United States Patent and Trademark Office WIPO Revision Working Group Project: A023 Date: October 15, 2010 Photo-masks and screens (T036) Title – G03F 1/00 Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof Definition statement This group covers: Patterned radiation modifying products that are chemically defined and have been patterned to modify radiation during imaging (e.g., masks, photomasks, reticles), preparation of such patterned radiation modifying products, similar or like products that function as mask blanks or specialized substrates, per se, for preparing such patterned radiation modifying products, processes of preparing such mask blanks or specialized substrates, per se (when not provided for elsewhere), pellicles, per se or pellicles in combination with patterned radiation modifying products, processes of preparing such pellicles (when not provided for elsewhere), containers that are specially adapted therefor, or processes of preparing the same (when not provided for elsewhere). Informative references Attention is drawn to the following places, which may be of interest for search: Electrography; electrophotography G03G Photomechanical process; apparatus; photosensitive material, e.g., photoresist, in general G03F 7/00 Use of photoresist structures for special production processes, e.g.: Producing decorative effects Manufacture or treatment of semiconductor or solid state devices or parts thereof B44C H01L 21/00 Printed circuits; details of electric apparatus; manufacture of electrical components, in general H05K Holographic processes or apparatus G03H Special rules of classification within this group In this main group, at each hierarchical level, in the absence of an indication to the contrary, classification is made in the first appropriate place. Title – G03F 1/20 Masks or mask blanks for imaging by charged particle beam (CPB) radiation, e.g., by electron beam; Preparation thereof Definition statement This subgroup covers: Subject matter of main group G03F 1/00 in which the radiation modifying products are either patterned masks for imaging by charged particle beam (CPB) radiation (e.g., by electron beam), mask blanks therefor, or specialized substrates for preparing such patterned masks; and the processes of preparing are directed to preparation of such patterned masks for imaging by charged particle beam (CPB) radiation, preparation of mask blanks therefor, or preparation of specialized substrates therefor. Title – G03F 1/22 Masks or mask blanks for imaging by radiation of 100nm or shorter wavelength, e.g., X-ray masks, Extreme ultraviolet (EUV) masks; Preparation thereof Definition statement This subgroup covers: Subject matter of main group G03F 1/00 in which the radiation modifying products are either patterned masks for imaging by radiation of 100 nanometers or shorter wavelength (e.g., X-ray masks, extreme ultraviolet (EUV) masks), mask blanks therefor, or specialized substrates for preparing such patterned masks; and the processes of preparing are directed to preparation of such patterned masks for imaging by radiation of 100 nanometers or shorter wavelength (e.g., X-ray masks, extreme ultraviolet (EUV) masks), preparation of mask blanks therefor, or preparation of specialized substrates therefor. Title – G03F 1/26 Phase shift masks (PSM’s); PSM blanks therefor; Preparation thereof Definition statement This subgroup covers: Subject matter of main group G03F 1/00 in which the radiation modifying products are either patterned phase shift masks (PSM’s), PSM blanks therefor, or specialized substrates for preparing such patterned PSM’s; and the processes of preparing are directed to preparation of such patterned PSM’s, preparation of PSM blanks therefor, or preparation of specialized substrates therefor. (1) Note. In this subgroup, the phase shift mask (PSM) has a phase shift (PS) transmissive or reflective region that provides a different effective optical path length for illumination exiting the PS region than that of another (usually adjacent non-PS) region, so that exiting illumination from these separate regions are at different phases from each other. When the phase difference between adjacent PS and non-PS regions is 180 degrees, destructive interference is maximized for the exiting illumination between these regions, causing minimum combined diffracted light intensity, which results in a darkened projected light intensity that improves resolution when exposing a photosensitive layer (such as a photoresist). (2) Note. For a transmissive PSM, the phase shift (PS) region is usually produced by selective addition of a transparent PS layer that increases the effective thickness of a transmissive substrate or by selective etching to create a recess that decreases the thickness of the transmissive substrate, each of which provides exiting illumination that differs in phase from illumination exiting another unchanged region of the transmissive substrate. However, the difference in phase at the phase shifting region can also be produced by selective doping or implantation of particular ions into the transmissive substrate to selectively change the refractive index or other optical characteristic