金属有机化学国家重点实验室
学科带头人现状与需求
现有人员
目前学科方向
陆熙炎院士
戴立信院士
麻生明院士
侯雪龙研究员
施敏研究员
丁奎玲研究员
唐勇研究员
刘元红研究员
陈耀峰研究员
游书力研究员
刘国生研究员
邓亮研究员
李玉学副研究员
段伟良副研究员
过渡金属有机化学
不对称催化
过渡金属有机化学
不对称催化
过渡金属有机化学
不对称催化
不对称合成，高分子化学
钛锆金属有机化学
稀土金属有机化学
不对称催化
过渡金属有机化学
过渡金属配合物及其反应化学
金属有机计算化学
不对称催化
发展学科方向
需求计划人数
金属催化的小分子活化
金属络合物及反应化学
后过渡金属有机化学
前过渡金属有机化学
主族元素金属有机化学
金属有机计算化学
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2OO9 年重大记事
一．实验室开放课题和自主课题
按照国家科技部最新要求和规定，2009 年实验室面向所外单位设立的开放基金
项目有 4 项，资助总额 90 万。实验室设立自由探索课题 10 项，资助总额 151 万；
团队重点课题 5 项，资助总额 670 万。
二．新一届领导班子及学术委员会的换届
2009 年，实验室顺利完成了领导班子及学术委员会的换届及工作交接，唐勇研
究员任金属有机国家重点实验室新一届主任，施敏研究员和游书力研究员任副主任，
麻生明院士任新一届学术委员会主任，侯雪龙研究员、谢作伟教授和金国新教授任
副主任。
三. “基于组合方法与组装策略的新型手性催化剂研究”项目获得国家
自然科学二等奖。
现代合成化学、药物化学和材料科学的发展使人们越来越认识到手性的重要性，
不对称催化是获得光学纯手性物质最有效的方法之一，其核心问题在于设计和选择
合适的催化剂。丁奎岭研究员及其领导的团队围绕手性催化剂这一核心问题，（1）
系统地将不对称活化和毒化、手性传递和放大等概念与组合化学方法结合进行手性
催化剂库的设计与评价，发展了多个系列新型、高效、高选择性手性催化剂，发现
并阐明了催化体系中的不对称放大效应、添加物的活化作用及其机理等；（2）突破
传统思路，基于分子组装原理，首次提出了手性催化剂自负载的概念，实现了包括
羰基-烯、氧化和氢化等在内的多个非均相催化反应的高选择性、高活性，为手性催
化剂的负载化开辟了新思路；（3）发展了一系列结构可调的新型手性配体，实现了
多个不对称反应的高活性和高对映选择性以及底物的普适性，为多种手性氨基酸等
药物关键中间体的合成提供了有效的方法。
该成果共发表论文 61 篇(其中 SCI 53 篇，SCI-E 5 篇)，其中影响因子>5 的有 18
篇，包括 J. AM. CHEM. SOC. 5 篇、ANGEW. CHEM. 3 篇、CHEM. EUR. J. 8 篇；被他引
1183 次，最高单篇他引 111 次，篇均他引 19 次；多篇论文被选为 HOT PAPER 或被
国际刊物专题评论、被 HIGHLIGHTS 栏目摘录；在 4 本国内专著中撰写 4 个章节；获
得授权专利 11 项；所发展的概念、方法、配体或催化剂被国内外同行应用于研究工
作 50 多次；在包括 IUPAC 在内的重要系列国际和国际双边会议做大会和邀请报告
36 次；培养 13 名博士、3 位博士后，其中 1 人获全国百篇优秀博士论文、1 人获中
科院院长优秀奖。
四. 实验室承担的科研项目运行正常
2009 年实验室主持的国家和省部委的在研重大重点项目有：(1)国家基金委创
新群体项目 1 项、重点项目 3 项、重大新药创新专项 1 项、国际合作重大项目 1 项；
(2)中科院知识创新方向性项目 2 项；(3)上海市科委 6 项，其中重点项目 1 项、人
才计划 2 项。作为课题骨干参加的国家和省部委的重大重点项目有：(1)973 项目 2
项；(2)国家基金委重点项目 2 项；另外实验室还承担了(1)国家基金委其他项目 15
项；(2)其他省部委项目 4 项。
实验室 2009 年共发表了 265 篇论文，其中 Acc. Chem. Soc. 1 篇，Chem. Rev. 1
篇，J. Am. Chem. Soc. 9 篇，Angew. Chem. Int. Ed. 15 篇。其中金属室固定成员发表
了 106 篇论文，其中包括 Chem. Rev. 1 篇，Chem. Soc. Rev. 1 篇，Coord. Chem. Rev. 1
篇，J. Am. Chem. Soc. 5 篇，Angew. Chem. Int. Ed. 6 篇，Chem. Eur. J. 12 篇，Adv. Synth.
Catal. 7 篇，Org. Lett. 14 篇等。
2009 年度，以丁奎岭研究员为项目首席科学家的科技部 973 项目“手性催化的
重要科学基础”获得立项批准，于 2010 年正式启动。丁奎岭研究员主持的重大新药
专项“手性药物及其中间体的不对称合成与生物活性评价技术以及丁奎岭研究员主
持的国家基金委优秀实验室重点项目“基于金属催化的选择性控制”获得立项批准，
今年启动；唐勇研究员主持的国家自然科学基金委的重点项目“调控有机合成反应
选择性的新方法”于 2010 年启动。中科院知识重要方向性项目“超高分子量聚乙烯
纤维制备与应用”的课题之一 “结构可控 UHMWPE 催化剂技术的研制”获得批准立
项，于 2009 年 6 月启动。
唐勇研究员领衔的国家自然科学基金委创新群体项目“化学键活化与可控性重
组研究” 进展顺利。中科院方向性重大项目“新型乙烯聚合催化剂技术的工业化应
用研究”于 2009 年顺利通过了中科院组织的中期答辩。丁奎岭研究员主持的基金委
重点项目“手性催化剂负载化中若干新方法研究”和国际合作交流重大项目“不对
称催化反应研究”以及中科院方向性项目“手性诱导、传递与放大中的科学问题研
究”；施敏研究员主持的基金委重点项目“有机合成中的串联及多组分反应”今年
均进展良好。实验室主持的 973 项目“物质创造与化学转化过程中的若干前沿科学
问题研究”中的两个课题“金属参与的化学键断裂和形成研究”和“手性分子的构
筑及相关规律研究”以及 973 项目“惰性化学键的选择性激活、重组及其控制”中
的课题四“小分子二氧化碳、一氧化碳和氧气等的活化”均顺利完成了 2009 年度的
工作计划。
侯雪龙研究员主持的基金委重点项目“有机化学反应中的选择性控制”已经结
题，顺利通过验收。唐勇研究员主持的基金委国际合作项目“用于制备结构可控聚
烯烃/烯烃共聚物的催化材料”已经完成预定目标，于 2009 年年底结题。
2009 年 12 月 22-23 日中国科学院上海有机所“均相催化研究”国际合作伙伴计
划团队在苏州召开了 2009 年学术交流会，会议邀请到了国家自然科学基金委化学部
陈拥军和杜灿屏老师参加。团队 6 位海外成员中的 5 位：美国 The State University of
New Jersey 的张绪穆教授、美国 The Ohio State University 的王鹏教授、美国 Texas
Tech University 的李桂根教授、香港中文大学的谢作伟教授、香港科技大学的贾国
成教授和团队有机所全体成员：麻生明、侯雪龙、施敏、丁奎岭、唐勇、刘元红 6
位研究员参加了本次会议并汇报交流了近一年来的研究工作和合作进展。会上基金
委化学部副主任陈拥军和基金委化学部二处处长杜灿屏均发言希望团队成员要在自
身发展的同时关注、引导青年人，做好承上启下的工作，推进有机化学学科的发展。
参会的团队成员一致认为应该结合国家需求开展研究工作，团队通过合作发挥每人
的专长，做一些有国际影响的原创性工作。
五．对外交流
实验室今年分别接待了美国、俄罗斯、德国、法国、英国、加拿大等国的 15
位科学家来室访问进行了学术交流；另外，包括台湾在内的 7 位国内专家应邀到实
验室作了精彩学术报告，具体情况见 17-20 页。同时实验室学术带头人积极参加国
际国内的重要学术会议，应邀在国际学术会议上作邀请报告 11 次，在国内学术会议
上作特邀报告 3 次。
六．实验室学术委员会工作
2009 年 10 月 16 日-20 日，在成都召开金属有机化学国家重点实验室 2009 年学
术委员会第二届学术委员会第五次会议和实验室成立 20 周年庆典大会暨学术报告
会。会议邀请到了中国科学院高技术与发展局综合处杨永峰老师和化工处白路娜、
唐清老师，国家自然科学基金委化学部副主任陈拥军及二处处长杜灿屏参加。在实
验室成立 20 周年庆典大会暨学术报告会上，麻生明院士总结了金属有机开放实验室
20 年来的历程，并展望了金属室未来的发展。会议还邀请了 T. Hayashi 教授，G.
Helmchen 教授、谢作伟教授、侯雪龙研究员、丁奎岭研究员和席振峰教授分别作了
学术报告，具体题目为：
1. T. Hayashi 教授，Recent Advances in Chiral Diene Ligands for Asymmetric Catalysis
2. G. Helmchen 教 授 ， Iridium-Catalyzed Allylic Substitutions-Fundamentals and
Applications
3. 侯雪龙研究员，钯催化不对称烯丙基取代反应中的“硬”亲核试剂
4. 谢作伟教授，Unique Chemical Properties of Non-Traditional Metal-Carbon Bonds
5. 席振峰教授，Cooperative Effect: Development of Organo-bi-Lithio Reagents
6. 丁奎岭研究员，不对称催化研究：从组合到组装
在学术委员会会议上，时任实验室常务副主任唐勇研究员向委员会汇报了金属
室 2009 年度的工作总结，席振峰、游书力、刘国生及唐勇教授分别介绍了第十届
Tetrahedron Symposium、第十三届亚洲大会、第十五届 OMCOS 及 ICHAC-9 的会议情
况。麻生明、王绍武、周锡庚、曹卫国和段伟良等在会上分别汇报了各自的工作。
与会老师进行了充分的交流。2009 年 10 月 17 日，到会的学术委员及被邀请的领导、
专家就实验室今后的人才引进、课题组队伍梯队建设、研究方向和客座课题资助力
度等方面展开了热烈讨论，并提出了建设性的意见。
七．获奖情况
获奖成果表
序号
1
获 奖 题 目
基于组合方法与组装策略的新
型手性催化剂研究
类别(国家/部
委)
国家自然科学奖
个人(包括研究生)获奖表
序号
获奖姓名
获奖名称
1
崔鹏
中国科学院院长优秀奖
2
陆平
中国科学院院长奖优秀奖
3
姜雪峰
中国科学院优秀博士学位论文奖
4
顾振华
全国优秀博士学位论文
5
麻生明
全国优秀博士学位论文指导教师
6
麻生明
中国科学院优秀研究生指导教师奖
7
麻生明
宝洁优秀研究生导师
8
唐勇
中国科学院“朱李月华优秀教师”奖
9
王庆刚
中国科学院朱李月华优秀博士生奖学金
10
林芳
中国科学院研究生院三好学生标兵
11
王庆刚
中国科学院研究生院三好学生标兵
12
唐翔鹰
中国科学院研究生院优秀学生干部
13
阴国印
08-09 年度院三好学生
14
郭胜海
08-09 年度院三好学生
15
李跃辉
08-09 年度院三好学生
16
陆平
08-09 年度院三好学生
17
李毅
08-09 年度院三好学生
18
蒋敏
08-09 年度院三好学生
19
陆而立
08-09 年度院三好学生
20
陈建平
08-09 年度院三好学生
21
郑素清
08-09 年度院三好学生
22
郑素清
中国科学院研究生院优秀毕业生
23
林芳
20009 年度上海市高校优秀毕业生
24
戴伦治
GSK 奖学金
25
刘海林
GSK 奖学金
26
付晓平
GSK 奖学金
27
李跃辉
GSK 奖学金
28
汪日新
GSK 奖学金
29
刘文博
GSK 奖学金
30
阴国印
GSK 奖学金
等
级
二等
承担
类别
A
等级
一等
一等
一等
二等
二等
二等
二等
完成
时间
19962006
获奖
时间
2009
获奖时间
2009
2009
2009
2009
2009
2009
2009
2009.12
2009.12
2009.6
2009.6
2009.6
2009.6
2009.6
2009.6
2009.6
2009.6
2009.6
2009.6
2009.6
2009.6
2009.6
2009.6
2009.6
2009.6
2009.6
2009.6
2009.6
2009.6
2009.6
金属有机化学国家重点实验室
第二届学术委员会第五次会议简报
10 月 16 日-20 日，在成都召开金属有机化学国家重点实验室 2009 年学术委员
会第二届学术委员会第五次会议和实验室成立 20 周年庆典大会暨学术报告会。除 3
名学术委员因故未能参加外，其余委员均参加了会议。会议邀请到了中国科学院高
技术与发展局杨永峰副处长和化工处白路娜研究员、唐清副处长，国家自然科学基
金委化学部副主任陈拥军及二处处长杜灿屏参加。会议上麻生明主任总结了金属有
机开放实验室 20 年来的历程，并展望了金属室未来的发展。会议还邀请了 T.
