Issue Date: July 1, 1996 Rev.Date June 27,2000 Material Safety Data Sheet Increte Systems Inc. P. O. Box 151103 Tampa, Florida 33684 (813)886-8811 Fax (813)886-0188 Emergency Only 1-800-424-9300 (CHEMTREC) International 1-202-483-7616 Page: 1 of 3 Section I – Identification Product Name: A240-80 Series Isocyanate’A’ HMIS Rating Health: 1 Flammability: 0 Reactivity: 0 Classification: Polymeric Isocyanate D.O.T. Hazard Class: 6.1 Dipenylmethane 4.4 Diisocyanate, UN 2489, PGIII Ingredient C.A.S.# Diphenylmethane 101-68-8 Diisocyanate Aromatic Isocyanate Adduct 9016-87-9 Section II – Components Wt.% PEL .02PPM NE TLV 37-43 STEL NE Notes 57-63 Section III – Physical Properties Boiling Point: 392 F (300C) Vapor Pressure: Below 0.0001 Melting Point: n.a. Vapor Density: Air = 1) .. 8.6 Evaporation Rate: n.a. Specific Gravity: 1.22 Water Solubility: Reacts Non-volatile: na Physical Appearance: Clear –Yellow- Viscous Liquid Section IV – Fire and Explosion Hazard Data Flash Point: >392’F (177’C) COC Explosion Limits (LEL): n.a. UEL: n.a. Extinguishing Media: Dry Chemical extinguishers such as Monoammonium Phosphate, Potassuim Sulfate, potassium Chloride, additionally, carbon dioxide high expansion (Proteinic) chemical foam, water spray for large fires. Hazardous Decomposition Products: Water contamination will produce carbon dioxide. Do not re-seal contaminated containers as pressure buildup may rupture them. Firefighting Procedures: Wear seld-contained breathing apparatus with full facepiece operated in the positive pressure demand mode. Special Fire & Explosion Hazards: None Section V – Health Hazard Information Primary Route(s) of Entry: Inhalation, skin contact, and eye contact. Effects of Acute Overexposure: Eyes – Not irritating (rabbits) OECD guide lines. Skin – Slight irritation, (rabbits) OECD guide lines.Pre-existing skin conditions can be aggravated by use of this product. Respiratory – May cause respiratory sensation in susceptible individuals. At room temperature vapors are minimal due to low vapor pressure. If heated or sprayed as an aerosol, excessiveconcentrations are attainable that could be hazardous on single exposure. Excessive exposure may cause irritation of the eyes. Upper respiratory tract and lungs effects may be delayed. 2 Decreased ventilatory capacity has been associated with exposure to similar isocyanates. It is possible that exposure to MDI may cause impairment of lung function. Ingestion – Single dose oral toxicity is low, and unlikely to occur with normal handlng. Do not induce vomiting. Consult physician immediately. Section VI – Chemical Reactivity Stability: Storage temperature (min/max) 65F (18C) to 75F (24C) Incompatibility: Reactive with water. Containers should be tightly sealed to prevent moisture contamination. Conditions to Avoid: A nitrogen blanket should be used for bulk storage. Store at a temperature of 65F to 75F protect from freezing.. Section VII – Spill Procedures Small Spill: Absorb spilled product onto inert absorbent material. Large Spill: Call PDL immediately. If a transportation spill notify Chemtrec (800-424-9300) evacuate and ventilate spill area. Dike spill to prevent entry into the enviroment. Wear full protective equipment including respiratory protection during clean up. If temporary control of Isocyanate vapor is required. A blanket of protein foam may be placed over the spill. Large quantities may be pumped into closed but not sealed containers for disposal. Clean up: Decontaminate area using water/ammonia solution with 1-2% added detergent. Letting it stand over affected area for at least 10 minutes. Cover mops, brooms, etc used for this with plastic and dispose of properly (often by incineration). Waste Disposal Method: Generally, material can be disposed in a local landfill, however, any disposal practice must be in compliance with local, state, or federal agency. For further information, contact your local waste agency or the United States Environmental Protection Agency's RCRA hotline (1-800-424-9346) Section VIII – Special Protection Information Respiratory Protection: Use an approved respirator with dust protection, replace dust filters often. Ventilation: Access to fresh air is important, but avoid any ventilation procedures which will produce unnecessary air-borne dust. Gloves: If necessary, any latex, rubber, nitrile, neoprene or other type of water-proof glove should provide adequate protection. Eye Protection: Wear face-shield or chemically-resistant goggles. Other Protective Equipment: Wear appropriate work clothing to prevent skin contact. Wash clothing before reuse. Eye wash station and safety shower should be available. Section IX – Special Precautions Handling and Storing: storage tmeperature 65F to 75F. average shelf like is 6 months from date of mfg. Section X – Special Precautions Precaution in handling and storage if contamination of the MDI is suspected. Do not re-seal container because of possible rupture due to pressure buildup. Always slowly vent container when opening to relieve any pressure buildup. This product has been reviewed according to the EPA Hazard Categories promulated under SARA, Sections 311 and 312 and is considered a hazardous chemical and a delayed health hazard. 3 This information is provided in good faith and is correct to the best knowledge of Inco Chemical Company, Inc. Inco Chemical Co., Inc. makes no representation as to its completeness or accuracy. Customers are encouraged to make their own determination as to the suitability of this product for their purpose prior to use. Inco Chemical Co, Inc. disclaims responsibility for damages of any kind resulting from the use of this information. No warranty of merchantability, fitness for use, or any other warranty is expressed or is to be implied regarding the accuracy of these data. This information is provided in good faith and is correct to the best knowledge of Inco Chemical Company, Inc. Inco Chemical Co., Inc. makes no representation as to its completeness or accuracy. Customers are encouraged to make their own determination as to the suitability of this product for their purpose prior to use. Inco Chemical Co., Inc. disclaims responsibility for damages of any kind resulting from the use of this information. No warranty of merchantability, fitness for use, or any other warranty is expressed or is to be implied regarding the accuracy of these data.