of the transparent substrate, altering the passage of illuminated light exiting from the phase shifting region relative to light exiting from another (non-PS) region of the transmissive substrate for the PSM. Title – G03F 1/28 Three or more diverse phases from the same PSM; Preparation thereof Definition statement This subgroup covers: Subject matter of subgroup G03F 1/26 in which the phase shift mask (PSM) has three (3) or more different transmissive or reflective portions thereon that provide three (3) or more diverse phases of exiting illumination (e.g., tri-tone PSM for 0°, 90°, and 180° phases); and in which the process of preparing is directed to preparation of such a patterned PSM. Title – G03F 1/29 Rim PSM or outrigger PSM; Preparation thereof Definition statement This subgroup covers: Subject matter of subgroup G03F 1/26 in which the phase shift mask (PSM) has an absorber region with an adjacent clear narrow ridge that produces phase shifted exiting illumination (180 degrees out of phase) with respect to non-phase shifted illumination exiting a non-phase shifted clear region of a transparent substrate, where the absorber region represents a pattern to be reproduced (rim PSM or outrigger PSM); and in which the process of preparing is directed to preparation of such a rim PSM or an outrigger PSM. Title – G03F 1/30 Alternating PSM, e.g. Levenson-Shibuya PSM; Preparation thereof Definition statement This subgroup covers: Subject matter of subgroup G03F 1/26 in which the phase shift mask (PSM) has alternating diverse phase clear regions separated by an absorber region that represents a pattern to be reproduced, where the absorber region is usually in the form of absorber lines separated by alternating phase shift (PS) spaces and non-phase shift (non-PS) spaces in repeating sequence across a major surface of the PSM (e.g., Levenson-Shibuya PSM, etc.); and in which the process of preparing is directed to preparation of such an alternating PSM (alt-PSM). Title – G03F 1/32 Attenuating phase shift mask (att-PSM), e.g., PSM having semi-transparent phase shift portion, halftone PSM; Preparation thereof Definition statement This subgroup covers: Subject matter of subgroup G03F 1/26 in which the phase shift mask (PSM) has an attenuating region that produces phase shifted exiting illumination at a different phase from that produced by a non-attenuating clear region of the attenuating PSM (e.g., PSM having semi-transparent phase shift portion, halftone PSM); and in which the process of preparing is directed to preparation of such an attenuating PSM (att-PSM). (1) Note. In this attenuating PSM (att-PSM, halftone PSM), the attenuating or halftone region is partially transmissive and provides a phase shift (PS) in exiting illumination. The degree of PS and the transmissiveness of the att-PS region depends on the material and thickness of the att-PS region, as well as depending on the wavelength of the illumination. Such an att-PS region or a halftone PS region can be formed by adding an appropriate material at a suitable thickness, reducing the thickness of a previously formed layer (whether a supporting substrate of the att-PSM or an additional layer thereon), or other post-treatment of an att-PSM portion (such as selective doping or ion implantation). (2) Note. An att-PS region can be created by sufficiently reducing the thickness of a normally opaque absorber layer material, such as a thin layer of chromium (Cr) often called “leaky chrome”. Title – G03F 1/34 Phase-edge PSM, e.g. chromeless PSM; Preparation thereof Definition statement This subgroup covers: Subject matter of subgroup G03F 1/26 in which the phase shift mask (PSM) has at least two clear regions directly adjacent to each other that produce different phases (usually 180 degrees apart) to create a phase edge between these diverse clear regions in corresponding portions of exiting illumination, where the phase edge represents a pattern to be reproduced (e.g., chromeless PSM, etc.); and in which the process of preparing is directed to preparation of such a phase edge PSM. Note. In this subgroup, such a phase edge PSM can be without any opaque region (as a chromeless PSM). Alternatively, the phase edge PSM is permitted to include an opaque region or an absorber region, such as at the peripheral border of this phase edge PSM to avoid unwanted artifacts that might otherwise be produced in a common photoresist layer by step-and-repeat exposures from this phase edge PSM. However, this phase edge PSM must still have at least one unobstructed phase edge between two directly adjacent clear regions that produce exiting illumination having different phases (e.g., at 0° and 180°, etc.), where the phase edge represents a pattern to be reproduced, as described above. Title – G03F 1/36 Masks having proximity correction features; Preparation thereof, e.g. optical proximity correction [OPC] design processes Definition statement This subgroup covers: Subject matter of main group G03F 1/00 in which the patterned radiation modifying products are masks, where the mask has a pattern that includes a proximity correction feature or a changed dimension of a printing feature for improving a