Hayashi 教授，G. Helmchen 教授、谢作伟教授、侯雪龙研究员和席振峰教授、丁奎
岭教授分别作了学术报告，题目分别为：
1. T. Hayashi 教授，Recent Advances in Chiral Diene Ligands for Asymmetric
Catalysis
2. G. Helmchen 教授，Iridium-Catalyzed Allylic Substitutions-Fundamentals
and Applications
3. 侯雪龙研究员，钯催化不对称烯丙基取代反应中的“硬”亲核试剂
4. 谢作伟教授，Unique Chemical Properties of Non-Traditional Metal-Carbon
Bonds
5. 席振峰教授，Cooperative Effect: Development of Organo-bi-Lithio Reagents
6. 丁奎岭研究员，不对称催化研究：从组合到组装
在学术委员会会议上，时任实验室常务副主任唐勇研究员向委员会汇报了金属
室 2009 年度的工作总结，席振峰、游书力、刘国生及唐勇教授分别介绍了第十届
Tetrahedron Symposium、第十五届亚洲大会、第十五届 OMCOS 及 ICHAC-9 的会议情
况。麻生明、王绍武、周锡庚、曹卫国和段伟良等在会上分别介绍了各自的工作。
与会老师进行了充分的交流。2009 年 10 月 17 日，与会委员与专家、领导就实验室
今后的人才引进、课题组队伍梯队建设、研究方向和客座课题资助力度等方面展开
了热烈讨论,并给出了建设性的意见。
2009 年自由探索课题（2008-2009 年）
序 号
姓
名
2008-01
陆熙炎
阳离子钯催化的芳基对碳-杂原子重键的加成反应
2008-02
麻生明
联烯的锂化反应及其金属参与的偶联反应研究
2008-03
侯雪龙
手性环钯催化的动力学拆分
2008-04
施
基于联萘胺的手性氮杂环卡宾配体的合成及其在不对称催化反应
敏
题
目
的应用
2008-05
丁奎岭
新型手性螺环配体的设计合成及其在不对称催化反应中的应用研究
2008-06
唐 勇
新型单中心聚烯烃催化剂的设计、合成及应用
2008-07
刘元红
金催化的新型有机反应研究
2008-08
陈耀峰
单茚基烯土烷基配合物的合成及其催化的烯烃聚合
(钱长涛)
2008-09
游书力
惰性碳氢键活化及选择性转化研究
2008-10
刘国生
金属催化烯丙位碳氢键活化反应的研究
2009 年实验室团队重点研究课题（2007-2011 年）
(1) 惰性碳－碳键和碳－氢键的活化与官能团化中的金属有机化学
课题负责人：游书力
研究队伍：游书力，刘国生，段伟良
(2) 反应选择性的控制中的金属有机化学
课题负责人：侯雪龙
研究队伍：戴立信，侯雪龙，丁奎岭，王正，Christian A. Sandoval
(3) 金属配合物的结构、合成及反应化学
课题负责人：刘元红
研究队伍：刘元红，施敏，李玉学，孙杰
(4) 含碳－过渡金属键的中间体的形成和反应研究
项目负责人：麻生明
研究队伍：麻生明，陆熙炎，韩秀玲
(5) 新型单中心烯烃聚合催化剂的研究
项目负责人：唐勇
研究队伍：唐勇，陈耀锋，孙秀丽
2009 年实验室开放课题（2007-2011 年）
项目一：碳－碳(杂)键形成的的过渡金属有机化学
项目负责人：黄宪
研究队伍：黄宪，吴劼，王佰全，朱成建，陈忠宁，王磊，郎建平，施章杰，张兆国
研究时间: 2007-2011 年
经费总额: 185 万
项目二：过渡金属卡宾化学
项目负责人：王剑波
研究队伍：王剑波，张俊良，余正坤，雷爱文，焦宁
研究时间: 2007-2011 年
经费总额: 102.5 万
项目三：主族金属有机化合物的反应化学
项目目负责人：席振峰
研究队伍：席振峰，周永贵，甘良兵，曹卫国
研究时间: 2007-2011 年
经费总额: 81.25 万
项目四：稀土金属有机物的合成、结构与反应化学
项目负责人：沈琪
研究队伍：沈琪，王绍武，苏成勇，周锡庚
研究时间: 2007-2011 年
经费总额: 81.25 万
2009 年全室专利申请、授权一览表
2009 年申请专利
编
号
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
专利名称
一种含有α手性的酰胺类化合物
的合成方法
一种光学活性 2－(2-硝基－乙
基)吡咯、合成方法和用途
一种合成 3－卤代中氮茚类化合
物的方法
一种合成 4,6-位取代 3,-4-二氢
－吡喃－2－酮衍生物的方法
新型三齿氮配体及其稀土金属配
合物
四氢喹晽和吲哚啉衍生的磷氮配
体、合成方法和应用
螺环骨架膦噁唑啉配体、合成方
法及其在不对称氢化反应中的应
用
含氮侧链 β 二亚胺配体金属催化
剂及在聚酯合成中的应用
α-萘甲基取代的螺环双噁唑啉
配体、合成及其在合成吡咯烷衍
生物中的应用
一种制备光学活性 3-（9-芴）－
吲哚类化合物的方法
3-二磺酰基氟甲烷取代－1－丙
烯类化合物、合成方法和用途
一种合成 1,6-烯炔类化合物的
方法
乙烯齐聚催化剂、合成方法和用
途
β-萘甲基取代的螺环双噁唑啉
配体、合成方法及其应用
一种合成氟代含氮杂环化合物的
方法
2,2-二取代-2,3-二氢喹啉酮类
手性化合物、制备方法和应用
申请日
申请号
发明人
2009-2-11
200910046081.8
2009-2-11
200910046082.2
2009-2-11
200910046083.7
2009-3-4
200910046987.X
2009-3-6
200910047182.7
2009-3-27
200910048438.6
2009-5-15
200910051314.3
丁奎岭、韩召
斌、王正
2009-5-22
200910051776.5
陈耀峰、徐信
2009-5-22
200910051785.4
麻生明、舒伟
2009-5-27
200910052117.3
2009-6-2
200910052377.0
2009-7-3
200910054359.6
2009-7-3
200910054361.3
陈耀峰、徐信
2009-9-23
200910196167.9
舒伟、麻生明
2009-10-15
200910197231.5
刘国生、吴涛
2009-12-4
200910199930.3
侯雪龙、雷柏
林、丁昌华
侯雪龙、吕伟
静
游书力、盛益
飞
游书力、夏纪
宝
游书力、李公
强、赵卓安
陈耀峰、陆而
立、甘伟
游书力、刘文
博
游书力、孙丰
来、顾庆
游书力、刘文
博
游书力、夏纪
宝
2009 年授权专利
编
号
1
2
专利名称
专利号
发明人
手性单膦配体、合成方法及其用途
一种合成 3-甲氨基吲哚化合物的方法
一种合成 1,3-二取代-4-烯-1-戊酮类化合物
的新方法
ZL200410066892.1
ZL200710036408.4
丁奎岭、赵宝国
游书力
ZL200710043018.X
游书力、贺虎
4
3-位取代中氮茚类化合物和高效合成方法
ZL200610117996.X
5
一类含杂原子的有机化合物及其在齐格勒－
纳塔催化剂中的应用
ZL200610026766.2
6
一类单活性中心齐格勒-纳塔烯烃聚合催化
剂
ZL200610026765.8
7
烯烃聚合催化剂
ZL200610025918.7
3
刘元红、宋智泉、
闫彬
唐勇、马志、杨小
红、刘博、孙秀丽、
高原、王聪
唐勇、孙秀丽、刘
博、马志、王聪、
高原、杨小红
唐勇、高明丽、王
聪、孙秀丽、谢作
伟、高原、马志
2009 年金属有机化学国家重点实验室来访人员报告目录
编
号
1
题目
报告人
单位
Palladium Complexes with
Low Coordination Number for
Catalysis
Professor C. J.
Elsevier
Van’t Hoff Institute for
Molecular
Sciences,
Universiteit
Van
Amsterdam,
Netherlands
2
挤出法超高分子量聚乙烯制
品加工技术进展
王德禧 教授
中国科学院化学研究
所
唐勇
3
Asymmetric
Synthesis of
Organo Boron Compounds via
Carbenoids
Dr.
Fang
Guangyu
University of Bristol
唐勇
4
Asymmetric Catalysis and
Synthesis: from Small Organic
Molecules to Bio-inspired
Hyperbranched Polymers
Dr. Robin Chi
Department
of
Chemistry, University
of California, Berkeley
刘国
生
5
High
Efficiency
OLED
Phosphors Prepared From
Orthometalation; Bases and
Applications
Professor Yun
Chi
National Tsing
University
Hua
唐勇
6
Alternating
Ethylene-Norbornene
Co-polymerization Catalyzed
by Cationic Organopalladium
Complexes
Bearing
Hemi-labile Bidentate Ligands
of alpha-Amino-Pyridines
New
P-Chiral
Phosphine
Ligands
for
Highly
Enantioselective Catalyses
Professor
Jwu-Ting
Chen
National
University
Taiwan
唐勇
Professor
Tsuneo
Imamoto
Department
of
Chemistry, Faculty of
Science, University of
Chiba, Japan
侯雪
龙
Advances in the Chemistry of
Polyhedral Boron Compounds
Professor
Vladimir
7
8
I.
A.N.Nesmeyanov
Institute of
主持
人
麻生
明
时间
2009 年
1 月 10
日 ( 周
六) 上午
10:00
2009 年
2月4日
(
周
三) 上午
10:00
2009 年
2月9日
(
周
一) 上午
10:00
2009 年
3 月 18
日 ( 周
三) 下午
15:00
2009 年
4月3日
(
周
五) 下午
13:45
2009 年
4月4日
(
周
六) 上午
09:30
2009 年
4月8日
(
周
三) 上午
10:00
陈耀 2009 年
9
Transition Metal Complexes
Stabilized by Various Rare
C-centered Ligands: Synthesis,
Mechanism, Dynamics and
Catalysis
10
烯烃聚合多相催化计算机分
子模拟
11
The Use of Web Technology to
Support the Research of
Students and in their Personal
Lives. How some of those
Technologies Apply to the
Professional Lives in the
Future
A Molecular Approach to
Artificial Photosynthesis and
the Light Driven Generation of
Hydrogen from Water
12
13
Computational Prediction of
Enantioselectivity
in
Asymmetic Synthesis
Bregadze
Organoelement
Compounds
Russian Academy
Sciences
峰
Professor Rich
Eisenberg
University of Rochester,
Editor of Inorganic
Chemistry
侯雪
龙
Professor Olaf
Wiest
Department
Chemistry
Biochemistry,
University of
Dame
丁奎
岭
4 月 16
日 ( 周
of
四) 上午
10:00
李兴伟 博士 美 国 Scripps 研 究 所 游书 2009 年
（Florida 分院）
力
4 月 18
日 ( 周
六) 上午
10:00
刘柏平 教授 华东理工大学，化学工 唐勇 2009 年
程联合国家重点实验
4 月 20
室
日 ( 周
一) 下午
15:00
Dr. David P. Strategic
Planning 侯雪 2009 年
Martinsen
Group
Publications 龙
4 月 21
Division,
American
日 ( 周
Chemical Society
二) 上午
09:00
of
and
Notre
14
Natural Product Chemistry in
Post-genome
era:
Metabolomics and Synthetic
Biology
Professor
Pinghua Liu
Department
Chemistry,
Univeristy
of
Boston
丁奎
岭
15
Transition
Metal-Catalyzed
Reaction
of
Diazo
Compounds, Alkynes and
Allenes
王剑波 教授
北京大学化学与分子
工程学院
唐勇
16
Alkene Metathesis : From New
Catalysts
to
Plant
Oil
Applications
Professor
Pierre
Dixneuf
University of Rennes
丁奎
岭
H.
2009 年
4 月 21
日 ( 周
二) 上午
10:00
2009 年
5 月 26
日 ( 周
二) 下午
13:30
2009 年
7 月 24
日 ( 周
五) 上午
10:00
2009 年
8 月 25
日 ( 周
二) 上午
09:30
2009 年
9月7日
University of Rennes
唐勇
Department
Chemistry,
University,
Canada
of
York
Toronto,
麻生
明
Professor
Carsten Bolm
RWTH
University
Aachen
侯雪
龙
Mechanistic
Aspects
of
Transition Metal Catalyzed
Allylic Substitutions
Professor Dr.
Guenter
Helmchen
Organisch-Chemisches
Institut der University
Heidelberg
游书
力
21
Generation
and
Stereocontrolled Reaction of
Some Cyclopropenes
Professor
Mark Baird
School of Chemistry,
University of Wales, UK
施敏
22
Oxidative Coupling, Chemistry
between Two Nucleophiles
雷爱文 教授
武汉大学
侯雪
龙
23
杂原子桥连杯芳烃的超分子
化学
王梅祥 教授
清华大学化学系
丁奎
岭
17
C-H Bond Functionalisation
with Ruthenium(II)
Professor
Pierre
Dixneuf
H.
Pd N-Heterocyclic Carbene
Catalysts: How Much Bigger
is Better?
Professor
Michael
Organ
G.
19
Iron Salts in Catalyzed Organic
Synthesis
20
18
(
周
一) 上午
10:00
2009 年
9月8日
(
周
二) 上午
10:00
2009 年
9 月 17
日 ( 周
四) 下午
15:00
2009 年
9 月 22
日 ( 周
二) 上午
10:00
2009 年
10 月 14
日 ( 周
三) 上午
10:00
2009 年
12 月 13
日 ( 周
日) 下午
15:00
2009 年
12 月 14
日 ( 周
一) 上午
10:00
2009 年
12 月 17
日 ( 周
四) 下午
15:00
24
Chemometrics Opportunities
in Forensic Chemistry
Professor
Peter
de
Boves
Harrington
25
高官能团化的噁唑啉配体的
合成及其在高极性溶剂中的
催化应用
康彦彪 博士
26
Development of Recyclable
Chiral Organocatalysts for the
Highly Asymmetric Michael
Addition Reaction
倪步阔 博士
Center for Intelligent
Chemical
Instrumentation
，
Department
of
Chemistry
and
Biochemistry
Clippinger Laboratories
Ohio University
德国海德堡大学
游书
力
2009 年
12 月 12
日(周
六) 下
午 15:00
唐勇
2009 年
12 月 25
日(周
五) 下
午 18:00
Department
of
Chemistry, Texas A&M
University-Commerce
刘国
生
2009 年
12 月 30
日 ( 周
三) 下
午 15:00
二 00 九年发表专著目录
专著(章节)题目
作者
Unsymmetrical
1,1’-Bidentate
Shu-Li You
Ferrocenyl Ligands
Ji-Bao Xia,
Monodentate Chiral Timothy F.
