): SONTHEIMER H, HEILKER E, JEKEL MR, NOLTE H, VOLLMER FH Source: JOURNAL AMERICAN WATER WORKS ASSOCIATION 70 (7): 393-396 1978 Document Type: Article Language: English Cited References: 15 Times Cited: 59 Addresses: SONTHEIMER H (reprint author), UNIV KARLSRUHE, ENGLER BUNTE INST, DEPT WATER CHEM, KARLSRUHE, D-7500 FED REP GER RHEIN WESTFAL TH AACHEN, WASSERWERK GESELL, AACHEN, D-5100 FED REP GER Publisher: AMER WATER WORKS ASSOC, 6666 W QUINCY AVE, DENVER, CO 80235 Subject Category: ENGINEERING, CIVIL; WATER RESOURCES Title: EXPERIENCE WITH RIVERBANK FILTRATION ALONG THE RHINE RIVER Author(s): SONTHEIMER H Source: JOURNAL AMERICAN WATER WORKS ASSOCIATION 72 (7): 386-390 1980 Document Type: Article Language: English Cited References: 8 Times Cited: 26 Addresses: UNIV KARLSRUHE, ENGLER BUNTE INST, KARLSRUHE, D-7500 FED REP GER Publisher: AMER WATER WORKS ASSOC, 6666 W QUINCY AVE, DENVER, CO 80235 Subject Category: ENGINEERING, CIVIL; WATER RESOURCES Title: Environmental impact and mechanisms of the biological clogging of saturated soils and aquifer materials Author(s): Baveye P, Vandevivere P, Hoyle BL, DeLeo PC, de Lozada DS Source: CRITICAL REVIEWS IN ENVIRONMENTAL SCIENCE AND TECHNOLOGY 28 (2): 123-191 1998 Document Type: Review Language: English Cited References: 244 Times Cited: 41 Abstract: The biological clogging of natural porous media, often in conjunction with physical or chemical clogging, is encountered under a wide range of conditions. Wastewater disposal, artificial groundwater recharge, in situ bioremediation of contaminated aquifers, construction of water reservoirs, or secondary oil recovery are all affected by this process. The present review provides an overview of the techniques that are used to study clogging in the laboratory, or to monitor it in field applications. After a brief survey of the clogging patterns most commonly observed in practice, and of a number of physical and chemical causes of clogging, the various mechanisms by which microorganisms dog soils and other natural porous media are analyzed in detail. A critical assessment is also provided of the few mathematical models that have been developed in the last few years to describe the biological clogging process. The overall conclusion of the review is that although information is available on several aspects of the biological clogging of natural porous media, further research is required to predict its extent quantitatively in a given situation. This is particularly true in cases that involve complicating factors such as predation or competition among organisms. Author Keywords: bioremediation; groundwater; soil; hydraulic conductivity; artificial recharge; bacteria; microorganisms; subsurface environment KeyWords Plus: SCANNING ELECTRON-MICROSCOPY; HYDRAULIC CONDUCTIVITY; POROUS-MEDIA; EXOPOLYSACCHARIDE PRODUCTION; ARTIFICIAL RECHARGE; SAND COLUMNS; METHANOSARCINA-BARKERI; MATHEMATICAL-MODELS; PHYSICALPROPERTIES; SANDSTONE CORES Title: Human pharmaceuticals in wastewater treatment processes Author(s): Jones OAH, Voulvoulis N, Lester JN Source: CRITICAL REVIEWS IN ENVIRONMENTAL SCIENCE AND TECHNOLOGY 35 (4): 401-427 2005 Document Type: Review Language: English Cited References: 133 Times Cited: 0 Abstract: The presence of human pharmaceutical compounds in surface waters is an emerging issue in environmental science. In this study the occurrence and behavior of human pharmaceuticals in a variety of wastewater treatment processes is reviewed. Although some groups are not affected by sewage treatment processes others are amenable to degradation, albeit incomplete. While water purification techniques such as granular activated carbon could potentially remove these pollutants from wastewater streams, the high cost involved suggests that more attention should be given to the potential for the optimization of current treatment processes, and reduction at source in order to reduce environmental contamination. Author Keywords: fate; pharmaceuticals; pollution; sewage treatment plants; wastewater KeyWords Plus: SEWAGE-TREATMENT PLANTS; PERSONAL CARE PRODUCTS; FLUOROQUINOLONE ANTIBACTERIAL AGENTS; CHROMATOGRAPHY-MASS SPECTROMETRY; RAY CONTRAST-MEDIA; IN-GROUND WATER; AQUATIC ENVIRONMENT; DRINKING-WATER; MUNICIPAL SEWAGE; STEROID ESTROGENS Addresses: Lester JN (reprint author), Univ London Imperial Coll Sci Technol & Med, Fac Life Sci, Dept Environm Sci & Technol, London, SW7 2BP England Univ London Imperial Coll Sci Technol & Med, Fac Life Sci, Dept Environm Sci & Technol, London, SW7 2BP England E-mail Addresses: j.lester@imperial.ac.uk Publisher: TAYLOR & FRANCIS INC, 325 CHESTNUT ST, SUITE 800, PHILADELPHIA, PA 19106 USA Title: Water analysis: Emerging contaminants and current issues Author(s): Richardson SD, Ternes TA Source: ANALYTICAL CHEMISTRY 77 (12): 3807-3838 JUN 15 2005 Document