resulting printed pattern formed thereby (e.g., enhancing sub-resolution sized patterns, reducing sidelobe formation between closely spaced patterns); and in which the processes of preparing are directed to preparation of such masks having proximity correction features (e.g., optical proximity correction [OPC] design processes). (1) Note. Proximity correction addresses problems resulting from the miniaturization of patterns for radiation modifying masks, which typically results in degradation of the pattern, with the degradation not being uniform between sorts of pattern such as, for example, a line-and-space pattern, an isolated pattern, etc. (2) Note. The proximity correction features can be sub-resolution patterns (e.g. serifs, assist bars) or modified patterns (e.g. biased) to compensate for optical proximity effects in a basic layout of a mask pattern. Alternatively, the proximity correction features can be dummy patterns, which are placed in a vacant region of a mask pattern to reduce inhomogeneous processing due to proximity effects. Informative references Attention is drawn to the following places, which may be of interest for search: Adapting basic layout or design of a mask to a lithographic process requirement for preparation of masks without proximity G03F 1/70 correction features Computer-aided design in general G06F 17/50 Title – G03F 1/38 Masks having auxiliary features, e.g., marks for alignment or testing, special coatings; Preparation thereof Definition statement This subgroup covers: Subject matter of main group G03F 1/00 in which the patterned radiation modifying products are masks having auxiliary features, where the mask possesses some structure in addition to that used for imaging and this structure is used for subsidiary purposes; and in which the processes of preparing are directed to preparation of such masks having auxiliary features. Note. For example, the subsidiary purposes may be for alignment of the mask within an exposure apparatus, for testing of the mask, for protecting the mask, or for improving an image obtained from the mask. Title – G03F 1/50 Mask blanks; Preparation thereof Definition statement This subgroup covers: Subject matter of main group G03F 1/00 in which the radiation modifying products are mask blanks for producing patterned masks; and in which the processes of preparing are directed to preparation of such mask blanks. Title – G03F 1/52 Reflectors Definition statement This subgroup covers: Subject matter of main group G03F 1/00 in which the radiation modifying products have a reflector that functions as a mirror to deflect incident radiation. Note. The reflector can be a particular material that is chemically defined. Alternatively, the specified reflector can have a specific shape, a particular thickness, or a given internal microstructure (such as a reflector that was subjected to a particular heat treatment to relieve internal stress). Title – G03F 1/54 Absorbers, e.g. of opaque material Definition statement This subgroup covers: Subject matter of main group G03F 1/00 in which the radiation modifying products have an absorber (e.g., of opaque material) which functions to absorb incident radiation. (1) Note. The absorber can be a particular opaque material that is chemically defined (e.g., tantalum (Ta), gold (Au), chromium (Cr), carbon (C), molybdenum silicide (MoSi)). Alternatively, the absorber can have a specific pattern (e.g., an unresolvable grid pattern leading to a grey tone mask, a gradient mask), a particular thickness (e.g., making the absorber region semi-transparent to provide only 20% transmittance for incident radiation at a target wavelength for imaging), or a given internal structure (e.g., multilayer absorber, ion implanted opaque layer to change an optical property for absorbing more incident radiation). (2) Note. Excluded from this subgroup are attenuating phase shift masks (PSMs) having PS regions created by sufficiently reducing the thickness of a normally opaque absorber layer material, such as a thin layer of chromium (Cr) often called “leaky chrome”. Title – G03F 1/60 Substrates Definition statement This subgroup covers: Subject matter of main group G03F 1/00 in which the radiation modifying products or similar products have a substrate defined by a particular material, a given structure, or a stated property, making the substrate especially suited (e.g., in a patterned mask, in a mask blank therefor) for use in radiation imaging. Informative References Attention is drawn to the following places, which may be of interest for search: Layered products characterized by the non-homogeneity or physical structure of a layer B32B 5/00 Title – G03F 1/62 Pellicles, e.g. pellicle assembly having membrane on support frame; Preparation thereof Definition statement This subgroup covers: Subject matter of main group G03F 1/00 in which the pellicles, per se, or the pellicles in combination with radiation modifying products, provide protection for a patterned mask by excluding foreign matter (e.g., solid particles of dust) that would otherwise degrade proper imaging from the patterned mask (e.g., pellicle assembly having membrane on support frame). Note. In this