Ferrocenyl Ligands
Jamison,
Shu-Li You
专著名称
Chiral
Ferrocene
Ligands in
Asymmetric
Catalysis
Chiral
Ferrocene
Ligands in
Asymmetric
Catalysis
出版社名称 年份
页码 主编姓名
215-2
Wiley-VCH
2009
Wiley-VCH
Li-Xin
Dai,
2009 55-71
Xue-Long
Hou
56
Marco
Catalytic
Addition to
Carbonyl
Shu-Li You
Compounds-Imines
Friedel-Crafts
Wiley-VCH
2009
119-1
44
Alkylations
组合酸催化剂在不 游书力，郑晓
对称催化中的应用
Asymmetric
建，康强
Asymmetric
Catalysis of
Haifeng Du，
Diels–Alder
Kuiling Ding
Reaction
不对称催化—新概 丁奎岭，范青
念与新方法
华
绿色氧化
刘国生
不对称催化
新概念与新
方法
Handbook of
Cyclization
Reactions
不对称催化
新概念与新
方法
10000 个科学
难题
Li-Xin
Dai,
Xue-Long
Hou
Bandini,
Achille
Umani-Ro
nchi
化学工业出
版社
Wiley-VCH,
Weinheim
2008
2009
化学工业出
版社
科学出版社
2008
2009
319-3 丁奎岭，
65
范青华
pp.1-5 Shengmin
7
g Ma
319-3 丁奎岭，
65
267
范青华
手性配体设计中的
不对称催化
对称性问题：从 C2 唐勇、孙秀丽 —新概念与
到 C3 的对称性
新方法
Xuefeng
Handbook of
Jiang and
Cyclization
Sheming Ma Reactions
Cyclizations Based
Handbook of
Hao Guo and
on
Cyclization
Sheming Ma
Cyclometallation
Reactions
Intramolecular
Handbook of
陆熙炎、
1,2-Addition and
Cyclization
1,4-Addition
韩秀玲
Reactions
Reactions
Cyclic Coupling
Reactions
Furan and
Benzofuran
Xue Long
Hou, Zhen
Progress in
Yang,
Heterocyclic
Kap-Sun
Chemistry
Yeung and H.
N. C. Wong
化学工业出
版社
2009
142-1
62
Wiley-VCH
315-3
Verlag GmbH 2009
66
& Co. KGaA
Wiley-VCH
407-4
Verlag GmbH 2009
56
& Co. KGaA
丁奎岭，
范青华
麻生明
麻生明
Wiley-VCH
Vol. 1,
麻生明
Verlag GmbH 2009 pp.
169
& Co.
-226
Elsvier
2009
Vol.
G. W.
20,
Gribble
152-1 and J. A.
89
Joule
二 00 九年论文目录
一、固定人员论文目录（按通讯作者姓氏首字母排序）
1. Xin Xu, Yaofeng Chen*, Jie Sun, Indenyl Abstraction vs Alkyl Abstraction of
(Indenyl) ScR2(THF) by [Ph3C][B(C6F5)4]: Aspecific and Syndiospecific Styrene
Polymerization. Chem. Eur. J. 2009, 15, 846-850.
2. Erli Lu, Wei Gan, Yaofeng Chen*, Monoalkyllanthanide Complexes with New
-Diketiminato
Derivative
Dianionic
Ligands,
Organometallics
2009,
28,
2318-2324.
3. Guangyong Xie, Yuxue Li, Jie Sun, Changtao Qian*, Titanium Complexes with
-ketoiminate Chelate Ligands for Ethylene Polymerization: The Significant Influence
of Substitutes on Structures and Catalytic Activities” Inorg. Chem. Commun. 2009, 12,
796-799.
4. Zheng Wang, Hongji Li, Jiang Wu, Liting Yu, Kuiling Ding*, Development of a
Continuous-Flow System for Asymmetric Hydrogenation Using Self-Supported
Chiral Catalysts. Lei Shi, Xingwang Wang, Christian A. Sandoval, Chem. Eur. J.
2009, 15, 9855-9867.
5. Zhaobin
Han,
Zheng
Wang,
Xumu
Zhang,
Kuiling
Ding*,
Spiro[4,4]-1,6-nonadiene-Based Phosphine-Oxazoline Ligands for Iridium-Catalyzed
Enantioselective Hydrogenation of Ketimines. Angew. Chem. Int. Ed. 2009, 48,
5345-5349.
6. Zheng Wang, Gang Chen, Kuiling Ding*, Self-Supported Catalysts. Chem. Rev.
2009, 109, 322-359.
7. Haiming Wang, Zheng Wang, Kuiling Ding*, Self-supported BINOL-Zn catalysts
for heterogeneous enantioselective epoxidation of (E)-α, β-unsaturated ketones.
Tetrahedron Lett. 2009, 50, 2200-2203.
8. Kuiling Ding*, Zhaobin Han, Zheng Wang, Spiro skeletons, a class of privileged
structure for chiral ligand design. Chem. Asian J. 2009, 4, 32-41.
9. Gang Chen, Zheng Wang, Kuiling Ding*, Asymmetric conjugate addition of
unmodified cyclic ketones to nitroolefins using aminophosphonate as the
organocatalyst. Chin. J. Chem. 2009, 27, 163-168.
10. Hai Lin Liu, XueLong Hou*, Lin Pu*, Enantioselective Precipitation and
Fluorescent Enhancement in the Recognition of -Hydroxycarboxylic acids ，
Angew. Chem. Int. Ed. 2009, 48, 382-385
11. XueLong Hou*, Bao Hui Zheng, Kinetic Resolution of Indolines by Pd-Catalyzed
Asymmetric Allylic Amination. Org. Lett. 2009, 11, 1789-1791
12. WeiJing Lu, XueLong Hou*，Highly Enantioselective construction of -Chiral
Center of Amides via Iridium-Catalyzed Hydrogenation of α, β-Unsaturated Amides，
Adv. Synth. Catal. 2009, 351, 1224-1228
13. ChunGen Chen, XueLong Hou*, Lin Pu*, Highly Enantioselective Cu-Catalyzed
Conjugate Addition-Elimination of Activated Allylic Acetates with Glycine
Derivatives，Org. Lett. 2009, 11, 2073-2075
14. Wei Liu, Di Chen, XiaZhen Zhu, XiaoLong Wan, XueLong Hou*, Highly Diastereoand Enantioselective Pd-Catalyzed Cyclopropanation of Acyclic Amides with
Substituted Allyl Carbonates , J. Am. Chem. Soc. 2009, 131, 8734-8735.
15. DongLiang Mo, LiXin Dai, XueLong Hou*,
The Reaction of Terminal Alkynes
with PhI (OAc) 2: A Convenient Procedure for the
Preparation
of
-Acyloxy
Ketones. Tetrahedron Lett. 2009, 50, 5578-5581
16. DongDong Chen, XueLong Hou*, LiXin Dai, A Facile and Regioselective Synthesis
of
2,5-Disubstituted
Pyrroles
via
Au-Catalyzed
Cycloisomerization
of
Acetylenylaziridines, Tetrahedron Lett. 2009, 50, 6944-6946.
17. Ping Fang, XueLong Hou*, Asymmetric Copper-Catalyzed Propargylic Substitution
Reaction of Propargylic
Acetates with Enamines. Org. Lett. 2009, 11, 4612-4615
18. BaiLin Lei, ChangHua Ding, XiaoFei Yang, XiaoLong Wan, XueLong Hou*, Highly
Efficient
Kinetic
Resolution
of
2-Substituted-2,3-Dihydro-4-Quinolones
by
Palladium-Catalyzed Asymmetric Allylic Alkylation, J. Am. Chem. Soc. 2009, 131,
18250-18251.
19.Shuifa Qiu, Yunyang Wei, Guosheng Liu*, Palladium-Catalyzed Intramolecular
Hydroamination of Allenes Coupled to Aerobic Alcohol Oxidation. Chem.Eur. J.
2009, 15, 2751-2754.
20. Liang Wu, Shuifa Qiu, Guosheng Liu*, Bronsted Base-Modulated Regioselective
Palladium-Catalyzed Intramolecular Aerobic Oxidative Amination of Alkenes:
Formation of Seven-Membered Amides and Evidence for Allylic C-H Activation.
Org. Lett. 2009, 11, 2707-2710.
21.Tao Wu, Guoyin Yin, Guosheng Liu*, Palladium-Catalyzed Intramolecular
Aminofluorination of Alkenes. J. Am. Chem. Soc. 2009, 131, 16354-16355.
22. Xiaoping Fu, Jingjin Chen, Guangyu Li, Yuanhong Liu*, Diverse Reactivity of
Zirconacyclocumulenes Derived from Coupling of Benzynezirconocenes with
1,3-Butadiynes towards Acyl Cyanides: Synthesis of Indeno[2,1-b]pyrroles or
[3]Cumulenones. Angew. Chem. Int. Ed. 2009, 48, 5500 –5504.
23.Yifeng Chen, Yuhua Lu, Guijie Li, Yuanhong Liu*, Gold-Catalyzed Cascade
Friedel-Crafts/Furan-Alkyne Cycloisomerizations for the Highly Efficient Synthesis of
Arylated (Z)-Enones or –Enals. Org. Lett., 2009, 11, 3838-3841.
24. Hongfeng Li, JingyuYang, Yuanhong Liu*, Yanzhong Li, Iron-Catalyzed Cascade
Arene-Aldehyde Addition/Cyclizations for the Highly Efficient Synthesis of
Xanthenes and Its Analogous: Observation of a C-C Bond Cleavage in Indole-Based
Triarylmethanes. J. Org. Chem, 2009, 74, 6797-6801.
25. Yebing Zhou, Jingjin Chen, Chunbin Zhao, Erjuan Wang, Yuanhong Liu*, Yuxue Li,
Stereoselective Synthesis of β-Hydroxyallenes with Multiple Contiguous tereogenic
Centers via Aldehyde Addition to
-alkenyl-Substituted irconacyclopentenes. J. Org.
Chem. 2009, 74, 5326–5330.
26. Yuhua Lu, Xiangwei Du, Xueshun Jia, Yuanhong Liu*, Gold-Catalyzed
Intermolecular Reactions of (Z)-Enynols with Indoles for the Construction of
Dihydrocyclohepta[b]indole
Skeletons
through
a
Cascade
Friedel–Crafts/Hydroarylation Sequence. Adv. Synth. Catal. 2009, 351, 1517 – 1522.
27. Yuhua Lu, Xiaoping Fu, Haoyi Chen, Xiangwei Du, Xueshun Jia, Yuanhong, Liu*,
An Efficient Domino Approach for the Synthesis of Multisubstituted Pyrroles via
Gold/Silver-Catalyzed Amination/Cycloisomerization of (Z)-2-En-4-yn-1-ols. Adv.
Synth. Catal. 2009, 351, 129-134.
28. Feijie Song, Yuanhong Liu*, A facile approach to spirocyclic butenolides through
cascade cyclization/oxidative cleavage reactions of (Z)-enynols catalyzed by gold
under dioxygen atmosphere. J. Organomet. Chem. 2009, 694, 502-509.
29. Xiangwei Du, Feijie Song, Yuhua Lu, Haoyi Chen, Yuanhong Liu*, A general and
efficient synthesis of substituted furans and dihydrofurans via
gold-catalyzed cyclization of (Z)-2-en-4-yn-1-ols. Tetrahedron 2009, 65, 1839-1845.
30. Hao Zhang, Xiaoping Fu, Jingjin Chen, Erjuan Wang, Yuanhong Liu*, Yuxue Li*,
Generation
of
Allenic/Propargylic
Zirconium
Complexes
and
Subsequent
Cross-Coupling Reactions: A Facile Synthesis of Multisubstituted Allenes. J. Org.
Chem. 2009, 74, 9351–9358.
31. Feng Zhou, Miao Yang, Xiyan Lu*, Cationic Palladium(II)-Catalyzed Highly
Enantioselective Tandem Reactions of ortho-Boronate- Substituted Cinnamic
Ketones and Internal Alkynes. A Convenient Synthesis of Optically Active Indenes,
Org. Lett. 2009, 11, 1405-1408.
32. Huixiong Dai, Xiyan Lu*, Palladium (II)/2, 2’-bipyridine-catalyzed addition of
arylboronic acids to N-tosyl-arylaldimines, Tetrahedron Lett. 2009, 50, 3478-3481.
33. Xiuling Han, Xiyan Lu*, Novel Palladium-Catalyzed Acyloxylation/Cyclization of
2-(3′-Alkenyl) indoles, Org. Lett. 2009, 11, 2381-2384.
34. Suqing Zheng, Xiyan Lu*, Phosphine-catalyzed [3+3] annulation reaction of
modified tert-butyl allylic carbonates and substituted alkylidenemalononitriles.
Tetrahedron
Lett. 2009, 50, 4532-4535.
35. Suqing Zheng, Xiyan Lu*, Phosphine-Catalyzed [4 + 3] Annulation for the Synthesis
of Highly Functionalized Bicyclo [3.2.2] nonadienes .Org. Lett. 2009, 11, 3978-3981.
36. Xufen Yu, Xiyan Lu*, Cationic Palladium Complex Catalyzed Diastereo- and
Enantioselective Tandem Annulation of 2-Formylarylboronic Acids with Allenoates.
Org. Lett, 2009, 11, 4366-4369.
37．Zengming Shen, Xiyan Lu*, Cupric Halide-Mediated Intramolecular Halocyclization
of N-Electron-Withdrawing Group-Substituted 2-Alkynylanilines for the Synthesis of
3-Haloindoles. Adv. Synth. Catal. 2009, 351, 3107-3112.
38. Fei Yu, Xiongdong Lian, Jinbo Zhao, Yihua Yu, Shengming Ma*, CuX2-Mediated
Halolactonization Reaction of Monoesters of 1,2-Allenyl Phosphonic Acids and Their
Suzuki Cross-Coupling Reaction. J. Org. Chem. 2009, 74, 1130-1134.
39. Wei Shu, Guochen Jia, Shengming Ma*, Palladium-Catalyzed Regioselective
Cyclopropanating Allenylation of (2, 3-Butadienyl) malonates with Propargylic
Carbonates and Their Application to Synthesize Cyclopentenones. Org. Lett. 2009, 11,
117-120.
40. Wei Shu, Guochen Jia, Shengming Ma*, Palladium-Catalyzed Three-Component
Cascade Cyclization Reaction of Bisallenes with Propargylic Carbonates and
Organoboronic Acids: Efficient Construction of cis-Fused Bicyclo [4.3.0] nonenes
Angew. Chem. Int. Ed. 2009, 48, 2788-2791.
41. Tao Bai, Shengming Ma*, Guochen Jia*, Insertion Reactions of Allenes with
Transition Metal Complexes Coord. Chem. Rev. 2009, 253, 423-448.
