Finland EST_HOR (Estimated horizon database): PROF_NUM: The profile numbers are altered (see EST_PROF). HOR_NUM: ok HOR_NAME: ok. A few of the horizon names have been altered slightly so that the designation of horizons and suffixes generally follow the FAO nomenclature (marked yellow in spreadsheet). The horizons have no suffixes! Some of the horizons contain too much organic matter to be classified as Ap. DEPTHSTART: ok DEPTHEND: ok AR_NA: Most values “-4” (meaning less than 4 (humid areas) a few “-999” (meaning no value) BD (bulk density): Origin of data: Expert judgment The chart below shows the relation between bulk density and organic matter. Theoretically the bulk density should decrease with increasing amount of organic matter. 1 Finland bulk density (g/cm3) 1,60 1,40 1,20 1,00 0,80 0,60 0,40 0,20 0,00 0,0 20,0 40,0 60,0 80,0 100,0 % organic matter All of the horizons have data for bulk density. Some of the horizons rich in organic matter have rather high bulk densities. Profile FI2 – horizon 1 (Ap) with a bulk density 1,1 g/cm3 and a content of 70% organic matter. Profile FI3 – horizon 1 (Ap) with a bulk density 1,0 g/cm3 and a content of 98% organic matter. These are marked “yellow” in the spreadsheet. Conclusion: Most of the data for bulk density seem reliable, except for the two organic rich horizons. Profie FI2 is a Cambisol (Bv) and profile FI3 a Gleysol (Gd). Perhaps the contents of organic matter are a factor 10 wrong. So that the two Ap-horizons would have organic matter contents of 7,0% and 9,8%. This should be verified by the stakeholder. BS (base saturation): Origin of data: Expert judgment Base saturation = TEB CEC TEB = Total amount of Exchangeable Bases CEC = The CEC should be measured at pH 8,1. The validity of the data is checked by summing the base cations and dividing with CEC. Result: Many of the horizons had calculated base saturations that differed more than 5% from the given value. These are listed below: 2 Profile Horizon pH BS FI4 FI4 FI4 FI4 FI4 FI5 FI5 FI5 FI5 FI6 FI6 FI6 1 (O) 2 (Ae) 3 (Bhs) 4 (Bs) 5 (C) 1 (H1) 2 (H2) 3 (H3) 4 (H4) 1 (Hp) 2 (H1) 3 (H2) 4,0 4,3 4,9 5,0 5,6 4,3 3,8 3,8 -998 5,1 5,0 4,9 14 11 9 10 21 10 8 7 6 10 44 46 Calculated BS (TEB/CEC) 139 100 83 100 180 100 80 70 60 339 440 462 CaCO3 0 0 -999 -999 0 0 0 0 -998 0 0 0 Result: There seem to be a factor 10 error for these horizons. The base saturations exceed in many cases 100% because the amount of exchangeable cations exceeds the CEC-value. However the base saturations fit rather well with the expected base saturations at the given pH-values. The values for CEC seem very low. Most likely a factor 10 too low. When corrections are carried out on CEC and organic matter content the data for base saturation will be correct. Markings in the spreadsheet: Colour Meaning Correct after correction of CEC by a factor 10. The following formula gives a good estimate of base saturation in the soil. BS pH (1 : 2,5 H 2 O) 4 0,041 The chart below shows the relationship between pH and base saturation for the existing data in the database for Finland. The red line indicates the above formula. Here the base saturation at pH 4,0 should ideally be 0% and 100% at pH 8,1. The dashed lines indicate a bufferzone of 1 pH unit on each side of the red line. If the data are within this bufferzone the data are considered reliable. The green line indicates a base saturation at 100% at pH 7,0. If the scatter diagram seem to fit better with this line it is likely that the CEC is measured by the distillation method at pH 7,0 and not by the required method as the sum of exchangeable bases and the exchangeable acidity at pH 8,1. Yellow dots mark organic horizons (above 20% organic matter). 