Type: Review Language: English Cited References: 195 Times Cited: 0 KeyWords Plus: DISINFECTION BY-PRODUCTS; TANDEM MASS-SPECTROMETRY; SOLID-PHASE EXTRACTION; POLYBROMINATED DIPHENYL ETHERS; TERT-BUTYL ETHER; NATURAL ORGANIC-MATTER; TIME-OF-FLIGHT; CYANOBACTERIAL PEPTIDE HEPATOTOXINS; ENDOCRINE-DISRUPTING CHEMICALS; BROMINATED FLAME RETARDANTS Addresses: Richardson SD (reprint author), US EPA, Natl Exposure Res Lab, Athens, GA 30605 USA US EPA, Natl Exposure Res Lab, Athens, GA 30605 USA Fed Inst Hydrol, Koblenz, D-56068 Germany Publisher: AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA Subject Category: CHEMISTRY, ANALYTICAL Title: An overview of the environmental effects of land application of farm effluents Author(s): Wang HL, Magesan GN, Bolan NS Source: NEW ZEALAND JOURNAL OF AGRICULTURAL RESEARCH 47 (4): 389-403 DEC 2004 Document Type: Article Language: English Cited References: 74 Times Cited: 0 Abstract: New Zealand dairy and pig farms generate significant amounts of effluents that contain high concentrations of nutrients such as nitrogen (N), potassium (K), and phosphorus (P), and various trace contaminants (e.g., heavy metals, organic compounds, and endocrine-disrupting chemicals). Land application is a preferred option for farm effluent management. Regulations have been imposed to limit the land application of farm effluent to 150200 kg N ha I to minimise potential leaching loss of nitrate to groundwater. However, focusing mainly on nutrient recycling from farm effluent application has resulted in the effects of other effluent constituents, such as microbial pathogens, heavy metals, odorants and oestrogens, on the receiving ecosystems being overlooked. In this literature review, we assess land-applied farm effluents and their beneficial and potentially adverse effects on the receiving environment. Long-term application of farm effluent based on N loading can lead to P and heavy metal accumulation in the soil. High concentrations of K in effluent are likely to cause pasture nutrient imbalance and induce animal health problems. Recently, there has been some research interest in the role of runoff P in eutrophication of receiving water, effluentderived pathogen survival and movement in soil ecosystems, effect of effluent-borne dissolved organic matter on pesticide transport in soil profile, and degradation of oestrogens in land-applied effluent. Further research in these areas in New Zealand is needed to help sustain the agricultural industry. Author Keywords: effluent; farm dairy; irrigation; land application; pasture; piggery; wastewater KeyWords Plus: DISSOLVED ORGANIC-MATTER; DAIRY SHED EFFLUENT; SWINE MANURE; NEW-ZEALAND; AGRICULTURAL RUNOFF; ESTROGENIC HORMONES; FECAL CONTAMINATION; LIVESTOCK WASTES; NORTH-CAROLINA; SOIL Addresses: Wang HL (reprint author), Forest Res, Private Bag 3020, Rotorua, New Zealand Forest Res, Rotorua, New Zealand Massey Univ, Inst Nat Resources, Palmerston North, New Zealand Title: Human pharmaceuticals in the aquatic environment - A review Author(s): Jones OAH, Voulvoulis N, Lester JN Source: ENVIRONMENTAL TECHNOLOGY 22 (12): 1383-1394 DEC 2001 Document Type: Review Language: English Cited References: 67 Times Cited: 32 Abstract: There has beat increasing concern in recent years about the occurrence, fate and toxicity of pharmaceutical products in the aquatic environment. Many of the more commonly used drug groups (for example antibiotics) are used in quantities similar to those of pesticides and other organic micropollutants, but they are not required to undergo the same level of testing for possible environmental effects. The full extent and consequences of the presence of these compounds in the environment are therefore largely unknown and the issue as a whole is ill-defined. Although these compounds have been detected in a wide variety of environmental samples including sewage effluent, surface waters, groundwater and drinking water, their concentrations generally range from the low ppt to ppb levels. It is therefore often thought to be unlikely that pharmaceuticals will have a detrimental effect on the environment. However, the lack of validated analytical methods, limited monitoring data and the lack of information about the fate and toxicity of these compounds and/or their metabolites in the aquatic environment makes accurate risk assessments very difficult. Author Keywords: pharmaceuticals; review; occurrence; fate; toxicity KeyWords Plus: DRINKING-WATER TREATMENT; HOSPITAL WASTE-WATER; INGROUND WATER; ORGANIC CONTAMINANTS; SEWAGE-TREATMENT; SURFACE WATERS; CLOFIBRIC ACID; DRUG RESIDUES; BEHAVIOR; FATE Addresses: Jones OAH (reprint author), Univ London Imperial Coll Sci Technol & Med, Dept Environm Sci & Technol, Environm Proc & Water Technol Grp, London, SW7 2BP England Univ London Imperial Coll Sci