42. Xin Chenga, Shengming Ma*, Efficient Synthesis of 2,3-Dihydro-1H-pyrazoles via a
Highly Selective Pd(0)-Catalyzed Coupling-Cyclization Reaction of Terminal
2-Substituted 2,3-Allenyl Hydrazines with Aryl Iodides. Chem. Commun. 2009,
4263-4265.
43. Jie Chen, Shengming Ma*, An X- (X = I, Br)-Triggered Ring-Opening Cyclization
of Cyclopropenyl-substituted Alkyl Halides or Mesylates: An Efficient and Highly
Regio- and Stereoselective Approach to (E)-Haloalkylidene 4~7-Membered Cyclic
Compounds. J. Org. Chem. 2009, 74, 5595-5598.
44. Wei Shu, Qiong Yu, Shengming Ma*, The Effect of Naphthylmethyl Substituent on
the
Sipro-BOX
Ligand:
Highly
Enantioselective
Construction
of
3-Alkylideneindolines from Pd-Catalyzed Cyclization of 2-Iodoanilines with Allenes.
Adv. Synth. Catal. 2009, 351, 2807-2810.
45. Wei Shu, Shengming Ma*, Synthesis of A New Spiro-BOX Ligand and Its
Application in Enantioselective Allylic Cyclization Based on Carbopalladation of
Allenylhydrazines, Chem. Commun. 2009, 6198-6200
46. Jinbo Zhao, Yu Liu, Qiwen He, Yuxue Li*, Shengming Ma*, Experimental and
Theoretical Study of Tunable 1,3-Lithium Shift of Propargylic/Allenylic Species,
Transmetallation, and Pd-Catalyzed Cross-Coupling Reactions.Chem. Eur. J. 2009,
15, 11361-11372.
47. Jie Chen, Ning Xin, Shengming Ma*, Synthesis of polyfunctionalized vinyl
cyclopropanes via the NaI-catalyzed ring-opening cyclization of doubly activated
cyclopropenes with1,1-bis(phenylsulfonyl)ethylene Tetrahedron Letters 2009, 50,
3175-3177
48. WanPo Yin, Min Shi*, Nitration of Substituted Phenols by Metal Salts Impregnated
Yb-Mo-Montmorillonite KSF. ARKIVOC 2009, v, 6-16.
49. JianMei Lu, ZhiBin Zhu, Min Shi*, Lewis acid or Brønsted acid-catalyzed Reactions
of Vinylidenecyclopropanes with Activated Carbon-Nitrogen, Nitrogen-Nitrogen, and
Iodine-Nitrogen Double Bond Containing Compounds. Chem. Eur. J. 2009, 15,
963-971.
50. Wei Li, Min Shi*, Palladium-Catalyzed Coupling Reactions of Diarylvinylidene
cyclopropanes
with
2-Iodophenol
and
N-(2-Iodophenyl)-4-methylbenzenesulfonamide. Eur. J. Org. Chem. 2009, 270-274.
51. Wei Li, Min Shi*, A Catalytic Method for the Preparation of Polysubstituted
Cyclopentanes: [3+2] Cycloaddition of Vinylidenecyclopropanes with Activated
Olefins Catalyzed by Triflic Imide. J. Org. Chem. 2009, 74, 856-860.
52. Zhen Liu, Min Shi*, Efficient Chirality Switching in the Asymmetric Addition of
Indole to N-Tosylarylimines in the Presence of Axially Chiral Cyclometalated
Bidentate
N-Heterocyclic
Carbene
Palladium(II)
Complexes.
Tetrahedron:
Asymmetry 2009, 20, 119-123.
53. Min Jiang, Min Shi*, The Reaction of Methylenecyclobutanes with Diphenyl
Diselenide in the Presence of Iodosobenzene Diacetate and H2O. Tetrahedron 2009,
65, 798-801.
54. LiangFeng Yao, Min Shi*, Lewis Acid-Catalyzed Cascade Reactions of 1, 6-Diynes
and 1, 6-Enynes with Vinylidenecyclopropanes. Chem. Eur. J. 2009, 15, 3875-3881.
55. LunZhi Dai, Min Shi*, A Convenient and Efficient One-pot Way to synthesize,
-Epoxy Ketones Directly from Acetophenones and Arylaldehydes. Tetrahedron Lett.
2009, 50, 651-655.
56. XiaoYang Guan, Min Shi*, Phosphine-mediated [3+2] Cycloaddition Reactions of
Ethyl 5, 5-Diarylpenta-2, 3, 4-trienoates with Arylmethylidenemalononitriles and
N-Tosylimines. J. Org. Chem. 2009, 74, 1977-1981.
57. Lei Wu, Min Shi*, AgOAc-Mediated Rearrangement of gem-Dibromospiropentanes
in Trifluoroacetic Acid. Tetrahedron Lett. 2009, 50, 1636-1638.
58. Min Jiang, Min Shi*, Reactions of mono-Aryl Substituted Methylenecyclobutanes
and Methylenecyclopropanes with 1-Hydroxybenzotriazole (HOBt),
1-Hydroxy-7-azabenzotriazole (HOAt) and 1-Hydroxysuccinimide (HOSu). J. Org.
Chem. 2009, 74, 2516-2520.
59. ZhiBin Zhu, Min Shi*, Acid Catalyzed Cascade Ring-Opening and Addition
-Unsaturated Substrates, Scope and
Limitations. J. Org. Chem. 2009, 74, 2481-2485.
60. Min Shi*, GuoQiang Tian, Jia Li, Palladium (II) and Palladium (0)-Cocatalyzed Ring
Opening and Oxidation Reactions of 2-(Arylmethylene) cyclopropylcarbinols.
Tetrahedron 2009, 65, 3404-3408.
61. Wei Li, Min Shi*, Triflic Imide-Catalyzed Cascade Cycloaddition and Friedel-Crafts
Reaction of Diarylvinylidenecyclopropanes with Ethyl 5,5-Diarylpenta-2,3,4-trienoate.
Org. Bio. Chem. 2009, 7, 1775-1777.
62. JianMei Lu, Min Shi*, LDA-Mediated Carbolithiation Reactions of Vinylidenecyclopropanes and Further Transformations of the Adducts. Chem. Eur. J. 2009, 15,
6065-6073.
63. LunZhi Dai, Min Shi*, Gold (I) Catalysis: Selective Synthesis of Six- or
Seven-membered Heterocycles from Epoxy Alkynes. Eur. J. Org. Chem. 2009,
3129-3133.
64.
Min
Jiang,
Min
Shi*,
Reactions
of
Methylenecyclopropanes
and
Vinylidenecyclopropanes with N-Fluorodibenzenesulfonimide. Tetrahedron. 2009, 65,
5222-5227.
65. Wei Li, Min Shi*, Yuxue Li*, Brønsted Acids-Mediated Novel Rearrangements of
Diarylvinylidenecyclopropanes and Their Mechanistic Investigations Based on the
DFT Calculation. Chem. Eur. J. 2009, 15, 8852-8860.
66. Wei Li, Min Shi*, Addition of Diphenylphosphinodithioic Acid and Thioacetic Acid
with Vinylidenecyclopropanes: Reversed Regioselectivities. Tetrahedron .2009, 65,
6815-6821.
67. XiangYing Tang, Min Shi*, An Efficient Route to 2, 3-Disubstituted Pyrrole-amides
by
Ring-Opening
Cyclization
of
Benzylidene-
and
Alkylidenecyclo-
propylcarbaldehydes with Hydrazides. J. Org. Chem. 2009, 74, 5983-5986.
68. XiaoYang Guan, Yin Wei*, Min Shi*, Beyond the aza-Morita-Baylis-Hillman
reaction: Lewis bases catalyzed reactions of N-Boc imines with ethyl 2,
3-butadienoate. J. Org. Chem. 2009, 74, 6343-6346.
69. XiangYing Tang, Min Shi*, Pd (0) or Pd (II) Catalyzed Ring-Opening Reactions of
Benzylidene- and Alkylidenecyclopropyl Ketones and Aldehydes. Tetrahedron. 2009,
65, 8863-8868.
70. XiangYing Tang, Min Shi*, Lewis Acid-Mediated Reactions of
1-Cyclopropyl-2-arylethanone Derivatives with Diethyl 2-Oxomalonate and Ethyl
2-Oxoacetate. Tetrahedron. 2009, 65, 9336-9343.
71. BeiLi Lu, JianMei Lu, Min Shi*, Butyl Lithium (nBuLi)-Mediated Carboxylation of
Vinylidenecyclopropanes with CO2. Tetrahedron. 2009, 65, 9328-9335.
72. Min Jiang, Min Shi*, Pd Catalyzed Diacetoxylation of Methylenecyclopropanes via
C (sp3)-C (sp3) Bond Breaking .Organometallics .2009, 28, 5600-5602.
73. HongPing Deng, Yin Wei, Min Shi*, Axially Chiral Phosphine-Oxazoline Ligands in
Silver
(I)-Catalyzed
Asymmetric
Mannich
Reaction
of
Aldimines
with
Trimethylsiloxyfuran. Adv. Synth. & Catal. 2009, 351, 2897-2902.
74. LunZhi Dai, Min Shi*, Gold (I)-catalyzed Reactions: Substituents-Dependent
Selective Formation of Bisfurans and 1,3-Diketones from 1-Alkynyl-2,3-epoxy
Alcohols. Tetrahedron Lett. 2008, 49, 6437-6439.
75. Min Jiang, Min Shi*, Allylic Lithiation of Methylenecyclobutanes. Tetrahedron 2008,
64, 10140-10147.
76.MingJuan
Qi,
Teng
Ai,
Min
Shi*, Guigen
Li*,
Asymmetric
Catalytic
Aza-Morita-Baylis-Hillman Reaction using Chiral Bifunctional Phosphine Amides as
Catalysts. Tetrahedron. 2008, 64, 1181-1186.
77. LiXiong Shao, MingHui Qi, Min Shi*, Lewis acid-catalyzed Prins-type reactions of
methylenecyclopropylcarbinols with aldehydes and aldimines. Tetrahedron Lett. 2008,
49, 165-168.
78. Min Shi*, Lei Wu, JianMei Lu, AlCl3-Mediated Tandem Friedel-Crafts Reactions of
Vinylidenecyclopropanes with Acyl Chlorides: A Facile Synthetic Method for the
Construction of 1-[2-(2,2-Diarylvinyl)-1-phenyl-3H-inden-5-yl]ethanone Derivatives.
Tetrahedron 2008, 64, 3315-3321.
79. Xiaohong Yang, Zheng Wang, Xiuli Sun*, Yong Tang*, Synthesis, characterization,
and catalytic behaviours of b-carbonylenamine-derived [O-NS] TiCl3 complexes in
ethylene homo- and copolymerization. Dalton Trans., 2009, 8945–8954.
80. Chunli Cao, Youyun Zhou, Jian Zhou, Xiuli Sun, Yong Tang*, Yuxue Li*, Guangyu
Li, Jie Sun, An Organocatalytic Asymmetric Tandem Reaction for the Construction
of Bicyclic Skeletons. Chem. Eur. J. 2009, 15, 11384 –11389.
81. Chunyin Zhu, Xiaoyu Cao, Benhu Zhu, Chao Deng, Xiuli Sun, Biqin Wang, Qi Shen,
Yong Tang*, Application of Asymmetric Ylide Cyclopropanation in the Total
Synthesis of Halicholactone. Chem. Eur. J. 2009, 15, 11465 –11468.
82. Jianping Qu, Chao Deng, Jian Zhou, Xiuli Sun, Yong Tang*, Switchable Reactions
of Cyclopropanes with Enol Silyl Ethers. Controllable Synthesis of Cyclopentanes
and 1,6-Dicarbonyl Compounds. J. Org. Chem. 2009, 74, 7684–7689.
83. Xiaohong Yang, Chunrong Liu, Cong Wang, Xiuli Sun, Yanghui Guo, Xinke Wang,
Zheng Wang, Zuowei Xie, Yong Tang*, [O-NSR]TiCl3-Catalyzed Copolymerization
of Ethylene with Functionalized Olefins. Angew. Chem. Int. Ed. 2009, 48, 8099–
8102.
84. Jiaolong
Zhou,
Mengchun
Ye,
Xiuli
Sun,
Yong
Tang*,
Trisoxazoline/Cu(II)-catalyzed asymmetric intramolecular Friedel–Crafts alkylation
reaction of indoles. Tetrahedron 2009, 65, 6877–6881.
85. Peng Cao, Xiuli Sun, Benhu Zhu, Qi Shen, Zuowei Xie, Yong Tang*, Multistep
One-Pot Wittig/Nazarov Reaction for Construction of Cyclopentenone with Diazo
Compounds and Acid Chlorides. Org. Lett., 2009, 11, 3048-3051.
86. Jianping Qu, Zhenghu Xu, Jian Zhou, Chunli Cao, Xiuli Sun, Lixin Dai, Yong Tang*,
Ligand-Accelerated Asymmetric [1,2]-Stevens Rearrangment of Sulfur Ylides via
Decomposition of Diazomalonates Catalyzed by Chiral Bisoxazoline/Copper
Complex. Adv. Synth. Catal. 2009, 351, 308-312.
87. Longwu Ye, Shoubing Wang, Qinggang Wang, Xiuli Sun, Yong Tang*, Yonggui
Zhou*, Asymmetric Tandem Michael Addition–ylide Olefination Reaction for the
Synthesis of Optically Active Cyclohexa-1,3-diene Derivatives. Chem. Commun.
2009, 7, 3092-3094.
88. Sunewang R. Wang, Chunyin Zhu, Xiuli Sun, Yong Tang*, Reaction of Allylic
Phosphoranes with Iron Porphyrin Carbenoids: Efficient, Selective, and Catalytic
Intermolecular Formal Carbenoid Insertion into Olefinic C-H Bonds. J. Am. Chem.
Soc. 2009, 131, 4192-4193.
89. Xun Han, Longwu Ye, Xiuli Sun, Yong Tang*, Catalytic Intramolecular Formal [3 +
2] Cycloaddition for the Synthesis of Benzobicyclo[4.3.0] Compounds. J. Org. Chem.
2009, 74, 3394–3397.
90. Xun Han, Longwu Ye, Xiuli Sun*, Cyclization Reactions for the Stereoselective
Synthesis of Small Ring Compounds via Selenonium and Telluronium Ylides.
Chinese J. Org. Chem., 2009, 29, 3, 309-320.
