Sample Stage 6 Chemistry Program 8.3 METALS 30 Indicative Hours The following sample stage 6 preliminary Biology program for the module, Metals was written by Trish Stockbridge from Kincoppal, Gaye Deck from Ravenswood and peter Newcombe an independent consultant. This module is an example of how the knowledge and understanding, Prescribed Focus Area and skills content for the unit can be taught in an integrated manner. Whereas all care has been taken in constructing the program for this module, teachers using this program must take responsibility for ensuring that the outcomes addressed in this module together with the outcomes addressed in the other modules for the preliminary course fulfill the Chemistry preliminary course requirements. We sincerely thank the writers for their time and commitment in writing this program and for sharing with teachers their expertise in Chemistry and pedagogy for teaching stage 6 students. Contextual Outline: The cultural development of humans has been closely connected with their discovery of materials and invention of tools to the point where major advances in cultural achievement have been described in terms of the materials they learned to use. This has included their use of metals and discoveries of increasingly sophisticated methods of extraction of metals from their ores. Because metals make up the majority of elements, an examination of the physical and chemical properties of metals is also an appropriate context in which to consider the organisation of the common Periodic Table. The development of a Periodic Table represented a breakthrough in the systematic organisation and study of chemistry and enabled scientists to predict the discovery of further elements. This module increases students’ understanding of the history, applications and use of chemistry and current issues, research and developments in chemistry. Contextual Focus Activity: Teacher introduces the task which is due for completion by the end of this module. Each student will be responsible for writing up their own practical report and research. The task will integrate the contextual framework of the module and assist students to make meaning of the Prescribed Focus Areas – the application and use of chemistry and the history of chemistry. “You are a geochemist working for a major mining company and have just discovered a large deposit of a metal bearing ore in an isolated area of Australia. Your task is to research each of the following aspects related to this metal: - Methods which have been used throughout history to extract a variety of metals from their ores. You should also consider possible environmental aspects to all extraction processes. - Relate various methods of extraction to the relative reactivity of metals. - Describe how the reactivity of metals is also related to their use and their location in the Periodic Table - Quantitatively describe the mass changes in samples of metals when they undergo reactions Module Overview: 8.5.1 Metals have been extracted and used for many thousands of years 8.5.2 Metals differ in their reactivity with other chemicals and this influences their uses P1 Outlines the historical development of major principles, concepts and ideas in chemistry P3 Assesses the impact of particular technological advances on understanding in chemistry 8.5.5 The relative abundance and ease of extraction of metals influences their value and breadth of use in the community 8.5.3 As metals and other elements were discovered scientists recognised that patterns in their physical and chemical properties could be used to organise the elements into a Periodic Table 8.5.4 For efficient resource use industrial chemical reactions must use measured amounts of each reactant Target Outcomes: A student: P1 P3 P6 P10 P12 P14 outlines the historical development of major principles, concepts and ideas in chemistry assesses the impact of particular technological advances on understanding in chemistry explains trends and relationships between elements in terms of atomic structure and bonding applies simple stoichiometric relationships discusses validity and reliability of data gathered from first-hand investigations and secondary sources draws valid conclusions from gathered data and information P16 demonstrates positive values about and attitude towards both the living and non-living components of the environment, ethical behaviour and a desire for critical evaluation of the consequences of the applications of science Resources: Conquering Chemistry – Preliminary Course – R. Smith (2002) Spotlight Chemistry – Preliminary – R. Alliband et al (2004) Chemistry 1 – Preliminary Course – G. Thickett (2007) Pathways to Chemistry – G. Thickett (1996) Deretic, G – FOSChem Practical Manual (1982) 8.3.1. Metals have been extracted and used for many thousands of years Module Content (column 2 and 3) Reg 8.1 Skills Content Suggested Teaching and Learning Strategies Introductory Activity: Class discussion about the properties of metals; differences between metals, minerals, alloys and ores and how some metals are found in nature and possibly extracted from their ores. Also consider how chemists classify metals and nonmetals, using the Periodic Table as a basis. Review