Technol & Med, Dept Environm Sci & Technol, Environm Proc & Water Technol Grp, London, SW7 2BP England Title: Detection and occurrence of indicator organisms and pathogens Author(s): Hashsham SA, Alm EW, Stedtfeld RD, Traver RG, Duran M Source: WATER ENVIRONMENT RESEARCH 76 (6): 531-604 2004 Document Type: Review Language: English Cited References: 135 Times Cited: 0 KeyWords Plus: BACTERIAL SOURCE TRACKING; ESCHERICHIA-COLI O157-H7; ANTIBIOTIC-RESISTANCE PATTERNS; CRYPTOSPORIDIUM-PARVUM OOCYSTS; RECREATIONAL WATER-QUALITY; TOXOPLASMA-GONDII OOCYSTS; REAL-TIME PCR; DRINKING-WATER; FECAL CONTAMINATION; WASTE-WATER Addresses: Hashsham SA (reprint author), Michigan State Univ, Dept Civil & Environm Engn, A124 Res Complex Engn, E Lansing, MI 48824 USA Michigan State Univ, Dept Civil & Environm Engn, E Lansing, MI 48824 USA Michigan State Univ, Ctr Microbial Ecol, E Lansing, MI 48824 USA Cent Michigan Univ, Dept Biol, Mt Pleasant, MI 48859 USA Villanova Univ, Dept Civil & Environm Engn, Villanova, PA 19085 USA E-mail Addresses: hashsham@egr.msu.edu Publisher: WATER ENVIRONMENT FEDERATION, 601 WYTHE ST, ALEXANDRIA, VA 22314-1994 USA Title: Cryptosporidium parvum and Cyclospora cayetanensis: a review of laboratory methods for detection of these waterborne parasites Author(s): Quintero-Betancourt W, Peele ER, Rose JB Source: JOURNAL OF MICROBIOLOGICAL METHODS 49 (3): 209-224 MAY 2002 Document Type: Review Language: English Cited References: 123 Times Cited: 19 Abstract: Cryptosporidium and Cyclospora are obligate, intracellular, coccidian protozoan parasites that infest the gastrointestinal tract of humans and animals causing severe diarrhea illness. In this paper, we present an overview of the conventional and more novel techniques that are currently available to detect Cryptosporidium and Cyclospora in water. Conventional techniques and new immunological and genetic/molecular methods make it possible to assess the occurrence, prevalence, virulence (to a lesser extent), viability, levels, and sources of waterborne protozoa, Concentration, purification, and detection are the three key steps in all methods that have been approved for routine monitoring of waterbome oocysts. These steps have been optimized to such an extent that low levels of naturally occurring Cryptosporidium oocysts can be efficiently recovered from water. The filtration systems developed in the US and Europe trap oocysts more effectively and are part of the standard methodologies for environmental monitoring of Ctyptosporidium oocysts in source and treated water. Purification techniques such as immunomagnetic separation and flow cytometry with fluorescent activated cell sorting impart high capture efficiency and selective separation of oocysts from sample debris. Monoclonal antibodies with higher avidity and specificity to oocysts in water concentrates have significantly improved the detection and enumeration steps. To date, PCR-based detection methods allow us to differentiate the human pathogenic Cryptosporidium parasites from those that do not infect humans. and to track the source of oocyst contamination in the environment. Cell culture techniques are now used to examine oocyst viability. While fewer studies have focused on Cyclospora cayetanensis, the parasite has been successfully detected in drinking water and wastewater using current methods to recover Cryptosporidium oocysts. More research is needed for monitoring of Cyclospora in the environment. Meanwhile, molecular methods (e.g. molecular markers such as intervening transcribed spacer regions), which can identify different genotypes of C. cayetanensis, show good promise for detection of this emerging coccidian parasite in water. (C) 2002 Elsevier Science B.V. All rights reserved. Author Keywords: waterborne; Cryptosporidium; Cyclospora; detection; environment KeyWords Plus: REVERSE TRANSCRIPTION-PCR; VIABLE GIARDIA CYSTS; CELLCULTURE; IMMUNOMAGNETIC SEPARATION; ENVIRONMENTAL-SAMPLES; INVITRO EXCYSTATION; ANIMAL INFECTIVITY; OOCYST VIABILITY; FLOW-CYTOMETRY; DRINKING-WATER Addresses: Rose JB (reprint author), Univ S Florida, Coll Marine Sci, 140 7th Ave S, St Petersburg, FL 33701 USA Univ S Florida, Coll Marine Sci, St Petersburg, FL 33701 USA Western Washington Univ, Dept Biol, Bellingham, WA 98225 USA Publisher: ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS Subject Category: BIOCHEMICAL RESEARCH METHODS; MICROBIOLOGY Title: Colloid transport in the subsurface: Past, present, and future challenges Author(s): McCarthy JF, McKay LD Source: VADOSE ZONE JOURNAL 3 (2): 326-337 MAY 2004 Document Type: Article Language: English Cited References: 96 Times Cited: 1 Abstract: This paper attempts to introduce the work described in this special section on colloid transport within a more general perspective of the evolution of our understanding