91. Jibao Xia, Xueqiang Wang, Shuli You*, Synthesis of Biindolizines through Highly
Regioselective Palladium-Catalyzed C-H Functionalization. J. Org. Chem. 2009, 74,
456-458.
92. Qiang
Kang,
Zhuoan
Zhao,
Shuli
You*,
Enantioselective
Synthesis
of
(3-Indolyl)glycine Derivatives via Asymmetric Friedel-Crafts Reaction between
Indoles and Glyoxylate Imines. Tetrahedron. 2009, 65, 1603-1607.
93. Jibao Xia, Shuli You*, Synthesis of 3-Haloindolizines by Copper(II) Halides
Mediated Direct Functionalization of Indolizines. Org. Lett. 2009, 11, 1187-1190.
94. Yifei Sheng, G.ongqiang Li, Qiang Kang, Anjiang Zhang, Shuli You*, Asymmetric
Friedel-Crafts Reaction of 4, 7-Dihydroindoles with Nitroolefins by Chiral Brønsted
Acids in Low Catalyst Loading. Chem. Eur. J. 2009, 15, 3351-3354.
95. Gongqiang Li, Lixin Dai, Shuli You*, N-Heterocyclic Carbene-Catalyzed Ring
Expansion of Formylcyclopropanes: Synthesis of 3, 4-Dihydro-α-pyrones Derivatives.
Org. Lett. 2009, 11, 1623-1625.
96. Qingli He, Fenglai Sun, Xiaojian Zheng, Shuli You*, Brønsted Acid-Catalyzed
Synthesis of Unsymmetrical Arylbis(3-indolyl)methanes. Synlett 2009, 1111-1114.
97. Shuli You*, Quan Cai, Mi Zeng, Chiral Brønsted Acids Catalyzed Friedel-Crafts
Alkylation Reaction. Chem. Soc. Rev. 2009, 38, 2190-2201.
98. Xueqiang Wang, Jibao Xia, Xiaoyang Dai, Shuli You*, Preparation of ferrocenyl
imidazolines using bis(triphenyl)oxodiphosphonium trifluoromethanesulfonate. Sci
China Ser B-Chem. 2009, 52, 1331-1336.
99. Wenbo Liu, Hu He, Lixin Dai, Shuli You*, Synthesis of 2-Methylindoline and
2-Methyl-1,2,3,4-tetrahydroquinoline
Derived
Phosphoramidites
and
Their
Applications in Iridium-Catalyzed Allylic Alkylation of Indoles. Synthesis. 2009,
2076-2082.
100. Hu He, Wenbo Liu, Lixin Dai, Shuli You*, Ir-Catalyzed Cross-Coupling of Styrene
Derivatives with Allylic Carbonates: Free Amine Assisted Vinyl C-H Bond Activation.
J. Am. Chem. Soc. 2009, 131, 8346-8347.
101. Yifei Sheng, Qing Gu, Anjiang Zhang, Shuli You*, Chiral Brønsted Acid Catalyzed
Asymmetric Friedel−Crafts Alkylation of Pyrroles with Nitroolefins. J. Org. Chem.
2009, 74, 6899-6901.
102. Fenglai Sun, Mi Zeng, Qing Gu, Shuli You*, Enantioselective Synthesis of
Fluorene Derivatives by Chiral Phosphoric Acid Catalyzed Tandem Double
Friedel-Crafts Reaction. Chem. Eur. J. 2009, 15, 8709-8712.
103. Yi Li, Fuqiang Shi, Qingli He, Shuli You*, N-Heterocyclic Carbene-Catalyzed
Cross-Coupling of Aldehydes with Arylsulfonyl Indoles. Org. Lett. 2009, 11,
3182-3185.
104.Quan Cai, Zhuoan Zhao, Shuli You*, Asymmetric Construction of Polycyclic
Indoles through Olefin Cross-Metathesis/ Intramolecular Friedel-Crafts Alkylation
under Sequential Catalysis. Angew. Chem. Int. Ed. 2009, 48, 7428-7431.
105. Yi Li, Xueqiang Wang, Shuli You*, Highly Enantioselective Intramolecular
Michael Reactions by D-Camphor-Derived Triazolium Salts. Chem. Commun. 2009,
5823-5825.
106. Wenbo Liu, Shengcai Zheng, Hu He, Xiaoming Zhao*, Lixin Dai, Shuli You*,
Iridium-catalyzed Regio- and Enantioselective Allylic Alkylation of Fluorobis
(phenylsulfonyl) methane. Chem. Commun. 2009, 6604-6606.
以下论文重点实验室为作者第二单位
1．甘伟,聂万丽*, 陈耀峰*, 烯烃聚合中金属化合物间的链转移反应. 有机化学
2009,29, 1200-1208.
2．Guangming Wu, Yaofeng Chen, Duan-Jun Xu, Jia-Chu Liu, Weilin Sun*, Zhiquan
Shen*, Synthesis and molecular structure of a tetrameric neodymium silsesquioxane
cage complex: {[(i-C4H9)7(Si7O12) Nd]4NaCl}.
J. Organomet. Chem. 2009,694,
1571-1574.
3．Jinqiang Kuang, Shengming Ma*, An Efficient Synthesis of Terminal Allenes from
Terminal 1-Alkynes. J. Org. Chem. 2009, 74, 1763-1765.
4. Youqian Deng, Xin Jin, Chunling Fu, Shengming Ma*, Efficient Highly Selective
Synthesis
of
Methyl
2-(Ethynyl)alk-2(E)-enoates
and
2-(1’-Chlorovinyl)alk-2(Z)-enoates from 2-(Methoxycarbonyl)-2,3-allenols. Org.
Lett. 2009, 11, 2169-1272.
5. Guangke He, Hao Guo, Rong Qian, Yinlong Guo, Chunling Fu*, Shengming Ma*,
Studies on Highly Regio- and Stereoselective Selenohydroxylation Reaction of
1,2-Allenyl Phosphine Oxides with PhSeCl. Tetrahedron 2009, 65, 4877-4889.
6. Shengming Ma*, Electrophilic Addition and Cyclization Reactions of Allenes
Acc. Chem. Res. 2009, 42, 1679-1688.
7. Lianjun Liu, Feijun Wang*, Min Shi*, Elimination of an Alkyl Group from
Imidazolium Salts: Imidazole Coordinated Dinuclear Monodentate NHC-Palladium
Complexes Driven by Self-assembly and Their Application in Heck Reaction. Eur. J.
Inorg. Chem. 2009, 1723-1728.
8. FangFang Yu, WangGui Yang, Min Shi*, Photolysis of Diarylvinylcyclopropenes for
the Construction of 1-Methylene-8a-aryl-1,8a-dihydroazulene Skeletons. Chem.
Commun. 2009, 1392-1394.
9. Guangning Ma, Tao Zhang, Min Shi*, Catalytic Enantioselective Arylation of
N-Tosylarylimines
with
Arylboronic
Acids
Using
C2-Symmetric
Cationic
N-Heterocyclic Carbenes (NHCs) Pd2+ Diaquo Complexes. Org. Lett. 2009, 11,
875-878.
10. Xingxing Gu, Feijun Wang*, Minghui Qi, Lixiong Shao, Min Shi*, Synthesis of
2
Promoted Ring-Opening
Reactions of Vinylidenecyclopropanes and Their Application in Suzuki Coupling
Reaction. Organometallics 2009, 28, 1569-1574.
11. ShiJia Liu, Lianjun Liu, Min Shi*, Preparation of Novel Axially Chiral NHC-Pd(II)
Complexes and Their Application in Oxidative Kinetic Resolution of Secondary
Alcohols. Applied Organometa. Chem. 2009, 23, 183-190.
12. ZhiBin Zhu, LiXiong Shao*, Min Shi*, Bronsted Acid- or Solid Acid-Catalyzed
Aza-Diels-Alder Reactions of Methylenecyclopropanes with Ethyl (Arylimino)acetates.
Eur. J. Org. Chem. 2009, 2576-2580.
13. Wenfeng Wang, Tao Zhang, Min Shi*, Chiral Bis(NHC)-Pd(II) Complexes-Catalyzed
and Diethylzinc-Mediated Enantioselective Umpolung Allylation of Aldehydes.
Organometallics 2009, 28, 2640-2642.
14. Guangning Ma, Shuhua Cao, Min Shi*, Chiral phosphine-catalyzed regio- and
enantioselective allylic amination of Morita-Baylis-Hillman acetates. Tetrahedron :
Asymmetry 2009, 20, 1086-1089.
15. Zhiliang Yuan, Jiajun Jiang, Min Shi*, The Application of Chiral Phosphine-Schiff
base Type Ligands in Silver(I)-Catalyzed Asymmetric Vinylogous Mannich Reaction
of Aldimines with Trimethylsiloxyfuran. Tetrahedron 2009, 65, 6001-6007.
16. Zhibin Zhu, Yin Wei, Min Shi*, Acid-Catalyzed Cascade Reactions of
Arylvinylcyclopropenes with Acetals and Aldehydes for the Construction of Different
Aromatic Systems. Chem. Eur. J. 2009, 15, 7543-7548.
17. Lianjun Liu, Feijun Wang* , Min Shi*, Synthesis of Chiral Bis(N-Heterocyclic
Carbene) Palladium and Rhodium Complexes with 1,1’-Biphenyl Scaffold and Their
Application in Asymmetric Catalysis. Organometallics 2009, 28, 4416-4420.
18. Guangning Ma, Jiajun Jiang, Min Shi*, Yin Wei, Recent extensions of
Morita-Baylis-Hillman reaction. Chem. Commun. 2009, 5496-5514.
19. Liangfeng Yao, Min Shi*, Nd(OTf)3 Catalyzed Cascade Reactions of
Vinylidenecyclopropanes with Enynol, A New Method for the Construction of 5-7-6
Tricyclic Framework and Its Scope and Limitations. Eur. J. Org. Chem. 2009,
4036-4040.
20.
Liang-Feng
Yao,
Min
Shi*,
Lewis
Acid-catalyzed
Reactions
of
Bis(4-alkoxyphenyl)methanol with Methylenecyclopropanes. Eur. J. Org. Chem. 2009,
4971-4983.
21. Xuguang Liu, Yin Wei*, Min Shi*, The Reaction of Acyl Cyanides with “Huisgen
Zwitterion”: an Interesting Rearrangement Involving Ester Group Migration between
Oxygen and Nitrogen Atoms. Org. Bio. Chem. 2009, 7, 4708-4714.
22. Zhibin Zhu, Min Shi*, Palladium(II) Acetate-catalyzed Tandem Cycloisomerization
and Oxidation of Arylvinylcyclopropenes Using p-Benzoquinone as Oxidant and
Pro-nucleophile. Org. Lett. 2009, 11, 5278-5281.
23. Liangfeng Yao, Yin Wei, Min Shi*, Silver and Gold-Catalyzed Intramolecular
Rearrangement of Propargylic Alcohols Tethered with Methylenecyclopropanes:
Stereoselective
Synthesis
of
Allenylcyclobutanols
and
1-Vinyl-
3-oxabicyclo[3.2.1]octan-8-one Derivatives. J. Org. Chem. 2009, 74, 9466-9469.
二、客座人员论文目录（按通讯作者姓氏首字母排序）
1． Lei Lu, Weiguo Cao*, Jie Chen, Hui Zhang, Jiaping Zhang, Huiyun Chen, Jiamei Wei,
Hongmei
Deng,
Min
Shao,
A
Facile
Steroselective
Synthesis
of
2-Perfluoroalkyl-3a,4,5,6-tetrahydroimidazo[1,5-b] isoxazoles. J. Fluorine Chem. 2009,
130, 295-300
2.
Ying Liu, Dong Zhou, Zhongjiao Ren, Weiguo Cao*, Jie Chen, Hongmei Deng, Qing Gu,
A Green Efficient Synthesis of Spiro[indoline-3,4’(1H’)-pyrano-[2,3-c]pyrazol]-2-one
Derivatives. J. Chem. Res. 2009, 3, 154-156.
3.
Weiqi Tong, Changqing Wang, Wenwen Zhao, Jie Chen, Xiaoyu Wu, Min Zhang,
Hongmei Deng, Min Shao, Zhongjiao Ren, Weiguo Cao*, Facile, Highly Stereoselective
Synthesis of Cyclopropyl Benzoimidazoles via Cyclopropanation of Olefin with
Arsonium Ylides. Synth. Commun. 2009, 39, 3471-3481.
4. Lei Lu, Jiamei Wei, Jie Chen, Jiaping Zhang, Hongmei Deng, Min Shao, Hui Zhang,
Weiguo Cao*, A Simple and Convenient Synthesis of 2-(Perfluoroalkyl)-4H-chromenes
from Salicyl N-Tosylimines or Salicylaldehydes with Methyl 2-Perfluoroalkynoates.
Tetrahedron 2009, 65, 9152-9156.
5. 王猛, 张慧, 陈杰, 吴小余, 邓红梅, 邵敏, 曹卫国*, 氮叶立德高立体选择性地合成
螺[环丙烷-1,4’-吡唑啉-5’-酮]衍生物反应的研究, 有机化学
2009, 29, 1611-1616.
6. Qian Geng, Hui Zhang, Weiguo Cao*, Yali Chen. A Facile Synthesis of N-Aryl
Substituted Piperidones. Chin. J. Chem. 2009, 27,1995-2000.
7. Na Zhao, Yuhui Wu, Huimin Wen, Xu Zhang, Zhongning Chen*, Conversion from ILCT
to LLCT/MLCT Excited State by Heavy Metal Ion Binding in Iridium(III) Complexes
with Functionalized 2,2’-Bipyridyl Ligands, Organometallics 2009, 28, 5603–5611.
8. Jun Ni, Yuhui Wu, Xu Zhang, Bin Li, Liyi Zhang, Zhongning Chen*, Luminescence
Vapochromism of a Platinum(II) Complex for Detection of Low Molecular Weight
Halohydrocarbon, Inorg. Chem. 2009, 48, 10202–10210.
9. Jun Ni, Liyi Zhang, Zhongning Chen*, Syntheses, Characterization and Sensitized
Lanthanide Luminescence of Heteronuclear Pt-Ln (Ln = Eu, Nd, Yb) Complexes with
2,2’-Bipyridyl Ethynl Ligands, J. Organomet. Chem. 2009, 694, 339-345.