3 Finland 10,0 9,0 pH (H2O) 8,0 7,0 6,0 5,0 4,0 3,0 0 20 40 60 80 100 % Base saturation Result: Some of the horizons show rather high base saturations at a given pH compared to theory (base saturations at 80-90% at pH 5,8-6,0). As stated above there is a possibility that the values for CEC are a factor 10 too low. Also the data set seem more to follow the green line in the chart above. This line indicates 100% base saturation at pH 7,0 which means that the CEC-values might have been given at the distillation method that is carried out at pH 7,0. Note: Base saturation values that are outside the bufferzone created by the two dashed lines are highlighted in the spreadsheet. The values are marked “red” if the base saturation is too high compared to the value obtained by the above formula (below lower dashed line). The value is marked “turquoise” if it too low (above the upper dashed line). Conclusion: The base saturation values given are apparently correct for all profiles. However when the base saturations are recalculated the profiles FI4, FI5 and FI6 have base saturations that are a factor 10 too high. This is because the reported CEC values are far too low. All three profiles are rich in organic matter. The CEC values are most likely a factor wrong. C_N (C/N-ratio): ok (The C/N-ratio for the organic horizons are high 55-70) Origin of data: Expert judgment or Average of a number of profiles CACO3_ACT: ok Origin of data: Expert judgment CACO3_TOT: ok. 4 Origin of data: Expert judgment CASO4: ok Origin of data: Expert judgment CEC: Origin of data: Expert judgment The CEC values (cmol(+)/kg) should be measured as the sum of exchangeable bases and the exchangeable acidity at pH 8,1. Control of the data: The CEC values are controlled by two equations. A low estimate and a high estimate. The CEC value of the horizons should be within range of these two estimates: Low estimate: CEClow = 0,1 * % clay + % humus High estimate: CEChigh= 1,3 * % clay + 3,5 humus The theory of the low estimate is that the clay is dominated by clay with low cation adsorption potential (kaolinit: 5-15 cmol(+)/kg) and only little reactive humus/organic matter (100 cmol(+)/kg). The high estimate is based on the assumption that the clay is dominated by highly reactive clay minerals as vermiculit (100-120 cmol(+)/kg and that the humus/organic matter is very reactive (350 cmol(+)/kg. Result: Many horizons have CEC values lower than the calculated low level (these are marked turquoise). Profile FI1 (Bd) FI1 FI1 FI2 (Bv) FI2 FI2 FI3 (Gd) FI3 FI3 FI4 (Po) FI4 FI4 Horizon Ap (1) B C Ap (1) B C Ap (1) B (2) C (3) O (1) Ae (2) Bhs (3) OM 40,0* 7,0* 3,0* 70,0* 10,0* 6,0* 98,0* 34,0* 44,0* 60,0 2,0 1,0 Clay 15 31 50 42 58 77 38 42 50 -998 2 2 CEC 19,2 13,4 16,0 32,5 28,6 31,4 30,7 26,3 23,8 7,5 0,4 0,6 5 CEC(low) 41,5 10,1 8,0 74,2 15,8 13,7 101,8 38,2 49,0 60 2,2 1,2 CEC(high) 159,5 64,8 75,5 299,6 110,4 121,1 392,4 173,6 219,0 210 9,6 6,1 FI4 FI4 FI5 (Od) FI5 FI5 FI5 FI6 (Oe) FI6 FI6 Bs (4) C (5) H1 (1) H2 (2) H3 (3) H4 (4) Hp (1) H1 (2) H2 (3) 2,0 2,0 68,0 69,0 70,0 72,0 52,0 52,0 52,0 2 5 -998 -998 -998 -998 -998 -998 -998 0,8 0,5 12,0 12,5 12,5 13,0 12,0 11,0 12,0 2,2 2,5 68,0 69,0 70,0 72,0 52,0 52,0 52,0 9,6 13,5 238 242 245 252 182 182 182 * Organic matter a factor 10 too high. Result: Many of the CEC-values are highly underestimated based on the data of organic matter and clay. The horizons that are highlighted in turquoise are below the low estimate. The four horizons that are within the zone created by the two estimates are marked white. They however all have rather low CEC-values. For the first three profiles (FI1, FI2 & FI3) the contents of organic matter seem very high. There is most likely a factor 10 error here! If not then profile FI3 (Gd – dystric Gleysol) should be reclassified as a Histosol. For the last three profiles (FI4, FI5 & FI6) the CEC-values are very low, especially since profile FI5 and FI6 are very rich in organic matter. For comparison Histosols in Norway have CEC-values between 20,2 and 93 cmol(+)/kg and in Latvia 110,5-176,5 cmol(+)/kg. Conclusion: The CEC values for profile FI4, FI5 and FI6 seem unreliable low. Most likely a factor 10. The given values for profile FI1, FI2 and FI3 seem more reliable. The