some reactions of metals – eg: metals + acids; metals corroding and the uses of metals in society today. (Smith p107) Contextual Focus Activity: Teacher introduces the task which is due for completion by the end of this module. Each student will be responsible for writing up their own practical reports and research. The task will integrate the contextual framework of the module and assist students to make meaning of the Prescribed Focus Areas – the application and use of chemistry and the history of chemistry. “You are a geochemist working for a major mining company and have just discovered a large deposit of a metal bearing ore in an isolated area of Australia. Your task is to research each of the following aspects related to this metal: - Methods which have been used throughout history to extract a variety of metals from their ores. You should also consider possible environmental aspects to all extraction processes. - Relate various methods of extraction to the relative reactivity of metals. - Describe how the reactivity of metals is also related to their use and their location in the Periodic Table - Quantitatively describe the mass changes in samples of metals when they undergo reactions A suitable assessment task is given at the end of this module Module Content (column 2 and 3) Students learn to: - outline and examine some uses of different metals through history, including contemporary uses, as uncombined metals or as alloys - analyse information to relate the chronology of the Bronze Age, the Iron Age and the modern era and possible future developments - identify why there are more metals available for people to use now than there were 200 years ago - gather, process, analyse and present information from secondary sources on the range of alloys produced and the reasons for the production and use of these alloys - describe the use of common alloys including steel, brass and solder and explain how these relate to their properties Reg 8.1 Skills Content Students: P12.3 gather information from secondary sources by: a) accessing information from a range of resources including popular scientific journals, digital technologies and the Internet b) practising efficient data collection techniques to identify useful information in secondary sources d) summarising and collating information from a range of resources P11.1 identify data sources to: e) recommend the use of an appropriate technology or strategy for data collection or gathering information that will assist efficient future analysis P 14.1 analyse information to: a) identify trends, patterns and relationships as well as contradictions in data and information. Suggested Teaching and Learning Strategies . Students develop a class timeline for the discovery of metals throughout history. Individual students research one or two metals and combine their results. The timeline could combine dates with the methods used to extract the metal. In addition, students could also research types and uses of various alloys and tabulate their findings on alloys such as steel, brass and solder Data analysis and accessing information - Thickett, p124 – 125 8.3.2 Metals differ in their reactivity with other chemicals and this influences their uses Module Content (column 2 and 3) describe observable changes when metals react with dilute acid, water and oxygen describe and justify the criteria used to place metals into an order of activity based on their ease of reaction with oxygen, water and dilute acids perform a first-hand investigation incorporating information from secondary sources to determine the metal activity series construct word and balanced formulae equations for the reaction of metals with water, oxygen, dilute acid outline examples of the selection of metals for different purposes based on their reactivity, with a particular emphasis on current developments in the use of metals identify the reaction of metals with acids as requiring the transfer of electrons construct half-equations to represent the electron transfer reactions occurring when metals react with dilute hydrochloric and dilute sulfuric acids outline the relationship between the relative activities of metals and their positions on the Periodic Table identify the importance of first ionisation energy in determining the relative reactivity of metals Reg 8.1 Skills Content Suggested Teaching and Learning Strategies 11.2 plan first-hand investigations to: a) demonstrate the use of the terms ‘dependent’ and ‘independent’ to describe variables involved in the investigation b) identify variables that need to be kept constant, develop strategies to ensure that these variables are kept constant, and demonstrate the use of a control c) design investigations that allow valid and reliable data and information to be collected Practical investigation: - To develop a metal activity series using the reactions of metals with dilute acid, water and oxygen. Students: - plan the investigation selecting the appropriate equipment and reagents, including a range of common metals and dilute HCl, water and oxidation in air - carry out a risk assessment and identify hazards - identify variables - carry out the planned procedure and record results - carry out repeat trials - justify inferences and conclusions - construct word and balanced formula and word equations for the reactions observed 14.1 analyse information to: b) justify inferences and conclusions 14.1 analyse information to: f) use models, including mathematical ones, to explain phenomena and/or make predictions Discuss the relationship between uses of metals and their reactivity. In small groups, students present a model to represent the changes occurring when a metal is involved in an electron transfer reaction. Students may then construct half equations to represent electron-transfer reactions. 