of the importance of colloids in subsurface systems. The focus will be on the transport of colloidal in natural (i.e., chemically and physically heterogeneous) geological settings because the complexity imposed by these situations the greatest challenge to current and future understanding. Great progress has been made in addressing many of the key questions related to colloid transport. However, as in most areas of science, increased knowledge also serves to reveal new and more complex challenges that must be addressed. KeyWords Plus: UNSATURATED POROUS-MEDIA; NATURAL ORGANIC-MATTER; FRACTURED SHALE SAPROLITE; POLYMERASE CHAIN-REACTION; SANDY VADOSE ZONE; NEVADA TEST-SITE; SOIL COLUMNS; PREFERENTIAL FLOW; INVERSE PROBLEM; TRANSURANIC RADIONUCLIDES Addresses: McCarthy JF (reprint author), Univ Tennessee, Dept Earth & Planetary Sci, 306 Earth & Planetary Sci Bldg, Knoxville, TN 37996 USA Univ Tennessee, Dept Earth & Planetary Sci, Knoxville, TN 37996 USA E-mail Addresses: jmccart1@utk.edu Title: The implications of groundwater velocity variations on microbial transport and wellhead protection - review of field evidence Author(s): Taylor R, Cronin A, Pedley S, Barker J, Atkinson T Source: FEMS MICROBIOLOGY ECOLOGY 49 (1): 17-26 JUL 1 2004 Document Type: Article Language: English Cited References: 83 Times Cited: 0 Abstract: Current strategies to protect groundwater sources from microbial contamination (e.g., wellhead protection areas) rely upon natural attenuation of microorganisms between wells or springs and potential sources of contamination and are determined using average (macroscopic) groundwater flow velocities defined by Darcy's Law. However, field studies of sewage contamination and microbial transport using deliberately applied tracers provide evidence of groundwater flow paths that permit the transport of microorganisms by rapid, statistically extreme velocities. These paths can be detected because of (i) the high concentrations of bacteria and viruses that enter nearsurface environments in sewage or are deliberately applied as tracers (e.g., bacteriophage); and (ii) low detection limits of these microorganisms in water. Such paths must comprise linked microscopic pathways (sub-paths) that are biased toward high groundwater velocities. In media where microorganisms may be excluded from the matrix (pores and fissures), the disparity between the average linear velocity of groundwater flow and flow velocities transporting released or applied microorganisms is intensified. It is critical to recognise the limited protection afforded by source protection measures that disregard rapid, statistically extreme groundwater velocities transporting pathogenic microorganisms, particularly in areas dependent upon untreated groundwater supplies. (C) 2004 Published by Elsevier B.V. on behalf of the Federation of European Microbiological Societies. Author Keywords: bacteria; viruses; groundwater; transport; tracers; protection KeyWords Plus: DRINKING-WATER; GRAVEL AQUIFER; BACTERIAL TRANSPORT; INDICATOR BACTERIA; TRACER EXPERIMENTS; ESCHERICHIA-COLI; ENTERIC VIRUSES; SANDY AQUIFER; RISK-FACTORS; CONTAMINATION Addresses: Taylor R (reprint author), Univ Coll London, Dept Geog, 26 Bedford Way, London, WC1H 0AP England Univ Coll London, Dept Geog, London, WC1H 0AP England Univ Surrey, Robens Ctr Publ & Environm Hlth, Guildford, Surrey GU2 7XH England Univ Coll London, Dept Earth Sci, London, WC1E 6BT England E-mail Addresses: r.taylor@geog.ucl.ac.uk Title: Attenuation of groundwater pollution by bank filtration Author(s): Hiscock KM, Grischek T Source: JOURNAL OF HYDROLOGY 266 (3-4): 139-144 SEP 15 2002 Document Type: Article Language: English Cited References: 20 Times Cited: 8 Abstract: Bank filtration, either natural or induced through the river bed by pumping from a system of connected lateral or vertical wells, provides a means of obtaining public water supplies. The success of such schemes is dependent on the microbial activity and chemical transformations that are commonly enhanced in the colmation layer within the river bed compared to those that take place in surface or ground waters. The actual biogeochemical interactions that sustain the quality of the pumped bank filtrate depend on numerous factors including aquifer mineralogy, shape of the aquifer, oxygen and nitrate concentrations in the surface water, types of organic matter in the surface and ground water environments, and land use in the local catchment area. This paper provides an introduction to a series of nine papers contained in this Special Issue that highlight these factors and finishes with a list of recommendations for co-ordinated research into attenuation of groundwater pollution by bank filtration. (C) 2002 Elsevier Science B.V. All rights reserved. Author Keywords: bank filtration; colmation