10. Jiayao, Yao, Zuo Xiao, Jianxin Zhang, Xiaobing Yang, Liangbing Gan*, Wenxiong
Zhang*, Switched role of fullerene in the Diels-Alder reaction: facile addition of
dienophiles to the conjugated fullerene diene moiety Chem. Commun. 2009, 4, 401-403.
11. Jiayao Yao, DazhiYang, Zuo Xiao, Liangbing Gan*, ZhemingWang*, Synthesis of
Fullerene Oxides Containing Both 6,6-Closed Epoxide and 5,6-Open
Ether
Moieties
through Thermolysis of Fullerene Peroxides J. Org. Chem. 2009, 74, 3528-3531.
12. Chunxiao Song, Guixin Cai, Thomas R. Farrell, Zhongping Jiang, Hu Li, Liangbing Gan*,
Zhangjie Shi*, Direct functionalization of benzylic C-Hs with vinyl acetates via
Fe-catalysis. Chem. Commun. 2009, 40, 6002-6004.
13. Feng Sha, Xian Huang*, A Multicomponent Reaction of Arynes, Isocyanides, and
Terminal Alkynes: Highly Chemo- and Regioselective Synthesis of Polysubstituted
Pyridines and Isoquinolines, Angew. Chem.Int. Ed., 2009, 48(18), 3458-3461.
14. Ruwei Shen, Xian Huang*, Unexpected Multiple Electrophilic Addition Reaction of
(Z)-Alk-2-en-4-ynoates with N,N-Dibromo-p-toluenesulfonamide (TsNBr2): A Highly
Diastereoselective Synthesis of Densely Functionalized Aziridines, Org. Lett. 2009,
5698-5701.
15. Chenliang Su, Xian Huang*, Lewis Acid-Mediated Selective Cycloadditions of
Vinylidenecyclopropanes with Aromatic Aldehydes: An Efficient Protocol for the Synthesis
of Benzo[c]fluorene, Furan and Furo[2,3b]furan Derivatives, Adv. Synth. Catal. 2009,
135-140.
16. Ruwei Shen, Linzhu Chen, Xian Huang*, Facile Synthesis of Polycyclic Fluorene
Derivatives via a Palladium-catalyzed Coupling, Propargyl-allenyl Isomerization and
Schmittel Cyclization Sequence, Adv. Synth. Catal. 2009, 2833-2838.
17. Xian Huang*, Shugao Zhu, Rugui Shen, Palladium-catalyzed Sequential Reaction via
Allene Intermediates for the Rapid Synthesis of Fused Polycyclic Pyrrole Derivatives, Adv.
Synth. Catal. 2009, 3118-3122.
18. Ruwei Shen, Shugao Zhu, Xian Huang*, An Unexpected Pd-catalyzed Coupling,
Propargyl-allenyl Rearrangement and Alder-ene reaction: Facile Synthesis of Some
Not-readily Available 2,3-Dihydrofuran Derivatives, J. Org. Chem. 2009, 4118-4123.
19. Maozhong Miao, Xian Huang*, Organo-selenium Induced Radical Ring-Opening
Intramolecular
Cyclization
cyclopropylaldehyde:
A
or
Electrophilic
Tunable
Cyclization
Synthesis
of
of
2-
(Arylmethylene)
1-Naphthaldehydes
or
3-Oxabicyclo[3.1.0]hexan-2-ols, J. Org. Chem. 2009, 5636-5639.
20. Chenliang Su, Xian Huang*, Qingyang Liu, Xin Huang, Facile Synthesis of
Tetrahydrofurans from Cycloadditions of Vinylidenecyclopropanes with Aldehydes and
Further Tunable Transformations for the Construction of Furan, Indene, and
Benzo[c]fluorene Derivatives, J. Org. Chem. 2009, 8272-8279.
21. Xian Huang*, Jianfeng Xu, One-Pot Facile Synthesis of Substituted Isoindolinones via an
Ugi
Four-Component
Condensation/Diels−Alder
Cycloaddition/
Deselenization−Aromatization Sequence, J. Org. Chem. 2009, 8859-8861.
22. Xian Huang*, Jianfeng Xu, Solid-Phase Synthesis of 2,5-Dihydro-1H-pyrroles,
1,3-Dioxo-2,3,5,7a-tetrahydro-1H-pyrrolo[1,2-c]imidazoles and 1,4-Dioxo-1,2,3,4,6,8ahexahydropyrrolo[1,2-a]pyrazines Using a Supported Selenium Resin,
J. Comb. Chem.
2009, 350-354.
23. Xian Huang*, Jian Cao, Jianqiang Huang, Solid-Phase Synthesis of Benzofused Tricycles
Based on Benzimidazole from Resin-bound 3-(2-aminophenylamino)-2-seleno-ester, J.
Comb. Chem. 2009, 515-518.
24. Jianfeng Xu, Xian Huang*, Solid-Phase Synthesis of 2-Pyridones, 1,4-Diazepines, and
1,4-Oxazepines from Resin-Bound 3-Amino-2-seleno Ester, J. Comb. Chem. 2009,
938-942.
25. Ruwei Shen, Xian Huang*, Lingzhu Zhen, A Facile and Efficient Synthesis of
Dihydroisobenzofuran Derivatives via Tandem Pd-catalyzed Coupling, Propargyl-allenyl
Rearrangement, [4 + 2] Cycloaddition and Aromatization Reaction, Adv. Synth. Catal. 2008,
2865-2870.
26. Xian Huang*, Tiexin Zhang, Multicomponent reactions of pyridines, alpha-bromo
carbonyl compounds and silylaryl triflates as aryne precursors: a facile one-pot synthesis of
pyrido[2,1-a]isoindoles, Tedrahedron Lett. 2009, 208-211.
27. Tiexin Zhang, Xian Huang*, Jian Xue, Sha Sun, Ring expansion reaction of alpha-sulfonyl
cyclic ketones via insertion of arynes into C-C: a facile and mild access to medium- and
large-sized benzannulated carbocycles, Tedrahedron Lett. 2009, 1290-1294.
28. Bo Meng, Lei Yu, Xian Huang*, Difunctional Additions to1-Cyclopropylallenes: An
Efficient and Stereospecific Method for the Synthesis of 2,6- Difunctional-1,3-hexadienes,
Tedrahedron Lett. 2009, 1947-1950.
29. Chenliang Su, Qingyang Liu, Yong Ni, Xian Huang*, An Efficient Synthesis of
Polysubstituted Tetrahydrofuran and Indene Derivatives Via The Lewis Acid-Mediated
Cycloadditions of VCPs with Aldehydes, Tetrahedron Lett. 2009, 4381-4383.
30. Yewei Yang, Chenliang Su, Qingyang Liu, Xian Huang*, Halohydroxylation of
alkylidenecyclopropanes using N-halosuccinimide (NXS) as the halogen source: an
efficient synthesis of halocyclopropylmethanol and 3-halobut-3-en-1-ol derivatives,
Tedrahedron Lett. 2009, 5754-5756.
31.Feng Sha, Ying Lin, Xian Huang*, High Regio- and Stereoselective Synthesis of (Z)- or
(E)-N-Acryl Butenedioic Monoimide Derivatives by a Multicomponent Reaction,
Synthesis, 2009, 424-430.
32. Anjun Chen, Riyuan Lin, Qingjian Liu, Ning Jiao*, Fe-catalyzed Highly Selective Ring
Expansion
of
Alkynylcyclopropyl
Alkanols
to
Cyclobutanols. Chem.
Commun. 2009, 6842-6844.
33. Zhuangzhi Shi, Shengtao Ding, Yuxin Cui, Ning Jiao*, Pd-catalyzed Oxidative
Cycloaromatization of Biaryls with Alkynes
Using Dioxygen as Oxidant. Angew. Chem.
Int. Ed. 2009, 48, 7895-7898.
34. Shikai Xiang, Li-He Zhang, Ning Jiao*, Sp-sp3 C-C Bond Formation via
Fe(OTf)3/TfOH Cocatalyzed Coupling Reaction of Terminal Alkynes with Benzylic
Alcohols. Chem. Commun. 2009, 6487-6489.
35. Wang Zhou, Liangren Zhang, Ning Jiao*, Direct Transformation of Methyl Aromatics to
Aryl Nitriles at Room Temperature. Angew. Chem. Int. Ed. 2009, 48, 7094-7097.
36. Yijin Su, Ning Jiao*, Control of Chemo-, Regio-, and Stereoselectivities in Ligand-Free
Pd-Catalyzed Oxidative Heck Reactions of Arylboronic Acids or Alkenylboronate with
Allyl Esters. Org. Lett. 2009, 11, 2980-2983.
37. Zhuangzhi Shi, Chun Zhang, Si Li, Delin Pan, Sengtao Ding, Yuxin Cui, Ning Jiao*,
Indoles from Simple Anilines and Alkynes: Palladium-Catalyzed C-H Activation Using
Dioxygen as the Oxidant. Angew. Chem. Int. Ed. 2009, 48, 4572-4576.
38. Wang Zhou, Liangren Zhang, Ning Jiao*, The Tandem Reaction Combining Radical and
Ionic Processes: An Efficient Approach to Substituted 3,4-Dihydro- quinolin-2-ones.
Tetrahedron. 2009, 65, 1982-1987.
39. Si Li, Wei Jia, Ning Jiao*, Copper/Iron Cocatalyzed Highly Selective Tandem Reactions:
Efficient Approaches to Z-γ-Alkylidene Lactones. Adv. Synth. Catal. 2009, 351, 569-575.
40.
Zhenhong Wei, Hongxi Li, Meiling Cheng, Xiaoyan Tang, Yang Chen, Yong Zhang,
Jianping Lang*, Monomeric, Dimeric and Polymeric W/Cu/S Clusters based on
[Et4N][Tp*W(μ3-S)3(CuBr)3] and Various Nitrogen Donor Ligands, Inorg. Chem., 2009,
48, 2808-2817.
41.
Zhenhong Wei, Hongxi Li, Zhigang Ren, Jianping Lang*, Yong Zhang, Zhenrong Sun,
Stepwise Addition of CuNCS onto [Et4N][Tp*WS3]: Design, Syntheses, Structures and
Third-Order Nonlinear Optical Properties, Dalton Trans, 2009, 3425-3433.
42. Zhigang Ren, Junyi Yang, Yinling Song, Niya Li, Hongxi Li, Zhenhong Wei, Yang Chen,
Yong
Zhang,
Jianping
Lang*,
From
trans-[(η5-C5Me5)2Mo2S2(μ-S)4]
to
[(η5-C5Me5)2Mo2(μ3-S)4(CuMeCN)2]2+ to [(η5-C5Me5)2Mo2(μ3-S)4Cu2]-Based Polymeric
and Dimeric Clusters: Syntheses, Structures and Enhanced Third-Order Nonlinear
Optical Performances, Dalton Trans, 2009, 2578-2587.
43. Yang Chen, Ziou Wang, Zhigang Ren, Hongxi Li, Duanxiu Li, Dong Liu, Yong Zhang,
Jianping Lang*, Solvothermal Stepwise Formation of Cu/I/S-Based Semiconductors
from a Three-Dimensional Net to One-Dimensional Chains， Cryst. Growth & Des.,
2009, 9, 4963-4968.
44. Liqun Jin, Hua Zhang, Peng Li, Sowa, J. R., Aiwen Lei*, What is the Rate of the
Csp2-Csp2 Reductive Elimination Step? Revealing an Unusually Fast Ni-Catalyzed
Negishi-Type Oxidative Coupling Reaction J. Am. Chem. Soc. 2009, 131, 9892-9893.
45. Liqun Jin, Chao Liu, Jing Liu, Fang Hu, Yu Lan, Batsanov, A. S.; Howard, J. A. K.; Marder,
T. B.; Aiwen Lei*, Revelation of the Difference between Arylzinc Reagents Prepared from
Aryl Grignard and Aryllithium Reagents Respectively: Kinetic and Structural Features J.
Am. Chem. Soc. 2009, 131, 16656-16657
46. Qiang Liu, Yu Lan, Jing Liu, G.ang Li, Yudong Wu*, Aiwen Lei*, Revealing a Second
Transmetalation Step in the Negishi Coupling and Its Competition with Reductive
Elimination: Improvement in the Interpretation of the Mechanism of Biaryl Syntheses J.
Am. Chem. Soc. 2009, 131, 10201-10210.
47. Haibo Wang, Jing Liu, Yi Deng, Tianyin Min, Ganxiang Yu, Xiaojun Wu, Zhen Yang,
Aiwen Lei*, Pincer Thioamide and Pincer Thioimide Palladium Complexes Catalyze
Highly Efficient Negishi Coupling of Primary and Secondary Alkyl Zinc Reagents at Room
Temperature Chem. Eur. J. 2009, 15, 1499-1507
48. Heng Zhang, Xiancai Luo, Wongkhan, K., Hui Duan, Qiang Li, Lizheng Zhu, Jian Wang,
Batsanov, A. S., Howard, J. A. K., Marder, T. B.*, AiwenLei*, Acceleration of Reductive
Elimination of [Ar-Pd-Csp3] by a Phosphine/Electron-Deficient Olefin Ligand: A Kinetic
Investigation Chem. Eur. J. 2009, 15, 3823-3829.
49. Xuehua Zhu, Zhu Du, Fan Xu, Qi Shen*, Ytterbium Triflate: A Highly Active Catalyst for
Addition of Amines to Carbodiimides to N’,N’’ -Trisubstituted Guanidines J. Org. Chem.
2009, 74, 6347–6349.
50. Tao Cai , Xiaoniu Chen , Fan Xu , Yong Zhang , Yingming Yao , Qi Shen*, Synthesis and
molecular structures of lanthanocene amide complexes and their catalytic activity for
addition of amines to nitriles. J. Organomet. Chem. 2009, 694, 3167–3171.
51. Junfeng Wang, Junmei Li, Fan Xu, Qi Shen*, Anionic Bridged Bis(amidinate) Lithium
Lanthanide Complexes: Efficient Bimetallic Catalysts for Mild Amidation of Aldehydes
with Amines. Adv. Synth. Catal. 2009, 351, 1363 – 1370.
