Carbon Dioxide, Acid Rain, and Acid Buffering Capacity Objective This lab will demonstrate how carbon dioxide, when dissolved in water, forms carbonic acid, a weak acid. It will be shown how the alkalinity of different rocks can be recognized and how this relates to the acid buffering capacity of natural bodies of water. Procedure Part I 1. Take one can of cold carbonated beverage and one can of warm carbonated beverage and shake them gently. 2. Open each of the cans while holding them over the sink. Record what occurs in the table below. 3. With a nail and hammer, make a small hole in the top of a warm can of carbonated beverage. The hole should be about the same diameter as the straw. 4. Carefully slip the straw into the can. Hold the other end of the straw in the beaker filled with limewater. CAUTION: Limewater may irritate the skin. Avoid contact. Record your observations in the table below. Part II 1. 2. 3. 4. 5. 6. Take a piece of granite and a piece of limestone and place each on a piece of paper towel. Place two drops of vinegar on the granite and record your results in the table below. Place two drops of vinegar on the limestone and record your results in the table below. Take some granitic sand and a crushed up antacid tablet and place on separate pieces of paper towel. Place two drops of vinegar on the granitic sand and record your results in the table below. Place two drops of vinegar on the crushed up antacid tablet and record your results in the table below. Data and Observations Part I Can Observations Part II Rock Observations Cold Warm Limewater Granite Limestone Granitic Soil Crushed Up Antacid Tablet Questions and Conclusions 1. What gas is present in a carbonated drink? 2. What happens when you opened the two cans and why? 3. Which can lost its carbon dioxide faster and why? 4. Describe what happens when the beverage and the limewater are combined. 5. As the carbonic acid descends underground to greater depths, it dissolves CaCO3 (calcium carbonate). If the temperature were to increase, what would happen to the CaCO3? 6. As the carbonic acid seeps through the roof of a cave, part of the water evaporates. What happens to the calcium carbonate? 7. If underground water circulates close to the vent of a volcano, it might dissolve carbon dioxide. Would increased pressure or high temperature cause the carbon dioxide to dissolve? 8. Did you observe a difference in the reactions between the acid dropped on granite and on limestone? Why? 9. Which rock acted as a buffer? 10. When the increased surface area was exposed to acid, did the previously observed reactions change? 11. Why does limestone fizz when it is exposed to acid? What are the bubbles?