layer; alluvial aquifer; organic contaminents; biodegradation KeyWords Plus: RIVER WATER; INFILTRATION; AQUIFER Addresses: Hiscock KM (reprint author), Univ E Anglia, Sch Environm Sci, Norwich, Norfolk NR4 7TJ England Univ E Anglia, Sch Environm Sci, Norwich, Norfolk NR4 7TJ England Dresden Univ Technol, Inst Water Chem, Dresden, D-01062 Germany Publisher: ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS Subject Category: ENGINEERING, CIVIL; GEOSCIENCES, MULTIDISCIPLINARY; WATER RESOURCES Title: Liquid chromatography-tandem mass spectrometry for the analysis of pharmaceutical residues in environmental samples: a review Author(s): Petrovic M, Hernando MD, Diaz-Cruz MS, Barcelo D Source: JOURNAL OF CHROMATOGRAPHY A 1067 (1-2): 1-14 MAR 4 2005 Document Type: Review Language: English Cited References: 51 Times Cited: 0 Abstract: Pharmaceutical residues are environmental contaminants of recent concern and the requirements for analytical methods are mainly dictated by low concentrations found in aqueous and solid environmental samples. In the current article, a review of the liquid chromatography-tandem mass spectrometry (LC-MS/MS) based methods published so far for the determination of pharmaceuticals in the environment is presented. Pharmaceuticals included in this review are antibiotics, non-steroidal anti-inflammatory drugs, beta-blockers, lipid regulating agents and psychiatric drugs. Advanced aspects of current LC-MS/MS methodology, including sample preparation and matrix effects, are discussed. (c) 2004 Elsevier B.V. All rights reserved. Author Keywords: liquid chromatography-tandem mass spectrometry; non-steroidal anti-inflammatory drugs; beta-blockers; antibiotica; lipid regulating agents KeyWords Plus: SOLID-PHASE EXTRACTION; SEWAGE-TREATMENT PLANTS; FLUOROQUINOLONE ANTIBACTERIAL AGENTS; NONSTEROIDAL ANTIINFLAMMATORY DRUGS; PERSONAL CARE PRODUCTS; TIME-OF-FLIGHT; WASTE-WATER; AQUATIC ENVIRONMENT; TRIPLE-QUADRUPOLE; DRINKING-WATER Addresses: Petrovic M (reprint author), CSIC, IIQAB, Dept Environm Chem, C Jordi Girona 18-26, Barcelona, 08034 Spain CSIC, IIQAB, Dept Environm Chem, Barcelona, 08034 Spain E-mail Addresses: mpeqam@cid.csic.es Title: Environmental impact and mechanisms of the biological clogging of saturated soils and aquifer materials Author(s): Baveye P, Vandevivere P, Hoyle BL, DeLeo PC, de Lozada DS Source: CRITICAL REVIEWS IN ENVIRONMENTAL SCIENCE AND TECHNOLOGY 28 (2): 123-191 1998 Document Type: Review Language: English Cited References: 244 Times Cited: 41 Abstract: The biological clogging of natural porous media, often in conjunction with physical or chemical clogging, is encountered under a wide range of conditions. Wastewater disposal, artificial groundwater recharge, in situ bioremediation of contaminated aquifers, construction of water reservoirs, or secondary oil recovery are all affected by this process. The present review provides an overview of the techniques that are used to study clogging in the laboratory, or to monitor it in field applications. After a brief survey of the clogging patterns most commonly observed in practice, and of a number of physical and chemical causes of clogging, the various mechanisms by which microorganisms dog soils and other natural porous media are analyzed in detail. A critical assessment is also provided of the few mathematical models that have been developed in the last few years to describe the biological clogging process. The overall conclusion of the review is that although information is available on several aspects of the biological clogging of natural porous media, further research is required to predict its extent quantitatively in a given situation. This is particularly true in cases that involve complicating factors such as predation or competition among organisms. Author Keywords: bioremediation; groundwater; soil; hydraulic conductivity; artificial recharge; bacteria; microorganisms; subsurface environment KeyWords Plus: SCANNING ELECTRON-MICROSCOPY; HYDRAULIC CONDUCTIVITY; POROUS-MEDIA; EXOPOLYSACCHARIDE PRODUCTION; ARTIFICIAL RECHARGE; SAND COLUMNS; METHANOSARCINA-BARKERI; MATHEMATICAL-MODELS; PHYSICALPROPERTIES; SANDSTONE CORES Addresses: Baveye P (reprint author), Cornell Univ, Lab Environm Geophys, Bradfield Hall, Ithaca, NY 14853 USA Cornell Univ, Lab Environm Geophys, Ithaca, NY 14853 USA State Univ Ghent, Microbial Ecol Lab, Ghent, B-9000 Belgium Iowa State Univ, Dept Geol & Atmospher Sci, Ames, IA 50011 USA Syracuse Res Corp, Arlington, VA 22202 USA Publisher: CRC PRESS INC, 2000 CORPORATE BLVD NW, JOURNALS CUSTOMER SERVICE, BOCA RATON, FL 33431 USA Subject Category: ENVIRONMENTAL SCIENCES IDS Number: ZL971 ISSN: 1064-3389 Title: Small-scale spatial and temporal variance in the concentration of heavy metals in aquatic sediments: a review and some new concepts Author(s): Birch