calculated estimates are probably too high due to a factor 10 error in the content of organic matter. Correction: If the content of organic matter for the horizons of profile FI1, FI2 and FI3 are divided by 10 the CEC falls within the zone created by the two equations. If the CEC values for profile FI4, FI5 and FI6 are multiplied by 10 then the CEC values would lie within the zone crated by the two equations. Profile FI1 FI1 FI1 FI2 FI2 FI2 FI3 FI3 FI3 FI4 FI4 FI4 Horizon Ap (1) B C Ap (1) B C Ap (1) B (2) C (3) O (1) Ae (2) Bhs (3) OM 4,0* 0,7* 0,3* 7,0* 1,0* 0,6* 9,8* 3,4* 4,4* 60,0 2,0 1,0 Clay 15 31 50 42 58 77 38 42 50 -998 2 2 CEC 19,2 13,4 16,0 32,5 28,6 31,4 30,7 26,3 23,8 75 4,0 6,0 6 CEC(low) 5,5 3,8 5,3 11,2 6,8 8,3 13,6 7,6 9,4 60 2,2 1,2 CEC(high) 33,5 42,8 66,1 79,1 78,9 102,2 83,7 66,5 80,4 210 9,6 6,1 FI4 FI4 FI5 FI5 FI5 FI5 FI6 FI6 FI6 Bs (4) C (5) H1 (1) H2 (2) H3 (3) H4 (4) Hp (1) H1 (2) H2 (3) 2,0 2,0 68,0 69,0 70,0 72,0 52,0 52,0 52,0 2 5 -998 -998 -998 -998 -998 -998 -998 8,0 5,0 120 125 125 130 120 110 120 2,2 2,5 68,0 69,0 70,0 72,0 52,0 52,0 52,0 9,6 13,5 238 242 245 252 182 182 182 The corrected values for CEC and organic matter are marked “green” in the spreadsheet. Conclusion: If the corrections shown about are carried out, then the data seem more reliable. However this should be agreed upon by the stakeholder. EC: ok Origin of data: Average of a number of profiles or expert judgment EXCH_CA, EXCH_K, EXCH_MG & EXCH_NA: Origin of data: Expert judgment All of the horizons contain data on base cations. Quality of the data: The values in the dataset are difficult to evaluate, but a general assumption has been carried out that: exchangeable calcium exceeds the sum of exchangeable Mg, K and Na at pH (H20)-values > 5: [Ca2+] > [Mg2+] + [K+] + [Na+] if pH (H20) > 5,0 Result: The above assumption is fulfilled for all horizons. EXCH_NAP: Most values are “-10” (meaning: less than 15% (humid areas). Two horizons are given the value “-999” (meaning: missing value). The value can easily be measured as Na/CEC. GRAVEL: ok OM (organic matter): Origin of data: Mostly average of a number of profiles, but also from a single representative profile and expert judgment. 7 The content of organic matter for the horizons in profile F1, F2 and F3 are very high. The Aphorizons have organic matter content of 40,0, 70,0 & 98,0%. These should then be altered to Hhorizons. There is most likely a factor 10 error (see section on CEC)! The values are corrected and marked “green” in the spreadsheet. pH: ok Origin of data: Mostly average of a number of profiles, but also from from a single representative profile and expert judgment POR: The data was checked via the following formula: Origin of data: Expert judgment BD POR 1 100 PD where BD=Bulk density and PD=Particle density The particle density can be calculated/approximated from the following formula: PD( g / cm 3 ) 1,30 2,65 2,80 (2,65 2,80 (% OM / 100 )) (1,30 2,80 (% silicates / 100 )) (1,30 2,65 % CaCO3 / 100 )) The particle density of silicates is considered to be 2,65 g/cm3 The particle density of Organic matter (OM) is considered to be 1,3 g/cm3 The particle density of CaCO3 is considered to be 2,80 g/cm3 Soils with a low content of organic matter (0-5%) would therefore presumably have particle densities between 2,5 -2,8 g/cm3. Result: The following horizons had values for calculated porosity (via the above formula) that differed more than 5% from the values given in the spreadsheet. Profile FI1 FI2 FI3 FI3 FI3 FI4 FI4 FI4 FI4 Horizon 1 1 1 2 3 1 2 3 4 POR (%) 53 58 56 55 54 45 42 40 38 POR calculated (%) 41 (57) 28 (55) 24 (58) 44 (57) 40 (57) 82 54 54 50 8 Organic matter (%) 40 -> 4,0 70 -> 7,0 98 -> 9,8 34 -> 3,4 44 -> 4,4 60 2 1 2 FI4 FI5 FI5 5 2 4 38 85 80 46 94 87 2 69 72 Result: Most of the horizons where the calculated porosity differed more than 5% from the given value are rich in organic matter (marked yellow). Therefore the given data might be correct. However the high