subgroup, the pellicle often includes a thin transparent layer (such as a transparent flexible membrane) attached to a rigid frame to hold the thin transparent layer at a specified distance away from the mask pattern so that foreign matter collecting on the outside of the pellicle will not be in the range of focus during imaging, in order to avoid degradation of the resulting imaged pattern produced from the mask. Alternatively, the pellicle can be a hard selfsupporting layer, having a specified thickness and transparency, that is formed on the patterned mask. In either case, the pellicle still protects the mask, to which the pellicle is attached, from dust adhering on the mask pattern that would otherwise occur during imaging of the mask without any benefit of the pellicle. Title – G03F 1/64 having special frames, e.g. structure or material, including bonding means therefor Definition statement This subgroup covers: Subject matter of subgroup G03F 1/62 in which the pellicles have special frames (e.g. structure or material), including bonding means for the pellicle frame, which establishes a bond between the frame and a pellicle membrane or between a frame and a substrate of a radiation modifying product. Note. In this subgroup, the bonding means often includes an adhesive layer. Alternatively, the bonding means can include a structure that provides a physical attachment. Title – G03F 1/66 Containers specially adapted for masks, mask blanks, or pellicles; Preparation thereof Definition statement This subgroup covers: Subject matter of main group G03F 1/00 in which the containers are specially adapted for holding, protecting, or transporting of masks, mask blanks, or pellicles as defined therein; and the processes of preparing such containers (when not provided for elsewhere). Title – G03F 1/68 Preparation processes Definition statement This subgroup covers: Subject matter of main group G03F 1/00 in which the preparation processes for preparing radiation modifying products and similar or like products include particular preparation steps, specific manufacturing methods, or given design steps for preparing these products, but which preparation processes are not specifically provided for in the previous subgroups. Title – G03F 1/70 Adapting basic layout or design of mask to lithographic process requirement, e.g. second iteration correction of mask pattern for imaging Definition statement This subgroup covers: Subject matter of subgroup G03F 1/68 in which the preparation processes are for adapting basic layout of patterned radiation modifying products to a lithographic process requirement, which include methods for adapting, modifying or correcting of basic patterns for a radiation mask used for photomechanical production of textured or patterned surfaces (e.g. second iteration correction of mask pattern for imaging). Informative references Attention is drawn to the following places, which may be of interest for search: Proximity correction layout or design processes for preparation of masks with proximity correction features, e.g. OPC features G03F 1/36 Computer-aided design in general G06F 17/50 Title – G03F 1/72 Repair or correction of mask defects Definition statement This subgroup covers: Subject matter of subgroup G03F 1/68 in which the preparation processes for preparing patterned radiation modifying products include methods for repair or correction of mask defects. e.g., by removing excess part defects or filling in missing part defects. Title – G03F 1/76 Patterning of masks by imaging Definition statement This subgroup covers: Subject matter of subgroup G03F 1/68 in which the processes for preparing patterned radiation modifying products include patterning of masks by imaging. Note. Typically, this imaging to pattern the mask is accomplished by selectively exposing and developing a photosensitive layer (e.g., a photoresist layer on a mask blank) for defining a pattern therein that is used to form the resulting patterned mask. Title – G03F 1/80 Etching Definition statement This subgroup covers: Subject matter of subgroup G03F 1/68 in which the processes for preparing patterned radiation modifying products include an etching step to selectively remove material from a mask or a mask blank. Informative References Attention is drawn to the following places, which may be of interest for search: Etching metallic material by chemical means Title – G03F 1/82 Auxiliary processes, e.g. cleaning or inspecting C23F 1/00 Definition statement This subgroup covers: Subject matter of subgroup G03F 1/68 in which the processes for preparing radiation modifying products and similar or like products include performing operations that are ancillary to the manufacture or the design methods for these products, but which ancillary operations (as auxiliary processes) are not specifically provided for in the previous subgroups (e.g. cleaning or inspecting). Informative references Attention is drawn to the following places, which may be of interest for search: Cleaning in general B08B Testing of optical apparatus G01M 11/00 Methods or arrangements for reading or recognizing printed or written characters or for recognizing patterns G06K 9/00