GF, Taylor SE, Matthai C Source: ENVIRONMENTAL POLLUTION 113 (3): 357-372 2001 Document Type: Article Language: English Cited References: 75 Times Cited: 5 Abstract: Uncertainty associated with data derived by the analyses of heavy metals in aquatic sediment is due to variance produced in the laboratory (precision), plus 'natural', small-scale spatial variance, (or field variance) at the sampling site. Precision is easily determined and is usually reported in contaminant studies, but field variance is poorly understood and seldom documented. It is important to have an understanding of the field variance because if small-scale spatial variance in the concentration of heavy metals is excessive, regional trends may be of limited value. Similarly, if temporal change is large, the results of single synoptic surveys may be questionable and the ability to demonstrate anthropogenic contributions over time will be difficult. However, it is evident from the literature that the information needed to address problems of spatial and temporal variance in the field is beyond the resources of most researchers. Analytical precision of about 5% relative standard deviation (RSD) for heavy metal analysis is typical of a wellmanaged laboratory. Many studies of small-scale spatial variability made during the current investigation indicate that field variance is related to ambient energy and to the type of sedimentological environment. Total variance (analytical plus field variance) is approximately 10% RSD (mean for a suite of nine trace elements) fur depositional parts of estuaries and the marine environment, but increases to about 20-35% RSD for the more dynamic parts of the estuarine environment and the fluvial system. Repeated sampling over periods of up to 7 years undertaken during the present study, indicate a similar order of magnitude for temporal variability in these sedimentological environments. A proposed scheme to provide information on field variance is to undertake small-scale spatial and temporal studies in discrete sedimentological environments in the study area after sediment sampling and characterisation has been completed. The comparatively large proportion of total variance associated with smallscale spatial and temporal variability in the field questions the often excessive cost and effort made in attempting minor reductions in analytical precision in contaminant investigations. (C) 2001 Elsevier Science Ltd. All rights reserved. Author Keywords: small-scale spatial variance; small-scale temporal variance; field variance; heavy metals; aquatic sediments KeyWords Plus: SAN-FRANCISCO BAY; COASTAL SEDIMENTS; SIZE FRACTIONS; TRACE-METALS; GRAIN-SIZE; SURFICIAL SEDIMENTS; MARINE-SEDIMENTS; SEVERN ESTUARY; RIVER ESTUARY; AUSTRALIA Addresses: Birch GF (reprint author), Univ Sydney, Sch Geosci, Environm Geol Grp, Sydney, NSW 2006 Australia Univ Sydney, Sch Geosci, Environm Geol Grp, Sydney, NSW 2006 Australia Publisher: ELSEVIER SCI LTD, THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND Subject Category: ENVIRONMENTAL SCIENCES Title: Controls on the dynamics of dissolved organic matter in soils: A review Author(s): Kalbitz K, Solinger S, Park JH, Michalzik B, Matzner E Source: SOIL SCIENCE 165 (4): 277-304 APR 2000 Document Type: Review Language: English Cited References: 237 Times Cited: 125 Abstract: Dissolved organic matter (DOM) in soils plays an important role in the biogeochemistry of carbon, nitrogen, and phosphorus, in pedogenesis, and in the transport of pollutants in soils. The aim of this review is to summarize the recent literature about controls on DOM concentrations and fluxes in soils. We focus on comparing results between laboratory and field investigations and on the differences between the dynamics of dissolved organic carbon (DOC), nitrogen (DON), and phosphorus (DOP). Both laboratory and field studies show that litter and humus are the most important DOM sources in soils. However, it is impossible to quantify the individual contributions of each of these sources to DOM release. In addition, it is not clear how changes in the pool sizes of litter or humus may affect DOM release. High microbial activity, high fungal abundance, and any conditions that enhance mineralization all promote high DOM concentrations. However, under field conditions, hydrologic variability in soil horizons with high carbon contents may be more important than biotic controls. In subsoil horizons with low carbon contents, DOM may be adsorbed strongly to mineral surfaces, resulting in low DOM concentrations in the soil solution. There are strong indications that microbial degradation of DOM also controls the fate of DOM in the soil. Laboratory experiments on controls of DOM dynamics have often contradicted field observations, primarily because hydrology has not been taken