EMULSIOR PAINTS FOR INTERION AND EXTERIOR USES 1 – SCOPE AND FIELD OF APPLICATION * This Omani Standard specifies performance requirements and appropriate methods of test for emulsion paints for interior and exterior use applied by brush, roller or spray techniques. It covers matt and silk emulsion paints which can be applied to non-metallic substances classified into three types covering different circumstances where the paint may be applied. It also specifies requirements for the marking of containers which may be of a range of nominal capacities. 2 - DEFINITIONS 2.1 Emulsion A mixture formed by the incorporated of two liquids which are normally immiscible. One liquid is dispersed in the other in the form of minute drops. If the droplets reamin permanently dispersed the emulsion is said to be stable and certain compound are added as stabilizers of their power to keep the droplets dispersed. 2.2 Emulsion for paint A dispersion of 2 or more organic monomers which are copolymerised and dispersed in water. The dispersed phase is in the form of minute drops. The droplets remain permanently dispersed. The emulsion is said to be stable and certain compound are added as stabilizers because of their power to keep the droplet dispersed. 2.3 Vehicle The liquid portion of the paint in which the pigment is dispersed and it is composed of the binder and the thinner if any. 2.4 Pigment The insoluble dispersed particles in a paint which give the dried film its characteristic properties of colour and opacity. 2.5 Opacity The ability of a coat of paint to obscure (hide) an underlying surface. 2.6 Binder The non-volatile portion of the “Vehicle” of a paint. It binds or cements the pigments particles together and the paint film as a whole to the material to which it is applied. Paints/C.driver 2.7 Thinner Volatile liquids added to paints or varnishes to facilitate application and to aid penetration by lowering gather viscosity. They should be completely miscible with the paints or varnish at ordinary temperature and should not cause precipitation of the non-volatile portion either in the container or in the film during drying. For some purposes thinner containing a small proportion of non-volatile material may be used. 2.8 Drying time The time which elapses between the application of a coat of paint and the attainment of a specified dry state. 2.9 Lifting Failure caused by the swelling of a dry film of paint or varnish when another coat is applied over it an usually manifested by wrinkled appearance. 3 – CHARACTERISTICS AND REQUIREMENTS 3.1 Composition The emulsion paint shall consist of pigments with suitable extenders in suitable proportion in a medium consisting of any suitable stable synthetic polymer emulsion in water with other suitable ingredients as may be necessary to produce a material so as to satisfy the requirements of this standard. 3.2 Condition in container The material shall have no evidence of biological growth, levering, skinning, putrefication, hard settling of the pigment, lumps, or corrosion of the container. Any settled pigment shall be readily dispersible in the liquid medium by stirring with paddle to produce smooth homogeneous emulsion paints, free from persistent foam. The material shall have no irritating of offensive odor. 3.3 Non-volatile content The percent of non-volatile content of the emulsion paint shall not be less than 40% by weight. 3.4 Consistency The paint shall be in such a condition that stirring readily produces a smooth uniform mixture of good consistency. It shall have aminimum 80 KU viscosity for matt and 60 KU viscosity for silk and gloss at 25 ○C. Paints/C.driver 3.5 Colour The colour of the paint shall be close to the approved reference sample. 3.6 Thinning The paint shall have tendency to mix readily with water if necessary to a smooth and homogeneous state with minimum amount of foaming. Foaming if any shall dissipate rapidly. 3.7 Fineness of grind The particle size of the paint shall be less than 50 microns. 3.8 Lead content The lead content shall not exceed 0.06% of the total mass of the paint. 3.9 Application properties The material after recommended thinning shall be suitable for application by brush, spray, or roller. The resulting paint film shall not show pigment flocculation, foaming, coarseness or other undersirable characteristics. The paint film shall also produce no lifting, softening or any other defects upon recoating of a previously painted surface after minimum 4 hours for matt and minimum 8 hours for silk and gloss of air drying. 3.10 Drying time - 3.11 The paint shall have surface drying time not more than 30minutes for matt and not more than 2 hours for silk and gloss. The paint shall become hard-dry in a time not more than 4 hours for matt and not more than 8 hours for silk and glass at film thickness of 100 micron wet on glass panel under temperature of 27 + 2° C and humidity of 60% - 70% with air circulation and without exposing to the sun. Appearance of dried film (finish) When a film of the paint has dried for the specified drying period in 3.10, it shall have, smooth, firmly adherent and substantially free from brush marks or sagging or wrinkling, and shall in no way be inferior as regards finish to a film prepared in the same way and the same time from the approved reference sample. Paints/C.driver 3.12 Scrub resistance The paint film coating the panel test shall not worn when exposed to : 1500 scrub cycles for type A for interior/exterior gloss and semi-gloss 600 " " " B for interior/exterior flat emulsion paints emulsion paints 80 " " " C for interior flat emulsion paints 3.13 Water resistance The paint film shall show good adhesion hardness and shall show no wrinkling re-emulsification or other changes after 2 hours for type A and 1 hour for type B when water resistance test is carried out. 3.14 Alkali resistance (white and pastel shades) The paint film shall show no change in hue, lightness, gloss and any other surface defects when alkali resistance test is carried out. 3.15 Heat stability The viscosity of the paint shall not change more than 5% of the original and shall show no coagulation flocculation or discolorations after carrying out the test of heat stability. 