8.3.3 As metals and other elements were discovered, scientists recognized that patterns in their physical and chemical properties could be used to organized the elements into a Periodic Table Module Content (column 2 and 3) identify an appropriate model that has been developed to describe atomic structure outline the history of the development of the Periodic Table including its origins, the original data used to construct it and the predictions made after its construction process information from secondary sources to develop a Periodic Table by recognising patterns and trends in the properties of elements and use available evidence to predict the characteristics of unknown elements both in groups and across periods explain the relationship between the position of elements in the Periodic Table, and: - electrical conductivity - ionisation energy - atomic radius - melting point - boiling point - combining power (valency) - electronegativity - reactivity Reg 8.1 Skills Content 14.1 analyse information to: h) identify examples of the interconnectedness of ideas or scientific principles 14.1 analyse information to: f) use models, including mathematical ones, to explain phenomena and/or make predictions Suggested Teaching and Learning Strategies Students use a concept map to recall relationships between elements using the Periodic Table. This will include atomic structure, structure of elements in terms of protons, neutrons and electrons and electron shells. Students research: 1) Various models of atomic structure, including those of Dalton, Thomson, Rutherford and Bohr. Emphasis should be on the scientific process to explain how theories and models are modified in the light of new observations and phenomena. 2) The history of development of the Periodic Table, considering the work of Dobereiner, Newlands, Moseley and Mendeleev 12.4 process information to: c) best illustrate trends and patterns by selecting and using appropriate models including computer-assisted analysis Students process information to construct a Periodic Table. 12.3 gather information from secondary sources by: c) extracting information from numerical data in graphs and tables as well as from written and spoken material in all its forms Students conduct a group activity in which each group is to choose one physical property, as listed in the syllabus, and research that property for one period or one group of the Periodic Table. Use a computer to summarise this information. Findings are to be presented to the class, with discussion to explain the relationships between the position of the element in the Periodic Table and the property. Module Content (column 2 and 3) Reg 8.1 Skills Content Suggested Teaching and Learning Strategies use computer-based technologies to produce a table and a graph of changes in one physical property across a period and down a group 8.3.4 For efficient resource use, industrial chemical reactions must use measured amounts of each reactant: Module Content (column 2 and 3) define the mole as the number of atoms in exactly 12g of carbon-12 (Avogadro’s number) Reg 8.1 Skills Content 12.4 process information to: b) identify an appropriate mathematical formulae and concepts Suggested Teaching and Learning Strategies Students examine examples of a mole of different types of substances, both elements and compounds. Students carry out a procedure to estimate Avogadro’s Number 13.1 present information by: d) using symbols and formulae to express relationships and using appropriate units for physical quantities Using a teacher generated worksheet or similar, students practice writing word and balanced chemical equations for a variety of reactions compare mass changes in samples of metals when they combine with oxygen f) selecting and drawing appropriate graphs to convey information and relationships clearly and accurately Students analyse teacher provided data in a table and construct a line graph on the mass of a metal produced from reacting various masses of a metal with a fixed mass of non-metal. Teacher initiates discussion on the graph and students are asked to consider why the amount of produce reaches a constant level regardless of the amount of metal used. Discussion leads to the conclusion that in chemical reactions, a chemical engineer or geochemist needs to know the correct mass ratios of reactants to give the highest yield of product without wasting any reactant. perform a first-hand investigation to measure and identify the mass ratios of metal to non-metal(s) in a common compound and calculate its empirical formula 11.2 plan first-hand investigations to: d) design and trial procedures to undertake