into account. For example, laboratory findings on the effects of plant species (conifer vs. deciduous) on DOM release from forest floors and on the effects of substrate quality (e.g.: C/N ratio) or pH on DOC concentrations were often not confirmed in field studies. The high adsorption capacity of soil clay minerals and oxides for DOM shown in laboratory studies may not control the transport of DOM in soils in the field if macropore fluxes dominate under field conditions. Laboratory findings about the biodegradability of DOM also await verification under field conditions. Studies that include DON and DOP dynamics in addition to DOC are few. The rate of release and the fate of DOG, DON, and DOP in soils may differ to a far greater extent than previously assumed. Controls established for DOC might thus be not valid for DON and DOP. Despite intensive research in the last decade, our knowledge of the formation and fate of DOM in soils and its response to changing environmental conditions is still fragmented and often inconsistent. Predictions at the field scale are still very uncertain, and most of the information available today is the result of studies on temperate soils and forest ecosystems. Thus, future research on controls of DOM dynamics should be extended to soils under different land uses and in other climate zones. Emphasis should also be given to: (i) the effects of soil organic matter properties on the release of DOM (ii) environmental factors controlling DOM quantity and quality (iii) the assessment of biological versus physico-chemical controls on the release and retention of DOM in soils, and (iv) the differences between DOG, DON, and DOP. Finally, if our goal is to predict DOM concentrations and fluxes in soils, future research on the controls of DOM dynamics should have a strong focus on field studies. Author Keywords: dissolved organic matter (DOM); dissolved organic carbon (DOC); dissolved organic nitrogen (DON); dissolved organic phosphorus (DOP); soils; controls KeyWords Plus: ACID FOREST SOILS; CALIFORNIA AGRICULTURAL SOILS; WHEAT STRAW DECOMPOSITION; SANDY PRAIRIE SOIL; SOLUTION CHEMISTRY; HUMIC SUBSTANCES; CARBON CONCENTRATIONS; NUTRIENT DYNAMICS; CONIFEROUS FOREST; STREAM WATER Addresses: Kalbitz K (reprint author), Univ Bayreuth, BITOK, Inst Terr Ecosyst Res, Dept Soil Ecol, Dr Hans Frisch Str 1-3, Bayreuth, D-95440 Germany Univ Bayreuth, BITOK, Inst Terr Ecosyst Res, Dept Soil Ecol, Bayreuth, D-95440 Germany Publisher: LIPPINCOTT WILLIAMS & WILKINS, 530 WALNUT ST, PHILADELPHIA, PA 19106-3621 USA Subject Category: AGRICULTURE, SOIL SCIENCE IDS Number: 309MY ISSN: 0038-075X Title: Fate of environmental pollutants Author(s): Darnault C Source: WATER ENVIRONMENT RESEARCH 76 (6): 2297-2344 2004 Document Type: Article Language: English Cited References: 94 Times Cited: 0 Abstract: This section covers studies published during the calendar year 2003 on the fate of environmental pollutants in soil, groundwater and surface water resources. Studies related to water quality and sources of pollution by environmental pollutants as well as reaction kinetics and modeling are reviewed in detail. Also included in the coverage of the present review is research on pollutants such as nutrients, xenobiotics, pathogens, metals, and radionuclides. KeyWords Plus: HEAVY-METAL CONCENTRATIONS; ORGANIC-COMPOUNDS VOCS; UNITED-STATES; OVERLAND-FLOW; ARTIFICIAL RADIONUCLIDES; CRYPTOSPORIDIUMPARVUM; NITRATE CONTAMINATION; CONSTRUCTED WETLAND; POTENTIAL POLLUTION; NUTRIENT MANAGEMENT Addresses: Darnault C (reprint author), Environm Engn & Technol Inc, Water Resources Grp, 712 Gum Rock Court, Newport News, VA 23606 USA Environm Engn & Technol Inc, Water Resources Grp, Newport News, VA 23606 USA E-mail Addresses: cdarnault@eetinc.com Publisher: WATER ENVIRONMENT FEDERATION, 601 WYTHE ST, ALEXANDRIA, VA 22314-1994 USA Subject Category: ENGINEERING, ENVIRONMENTAL; ENVIRONMENTAL SCIENCES; LIMNOLOGY; WATER RESOURCES IDS Number: 905DM ISSN: 1061-4303 Title: Environmental fate of alkylphenols and alkylphenol ethoxylates - a review Author(s): Ying GG, Williams B, Kookana R Source: ENVIRONMENT INTERNATIONAL 28 (3): 215-226 JUL 2002 Document Type: Article Language: English Cited References: 70 Times Cited: 55 Abstract: Alkylphenol ethoxylates (APEs) are widely used surfactants in domestic and industrial products, which are commonly found in wastewater discharges and in sewage treatment plant (STP) effluents. Degradation of APEs in wastewater treatment plants or in the environment generates more persistent shorter-chain APEs and alkylphenols (APs) such as nonylphenol (NP), octylphenol (OP) and AT mono- to triethoxylates (NPE1, NPE2 and NPE3). There is concern that APE metabolites (NT, OP, NPE 1-3) can mimic natural hormones and that the levels present in the environment may be sufficient