3.16 Odour The odour of the paint shall not be putrid or otherwise offensive or irritating before, during and after application. There shall be no residual odour after 24 hours of drying. 3.17 Dry opacity (white and pastel shades) The paint when applied shall give a minimum dry film contrast ratio Type of the paint Category Matt Silk A B C 95% 90% 90% 80% 80% - % Gloss 75% 75% -% at 175 micrometer bar coated applicator on black and white chart paper allow to dry overnight test it on computer. 3.18 Colour fastness to light. (for interior use only) The paints shall show no darkening or other changes in appearance when subjected to 72 hours exposure for direct sun or any other light source light. Paints/C.driver 3.19 Durability test (For exterior use only) The paint film shall show no undue change, blistering, chalking, colour fading and films irregularities when subjected to 300 hours exposure for class A and 100 hour exposure for class B. 3.20 Resistance to biological growth The paint in container shall show no fungus growth for a period of 12 months at 40 C 3.21 Keeping properties The paint when stored under normal storage conditions i.e. in shed at temperature not exceeding 40º C in the original sealed containers, shall retain properties specified in this standard for a period of not less than 12 months. 4- SAMPLING 4.1 4.2 Take a representative sample of the paint not less than 500 ml according to the methods mentioned in Omanian Standards O.S. 194/1999 “Paints and varnishes-Sampling”. Sample shall be prepared to tests according to the methods mentioned in Omanian Standard O.S. 196/1990 :Paints and Varnishes. Examinational and preparation of samples for testing”. 5- METHODS OF TESTING 5.1 The following tests shall be carried out on the filled containers selected according to item 4.1 after carrying out the visual examination of the labeling information. 5.2 The following tests shall be carried out on the paint sample taken from each container selected in according with item, 4.1. 5.2.1 Determination of non-volatile content according to Omanian Standard O.S……241/92 “Paints and varnishes-Determination of volatile and non –volatile matter”. 5.2.2 5.2.3 Determination of colour according to this Gulf Standard. Determination colour according to ISO 3668/76. 5.2.4 Determination of fineness of grind according to Omani Standard O.S 239/92 “Paints and Varnishes-Determination of fineness of grind”. 5.2.5 Determination of lead content according ISO 3856/84 part I “Paints and VarnishesDetermination of lead content”. 5.2.6 Determination of application properties according to this Gulf Standard. 5.2.7 Determination of drying time according to Omani Standard No. 494/94 “Paints and Varnishes-Determination of drying time. Paints/C.driver 5.2.8 Determination of appearance of dried film (Finish) according to this Omani standard 5.2.9 Determination of scrub resistance according to ASTM D 2486/89 without using a scrub media and a detergent solution of 0.5%. 5.2.10 Determination of water resistance according to ISO 2812/93 part 2 5.2.11 Determination of alkali resistance according to Omani Standard 1298/2002 “Paints and Varnishes-Determination of alkali resistance”. 5.2.12 Determination of heat stability according to ISO 3248/98 “Paints and VarnishesDetermination of heat stability”. 5.2.13 Testing of Odour according to this Gulf Standard 5.2.14 Determination of dry opacity according to this Gulf Standard 5.2.15 Determination of colour fastness to light according to ISO 2809/76 5.2.16 Determination of resistance to biological growth according this Gulf Standard 5.2.17 Determination of durability according to ISO 2810/74 5.2.18 Determination of quantity of material in a container according to ISO 3232/1974 6- PACKING The paints shall be packed in suitable, clean air-tight containers, the containers shall be filled as to have an ullage for 15% maximum. The allowed tolerance should be + 2 % of the content. 7- LABELLING Each container shall be legibly and indelibly marked in Arabic at least by the following information: - The name and the type of the paint. A or B or C. as classified The word “Un whashable” for paints with scrub resistance less than 80 scrub cycles. The word “Un whashable” for paints with scrub resistance less than 80 scrub cycles. The colour of the paint should be shown on the container. The name of the manufacturer or his trade mark. Country of origin . If the paints manufacture is under licence it should be mentioned. Batch number Paints/C.driver - Date of production (month-year). Volume in litre of the paint in the container. Application instruction. Any warning information concerning the paint. Warning: Do not use this container for keeping food stuff. The number of this standard. 8- ACCEPTABNCE AND REJECTIONS 8.1 8.2 Each consignment of paints shall be accompanied with a certificate stating its compliance with this standard. In case of non-compliance of the tested sample with any of the following items of this standards the consignment shall be rejected. - 8.3 CONSISTENCY FINENESS SCRUB RESISTANCE DRY OPACITY PACKING In this case of one or more sample failed to pass one or more of the tests other than those in item 8.2 a second sample, double in volume of the first one, shall be withdrawn from, the same come consignment and subjected to all the tests. The consignment shall be considered complying when the second sample pass all the requirement shall be considered complying when the second sample pass all the required tests otherwise the consignment shall be considered not complying. Paints/C.driver