Addition reaction Alkanals ‘Aldehydes’ Alkanes Alkanoic acids ‘Carboxylic acids’ Alkanols ‘Alcohols’ Alkanones ‘Ketones’ Alkenes Alkyl groups Alkynes Amides A small molecule, say AB, adds to the multiple bond so that A joins to one atom and B to the other. Alkanes are a series of saturated hydrocarbons, all of which fit the general formulaCnH2n+2. Alkanols are a homologous series of alcohols based on the series of alkanes by replacing one hydrogen atom by a hydroxyl group. Alkenes are a series of unsaturated hydrocarbons which contain one C=C bond and which fit the general formula CnH2n. Alkynes are a series of unsaturated hydrocarbons containing one bond and which fit the general formula CnH2n-2. Alkanals are a homologous series of aldehydes based on the corresponding alkanes by changing one of the terminal carbon atoms into a carbonyl group. are a homologous series of carboxylic acids based on the parent alkanes in which one of the terminal carbon atoms is part of a carboxyl group Alkanones are a homologous series of ketones based on the corresponding alkanes by changing one of the middle chain carbon atoms into a carbonyl group. An alkyl group is an alkane molecule minus one hydrogen atom; a substituent. Amides, containing the CO-NH- link, can be formed in a condensation reaction between amines and carboxylic acids. Amino acids Condensation Cured resin Denatured Enzymes Ester exchange Fibrous Functional group Globular Homologous series Amino acids are compounds containing an amino group (-NH2) and a carboxyl group (-COOH). A condensation reaction is one in which two molecules combine to form a larger molecule at the same time eliminating a small molecule such as water. A cured polyester resin sets to a rigid solid, because the curing process produces cross linking between the linear polyester chains. When a protein molecule loses its highly ordered three dimensional shape it is said to be denatured. Ester exchange is a chemical process, in which one alcohol displaces Enzymes are protein molecules which another alcohol act as catalysts in biological processes. from an ester. Fibrous proteins are proteins that form long coils or align themselves in parallel to form long, water insoluble fibers. Globular proteins are proteins in which long coils fold into compact roughly spherical shapes. The functional group is that part of a molecule which gives the substance its characteristic properties. A homologous series is a family of compounds which have similar chemical properties and which all fit the same general formula. Hydrocarbon Hydrogenation Hydrolysis Isomer Oxidation Peptide Proteins Reduction Reforming Saponification These are compounds containing the elements carbon and hydrogen only. Hydrolysis is the breakdown of a molecule by reaction with water. When applied to carbon compounds, oxidation reactions result in an increase in the oxygen to hydrogen ratio. Proteins are biological polymers of small molecules called amino acids. Reforming is a catalytic process where straight chain alkanes in the naphtha distillation fraction are converted to branched alkanes, cycloalkanes and aromatic hydrocarbons, without necessarily changing the number of carbon atoms. This produces a higher octane fuel. Hydrogenation is the addition of hydrogen to a carbon to carbon multiple bond Isomers have the same molecular formula but different structural formula, i.e. they contain the same number and type of atoms but the atoms are arranged differently. Peptide bonds are the C-N bonds resulting from the condensation reaction between a carboxyl group of one amino acid and the amino group of a second amino acid. When applied to carbon compounds, reduction reactions result in a decrease in the oxygen to hydrogen ratio. Saponification is the process by which soaps are made from fats and oils in a hydrolysis reaction ‘alkaline hydrolysis’. Steam cracking Synthesis gas Thermoplastic Thermosetting plastic Triglycerides Unsaturated Volatile Essential amino acid Hydration Dehydration Steam cracking is used to produce ethene and propene from gaseous feedstock (ethane and propane) or from naphtha. Synthesis gas is a mixture of carbon monoxide and hydrogen obtained by steam reforming methane or coal. Thermoplastic polymers melt or soften on heating. They consist of polymer Thermosetting plastics do not soften or chains which have only weak forces melt on heating on account of a highly (typically van der Waals’) between cross-linked structure. them. Triglycerides are molecules formed through the condensation of one glycerol molecule with three fatty acid molecules. An unsaturated molecule has at least one carbon to carbon double bond. An unsaturated hydrocarbons does not contain the maximum number of hydrogen atoms for a given carbon atom framework. A volatile substance evaporates very easily to form a gas. An essential (in the sense of an amino acid) is a necessary material required by living organisms for normal growth. Addition reaction of an alkene with water to form an alcohol. Elimination of a water molecule from an alcohol to form an alkene. Ester Aromatic ‘Benzene’ Formed by a condensation reaction between carboxylic acid and alcohol. The molecular formula is C6H6. Each carbon atom in the ring uses three of its four outer electrons to form covalent bonds to the two neighbouring carbon atoms and one hydrogen atom, producing a planar, hexagonal ring. This leaves a ’spare’ electron on each carbon atom. These electrons are able to move from atom to atom around the ring.