to disrupt endocrine function in wildlife and humans. The physicochemical properties of the APE metabolites (NP, NPE1-4, OP, OPE1-4), in particular the high K., values, indicate that they will partition effectively into sediments following discharge from STPs. The aqueous solubility data for the APE metabolites indicate that the concentration in water combined with the high partition coefficients will provide a significant reservoir (load) in various environmental compartments. Data from studies conducted in many regions across the world have shown significant levels in samples of every environmental compartment examined. In the US, levels of NP in air ranged from 0.01 to 81 ng/m(3), with seasonal trends observed. Concentrations of APE metabolites in treated wastewater effluents in the US ranged from < 0.1 to 369 mug/l, in Spain they were between 6 and 343 mug/l and concentrations up to 330 mug/l were found in the UK. Levels in sediments reflected the high partition coefficients with concentrations reported ranging from < 0.1 to 13,700 mug/kg for sediments in the US. Fish in the UK were found to contain up to 0.8 mug/kg NP in muscle tissue. APEs degraded faster in the water column than in sediment. Aerobic conditions facilitate easier further biotransformation of APE metabolites than anaerobic conditions. (C) 2002 Elsevier Science Ltd. All rights reserved. Author Keywords: oetylphenol; nonylphenol; nonylphenol ethoxylate; partitioning; degradation; water; sediment; sewage effluent KeyWords Plus: SEWAGE-TREATMENT PLANTS; PERFORMANCE LIQUIDCHROMATOGRAPHY; PRIMARY DEGRADATION PRODUCTS; HUDSON RIVER ESTUARY; NONYLPHENOL ETHOXYLATES; NONIONIC SURFACTANTS; POLYETHOXYLATE SURFACTANTS; AROMATIC SURFACTANTS; WASTE-WATER; LINEAR ALKYLBENZENESULFONATES Addresses: Ying GG (reprint author), CSIRO Land & Water, Adelaide Lab, PMB 2, Glen Osmond, SA 5064 Australia CSIRO Land & Water, Adelaide Lab, Glen Osmond, SA 5064 Australia Publisher: PERGAMON-ELSEVIER SCIENCE LTD, THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND Subject Category: ENVIRONMENTAL SCIENCES IDS Number: 588XX Title: Article gives credence to Riverbank Filtration Author(s): Popkin BP Source: JOURNAL AMERICAN WATER WORKS ASSOCIATION 93 (3): 8-8 MAR 2001 Document Type: Letter Language: English Cited References: 0 Times Cited: 0 Publisher: AMER WATER WORKS ASSOC, 6666 W QUINCY AVE, DENVER, CO 80235 USA Subject Category: ENGINEERING, CIVIL; WATER RESOURCES IDS Number: 434VN Title: Dissolved organic nitrogen in drinking water supplies: a review Author(s): Westerhoff P, Mash H Source: JOURNAL OF WATER SUPPLY RESEARCH AND TECHNOLOGY-AQUA 51 (8): 415448 DEC 2002 Document Type: Review Language: English Cited References: 211 Times Cited: 1 Abstract: Dissolved organic nitrogen (DON) is an issue for the water field primarily due to the formation of disinfection by-products of health concern and its potential role in membrane fouling This article reviews the following DON issues: (1) analytical measurement, (2) occurrence, (3) structural composition, and (4) treatability during potable water treatment. There is no direct measurement for DON, rather DON is calculated by the difference between total dissolved nitrogen and inorganic nitrogen ions. DON concentrations range from <0.1 to >10 mg N/l with a median value of similar to0.3 mg N/l in surface waters. DON sources include wastewater discharges, agricultural fertilizers, algae, forest litter and Soils. DON is comprised of a broad spectrum of molecular weight compounds encompassing multiple N-containing functional groups. Carbon to nitrogen ratios (C/N or DOC/DON) range between 5 and 100 mg C/mg N (median similar to15 mg C/mg N), and may be a good indicator of organic matter sources. During chlorination higher org-N content leads to (1) increasing chlorine demand, (2) production of di-HAA>tri-HAA (3) production of HAA>THM and (4) production of higher levels for halogenated (nitromethanes, HANs) and non-halogenated (NDMA) org-N DBPs. Information on DON removal during potable water treatment is lacking and should be a focus of future research. Author Keywords: dissolved organic nitrogen; natural organic matter; organic carbon KeyWords Plus: DISINFECTION BY-PRODUCTS; PYROLYSIS-GC-MS; AQUATIC HUMIC SUBSTANCES; N-15 NMR-SPECTROSCOPY; MUNICIPAL WASTE-WATER; ALPHA-AMINOACIDS; NATURAL-WATERS; SURFACE WATERS; THM PRECURSORS; TRIHALOMETHANE PRECURSORS Addresses: Westerhoff P (reprint author), Arizona State Univ, Dept Civil & Environm Engn, Natl Ctr Sustainable Water Supply, Box 5306, Tempe, AZ 85287 USA Arizona State Univ, Dept Civil & Environm Engn, Natl Ctr Sustainable Water Supply, Tempe, AZ 85287 USA Publisher: I W A PUBLISHING, ALLIANCE HOUSE, 12 CAXTON ST, LONDON SW1H0QS, ENGLAND Subject Category: ENGINEERING, CIVIL; WATER RESOURCES IDS Number: 636QB ISSN: 0003-7214