52. Junmei Li, Fan Xu, Yong Zhang, Qi Shen*, Heterobimetallic Lanthanide/Sodium
Phenoxides: Efficient Catalysts for Amidation of Aldehydes with Amines
J. Org. Chem. 2009, 74, 2575–2577.
53. Cunwei Qian, Xingmin Zhang, Junmei Li, Fan Xu, Yong Zhang, Qi Shen*,
Trisguanidinate Lanthanide Complexes: Syntheses, Structures, and Catalytic Activity for
Mild Amidation of Aldehydes with Amines. Organometallics 2009, 28, 3856–3862.
54．Bijie Li, Li Xu, Zhenhua Wu, Bingtao Guan, Changliang Sun, Biqin Wang, Zhangjie Shi*,
Cross-Coupling of Alkenyl/Aryl Carboxylates with Grignard Reagent via Fe-Catalyzed
C-O Bond Activation. J. Am. Chem. Soc. 2009, 131, 14656-14657.
55．Dagang Yu, Miao Yu, Bingtao Guan, Bijie Li, Yang Zheng, Zhenhua Wu, Zhangjie Shi*,
Carbon-Carbon Formation via Ni-Catalyzed Suzuki-Miyaura Coupling through C-CN
Bond Cleavage of Aryl Nitrile. Org. Lett. 2009, 11, 3374-3377.
56．Yizhou Li, Bijie Li, Xingyu Lu, Song Lin, Zhangjie Shi*, Cross Dehydrogenative
Arylation (CDA) of a Benzylic C-H Bond with Arenes by Iron Catalysis. Angew. Chem. Int.
Ed. 2009, 48, 3817-3820.
57. Haiying Deng, Jianrong He, Mei Pan*, Lei Li, Chengyong Su*, Synergistic metal and
anion
effects
on
the
formation
of
coordination
assemblies
from
a
N,N-bis(3-pyridylmethyl)naphthalene diimide ligand, CrystEngComm, 2009, 11, 909-917.
58. Yongru Liu, Lei Li, Tao Yang, Xingwen Yu, Chengyong Su*, Dehydration and rehydration
behavior
of
a
trinodal
topological
3-D
framework
of
Cd(II)
benzimidazole-5,6-dicarboxylate, CrystEngComm, 2009, 11, 2712–2718.
59. Yongru Liu, Lisi He, Jianyong Zhang*, Xiaobing Wang, Cheng-Yong Su*, Evolution of
Spherical Assemblies to Fibrous Networked Pd(II) Metallogels from a Pyridine-Based
Tripodal Ligand and Their Catalytic Property,
Chem. Mater. 2009, 21(3), 557–563.
60. Yongru Liu, Tao Yang, Lei Li, Junmin Liu, Chengyong Su*, Two-Dimensional Layered
Metal–Organic Frameworks of Lanthanum(III) Pyridine-2,6-dicarboxylate, Aust. J. Chem.
2009, 62, 1667–1674.
61. Shuang Luo, Bo Shen, Bin Li, Haibin Song, Shansheng Xu, Baiquan Wang*, Synthesis,
structures and polymerization catalytic properties of doubly bridged biscyclopentadienyl
dinuclear (μ-oxo) titanium complexes, Organometallics 2009, 28, 3109-3112.
62. Kun Xu, Bin Li, Shansheng Xu, Haibin Song, Baiquan Wang*, Reactions of
dihydrooctamethyl-s-
indacene
and
1,2,3,4,7-pentamethylindene
with
Ru3(CO)12:
Intramolecular sp3 CH activation, Organometallics 2009, 28, 4438-4442.
63. Shuang Luo, Xi Zhao, Bin Mu, Haibin Song, Shansheng Xu, Baiquan Wang*, Diels-Alder
reactions of benzyne with indenyl and fluorenyl ruthenium complexes, Organometallics
2009, 28, 4602-4605.
64. Congying Zhang, Yang Zhao, Bin Li, Haibin Song, Shansheng Xu, Baiquan Wang*, The
intramolecular sp2 and sp3 C-H bond activation of (p-cymene)ruthenium(II) N-heterocyclic
carbene complexes, Dalton Trans. 2009, 5182-5189.
65. Congying Zhang, Feng Luo, Bin Cheng, Bin Li, Haibin Song, Shansheng Xu, Baiquan
Wang*, Reactions of indenyl-functionalized imidazolium salts and N-heterocyclic
carbenes with Ru3(CO)12, Dalton Trans. 2009, 7230-7235.
66. Qing Xiao, Jian Ma, Yang Yang, Yan Zhang, Jianbo Wang*, Pd-Catalyzed C=C Double
Bond Formation by Coupling of N-Tosylhydrazones with Benzyl Halides. Org. Lett. 2009,
11, 4732-4735.
67. Changkun Li, Fanyang Mo, Weibin Li, Jianbo Wang*, AuPPh3Cl/AgOTf-Catalyzed
Reaction of Terminal Alkynes: Nucleophilic Addition to Activated C=O Bond.
Tetrahedron Lett. 2009, 50, 6053-6056.
68. Changkun Li, Yi Zeng, Jianbo Wang*, Au-catalyzed isomerization of cyclopropenes: a
novel approach to indene derivatives. Tetrahedron Lett. 2009, 50, 2956–2959.
69. Yan Zhang, Jianbo Wang*, Recent Development of Reactions with alpha-Diazocarbonyl
Compounds as Nucleophiles. Chem. Commun. 2009, 5350-5361.
70. Pinhua Li, Yicheng Zhang, Lei Wang*, Iron-Catalyzed Ligand-Free Three-Component
Coupling Reactions of Aldehydes, Terminal Alkynes, and Amines. Chem. Eur. J. 2009,
15, 2045–2049.
71. Yicheng Zhang, Pinhua Li, Min Wang, Lei Wang*, Indium-Catalyzed Highly Efficient
Three-Component Coupling of Aldehyde, Alkyne, and Amine via CH Bond Activation.
J. Org. Chem. 2009, 74(11), 4364–4367.
72. Min Wang, Kai Ren, Lei Wang*, Iron-Catalyzed Ligand-Free CSe (Te) Coupling of
Arylboronic Acids with Diselenides and Ditellurides. Adv. Synth. Catal. 2009, 351,
1586–1594.
73. Min Wang, Kai Ren, Lei Wang*, Lewis Acid InBr3-Catalyzed Arylation of Diorgano
Diselenides and Ditellurides with Arylboronic Acids. Org. Biomol. Chem. 2009, 7,
4858–4861.
74. Lei Wang*, Hongji Li, Pinhua Li, Task-specific Ionic Liquid as Base, Ligand and
Reaction Medium for the Palladium-catalyzed Heck Reaction. Tetrahedron 2009, 65(1),
364–368.
75. Jincan Yan, Lei Wang*, Asymmetric Aldol Reactions Catalyzed by Efficient and
Recyclable Silica-supported Proline-based Peptides. Chirality 2009, 15, 413–420.
76. Zuli Wang, Jincan Yan, Xiuli Zhang, Lei Wang*, Merrifield Resin Supported Ionic
Liquids/L-Proline as Efficient and Recyclable Catalyst Systems for Asymmetric Aldol
Reaction. Synthesis 2009, (22), 3744–3750.
77. Xiaofang Chen, Lei Wang*, Homo-coupling of Aryl Iodides and Bromides Catalyzed by
Immobilized Palladium with a Bidentate Nitrogen Ligand. Chin. J. Chem. 2009, 27,
2037–2042.
78. Xiaofang Chen, Lei Wang*, Jie Liu, Kumada Cross-Coupling of Aryl Grignard Reagents
with Aryl Halides Catalyzed by an Immobilized Nickel Catalyst. Synthesis 2009, (14),
2408–2412.
79. Xiancui Zhu, Jiaxi Fan, Yunjun Wu, Shaowu Wang*, Lijun Zhang, Gaosheng Yang, Yun
Wei, Chengwei Yin, Hong Zhu, Shihong Wu, Hongtao Zhang, Synthesis, Characterization,
Selective Catalytic Activity, and Reactivity of Rare Earth Metal Amides with Different
Metal-Nitrogen Bonds. Organometallics 2009, 28, 3882-3888.
80. Yunjun Wu, Shaowu Wang*, Lijun Zhang, Gaosheng Yang, Xiancui Zhu, Chao Liu,
Chengwei Yin, Jiewei Rong, Efficient guanylation of aromatic and teterocyclic amines
catalyzed by cyclopentadienyl-free rare earth metal amides. Inorg. Chim. Acta. 2009, 362,
2814-2819.
81. Yimin Hu*, Fengfa Song, Fenghua Wu, Dong Cheng, Shaowu Wang*, An Efficient
Construction of Tri- and Tetracyclic Heterocycles from Linear 1,6-Dienes by Domino
Reaction. Chem. Eur. J. 2008, 14, 3110-3117.
82. Zhiyuan Chen, Xiaodi Yang, Jie Wu*, AgOTf-Catalyzed tandem reaction of
N'-(2-alkynylbenzylidene)hydrazide with alkyne, Chem. Commun. 2009, 3469-3471.
83. Shengqing Ye, Ke Gao, Haibo Zhou, Xiaodi Yang, Jie Wu*, Synthesis of
1-methyleneindenes via palladium-catalyzed tandem reactions, Chem. Commun. 2009,
5406-5408.
84. Zhiyuan Chen, Qiuping Ding, Xingxin Yu, Jie Wu*, Silver triflate-catalyzed or
electrophile-mediated tandem reaction of N'-(2-alkynylbenzylidene)hydrazide with
dimethyl acetylene dicarboxylate, Adv. Synth. Catal. 2009, 351, 1692-1698.
85. Zhiyuan Chen, Xingxin Yu, Mingchao Su, Xiaodi Yang, Jie Wu*, Multicatalytic tandem
reactions of 2-alkynylbenzaldoximes with isocyanides, Adv. Synth. Catal. 2009, 351,
2702-2708.
86. Qiuping Ding, Zhiyong Wang, Jie Wu*, Tandem electrophilic cyclization-[3+2]
cycloaddition-rearrangement reactions of 2-alkynylbenzaldoxime, DMAD, and Br2, J. Org.
Chem. 2009, 74, 921-924.
87. Yong Luo, Jie Wu*, Palladium-catalyzed coupling reactions of aryl imidazolylsulfonates
with H-phosphonate diesters, Organometallics 2009, 28, 6823-6826.
88. Qiuping Ding, Xiaodan He, Jie Wu*, Synthesis of 2-aminobenzothiazole via
copper(I)-catalyzed tandem reaction of 2-iodobenzenamine with isothiocyanate, J. Comb.
Chem. 2009, 11, 587-591.
89. Xingxin Yu, Jie Wu*, Synthesis of functionalized isoquinolines via sequential
cyclization/cross- coupling reactions, J. Comb. Chem. 2009, 11, 895-899.
90. Qiuping Ding, Xi-Gen Huang, Jie Wu*, Facile synthesis of benzothiazoles via cascade
reactions of 2-iodoanilines, acid chlorides and Lawesson’s reagent, J. Comb. Chem. 2009,
11, 1047-1049.
91. Zhiyong Wang, Qiuping Ding, Xiaodan He, Jie Wu*, Palladium-catalyzed decarboxylative
cross-coupling reaction of acrylic acid with aryl iodide, Org. Biomol. Chem. 2009, 7,
863-865.
92. Xingxin
Yu,
Xiaodi
Yang,
Jie
Wu*,
Multicatalytic
tandem
reaction
of
N'-(2-alkynylbenzylidene)hydrazide with indole, Org. Biomol. Chem. 2009, 7, 4526-4530.
93. Zhiyuan Chen, Mingchao Su, Xingxin Yu, Jie Wu*, Synthesis of functionalized
H-pyrazolo[5,1-a]isoquinolines
via
sequential
reactions
of
N'-(2-alkynylbenzylidene)hydrazides, Org. Biomol. Chem. 2009, 7, 4641-4646.
94. Qiuping Ding, Zhiyong Wang, Jie Wu*, Tandem cyclization-[3+3] cycloaddition reactions
of 2-alkynylbenzaldoxime: synthesis of fused 1,2-dihydroisoquinolines, Tetrahedron Lett.
2009, 50, 198-200.
95. Qiuping Ding, Zhiyuan Chen, Yiyuan Peng, Jie Wu*, Highly efficient electrophilic
cyclization of N'-(2-alkynylbenzylidene)hydrazides, Tetrahedron Lett. 2009, 50, 340-342.
96. Yong Luo, Jie Wu*, Palladium-catalyzed direct arylation of 4-hydroxycoumarins with
arylboronic acids via C-OH bond activation, Tetrahedron Lett. 2009, 50, 2103-2105.
97. Xingxin Yu, Qiuping Ding, Zhiyuan Chen, Jie Wu*, Lewis acid-catalyzed reactions of
N'-(2-alkynylbenzylidene)hydrazides with diethyl phosphite, Tetrahedron Lett. 2009, 50,
4279-4282.
98. Haibo Zhou, Hanpeng Jin, Shengqing Ye, Xiaodan He, Jie Wu*, Multicatalytic synthesis
of 1,2-dihydroisoquinolin-1-ylphosphonates via a tandem four-component reaction,
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99. Shengqing Ye, Jie Wu*, Silver triflate and triphenylphosphine co-catalyzed reactions of
2-alkynylbenzaldehyde, amine, and but-3-en-2-one, Tetrahedron Lett. 2009, 50, 6273-6275.
100. Shengqing
Ye,
Haibo
Zhou,
Jie
Wu*,
three-component
Synthesis
reactions
of
1,2-dihydroisoquinolin-1-ylphosphonates
via
of
2-(2-formylphenyl)ethanone, amine, and
diethyl phosphite, Tetrahedron 2009, 65,
1294-1299.
101. Zhiyong Wang, Qiuping Ding, Xiaodan He, Jie Wu*, Pd-catalyzed decarboxylative
couplings of arenecarboxylic acids with aryl iodides, Tetrahedron 2009, 65, 4635-4638.
102. Yong Luo, Jie Wu*, Copper-free Sonogashira reactions of 4-hydroxycoumarins with
alkynes, Tetrahedron 2009, 65, 6810-6814.
103. Lantao Liu, Wenxiong Zhang, Chao Wang, Congyang Wang, Zhenfeng Xi*, Isolation,
Structural Characterization and Synthetic Application of Oxy-cyclopentadienyl Dianions.
Angew. Chem. Int. Ed. 2009, 48, 8111-8114.