investigations and explain why a procedure, a sequence of procedures or repetition of procedures is appropriate Students to carry out practical on combustion of magnesium to calculate the empirical formula of magnesium oxide. - process information from secondary sources to interpret balanced chemical equations in terms of mole ratios Module Content (column 2 and 3) distinguish between empirical formulae and molecular formulae Reg 8.1 Skills Content Suggested Teaching and Learning Strategies 12.4 process information to: b) identify an appropriate mathematical formulae and concepts Students perform exercises in calculation of empirical and molecular formulae 14.1 analyse information to: c) identify and explain how data supports or refutes an hypothesis, a prediction or a proposed solution to a problem Students research the work of Gay-Lussac and Avogadro and describe how their work led to the determination of molecular formulae and the mole concept describe the contribution of Gay-Lussac to the understanding of gaseous reactions and apply this to an understanding of the mole concept process information from secondary sources to investigate the relationship between the volumes of gases involved in reactions involving a metal and relate this to an understanding of the mole recount Avogadro’s law and describe its importance in developing the mole concept solve problems and analyse information from secondary sources to perform calculations involving Avogadro’s Number and the equation for calculating the number of moles of a substance: n=m M 14.3 use available evidence to : c) apply critical thinking in the consideration of predictions, hypotheses and the results of investigations 12.4 process information to: b) identify an appropriate mathematical formulae and concepts Students perform exercises in calculations involving Avogadros’ Number and its application to reacting amounts in chemical equations 8.3.5 The relative abundance and ease of extraction of metals influences their value and breadth of use in the community: Module Content (column 2 and 3) define the terms mineral and ore with reference to economic and non-economic deposits of natural resources describe the relationship between the commercial prices of common metals, their actual abundances and relative costs of production discuss the importance of predicting yield in the identification, mining and extraction of commercial ore deposits explain why ores are nonrenewable resources describe the separation processes, chemical reactions and energy considerations involved in the extraction of copper from one of its ores Reg 8.1 Skills Content 12.3 gather information from secondary sources by: a) accessing information from a range of resources including popular scientific journals, digital technologies and the Internet b) practising efficient data collection techniques to identify useful information in secondary sources c) extracting information from numerical data in graphs and tables as well as from written and spoken material in all its forms d) summarising and collating information from a range of resources 14.1 analyse information to: c) identify and explain how data supports or refutes an hypothesis, a prediction or a proposed solution to a problem e) make and justify generalisations 13.1 present information by: e) using a variety of pictorial representation to show relationships and presenting information clearly and succinctly Suggested Teaching and Learning Strategies Students to research the terms mineral and ore and suggest reasons for the location of major mining areas in Australia eg: Broken Hill and areas of Western Australia Students to analyse information on: - commercial prices of metals - abundance of metals in the Earth’s crust - relative costs of production, using tables and graphs Spotlight p66 Revise renewable and non-renewable resource Students to complete exercises on extraction of copper from its ore to: - draw a flowchart of processes involved - distinguish between physical and chemical processes - write equations for the chemical processes - discuss economic issues involved Thickett p 186; CC p 111 Module Content (column 2 and 3) justify the increased recycling of metals in our society and across the world recount the steps taken to recycle aluminium analyse information to compare the cost and energy expenditure involved in the extraction of aluminium from its ore and the recycling of aluminium Reg 8.1 Skills Content 14.1 analyse information to: b) justify inferences and conclusions 12.3 gather information from secondary sources by: c) extracting information from numerical data in graphs and tables as well as from written and spoken material in all its forms Suggested Teaching and Learning Strategies Discuss the need to recycle metals after considering tables showing relative abundances of metals Spotlight p 75 Data analysis on recycling aluminum and steel Thickett p 196 Suggested Summative Assessment Task: A written report with oral presentation (PowerPoint; multimedia; OHP) considering each of the aspects given in the Contextual Focus Activity, for the extraction of a metal from its ore. Students may either be given a specific metal/ore or may choose one themselves, with teacher guidance.