contents of organic matter for F1, F2 and F3 are probably not correct (see section on CEC and organic matterabove). The values in brackets in the “POR calculated”-field are the values if the contents of organic matter are divided by 10. The data would then be satisfying. Therefore the data for these horizons remain. The following chart shows the relation between particle density (measured from the existing data of porosity and bulk density) and % organic matter. Note: The values for particle density should be around 2,5-2,8 g/cm3 if the content of organic matter is around 0% and decreasing to around 1,3 g/cm3 with increasing content of organic matter. PD measured from excisting data 3,00 2,50 g/cm3 2,00 1,50 1,00 0,50 0,00 0,0 20,0 40,0 60,0 80,0 100,0 120,0 % Organic matter Result: Some of the data have very high particle densities compared to the content of organic matter. The horizons marked “red” in the chart are the horizons with a supposed too high content of organic matter (should most likely be divided by 10!) Markings in the spreadsheet: Porosity too high compared to theory (> 5% above) Porosity too low compared to theory (> 5% below) WC_1 (the water retention at –1 kPa) is higher than POR The horizons are rich in organic matter but are >5% below the calculated porosity. 9 Conclusion: The data for porosity are apparently not very reliable, but if the contents of organic matter in profile FI1, FI2 and FI3 are divided by 10, then the data seem to be reliable. STRUCT (structure): Only for the mineral soils. TEXT_2, TEXT_20, TEXT_50, TEXT_200 & TEXT_2000: Origin of data: Mostly from a single representative profile, but also from an average of a number of profiles and expert judgment The combined values of the five texture fields should add up to 100%. For the horizons that do not total 100% the values are corrected as a weighted average. Example for profile FI3 horizon 2 (B). TEXT_2 42 TEXT_20 42 TEXT_50 7 TEXT_200 15 TEXT_2000 3 sum 109 TEXT_20 (42/109)*100 38 TEXT_50 (7/109)*100 6 TEXT_200 (15/109)*100 14 TEXT_2000 (3/109)*100 3 sum Correction: TEXT_2 (42/109)*100 39 100 3 Horizons had to be corrected while another 2 horizons had “-999” values replaced by “0” so that the total texture was 100%. After the correction of the texture classes, so that the combined texture classes add up to 100% profile FI3 no longer qualifies for the dominant surface textural class “4” (fine) (% clay above 35%). The corrections are therefore altered (see below): Profile Hor TEXT_2 TEXT_20 TEXT_50 TEXT_200 TEXT_2000 Texture class FI3 Ap 38 32 36 44 38 36 17 14 13 16 14 13 2 2 2 4 3 4 Corrected to 10 The markings in the spreadsheet mean the following: Colour Type of Changes/corrections In EST_HOR: The sum of the values did not add up to 100% Corrected as a weighted average. Corrections had to be carried out in EST_HOR.dbf. in order to qualify for the originally given dominant surface textural class. yellow orange WC_1, WC_10, WC_100, WC_1500, WC_FC: Origin of data: Expert judgment Data for water retention: Only data R-horizons are missing. Rock horizon has the value “-998” (not applicable (rock or organic horizon)). The quality of the data was controlled through the following criteria: 1) The value of porosity (POR) should be higher than WC_1: 2) The value of WC_FC should not be higher than WC_1 3) The volume percentage of water should decrease with increasing tension. All horizons fulfill 1) All horizons fulfill 2) except the horizons of profile FI6 as seen below: Profile FI6 FI6 FI6 Horizon Hp (1) H1 (2) H2 (3) POR 80 85 85 WC_1 80 75 75 WC_10 60 70 70 WC_100 40 50 50 WC_1500 15 25 30 WC_FC 80 -> 60 85 -> 70 85 -> 70 Correction: This values for WC_FC should be adjusted to be equal to “WC_10” as for the rest of the horizons. This is carried out and marked “green” in the spreadsheet. All horizons fulfill 3) Conclusion: The data for water retention are generally considered reliable except the data for profile FI6. This is however corrected. 11