104. Shaoguang Zhang, Xiaohua Sun, Wenxiong Zhang, Zhenfeng Xi*, One-pot
Multi-Component Synthesis of Azaindoles and Pyrroles from One Molecule of Si-Tethered
Diyne and Three or Two Molecules of Organonitriles Mediated by Zirconocence. Chem.
Eur. J. 2009, 15, 1260812617.
105. Fei Zhao, Chao Wang, Lantao Liu, Wenxiong Zhang, Zhenfeng Xi*, Skeletal
rearrangement of all-carbon spiro skeletons mediated by Lewis acid. Chem. Commun. 2009,
6569-6571.
106. Chao Wang, Liang Deng, Jun Yan, Hailin Wang, Qian Luo, Zhenfeng Xi*,
Zirconocene-Mediated Ligand-Switched Selective Cleavage of Active and Inert
Carbon-Carbon Bonds in Allylcyclopropanes Chem. Commun. 2009, 4414-4416.
107. Qifeng Wang, Lantao Liu, Chen Lin, Hui Sun, Wenxiong Zhang, Zhenfeng Xi*,
Hydride-Induced Cleavage of C-O Bond in Pyran Ring of 2-Pyranylidene Carbene
Complexes Followed by Ring Closure of Unsaturated Acylmetalates and Reductive
Elimination: Mechanism and Synthetic Application. Dalton Trans. 2009, 10433-10435.
108. Qian Luo, Li Gu, Chao Wang, Junhui Liu, Wenxiong Zhang, Zhenfeng Xi*, Synthesis of
functionalized siloles from Si-tethered diynes. Tetrahedron Lett. 2009, 50, 3213-3215.
109. Ning Luo, Zhengkun Yu*, Multiple Reactivities of Dithranol Towards 1-Alkynyl Fischer
Carbene Complexes (CO)5M=C(OEt)CCPh (M = Cr, W)-Efficient Chemical Synthesis of
Aromatic Polyketides. J. Organomet. Chem. 2009, 694, 3058-3067.
110. Haifeng Yu, Zhengkun Yu*, Direct Alkenylation of Indoles through Acid-mediated
Substitution Reactions with alpha-Oxo Ketene Dithioacetals: Efficient Synthesis of Indole
Alkaloids Meridianin Derivatives. Angew. Chem. Int. Ed. 2009, 48, 2929-2933.
111. Yu Li, Zhengkun Yu*, Palladium-Catalyzed Carbonylative Cycloisomerization of
gamma-Propynyl-1,3-diketones: A Concise Route to Polysubstituted Furans. J. Org. Chem.
2009, 74, 8904-8907.
112. Fanlong Zeng, Zhengkun Yu*, Construction of Highly Active Ruthenium(II) NNN
Complex Catalysts Bearing a Pyridyl-Supported Pyrazolyl-Imidazolyl Ligand for Transfer
Hydrogenation of Ketones. Organometallics 2009, 28, 1855-1862.
113. Feng Liu, Yihua Yu, Junliang Zhang*, Highly Substituted Furo[3,4-d][1,2]oxazines:
Gold-Catalyzed Regiospecific and Diastereoselective 1,3-Dipolar Cycloaddition of
2-(1-Alkynyl)-2- alken-1-ones with Nitrones. Angew. Chem. Int. Ed. 2009, 48, 5505 –5508.
114. Lu
liu,
Junliang
Zhang*,
Selectivity
Control
in
Lewis
Acid
Catalyzed
Regiodivergent Tandem Cationic Cyclization/Ring Expansion Terminated by Pinacol
Rearrangement. Angew. Chem. Int. Ed. 2009, 48, 6093–6096.
115. Hongyin Gao, Junliang Zhang*, A Dramatic Substituent Effect in
Silver(I)-Catalyzed
Regioselective Cyclization of ortho-Alkynylaryl Aldehyde Oxime Derivatives. Adv. Synth.
Catal. 2009, 351, 85-88
116. Yuanjing Xiao, Junliang Zhang*, Palladium(II)-Catalyzed Domino Reaction of
2-(1-Alkynyl)-2-alken-1-ones with Nucleophiles: Scope, Mechanism and Synthetic
Application in the Synthesis of 3,4-Fused Bicyclic Tetrasubstituted Furans. Adv. Synth.
Catal. 2009, 351, 617-629.
117. Yanqing Zhang, Zuliang Chen, Yuanjing Xiao, Junliang Zhang*, RhI-Catalyzed Regioand Stereospecific Carbonylation of 1-(1-Alkynyl) cyclopropyl Ketones: A Modular Entry
to Highly Substituted 5,6-Dihydrocyclopenta[c]furan-4-ones. Chem. Eur. J. 2009, 15,
5208-5211.
118. Renrong
Liu,
Junliang
Zhang*,
Tetrasubstituted
Furans
by
PdII-Catalyzed
Three-Component Domino Reactions of 2-(1-Alkynyl)-2-alken-1-ones with Nucleophiles
and Vinyl Ketones or Acrolein. Chem. Eur. J. 2009, 15, 9303-9306.
119. Yuanjing Xiao, Junliang Zhang*, Furans versus 4H-pyrans: catalyst-controlled
regiodivergent
tandem
Michael
addition–cyclization
reaction
of
2-(1-alkynyl)-2-alken-1-ones with 1,3- dicarbonyl compounds. Chem. Commun. 2009,
3594-3596.
120. Zuliang
Chen,
Junliang
Zhang*,
Highly
Functionalized
4-Alkylidenebicyclo
[3.1.0]hex-2-enes by Tandem Michael Addition and Annulation of Electron-Deficient
Enynes. Chem. Asian J. 2009, 4, 1527-1529.
121. Wenbo Li, Yuanjing Xiao, Junliang Zhang*, Alkynyl Group as Activating Group:
Base-Catalyzed Diastereo- selective Domino Reactions of Electron-Deficient Enynes. Adv.
Synth. Catal. 2009, 351, 3083-3088.
122. Yan Sun, Zhengxing Zhang, Xu Wang, Xiaoqing Li, Linhong Weng, Xigeng Zhou*,
Isocyanate diinsertion into the N–H bond of 2-pyridylamino ligand of organolanthanides,
Dalton Trans. 2009, 39, 221-226.
123. Yan Sun, Zhengxing Zhang, Xu Wang, Xiaoqing Li, Linhong Weng, Xigeng Zhou*,
Lanthanide-induced Diinsertion of Isocyanates into the N–H Bond: Synthesis, Structure
and Reactivity of Organolanthanides Containing Diureido Ligands, Organometallics, 2009,
28, 6320-6330.
124. Jialiang Wang, Lixin Zhang, Yufeng Jing, Wen Huang, Xigeng Zhou*, Efficient
synthesis of indenes by FeCl3·6H2O-catalyzed intramolecular Friedel-Crafts reaction of
aryl-substituted allylic alcohols, Tetrahedron Lett. 2009, 50, 4978-4982.
125. Wen Huang, Longcheng Hong, Pengzhi Zheng, Ruiting Liu, Xigeng Zhou*, Highly
efficient synthesis of functionalized dihydronaphthalenes, tetrahydronaphthalenes and
tetrahydroisoquinolines by iron-catalyzed intramolecular Friedel-Crafts reaction of
aryl-containing propargylic alcohols, Tetrahedron, 2009, 65, 3603-3610.
126. Jialiang Wang, Wen Huang, Zhengxing Zhang, Xu Xiang, Ruiting Liu, Xigeng Zhou*,
FeCl3·6H2O-Catalyzed Disproportionation of Allylic Alcohols and Selective Allylic
Reduction of Allylic Alcohols and Their Derivatives with Benzyl Alcohol, J. Org. Chem.,
2009, 74, 3299-3304.
127. Qingan Chen, Wei Zeng, Yonggui Zhou*, AgOAc-catalyzed asymmetric amination of
glycine Schiff bases with azodicarboxylates. Tetrahedron Lett. 2009, 50, 6866-6868.
128. Dawei Wang, Xiaobing Wang, Shengmei Lu, Changbin Yu, Yonggui Zhou*, Highly
Enantioselective
Iridium-Catalyzed
Hydrogenation
of
2-Benzylquinolines,
2-Functionalized and 2,3-Disubstituted Quinolines. J. Org. Chem. 2009, 74, 2780-2787.
129. Dawei Wang, Shengmei Lu, Yonggui Zhou*, A Simple and Highly Efficient Method for
Hydrogenation of Arenes by [Rh(COD)Cl]2. Tetrahedron Lett. 2009, 50, 1282-1285.
130. Ling Fang, Aijun Lin, Hongwen Hu, Chengjian Zhu* ， Highly Enantioselective
Sulfenylation of -Ketoesters: H-Bond Acceptor Catalysis, Chem. Eur. J. 2009, 15,
7039-7043.
131. Jiangtao Sun, Minghua Yang, Fang Yuan, Xuefeng Jia, Xia Yang, Yi Pan, Chengjian
Zhu*，Catalytic Asymmetric Ring-Opening Reaction of meso- Epoxides with Aryl
Selenols and Thiols Catalyzed by a Heterobimetallic Gallium- Titanium-Salen Complex,
Adv. Synth. Catal. 2009, 351, 920-930.
132. Hongwei Yang, Ling Fang, Ming Zhang, Chengjian Zhu*, An Efficient Molybdenum
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133. Xuefeng Jia, Ling Fang, Aijun Lin, Yi Pan, Chengjian Zhu*, Highly Efficient and Facile
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134. Jiangtao Sun, Fang Yuan, Minghua Yang, Yi Pan, Chengjian Zhu*, Enantioselective
Ring-Opening Reaction of meso-Epoxides with ArSH Catalyzed by Heterobimetallic
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135. Ling Fang, Aijun Lin, Xuefeng Jia, Jie Meng, Yangnian Wang, Chengjian Zhu*,
Diarylprolinols, Lett. Org. Chem. 2009, 6, 397-399.
136. Jiangtao Sun, Weijin Gu, Yijun Huang, Xu Pan, Chengjian Zhu*, Salan-Vanadium
Catalyzed Enantioselective Desymmetrization of meso-Epoxides with Aromatic Thiols,
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固定人员代表论文复印件
目录（按通讯作者姓氏首字母排序）
1. Zhaobin
Han,
Zheng
Wang,
Xumu
Zhang,
Kuiling
Ding*,
Spiro[4,4]-1,6-nonadiene-Based Phosphine-Oxazoline Ligands for Iridium-Catalyzed
Enantioselective Hydrogenation of Ketimines. Angew. Chem. Int. Ed. 2009, 48,
5345-5349.
2. Zheng Wang, Gang Chen, Kuiling Ding*, Self-Supported Catalysts. Chem. Rev.
2009, 109, 322-359.
3. Hai Lin Liu, XueLong Hou*, Lin Pu*, Enantioselective Precipitation and
Fluorescent Enhancement in the Recognition of -Hydroxycarboxylic acids ，
Angew. Chem. Int. Ed. 2009, 48, 382-385.
4. Wei Liu, Di Chen, XiaZhen Zhu, XiaoLong Wan, XueLong Hou*, Highly Diastereoand Enantioselective Pd-Catalyzed Cyclopropanation of Acyclic Amides with
Substituted Allyl Carbonates , J. Am. Chem. Soc. 2009, 131, 8734-8735.
5. BaiLin Lei, ChangHua Ding, XiaoFei Yang, XiaoLong Wan, XueLong Hou*, Highly
Efficient
Kinetic
Resolution
of
2-Substituted-2,3-Dihydro-4-Quinolones
by
Palladium-Catalyzed Asymmetric Allylic Alkylation, J. Am. Chem. Soc. 2009, 131,
18250-18251.
6. Tao Wu, Guoyin Yin, Guosheng Liu*, Palladium-Catalyzed Intramolecular
Aminofluorination of Alkenes, J. Am. Chem. Soc. 2009, 131, 16354-16355.
7. Xiaoping Fu, Jingjin Chen, Guangyu Li, Yuanhong Liu*, Diverse Reactivity of
Zirconacyclocumulenes Derived from Coupling of Benzynezirconocenes with
1,3-Butadiynes towards Acyl Cyanides: Synthesis of Indeno[2,1-b]pyrroles or
[3]Cumulenones. Angew. Chem. Int. Ed. 2009, 48, 5500 –5504.
8. Wei Shu, Guochen Jia, Shengming Ma*, Palladium-Catalyzed Three-Component
Cascade Cyclization Reaction of Bisallenes with Propargylic Carbonates and
Organoboronic Acids: Efficient Construction of cis-Fused Bicyclo [4.3.0] nonenes,
Angew. Chem. Int. Ed. 2009, 48, 2788-2791.
9. Tao Bai, Shengming Ma*, Guochen Jia*, Insertion Reactions of Allenes with
Transition Metal Complexes, Coord. Chem. Rev. 2009, 253, 423-448.
10. Xiao-Hong Yang, Chun-Rong Liu, Cong Wang, Xiu-Li Sun, Yang-Hui Guo, Xin-Ke
Wang, Zheng Wang, Zuowei Xie, Yong Tang*, [O-NSR]TiCl3-Catalyzed
Copolymerization of Ethylene with Functionalized Olefins, Angew. Chem. Int. Ed.
2009, 48, 8099–8102.
11. Sunewang R. Wang, Chun-Yin Zhu, Xiu-Li Sun, Yong Tang*, Reaction of Allylic
Phosphoranes with Iron Porphyrin Carbenoids: Efficient, Selective, and Catalytic
Intermolecular Formal Carbenoid Insertion into Olefinic C-H Bonds, J. Am. Chem.
Soc. 2009, 131, 4192-4193.
12. Shuli You*, Quan Cai, Mi Zeng, Chiral Brønsted Acids Catalyzed Friedel-Crafts
Alkylation Reaction, Chem. Soc. Rev. 2009, 38, 2190-2201.
13. Hu He, Wenbo Liu, Lixin Dai, Shuli You*, Ir-Catalyzed Cross-Coupling of Styrene
Derivatives with Allylic Carbonates: Free Amine Assisted Vinyl C-H Bond Activation,
J. Am. Chem. Soc. 2009, 131, 8346-8347.
14. Quan Cai, Zhuoan Zhao, Shuli You*, Asymmetric Construction of Polycyclic Indoles
through Olefin Cross-Metathesis/Intramolecular Friedel-Crafts Alkylation under
Sequential Catalysis, Angew. Chem. Int. Ed. 2009, 48, 7428-7431.